Temporal patterns and controls on runoff magnitude and solution chemistry of urban catchments in the semiarid southwestern United States

Urban expansion and the scarcity of water supplies in arid and semiarid regions have increased the importance of urban runoff to localized water resources. However, urban catchment responses to precipitation are poorly understood in semiarid regions where intense rainfall often results in large runoff events during the short summer monsoon season. To evaluate how urban runoff quantity and quality respond to rainfall magnitude and timing, we collected stream stage data and runoff samples throughout the 2007 and 2008 summer monsoons from four ephemeral drainages in Tucson, Arizona. Antecedent rainfall explained 20% to 30% of discharge (mm) and runoff ratio in the least impervious (22%) catchment but was not statistically related to hydrologic responses at more impervious sites. Regression models indicated that rainfall depth, imperviousness and their combined effect control discharge and runoff ratios (p < 0.01, r² = 0.91 and 0.75, respectively). In contrast, runoff quality did not vary with imperviousness or catchment size. Rainfall depth and duration, time since antecedent rainfall and event and cumulative discharge controlled runoff hydrochemistry and resulted in five specific solute response patterns: (i) strong event and seasonal solute mobilization (solute flush), (ii) event chemostasis and strong seasonal flush, (iii) event chemostasis and weak seasonal flush, (iv) event and seasonal chemostasis and (v) late seasonal flush. Our results indicate that hydrologic responses of semiarid catchments are controlled by rainfall partitioning at the event scale, whereas wetting magnitude, frequency and timing alter solute stores readily available for transport and control temporal runoff quality. Copyright © 2012 John Wiley & Sons, Ltd.     

The application of electrical conductivity as a tracer for hydrograph separation in urban catchments

Two‐component hydrograph separation was performed on 19 low‐to‐moderate intensity rainfall events in a 4·1‐km² urban watershed to infer the relative and absolute contribution of surface runoff (e.g. new water) to stormflow generation between 2001 and 2003. The electrical conductivity (EC) of water was used as a continuous and inexpensive tracer, with order of magnitude differences in precipitation (12–46 µS/cm) and pre‐event streamwater EC values (520–1297 µS/cm). While new water accounted for most of the increased discharge during storms (61–117%), the contribution of new water to total discharge during events was typically lower (18–78%) and negatively correlated with antecedent stream discharge (r² = 0·55, p < 0·01). The amount of new water was positively correlated with total rainfall (r² = 0·77), but hydrograph separation results suggest that less than half (9–46%) of the total rainfall on impervious surfaces is rapidly routed to the stream channel as new water. Comparison of hydrograph separation results using non‐conservative tracers (EC and Si) and a conservative isotopic tracer (δD) for two events showed similar results and highlighted the potential application of EC as an inexpensive, high frequency tracer for hydrograph separation studies in urban catchments. The use of a simple tracer‐based approach may help hydrologists and watershed managers to better understand impervious surface runoff, stormflow generation and non‐point‐source pollutant loading to urban streams. Copyright © 2007 John Wiley & Sons, Ltd.     

Hydrologic changes resulting from urban cover in seasonally snow‐covered catchments

There are few multibasin analyses of the effects of urban land cover on seasonal stream flow patterns within northern watersheds where winter snow cover is the norm. In this study, the effects of urban cover on stream flow were evaluated at nine catchments in southern Ontario, Canada, which vary greatly in urban impervious cover (1–84%) but cluster into two groups having ≥54% urban impervious area (‘urban’) and ≤11% impervious cover (‘rural’), respectively. Annual and seasonal run‐off totals (millimetres) were similar between the rural and urban groups and were relatively insensitive to urban cover. Instead, urban streams had significantly greater high flow frequency, flow variability and quickflow and lower baseflow compared with rural streams. Furthermore, differences in high flow frequency between urban and rural stream groups were largest in the summer and fall and less extreme in the winter and spring, perhaps because of the homogenizing effect of winter snow cover, frozen ground and spring melt on surface imperviousness. Although the clear clustering of streams into urban and rural groups precluded the identification of a threshold above which urban cover is the primary cause of flow differences, relatively high extreme flow frequency and flow variability in the two most urbanized of the rural streams (10–11% impervious) suggest that it may lie close to this range. Furthermore, whereas total run‐off volumes were not affected by urban cover, increases in stream flashiness and a greater frequency of high flow events particularly during the summer and fall may negatively impact stream biota and favour the transfer of surface‐deposited pollutants to urban streams. Copyright © 2014 John Wiley & Sons, Ltd.     

