Biogeochemical responses over 37 years to manipulation of phosphorus concentrations in an Arctic river: The Upper Kuparuk River Experiment

The climate of the Arctic region is changing rapidly, with important implications for permafrost, vegetation communities, and transport of solutes by streams and rivers to the Arctic Ocean. While research on Arctic streams and rivers has accelerated in recent years, long-term records are relatively rare compared to temperate and tropical regions. We began monitoring the upper Kuparuk River in 1983 as part of a long-term, low-level, whole-season phosphorus enrichment of a 4–6 km experimental reach, which was subsequently incorporated into the Arctic Long-Term Ecological Research (Arctic LTER) programme. The phosphorus enrichment phase of the Upper Kuparuk River Experiment (UKRE) ran continuously for 34 seasons, fundamentally altering the community structure and function of the Fertilized reach. The objectives of this paper are to (a) update observations of the environmental conditions in the Kuparuk River region as revealed by long-term, catchment-level monitoring, (b) compare long-term trends in biogeochemical characteristics of phosphorus-enriched and reference reaches of the Kuparuk River, and (c) report results from a new ‘ReFertilization’ experiment. During the UKRE, temperature and discharge did not change significantly, though precipitation increased slightly. However, the UKRE revealed unexpected community state changes attributable to phosphorus enrichment (e.g., appearance of colonizing bryophytes) and long-term legacy effects of these state changes after cessation of the phosphorus enrichment. The UKRE also revealed important biogeochemical trends (e.g., increased nitrate flux and benthic C:N, decreased DOP flux). The decrease in DOP is particularly notable in that this may be a pan-Arctic trend related to permafrost thaw and exposure to new sources of iron that reduce phosphorus mobility to streams and rivers. The trends revealed by the UKRE would have been difficult or impossible to identify without long-term, catchment level research and may have important influences on connections between Arctic headwater catchments and downstream receiving waters, including the Arctic Ocean.     

Using stable isotopes to estimate travel times in a data‐sparse Arctic catchment: Challenges and possible solutions

Use of isotopes to quantify the temporal dynamics of the transformation of precipitation into run‐off has revealed fundamental new insights into catchment flow paths and mixing processes that influence biogeochemical transport. However, catchments underlain by permafrost have received little attention in isotope‐based studies, despite their global importance in terms of rapid environmental change. These high‐latitude regions offer limited access for data collection during critical periods (e.g., early phases of snowmelt). Additionally, spatio‐temporal variable freeze–thaw cycles, together with the development of an active layer, have a time variant influence on catchment hydrology. All of these characteristics make the application of traditional transit time estimation approaches challenging. We describe an isotope‐based study undertaken to provide a preliminary assessment of travel times at Siksik Creek in the western Canadian Arctic. We adopted a model–data fusion approach to estimate the volumes and isotopic characteristics of snowpack and meltwater. Using samples collected in the spring/summer, we characterize the isotopic composition of summer rainfall, melt from snow, soil water, and stream water. In addition, soil moisture dynamics and the temporal evolution of the active layer profile were monitored. First approximations of transit times were estimated for soil and streamwater compositions using lumped convolution integral models and temporally variable inputs including snowmelt, ice thaw, and summer rainfall. Comparing transit time estimates using a variety of inputs revealed that transit time was best estimated using all available inflows (i.e., snowmelt, soil ice thaw, and rainfall). Early spring transit times were short, dominated by snowmelt and soil ice thaw and limited catchment storage when soils are predominantly frozen. However, significant and increasing mixing with water in the active layer during the summer resulted in more damped steam water variation and longer mean travel times (~1.5 years). The study has also highlighted key data needs to better constrain travel time estimates in permafrost catchments.     