Land-cover impacts on streamflow: a change-detection modelling approach that incorporates parameter uncertainty

Abstract

The effect of land-use or land-cover change on stream runoff dynamics is not fully understood. In many parts of the world, forest management is the major land-cover change agent. While the paired catchment approach has been the primary methodology used to quantify such effects, it is only possible for small headwater catchments where there is uniformity in precipitation inputs and catchment characteristics between the treatment and control catchments. This paper presents a model-based change-detection approach that includes model and parameter uncertainty as an alternative to the traditional paired-catchment method for larger catchments. We use the HBV model and data from the HJ Andrews Experimental Forest in Oregon, USA, to develop and test the approach on two small (<1 km²) headwater catchments (a 100% clear-cut and a control) and then apply the technique to the larger 62 km² Lookout catchment. Three different approaches are used to detect changes in stream peak flows using: (a) calibration for a period before (or after) change and simulation of runoff that would have been observed without land-cover changes (reconstruction of runoff series); (b) comparison of calibrated parameter values for periods before and after a land-cover change; and (c) comparison of runoff predicted with parameter sets calibrated for periods before and after a land-cover change. Our proof-of-concept change detection modelling showed that peak flows increased in the clear-cut headwater catchment, relative to the headwater control catchment, and several parameter values in the model changed after the clear-cutting. Some minor changes were also detected in the control, illustrating the problem of false detections. For the larger Lookout catchment, moderately increased peak flows were detected. Monte Carlo techniques used to quantify parameter uncertainty and compute confidence intervals in model results and parameter ranges showed rather wide distributions of model simulations. While this makes change detection more difficult, it also demonstrated the need to explicitly consider parameter uncertainty in the modelling approach to obtain reliable results.

Citation Seibert, J. & McDonnell, J. J. (2010) Land-cover impacts on streamflow: a change-detection modelling approach that incorporates parameter uncertainty. Hydrol. Sci. J. 55(3), 316–332.     

Spatial aggregation of time‐variant stream water ages in urbanizing catchments

We calibrated an integrated flow–tracer model to simulate spatially distributed isotope time series in stream water in a 7.9‐km² catchment with an urban area of 13%. The model used flux tracking to estimate the time‐varying age of stream water at the outlet and both urbanized (1.7 km²) and non‐urban (4.5 km²) sub‐catchments over a 2.5‐year period. This included extended wet and dry spells where precipitation equated to >10‐year return periods. Modelling indicated that stream water draining the most urbanized tributary was youngest with a mean transit time (MTT) of 171 days compared with 456 days in the non‐urban tributary. For the larger catchment, the MTT was 280 days. Here, the response of urban contributing areas dominated smaller and more moderate runoff events, but rural contributions dominated during the wettest periods, giving a bi‐modal distribution of water ages. Whilst the approach needs refining for sub‐daily time steps, it provides a basis for projecting the effects of urbanization on stream water transit times and their spatial aggregation. This offers a novel approach for understanding the cumulative impacts of urbanization on stream water quantity and quality, which can contribute to more sustainable management. Copyright © 2015 John Wiley & Sons, Ltd.     

Impact of the spatial distribution of imperviousness on the hydrologic response of an urbanizing basin

An event‐based model is used to investigate the impact of the spatial distribution of imperviousness on the hydrologic response of a basin characterized by an urban land use. The impact of the spatial distribution of imperviousness is investigated by accounting for its location within the basin when estimating the generated runoff and the hydrologic response. The event model accounts for infiltration and saturation excess; the excess runoff is routed to the outlet using a geomorphologic unit hydrograph. To represent the spatial distribution of rainfall and imperviousness, radar and remotely derived data are used, respectively. To estimate model parameters and analyse their behaviour, a split sample test and parameter sensitivity analysis are performed. From the analysis of parameters, we found the impervious cover tends to increase the sensitivity and storm dependency of channel routing parameters. The calibrated event model is used to investigate the impact of the imperviousness gradient by estimating and comparing hydrographs at internal locations in the basin. From this comparison, we found the urban land use and the spatial variability of rainfall can produce bigger increases in the peak flows of less impervious areas than the most urbanized ones in the basin. To examine the impacts of the imperviousness pattern, scenarios typifying extreme cases of sprawl type and clustered development are used while accounting for the uncertainty in parameters and the initial condition. These scenarios show that the imperviousness pattern can produce significant changes in the response at the main outlet and at locations internal to the overall watershed. Overall, the results indicate the imperviousness pattern can be an influential factor in shaping the hydrologic response of an urbanizing basin. Copyright © 2010 John Wiley & Sons, Ltd.     

Effects of land use intensity on stormwater runoff and its temporal occurrence in cold climates

The impacts of land use intensity, here defined as the degree of imperviousness, on stormwater volumes, runoff rates and their temporal occurrence were studied at three urban catchments in a cold region in southern Finland. The catchments with ‘High’ and ‘Intermediate’ land use intensity, located around the city centre, were characterized by 89% and 62% impervious surfaces, respectively. The ‘Low’ catchment was situated in a residential area of 19% imperviousness. During a 2‐year study period with divergent weather conditions, the generation of stormwater correlated positively with catchment imperviousness: The largest annual stormwater volumes and the highest runoff coefficients and number of stormwater runoff events occurred in the High catchment. Land use intensity also altered the seasonality of stormwater runoff: Most stormwater in the High catchment was generated during the warm period of the year, whereas the largest contribution to annual stormwater generation in the Low catchment took place during the cold period. In the two most urbanized catchments, spring snow melt occurred a few weeks earlier than in the Low catchment. The rate of stormwater runoff in the High and Intermediate catchments was higher in summer than during spring snow melt, and summer runoff rates in these more urbanized catchments were several times higher than in the Low catchment. Our study suggests that the effects of land use intensity on stormwater runoff are season dependent in cold climates and that cold seasons diminish the differences between land use intensities. Copyright © 2013 John Wiley & Sons, Ltd.     

Reduced channel morphological response to urbanization in a flood‐dominated humid tropical environment

Urbanization through the addition of impervious cover can alter catchment hydrology, often resulting in increased peak flows during floods. This phenomenon and the resulting impact on stream channel morphology is well documented in temperate climatic regions, but not well documented in the humid tropics where urbanization is rapidly occurring. This study investigates the long‐term effects of urbanization on channel morphology in the humid sub‐tropical region of Puerto Rico, an area characterized by frequent high‐magnitude flows, and steep coarse‐grained rivers. Grain size, low‐flow channel roughness, and the hydraulic geometry of streams across a land‐use gradient that ranges from pristine forest to high density urbanized catchments are compared. In areas that have been urbanized for several decades changes in channel features were measurable, but were smaller than those reported for comparable temperate streams. Decades of development has resulted in increased fine sediment and anthropogenic debris in urbanized catchments. Materials of anthropogenic origin comprise an average of 6% of the bed material in streams with catchments with 15% or greater impervious cover. At‐a‐station hydraulic geometry shows that velocity makes up a larger component of discharge for rural channels, while depth contributes a larger component of discharge in urban catchments. The average bank‐full cross‐sectional area of urbanized reaches was 1.5 times larger than comparable forested reaches, and less than the world average increase of 2.5. On average, stream width at bank‐full height did not change with urbanization while the world average increase is 1.5 times. Overall, this study indicates that the morphologic changes that occur in response to urban runoff are less in channels that are already subject to frequent large magnitude storms. Furthermore, this study suggests that developing regions in the humid tropics shouldn't rely on temperate analogues to determine the magnitude of impact of urbanization on stream morphology. Copyright © 2012 John Wiley & Sons, Ltd.     