Hydrochemical and sedimentary responses of paired High Arctic watersheds to unusual climate and permafrost disturbance,Cape Bounty,Melville Island,Canada

High Arctic river responses to changing hydroclimatic and landscape processes are poorly understood. In non‐glacierized basins, snowmelt and rainfall generate river discharge, which provides first order control over fluxes. Further factors include the seasonality of precipitation, seasonal active layer development, and permafrost disturbance. These controls were evaluated in terms of sedimentary and biogeochemical fluxes from paired catchments at Cape Bounty, Melville Island, Nunavut during 2006–2009. Results indicate that the source of runoff can be more important than the amount of runoff for sediment, solutes, and organic yields. Although the snowmelt period is typically the most important time for these yields, heavy late summer precipitation events can create disproportionately large yields. Rainfall increases yields because it hydrologically connects areas otherwise isolated. Inorganic solute yields from late summer rainfall are higher because the thick active layer maximizes hydrologic interactions with mineral soils and generates high solute concentrations. Results also indicate that while the catchments are broadly similar, subtle topographic differences result in important inter‐catchment differences in runoff and suspended and dissolved loads. The East watershed, which had less extensive permafrost disturbance, consistently had higher concentrations of dissolved solids. These higher dissolved fluxes cannot therefore be explained by thermokarst features, but rather by deeper active layer development, due to a greater proportion of south‐facing slopes. Although warm temperatures in 2007 led to extensive active layer disturbance in the West watershed, because the disturbances were largely hydrologically disconnected, the total disturbed area was small, and inter‐annual variability in discharge was high, there was no detectable response in dissolved loads to disturbances. Sediment availability increased after 2007, but yields have largely returned to pre‐disturbance levels. Results indicate that seasonality and frequency‐magnitude characteristics of projected increases in precipitation must be considered along with active layer changes to predict the fluvial sedimentary and biogeochemical response to regional climate change. Copyright © 2011 John Wiley & Sons, Ltd.     

High Arctic wetlands: Their occurrence, hydrological characteristics and sustainability

High Arctic wetlands, though limited in occurrence, are an important ecological niche, providing the major vegetated areas in an arid and cold polar desert environment. These wetlands are often found as patches in the barren landscape. At a few locales which may be ice-wedge polygonal grounds, glacial terrain and zones of recent coastal uplift, wetland occurrence can become extensive, forming a mosaic that comprises patches of different wetland types. Reliable water supply during the thawed season is a deciding factor in wetland sustainability. The sources include meltwater from late-lying snowbanks, localized ground water discharge, streamflow, inundation by lakes and the sea, and for some ice-wedge wetlands, ground-ice melt. Different types of wetlands have their own characteristics, and peat accumulation or diatom depositions are common. The peat cover insulates the wetland from summer heating and encourages permafrost aggradation, with the feedback that a shallow frost table reduces the moisture storage capacity in a thinly thawed layer, which becomes easily saturated. All the wetlands studied have high calcium content since they are formed on carbonate terrain. Coastal wetlands have high salt concentration while snowmelt and ground-ice melt provides dilution. The sustainability of High Arctic wetlands is predicated upon water supply exceeding the losses to evaporation and lateral drainage. Disturbances due to natural causes such as climatic variations, geomorphic changes, or human-induced drainage, can reduce inundation opportunities or increase outflow. Then, the water table drops, the vegetation changes and the peat degrades, leading to the detriment of the wetlands.     