Understanding changes in annual runoff following land use changes: a systematic data‐based approach

A simple modelling framework for assessing the response of ungauged catchments to land use change in South‐Western Australia is presented. The framework uses knowledge of transpiration losses from native vegetation and pasture and then partitions the ‘excess’ water (resulting from reduced transpiration after land use change) between runoff and deep storage. The simple partitioning is achieved by using soft information (satellite imagery, previous mapping and field assessment) to delimit the spread of the permanently saturated area close to the stream. Runoff is then assumed to increase in proportion to the saturated area, with the residual difference going to deep storage. The model parameters to describe the annual water yield are obtained a priori and no calibration to streamflow is required. We tested the model using gauged records over 25 years from paired catchment experiments in South‐Western Australia. Very good estimates of runoff were obtained from high rainfall (>1100 mm yr⁻¹) catchments (R² > 0·9) and for low rainfall (<900 mm yr⁻¹) catchments after clearing (R² = 0·96) but results were poorer (R² = 0·55) for an uncleared low rainfall catchment, although overall balances were reasonable. In the drier uncleared catchments, the within‐year distributions of rainfall may exert a substantial influence on runoff response that is not completely captured by the presented model. Copyright © 2005 John Wiley & Sons, Ltd.     

Effects of urbanization on streamflow in the Atlanta area (Georgia,USA): a comparative hydrological approach

For the period from 1958 to 1996, streamflow characteristics of a highly urbanized watershed were compared with less‐urbanized and non‐urbanized watersheds within a 20 000 km² region in the vicinity of Atlanta, Georgia: in the Piedmont and Blue Ridge physiographic provinces of the southeastern USA. Water levels in several wells completed in surficial and crystalline‐rock aquifers were also evaluated. Data were analysed for seven US Geological Survey (USGS) stream gauges, 17 National Weather Service rain gauges, and five USGS monitoring wells. Annual runoff coefficients (RCs; runoff as a fractional percentage of precipitation) for the urban stream (Peachtree Creek) were not significantly greater than for the less‐urbanized watersheds. The RCs for some streams were similar to others and the similar streams were grouped according to location. The RCs decreased from the higher elevation and higher relief watersheds to the lower elevation and lower relief watersheds: values were 0·54 for the two Blue Ridge streams, 0·37 for the four middle Piedmont streams (near Atlanta), and 0·28 for a southern Piedmont stream. For the 25 largest stormflows, the peak flows for Peachtree Creek were 30% to 100% greater than peak flows for the other streams. The storm recession period for the urban stream was 1–2 days less than that for the other streams and the recession was characterized by a 2‐day storm recession constant that was, on average, 40 to 100% greater, i.e. streamflow decreased more rapidly than for the other streams. Baseflow recession constants ranged from 35 to 40% lower for Peachtree Creek than for the other streams; this is attributed to lower evapotranspiration losses, which result in a smaller change in groundwater storage than in the less‐urbanized watersheds. Low flow of Peachtree Creek ranged from 25 to 35% less than the other streams, possibly the result of decreased infiltration caused by the more efficient routing of stormwater and the paving of groundwater recharge areas. The timing of daily or monthly groundwater‐level fluctuations was similar annually in each well, reflecting the seasonal recharge. Although water‐level monitoring only began in the 1980s for the two urban wells, water levels displayed a notable decline compared with non‐urban wells since then; this is attributed to decreased groundwater recharge in the urban watersheds due to increased imperviousness and related rapid storm runoff. Copyright © 2001 John Wiley & Sons, Ltd.     

Assessing the effectiveness of imperviousness on stormwater runoff in micro urban catchments by model simulation

Imperviousness, considered as a critical indicator of the hydrologic impacts of urbanization, has gained increasing attention both in the research field and in practice. However, the effectiveness of imperviousness on rainfall–runoff dynamics has not been fully determined in a fine spatiotemporal scale. In this study, 69 drainage subareas <1 ha of a typical residential catchment in Beijing were selected to evaluate the hydrologic impacts of imperviousness, under a typical storm event with a 3‐year return period. Two metrics, total impervious area (TIA) and effective impervious area (EIA), were identified to represent the impervious characteristics of the selected subareas. Three runoff variables, total runoff depth (TR), peak runoff depth (PR), and lag time (LT), were simulated by using a validated hydrologic model. Regression analyses were developed to explore the quantitative associations between imperviousness and runoff variables. Then, three scenarios were established to test the applicability of the results in considering the different infiltration conditions. Our results showed that runoff variables are significantly related to imperviousness. However, the hydrologic performances of TIA and EIA were scale dependent. Specifically, with finer spatial scale and the condition heavy rainfall, TIA rather than EIA was found to contribute more to TR and PR. EIA tended to have a greater impact on LT and showed a negative relationship. Moreover, the relative significance of TIA and EIA was maintained under the different infiltration conditions. These findings may provide potential implications for landscape and drainage design in urban areas, which help to mitigate the runoff risk. Copyright © 2015 John Wiley & Sons, Ltd.     

Rainfall/runoff processes in a small peri‐urban catchment in the Andes mountains. The Rumihurcu Quebrada,Quito (Ecuador)

Situated at the foot of the Pichincha volcano, the city of Quito is frequently subjected to hydroclimatic hazards. In 1995 an 11·2 km² watershed, located in the vicinity of the city, was equipped with eight rain gauges and two flow gauges to better understand the local rainfall/runoff transformation processes. Rainfall simulation experiments were carried out on more than 40 one‐square‐metre plots to measure infiltration point‐processes. The high density of measurement devices allowed us to identify the origin and nature of the various contributions to runoff for the different physiographic units of the watershed: urban area from an altitude of 2800 to 3200 m; farmland, pasture and forested land, and finally páramo above 3900 m. Runoff occurs mainly in the lower part of the basin and is caused by urbanization; however, the natural soils of this area can also produce Hortonian runoff, which is predominant in a few events. This contribution can be studied through rainfall simulation experiments. In the upper natural zone, the younger and more permeable soils generate less runoff on the slopes. However, almost permanently saturated contributing areas, which are located in the bottom of the quebradas, may generate flood events, the size of which depends on the extent of the area concerned. Variations in the runoff coefficients are related first to the baseflow and second to the amount of rainfall in the previous 24 h. This analysis, which underlines the complexity of a small, peri‐urban, volcanic catchment, is a necessary preliminary to runoff modelling in an area where very few experiments have been carried out on small catchments. Copyright © 2001 John Wiley & Sons, Ltd.     

A tracer‐based assessment of hydrological pathways at different spatial scales in a mesoscale Scottish catchment

Geochemically based hydrograph separation techniques were used in a preliminary assessment to infer how runoff processes change with landscape characteristics and spatial scale (1–233 km²) within a mesoscale catchment in upland Scotland. A two‐component end‐member mixing analysis (EMMA) used Gran alkalinity as an assumed conservative tracer. Analysis indicated that, at all scales investigated, acidic overland flow and shallow subsurface storm flows from the peaty soils covering the catchment headwaters dominated storm runoff generation. The estimated groundwater contribution to annual runoff varied from 30% in the smallest (ca 1 km²) peat‐dominated headwater catchment with limited groundwater storage, to >60% in larger catchments (>30 km²) with greater coverage of more freely draining soils and more extensive aquifers in alluvium and other drift. This simple approach offers a useful, integrated conceptualization of the hydrological functioning in a mesoscale catchment, which can be tested and further refined by focused modelling and process‐based research. However, even as it stands, the simple conceptualization of system behaviour will have significant utility as a tool for communicating hydrological issues in a range of planning and management decisions. Copyright © 2002 John Wiley & Sons, Ltd.     

Fluxes of inorganic carbon from two forested catchments in the Appalachian mountains

This study uses long‐term records of stream chemistry, discharge and air temperature from two neighbouring forested catchments in the southern Appalachians in order to calculate production of dissolved CO₂ and dissolved inorganic carbon (DIC). One of the pair of catchments was clear‐felled during the period of the study. The study shows that: (1) areal production rates of both dissolved CO₂ and DIC are similar between the two catchments even during and immediately after the period of clear‐felling; (2) flux of total inorganic carbon (dissolved CO₂+ DIC) rises dramatically in response to a catchment‐wide acidification event; (3) DIC and dissolved CO₂ are dominantly released on the old water portion of the discharge and concentrations peak in the early autumn when flows in the study catchments are at their lowest; (4) total fluvial carbon flux from the clear‐felled catchment is 11·6 t km⁻² year⁻¹ and for the control catchment is 11·4 t km⁻² year⁻¹. The total inorganic carbon flux represents 69% of the total fluvial carbon flux. The method presented in the study provides a useful way of estimating inorganic carbon flux from a catchment without detailed gas monitoring. The time series of dissolved CO₂ at emergence to the stream can also be a proxy for the soil flux of CO₂. Copyright © 2005 John Wiley & Sons, Ltd.     