Simulating pan‐Arctic runoff with a macro‐scale terrestrial water balance model

A terrestrial hydrological model, developed to simulate the high‐latitude water cycle, is described, along with comparisons with observed data across the pan‐Arctic drainage basin. Gridded fields of plant rooting depth, soil characteristics (texture, organic content), vegetation, and daily time series of precipitation and air temperature provide the primary inputs used to derive simulated runoff at a grid resolution of 25 km across the pan‐Arctic. The pan‐Arctic water balance model (P/WBM) includes a simple scheme for simulating daily changes in soil frozen and liquid water amounts, with the thaw–freeze model (TFM) driven by air temperature, modelled soil moisture content, and physiographic data. Climate time series (precipitation and air temperature) are from the National Centers for Environmental Prediction (NCEP) reanalysis project for the period 1980–2001. P/WBM‐generated maximum summer active‐layer thickness estimates differ from a set of observed data by an average of 12 cm at 27 sites in Alaska, with many of the differences within the variability (1σ) seen in field samples. Simulated long‐term annual runoffs are in the range 100 to 400 mm year^?1. The highest runoffs are found across northeastern Canada, southern Alaska, and Norway, and lower estimates are noted along the highest latitudes of the terrestrial Arctic in North America and Asia. Good agreement exists between simulated and observed long‐term seasonal (winter, spring, summer–fall) runoff to the ten Arctic sea basins (r = 0·84). Model water budgets are most sensitive to changes in precipitation and air temperature, whereas less affect is noted when other model parameters are altered. Increasing daily precipitation by 25% amplifies annual runoff by 50 to 80% for the largest Arctic drainage basins. Ignoring soil ice by eliminating the TFM sub‐model leads to runoffs that are 7 to 27% lower than the control run. The results of these model sensitivity experiments, along with other uncertainties in both observed validation data and model inputs, emphasize the need to develop improved spatial data sets of key geophysical quantities (particularly climate time series) to estimate terrestrial Arctic hydrological budgets better. Copyright © 2003 John Wiley & Sons, Ltd.     

北极夏季冰面上近地层特征及热量收支问题

应用1999年8月19～24日我国第1次北极考察资料对北极夏季近地层气象要素梯度特征和冰面热量收支问题进行了讨论.北极夏季近地层相对于冰面的相对湿度很大,经常接近于饱和状态,冰温具有明显的日变化,夜间冰面附近冰温梯度较大,白天很小.在冰温垂直分布中20cm冰层温度有时可出现极大值.冰面热量收支计算表明,夜间冰面辐射冷却损失热量主要由冰层向冰面热量输送来补偿.白天冰层的热量主要来源于穿透短波辐射,冰面和以下冰层间的热量交换很低.白天冰面冰雪融化热量是不可忽视的.     

The implications of permafrost thaw and land cover change on snow water equivalent accumulation,melt and runoff in discontinuous permafrost peatlands

In the discontinuous permafrost zone of the Northwest Territories (NWT), Canada, snow covers the ground surface for half the year. Snowmelt constitutes a primary source of moisture supply for the short growing season and strongly influences stream hydrographs. Permafrost thaw has changed the landscape by increasing the proportional coverage of permafrost-free wetlands at the expense of permafrost-cored peat plateau forests. The biophysical characteristics of each feature affect snow water equivalent (SWE) accumulation and melt rates. In headwater streams in the southern Dehcho region of the NWT, snowmelt runoff has significantly increased over the past 50 years, despite no significant change in annual SWE. At the Fort Simpson A climate station, we found that SWE measurements made by Environment and Climate Change Canada using a Nipher precipitation gauge were more accurate than the Adjusted and Homogenized Canadian Climate Dataset which was derived from snow depth measurements. Here, we: (a) provide 13 years of snow survey data to demonstrate differences in end-of-season SWE between wetlands and plateau forests; (b) provide ablation stake and radiation measurements to document differences in snow melt patterns among wetlands, plateau forests, and upland forests; and (c) evaluate the potential impact of permafrost-thaw induced wetland expansion on SWE accumulation, melt, and runoff. We found that plateaus retain significantly (p < 0.01) more SWE than wetlands. However, the differences are too small (123 mm and 111 mm, respectively) to cause any substantial change in basin SWE. During the snowmelt period in 2015, wetlands were the first feature to become snow-free in mid-April, followed by plateau forests (7 days after wetlands) and upland forests (18 days after wetlands). A transition to a higher percentage cover of wetlands may lead to more rapid snowmelt and provide a more hydrologically-connected landscape, a plausible mechanism driving the observed increase in spring freshet runoff.     