Evolution of the spatial and temporal characteristics of the isotope hydrology of a montane river basin

Abstract

Precipitation and streamwater were analysed weekly for δ¹⁸O in seven tributaries and five main stem sites of a 2100 km² catchment; >60% of it is upland in character. Precipitation δ¹⁸O followed seasonal patterns ranging from –20‰ in winter to –4‰ in summer. Seasonality was also evident in stream waters, though much more damped. Mean transit times (MTTs) were estimated using δ¹⁸O input–output relationships in a convolution integral with a gamma distribution. The MTTs were relatively similar (528–830 days): tributaries exhibited a greater range, being shorter in catchments with montane topography and hydrologically responsive soils, and longer where catchments have significant water storage. Along the main stem, MTTs increased modestly from 621 to 741 days. This indicates that montane headwaters are the dominant sources of runoff along the main stem of the river system. Models suggest that around 10% of runoff has transit times of less than two weeks during higher flows whilst older (>10-year old) water sustains low flows contributing around 5% of runoff.

Citation Speed, M., Tetzlaff, D., Hrachowitz, M. & Soulsby, C. (2011) Evolution of the spatial and temporal characteristics of the isotope hydrology of a montane river basin. Hydrol. Sci. J. 56(3), 426–442     

Storm runoff response to rainfall pattern,magnitude and urbanization in a developing urban catchment

This study explored the hydrological impacts of urbanization, rainfall pattern and magnitude in a developing catchment. The Stormwater Management Model was parameterized, calibrated and validated in three development phases, which had the same catchment area (12.3 ha) but different land use intensities. The model calibration and validation by using sub‐hourly hydro‐meteorological data demonstrated a good performance of the model in predicting stormwater runoff in the different development phases. Based on the results, a threshold between minor and major rainfall events was identified and conservatively determined to be about 17.5 mm in depth. Direct runoff for minor storm events has a linear relationship with rainfall; however, events with a rainfall depth greater than the threshold yield a rainfall–runoff regression line with a clearly steeper slope. The difference in urban runoff generation between minor and major rainfall events diminishes with the increase of imperviousness. Urbanization leads to an increase in the production of stormwater runoff, but during infrequent major storms, the runoff contribution from pervious surfaces reduces the runoff changes owing to urbanization. Rainfall pattern exerts an important effect on urban runoff, which is reflected in pervious runoff. With the same magnitude, prolonged rainfall events with unvarying low intensity yield the smallest peak flow and the smallest total runoff, yet rainfall events with high peak intensity produce the largest runoff volume. These results demonstrate the different roles of impervious and pervious surfaces in runoff generation, and how runoff responds to rainstorms in urban catchments depends on hyetograph and event magnitude. Furthermore, the study provides a scientific basis of the design guideline sustainable urban drainage systems, which are still arbitrary in many countries. Copyright © 2015 John Wiley & Sons, Ltd.     

The role of urban growth,climate change,and their interplay in altering runoff extremes