Analysis of trends in annual streamflow to the Arctic Ocean

There is increasing interest in the magnitude of the flow of freshwater to the Arctic Ocean due to its impacts on the biogeophysical and socio‐economic systems in the north and its influence on global climate. This study examines freshwater flow based on a dataset of 72 rivers that either directly or indirectly contribute flow to the Arctic Ocean or reflect the hydrologic regime of areas contributing flow to the Arctic Ocean. Annual streamflow for the 72 rivers is categorized as to the nature and location of the contribution to the Arctic Ocean, and composite series of annual flows are determined for each category for the period 1975 to 2015. A trend analysis is then conducted for the annual discharge series assembled for each category. The results reveal a general increase in freshwater flow to the Arctic Ocean with this increase being more prominent from the Eurasian rivers than from the North American rivers. A comparison with trends obtained from an earlier study ending in 2000 indicates similar trend response from the Eurasian rivers, but dramatic differences from some of the North American rivers. A total annual discharge increase of 8.7 km³/y/y is found, with an annual discharge increase of 5.8 km³/y/y observed for the rivers directly flowing to the Arctic Ocean. The influence of annual or seasonal climate oscillation indices on annual discharge series is also assessed. Several river categories are found to have significant correlations with the Arctic Oscillation, the North Atlantic Oscillation, or the Pacific Decadal Oscillation. However, no significant association with climate indices is found for the river categories leading to the largest freshwater contribution to the Arctic Ocean.     

After the peak water: the increasing influence of rock glaciers on alpine river systems

Human‐accelerated climate change is quickly leading to glacier‐free mountains, with consequences for the ecology and hydrology of alpine river systems. Water origin (i.e., glacier, snowmelt, precipitation, and groundwater) is a key control on multiple facets of alpine stream ecosystems, because it drives the physico‐chemical template of the habitat in which ecological communities reside and interact and ecosystem processes occur. Accordingly, distinct alpine stream types and associated communities have been identified. However, unlike streams fed by glaciers (i.e., kryal), groundwater (i.e., krenal), and snowmelt/precipitation (i.e., rhithral), those fed by rock glaciers are still poorly documented. We characterized the physical and chemical features of these streams and investigated the influence of rock glaciers on the habitat template of alpine river networks. We analysed two subcatchments in a deglaciating area of the Central European Alps, where rock glacier‐fed, groundwater‐fed, and glacier‐fed streams are all present. We monitored the spatial, seasonal, and diel variability of physical conditions (i.e., water temperature, turbidity, channel stability, and discharge) and chemical variables (electrical conductivity, major ions, and trace element concentrations) during the snowmelt, glacier ablation, and flow recession periods of two consecutive years. We observed distinct physical and chemical conditions and seasonal responses for the different stream types. Rock glacial streams were characterized by very low and constant water temperatures, stable channels, clear waters, and high concentrations of ions and trace elements that increased as summer progressed. Furthermore, one rock glacier strongly influenced the habitat template of downstream waters due to high solute export, especially in late summer under increased permafrost thaw. Given their unique set of environmental conditions, we suggest that streams fed by thawing rock glaciers are distinct river habitats that differ from those normally classified for alpine streams. Rock glaciers may become increasingly important in shaping the hydroecology of alpine river systems under continued deglaciation.     

Transformations of runoff chemistry in the Arctic tundra,Northwest Territories,Canada

The transformation of snowmelt water chemical composition during melt, elution and runoff in an Arctic tundra basin is investigated. The chemistry of the water flowing along pathways from the surface of melting snow to the 95·5 ha basin outlet is related to relevant hydrological processes. In so doing, this paper offers physically based explanations for the transformation of major ion concentrations and loads of runoff water associated with snowmelt and rainfall along hydrological pathways to the stream outlet. Late‐lying snowdrifts were found to influence the ion chemistry in adjacent reaches of the stream channel greatly. As the initial pulse of ion‐rich melt water drained from the snowdrift and was conveyed through hillslope flowpaths, the concentrations of most ions increased, and the duration of the peak ionic pulse lengthened. Over the first 3 m of overland flow, the concentrations of all ions except for NO increased by one to two orders of magnitude, with the largest increase for K⁺, Ca²⁺ and Mg²⁺. This was roughly equivalent to the concentration increase that resulted from percolation of relatively dilute water through 0·25 m of unsaturated soil. The Na⁺ and Cl^? were the dominant ions in snowmelt water, whereas Ca²⁺ and Mg²⁺ dominated the hillslope runoff. On slopes below a large melting snowdrift, ion concentrations of melt water flowing in the saturated layer of the soil were very similar to the relatively dilute concentrations found in surface runoff. However, once the snowdrift ablated, ion concentrations of subsurface flow increased above parent melt‐water concentrations. Three seasonally characteristic hydrochemical regimes were identified in a stream reach adjacent to late‐lying snowdrifts. In the first two stages, the water chemistry in the stream channel strongly resembled the hillslope drainage water. In the third stage, in‐stream geochemical processes, including the weathering/ion exchange of Ca²⁺ and Mg²⁺, were the main control of streamwater chemistry. Copyright © 2006 John Wiley & Sons, Ltd.     

Simulating the impacts of land-use and climate change on water resource availability for a large south Indian catchment

Abstract

A monthly rainfall-runoff model was calibrated for a large tropical catchment in southern India. Various land-use and climatic change scenarios were tested to assess their effects on mean annual runoff and assured water yield at the Bhavanisagar Reservoir in Tamil Nadu, India. The largest increase in runoff (19%) came from converting forest and savanna (the indigenous control scenario) to agriculture. Mean annual runoff decreased by 35% after conversion to commercial forest and 6% after partial conversion to tea plantations. The predicted climate scenarios of reduced dry season rainfall decreased the annual runoff by 5% while enhanced annual rainfall caused a 17% increase in runoff. Even if land-use and climate changes had relatively large effects on runoff, the changes in reservoir yield which can be assured every year, were often less severe. This was probably due to the buffering effect of the reservoir and variation in the mean annual runoff.     

Understanding the hydrological system dynamics of a glaciated alpine catchment in the Himalayan region using the J2000 hydrological model

This paper provides the results of hydrological modelling in a mesoscale glaciated alpine catchment of the Himalayan region. In the context of global climate change, the hydrological regime of an alpine mountain is likely to be affected, which might produce serious implications for downstream water availability. The main objective of this study was to understand the hydrological system dynamics of a glaciated catchment, the Dudh Kosi River basin, in Nepal, using the J2000 hydrological model and thereby understand how the rise in air temperature will affect the hydrological processes. The model is able to reproduce the overall hydrological dynamics quite well with an efficiency result of Nash–Sutcliffe (0.85), logarithm Nash–Sutcliffe (0.93) and coefficient of determination (0.85) for the study period. The average contribution from glacier areas to total streamflow is estimated to be 17%, and snowmelt (other than from glacier areas) accounts for another 17%. This indicates the significance of the snow and glacier runoff in the Himalayan region. The hypothetical rise in temperature scenarios at a rate of +2 and +4 °C indicated that the snowmelt process might be largely affected. An increase in snowmelt volume is noted during the premonsoon period, whereas the contribution during the monsoon season is significantly decreased. This occurs mainly because the rise in temperature will shift the snowline up to areas of higher altitude and thereby reduce the snow storage capacity of the basin. This indicates that the region is particularly vulnerable to global climate change and the associated risk of decreasing water availability to downstream areas. Under the assumed warming scenarios, it is likely that in the future, the river might shift from a ‘melt‐dominated river’ to a ‘rain‐dominated river’. The J2000 model should be considered a promising tool to better understand the hydrological dynamics in alpine mountain catchments of the Himalayan region. This understanding will be quite useful for further analysis of ‘what‐if scenarios’ in the context of global climate and land‐use changes and ultimately for sustainable Integrated Water Resources Management in the Himalayan region. Copyright © 2012 John Wiley & Sons, Ltd.     