Changes in climate and urban growth are the most influential factors affecting hydrological characteristics in urban and extra‐urban contexts. The assessment of the impacts of these changes on the extreme rainfall–runoff events may have important implications on urban and extra‐urban management policies against severe events, such as floods, and on the design of hydraulic infrastructures. Understanding the effects of the interaction between climate change and urban growth on the generation of runoff extremes is the main aim of this paper. We carried out a synthetic experiment on a river catchment of 64 km² to generate hourly runoff time series under different hypothetical scenarios. We imposed a growth of the percentage of urban coverage within the basin (from 1.5% to 25%), a rise in mean temperature of 2.6 °C, and an alternatively increase/decrease in mean annual precipitation of 25%; changes in mean annual precipitation were imposed following different schemes, either changing rainstorm frequency or rainstorm intensity. The modelling framework consists of a physically based distributed hydrological model, which simulates fast and slow mechanisms of runoff generation directly connected with the impervious areas, a land‐use change model, and a weather generator. The results indicate that the peaks over threshold and the hourly annual peaks, used as hydrological indicators, are very sensitive to the rainstorm intensity. Moreover, the effects of climate changes dominate on those of urban growth determining an exacerbation of the fast runoff component in extreme events and a reduction of the slow and deep runoff component, thus limiting changes in the overall runoff.     

The relationship between dissolved organic carbon in stream water and soil organic carbon pools at different spatial scales

The relationship between stream water DOC concentrations and soil organic C pools was investigated at a range of spatial scales in subcatchments of the River Dee system in north‐east Scotland. Catchment percentage peat cover and soil C pools, calculated using local, national and international soils databases, were related to mean DOC concentrations in streams draining small‐ (<5 km²), medium‐ (12–38 km²) and large‐scale (56–150 km²) catchments. The results show that, whilst soil C pool is a good predictor of stream water DOC concentration at all three scales, the strongest relationships were found in the small‐scale catchments. In addition, in both the small‐ and large‐scale catchments, percentage peat cover was as a good predictor of stream water DOC concentration as catchment soil C pool. The data also showed that, for a given soil C pool, streams draining lowland (<700 m) catchments had higher DOC concentrations than those draining upland (>700 m) catchments, suggesting that disturbance and land use may have a small effect on DOC concentration. Our results therefore suggest that the relationship between stream water DOC concentration and catchment soil C pools exists at a range of spatial scales and this relationship appears to be sufficiently robust to be used to predict the effects of changes in catchment soil C storage on stream water DOC concentration. Copyright © 1999 John Wiley & Sons, Ltd.     

CONTRIBUTION OF NITROGEN SPECIES AND PHOSPHORUS FRACTIONS TO STREAM WATER QUALITY IN AGRICULTURAL CATCHMENTS

The contribution from agricultural catchments to stream nitrogen and phosphorus concentrations was assessed by evaluation of the chemical composition of these nutrients in agricultural runoff for both surface and subsurface flow pathways. A range of land uses (grazed and ungrazed grassland, cereals, roots) in intensive agricultural systems was studied at scales from hillslope plots (0.5 m²) to large catchment (>300 km²). By fractionating the total nutrient load it was possible to establish that most of the phosphorus was transported in the unreactive (particulate and organic) fraction via surface runoff. This was true regardless of the scale of measurement. The form of the nitrogen load varied with land use and grazing intensity. High loads of dissolved inorganic nitrogen (with >90% transported as NH₄-N) were recorded in surface runoff from heavily grazed land. In subsurface flow from small (2 km²) subcatchments and in larger (>300 km²) catchments, organic nitrogen was found to be an important secondary constituent of the total nitrogen load, comprising 40% of the total annual load.     

Runoff and peak flow responses to timber harvest and forest age in southern Chile

Runoff and peak flows in three experimental catchments with different forest conditions were analysed in a rainy temperate climate in southern Chile. The hydrological effects of clearcutting a Pinus radiata plantation covering 79·4% of the La Reina catchment were studied by analysing runoff and peak flows in the pre‐ and post‐harvesting periods. Mean annual runoff increased 110% after timber harvesting. Clearcutting generated a 32% mean increase in peak flows. Peak flow and runoff were examined in two adjacent catchments with different forest conditions. The older plantation in Los Ulmos 1 increasingly consumed more water than the younger plantation established at Los Ulmos 2, whereas differences in peak flows between these two catchments were not significant. Runoff and peak flows comparisons not only reflected changes in forest cover, but also the effect of rainfall characteristics during the study periods and the basins' morphologies. Comparisons between pre‐ and post‐harvesting peak discharges must be undertaken with caution, because a previous analysis at La Reina using a partial set of data overestimated changes in peak flows after timber harvesting. Copyright © 2005 John Wiley & Sons, Ltd.