Assessing the effects of precipitation and temperature changes on hydrological processes in a glacier‐dominated catchment

The processes by which climate change affects streamflow in alpine river basins are not entirely understood. This study evaluated the impacts of temperature and precipitation changes on runoff and streamflow using glacier‐enhanced Soil and Water Assessment Tool model. The study used observed and detrended historical meteorological data for recent decades (1961–2005) to analyse individual and combined effects of temperature and precipitation changes on snow and glacier melts and discharges in the Sary‐Djaz‐Kumaric River Basin (SRB), Tianshan Mountains. The results showed a 1.3% increase in annual snowmelt in the basin, mainly because of an increase in precipitation. Snowmelt in the basin varied seasonally, increasing from April through May because of increasing precipitation and decreasing from July through September because of rising temperature. Glacier melt increased by 5.4%, 5.0% of which was due to rising temperature and only 0.4% due to increasing precipitation. Annual streamflow increased by 4.4%, of which temperature and precipitation increases accounted for 2.5% and 1.9%, respectively. The impacts of temperature and precipitation changes on streamflow were especially significant after 1980 and even more so in September. Glacier melt, due to temperature rise, was the dominant driver of increasing streamflow in the glacier‐dominated SRB, Tianshan Mountains. Copyright © 2015 John Wiley & Sons, Ltd.     

Prediction of climate change effects on the runoff regime of a forested catchment in northern Iran

ABSTRACT

The southern coast of the Caspian Sea in northern Iran is bordered by a mountain range with forested catchments which are susceptible to droughts and floods. This paper examines possible changes to runoff patterns from one of these catchments in response to climate change scenarios. The HEC-HMS rainfall–runoff model was used with downscaled future rainfall and temperature data from 13 global circulation models, and meteorological and hydrometrical data from the Casilian (or “Kassilian”) Catchment. Annual and seasonal predictions of runoff change for three future emissions scenarios were obtained, which suggest significantly higher spring rainfall with increased risk of flooding and significantly lower summer rainfall leading to a higher probability of drought. Flash floods arising from extreme rainfall may become more frequent, occurring at any time of year. These findings indicate a need for strategic planning of water resource management and mitigation measures for increasing flood hazards.

EDITOR M.C. Acreman ASSOCIATE EDITOR not assigned     

Arctic Mackenzie Delta channel planform evolution during 1983–2013 utilising Landsat data and hydrological time series

Arctic deltas, such as the Mackenzie Delta, are expected to face major climate change and increased human influence in the near future. Deltas are characterised by highly dynamic fluvial processes, and changing climate will cause considerable evolution of the riverine environment. The changes are difficult to predict with existing knowledge and data. This study quantified channel planform change of the Mackenzie Delta (1983–2013), analysing its temporal and spatial patterns. We addressed the main obstacle of research on large remote areas, the lack of data, by developing a unique work flow that utilised Landsat satellite imagery, hydrological time series, remote sensing‐based change analysis, and automatic vectorisation of channels. Our results indicate that the Mackenzie Delta experienced constant evolution but at a highly varying rate over the 30 years. The study demonstrates that the magnitude and duration of flood peaks and the presence of spring ice breakup floods determine the rate of Arctic delta planform change. Changing winter conditions and spring flood magnitudes may therefore affect the stability of Arctic deltas. However, no clear trends towards decreased recurrence or magnitude of spring floods or increased instability of the delta plain have yet been observed in the Mackenzie Delta. The delta plain was most dynamic at the beginning and at the end of the examined period, corresponding to intense flooding, whereas the rates of change were subtle during the low‐flood period 1994–2007. The largest changes have occurred along the wide Middle Channel and in the outermost delta. Relative to their size, however, smaller meandering channels have been highly dynamic. Hotspots of change in the delta plain are located in anastomosing and braiding channel segments and, at the local scale, in point bars and cut‐banks along meandering channels. Our study describes how Landsat satellite data can be utilised for advancing fluvial geomorphological research in remote areas. However, cloudiness in the delta restricts production of dense time series with simultaneous coverage of the whole area and requires manual preprocessing.     

The role of climate change and human interventions in affecting watershed runoff responses

Identifying the role of the two main driving factors—climate change and human interventions—in influencing runoff processes is essential for sustainable water resources management. For this purpose, runoff regime change detection methods were used to divide the available hydroclimatic variables into a baseline and a disturbed period. We applied hydrological modelling and the climate elasticity of runoff method to determine the contribution of climate change and human interventions to changes in runoff. The hydrological model, SWAT, was calibrated during the baseline period and used to simulate the naturalized runoff pattern for the disturbed period. Significant changes in runoff in the study watershed were detected from 1982, suggesting that human interventions play a dominant role in influencing runoff. The combined effects of climate change and human interventions resulted in a 41.3 mm (23.9%) decrease in runoff during the disturbed period, contributing about 40% and 60% to the total runoff change, respectively. Furthermore, analysis of changes in land cover dynamics in the watershed over the past four decades supported these changes in runoff. Contrary to other decades, the discrepancy between naturalized and observed runoff was small in the 2010s, likely due to increased baseflow as a result of storage and/or release of excess water during the dry season. This study contributes to our understanding of how climate change and human interventions affect hydrological responses of watersheds, which is important for future sustainable water management and drought adaptation.     

Climate models and hydrological parameter uncertainties in climate change impacts on monthly runoff and daily flow duration curve of a Mediterranean catchment

ABSTRACT

Climate models and hydrological parameter uncertainties were quantified and compared while assessing climate change impacts on monthly runoff and daily flow duration curve (FDC) in a Mediterranean catchment. Simulations of the Soil and Water Assessment Tool (SWAT) model using an ensemble of behavioural parameter sets derived from the Generalized Likelihood Uncertainty Estimation (GLUE) method were approximated by feed-forward artificial neural networks (FF-NN). Then, outputs of climate models were used as inputs to the FF-NN models. Subsequently, projected changes in runoff and FDC were calculated and their associated uncertainty was partitioned into climate model and hydrological parameter uncertainties. Runoff and daily discharge of the Chiba catchment were expected to decrease in response to drier and warmer climatic conditions in the 2050s. For both hydrological indicators, uncertainty magnitude increased when moving from dry to wet periods. The decomposition of uncertainty demonstrated that climate model uncertainty dominated hydrological parameter uncertainty in wet periods, whereas in dry periods hydrological parametric uncertainty became more important.

Editor M.C. Acreman; Associate editor S. Kanae     

Hydrological trends and the evolution of catchment research in the Alptal valley,central Switzerland

When the observation of small headwater catchments in the pre-Alpine Alptal valley (central Switzerland) started in the late 1960s, the researchers were mainly interested in questions related to floods and forest management. Investigations of geomorphological processes in the steep torrent channels followed in the 1980s, along with detailed observations of biogeochemical and ecohydrological processes in individual forest stands. More recently, research in the Alptal has addressed the impacts of climate change on water supply and runoff generation. In this article, we describe, for the first time, the evolution of catchment research at Alptal, and present new analyses of long-term trends and short-term hydrologic behaviour. Hydrometeorological time series from the past 50 years show substantial interannual variability, but only minimal long-term trends, except for the ~2°C increase in mean annual air temperature over the 50-year period, and a corresponding shift towards earlier snowmelt. Similar to previous studies in larger Alpine catchments, the decadal variations in mean annual runoff in Alptal's small research catchments reflect the long-term variability in annual precipitation. In the Alptal valley, the most evident hydrological trends were observed in late spring and are related to the substantial change in the duration of the snow cover. Streamflow and water quality are highly variable within and between hydrological events, suggesting rapid shifts in flow pathways and mixing, as well as changing connectivity of runoff-generating areas. This overview illustrates how catchment research in the Alptal has evolved in response to changing societal concerns and emerging scientific questions.     

Evaluating sulfur dynamics during storm events for three watersheds in the northeastern USA: a combined hydrological,chemical and isotopic approach

Concerns related to climate change have resulted in an increasing interest in the importance of hydrological events such as droughts in affecting biogeochemical responses of watersheds. The effects of an unusually dry summer in 2002 had a marked impact on the biogeochemistry of three watersheds in the north‐eastern USA. Chemical, isotopic and hydrological responses with particular emphasis on S dynamics were evaluated for Archer Creek (New York), Sleepers River (Vermont) and Cone Pond (New Hampshire) watersheds. From 1 August to 14 September 2002, all three watersheds had very low precipitation (48 to 69 mm) resulting in either very low or no discharge (mean 0·015, 0·15 and 0·000 mm day^?1 for Archer Creek, Sleepers River and Cone Pond, respectively). From 15 September to 31 October 2002, there was a substantial increase in precipitation totals (212, 246 and 198 mm, respectively) with increased discharge. Archer Creek was characterized by a large range of SO₄^2? concentrations (152 to 389 µeq L^?1, mean = 273 µeq L^?1) and also exhibited the greatest range in δ³⁴S values of SO₄^2? (?1·4 to 8·8 ‰ ). Sleepers River's SO₄^2? concentrations ranged from 136 to 243 µeq L^?1 (mean = 167 µeq L^?1) and δ³⁴S values of SO₄^2? ranged from 4·0 to 9·0 ‰ . Cone Pond's SO₄^2? concentrations (126–187 µeq L^?1, mean = 154 µeq L^?1) and δ³⁴S values (2·4 to 4·3 ‰ ) had the smallest ranges of the three watersheds. The range and mean of δ¹⁸O‐SO₄^2? values for Archer Creek and Cone Pond were similar (3·0 to 8·9 ‰ , mean = 4·5 ‰ ; 3·9 to 6·3 ‰ , mean = 4·9 ‰ ; respectively) while δ¹⁸O‐SO₄^2? values for Sleepers River covered a larger range with a lower mean (1·2 to 10·0 ‰ , mean = 2·5). The difference in Sleepers River chemical and isotopic responses was attributed to weathering reactions contributing SO₄^2?. For Archer Creek wetland areas containing previously reduced S compounds that were reoxidized to SO₄^2? probably provided a substantial source of S. Cone Pond had limited internal S sources and less chemical or isotopic response to storms. Differences among the three watersheds in S biogeochemical responses during these storm events were attributed to differences in S mineral weathering contributions, hydrological pathways and landscape features. Further evaluations of differences and similarities in biogeochemical and hydrological responses among watersheds are needed to predict the impacts of climate change. Copyright © 2008 John Wiley & Sons, Ltd.     

Investigation of soil water hydrological process in the permafrost active layer using stable isotopes

Here, we studied the isotope characteristics and source contributions of soil water in the permafrost active layer by collecting soil samples in July 2018 in Yangtze River basin. Soil moisture and temperature showed decreasing trends from 0–80 cm, and an increasing trend from 80–100 cm. The value of δ¹⁸O and δD first increased and then decreased in the soil profile of 0–100 cm; however, d-excess increased from 0–100 cm. δ¹⁸O values became gradually positive from the southwest to northeast of the study area, while d-excess gradually increased from southeast to northwest. The evaporation water line (EL) was δD = 7.56 δ¹⁸O + 1.50 (R² = 0.90, p < 0.01, n = 96). Due to intense solar radiation and evaporation on the Tibetan Plateau, the elevation did not impact the surface soil. The altitude effect of the soil depths of 0–20 cm was not obvious, but the other soil layers had a significant altitude effect. Soil moisture and temperature were closely related to the stable isotopic composition of soil water. The contribution of precipitation to soil water on the sunny slope was 86%, while the contribution of the shady slope was 84%. However, the contribution of ground ice to soil water on sunny slope was 14% and the shady slope was 16%. The contribution of ground ice to soil water increased with increasing altitude on the sunny slope, but the contribution of ground ice to soil water had no obvious trend on the shady slope.