Raman Spectroscopy of Nb,Ta-rich Cassiterite in Beauvoir and Montebras Granites,France

Cassiterites from both the Beauvoir and Montebras geanited of France are typically rich in trace elements such as Nb and Ta, and contain quite a number of inclusions of columbite (dominantly manganocolumbite).Two thin sections of cassiterite crystals have been prepared for Raman microprobe analysis).The spectra obtained from different parts of the cassiterites show that the vibra-tion frequency of the A1g peak decreases with increasing Nb ,Ta,Fe and Mn atomic contents.It is worthy to note that a new peak (named the “An peak”) has been reported for the first time in the part with oriented columbite inclusions.The vibration frequency varies from 827 to 830 cm^-1.The presence of th enew peak may be attributed to structural changes of cassiterite due to the excess of Nb and Ta in the lattice and the exsolution of columbite inclusions in cassiterite.     

锡石中铌钽赋存形式的研究

我们曾在研究广西某地钨锡矿时,用物相分析的方法于锡石中找到了钽锰矿,为该矿的采、选、冶提供了重要的依据。 近来,我们对贵州某地花岗伟晶岩中开采出的锡石中铌钽的赋存形式做了较详细的研究工作,同时对其地球化学规律进行初步探讨。     

法国中央高原Beauvoir花岗岩中铌钽矿的带状构造:类型、化学成分和形成条件

运用扫描电子显微镜和电子探针,对法国中央高原的Beauvoir花岗岩中铌钽矿进行的研究表明,这些矿物具有多种类型的带状构造。 大部分铌钽矿具有同心带状构造和平行带状构造,前者的每一个带的宽度可在2—60μm之间变化,而后者则在1—20μm。这两种带状构造主要是由于Nb和Ta的含量的变化。它们亦可以统称为韵律式带状构造。 铌钽矿的裂隙状带状构造只见于花岗岩岩体的顶部。不规则状的带沿铌钽矿晶体的边缘或微裂隙发育,常形成树枝状构造。从化学成分上来看,这种带状构造主要是由于Fe、Mn含量的变化。因此,它亦可被称为交代构造。 铌钽矿的韵律式带状构造由Beauvoir花岗岩的复杂的结晶过程引起,主要的影响因素可能有:岩浆的化学成分和岩浆结晶的物理化学条件的周期性变化。而来自围岩(云母片岩)的富铁的热液影响了铌钽矿的结晶,导致了铌钽矿的交代构造的形成。     

某地钽铌钨铍矿化花岗岩

The tantalum-, niobium-, tungsten-, beryllium-mineralized granite described in this paper is identified as albitizied fine-grained muscovite granite and occurs as a small discordant taeolity with a bulging central part, dipping and finning out outwards.A crust of quartz-pegmatoid, several tens of centimeters thick, dsvelopes in its apices. Major rock-forming minerals are plagioclase, mierocline, albite, muscovite and quartz. Partsehinite, fluorite and topaz are characteristically abundant among accessory minerals. Rare element and base metal minerals include wolframite,scbeellte, microlite, raanganese-rich columbite, berly, phenacite, xenotirae, monazite,cassitcrite, raolybdenite, bisrauthinite, etc. Niobium and beryllium mineralizations are uniformly present throughout the rock body, but tantalum is feund richer in upper parts than in lower parts. It is tentatively suggested that this is a differentiationmctasomatic deposit of fracture-filling type originated during late magmatic stage.     

某钽铌钨铍矿化花岗岩岩石化学特征

During the magmatie evolution from biotite granite through two-mlca granite to mineralized muscovite granite it has been noted that Na^ , Mm^2 , Si^4 increase while K^ , Ca^2 , Mg^2 , Fe^2 , Fe^3 , Ti^4 , and P^5 decrease systematically in this district. Oreforming metals occur in higher abundance in biotite granite which is thought to be the representative of primary magma, and have been enriched rapidly with magmatic evolution R^ /R^2 Na^ /K^ , Rb/K, Mn/Fe and other petrochemical parameters increase whereas Ti^4 /Si^4 decreases in a sympathetic way with the enrichment of niobium and tantalum, providing good indicators of the degree of differentiation and metasematism of the magma ,Within the mineralized granite, there is a same trend of variation upward whioh is found closely related to the enrichment of tantalum. Fluorine is strongly concentrated in wall rocks above blind mineralized granite, and the eontente of tantalum and niobium in wolframite from quartz veins genetically related to the granite increase towards buried mineralization. The latter two phenomena are suggested by the author as clues to buried ore bodies.     

某含钽铌花岗岩成岩成矿温度的研究

Formation temperatures are obtained for a tantalum-niobium-bearing granite(512-530℃）,the feldspar-quartz zone(495℃）,the quartz zone(483℃）in the pegmatoid and wolframite-quartz vein(262-273℃,no pressure corection has been made through studies of fluid inclusions in quartz,wolframite,Mn-rich columbite microlite and other minerals,The results demonstrate that petrogenesis and metallogenesis of this district are a protracted,multistage process.     

湖南耒阳上堡花岗岩风化壳型铌钽矿床铌钽的赋存状态

湖南耒阳上堡花岗岩风化壳型铌钽矿床有三种类型铌钽矿石：钽铌铁矿矿石(类型Ⅰ)、铌金红石矿石(类型Ⅱ)和细晶石-钽铌铁矿矿石(类型Ⅲ)，铌钽矿床中的铌钽主要赋存在独立矿物钽铌铁矿、铌金红石、细晶石中，其次赋存在铁锂云母中。在Ⅰ类型矿石中铌钽矿物所含铌占有率为46．36％，钽为50．94％，在Ⅱ类型矿石中铌钽矿物所含铌占有率为43．37％，钽为56．44％，在Ⅲ类型矿石中铌钽矿物所含铌的占有率为48．81％，钽为66．37％。在云母中所含铌钽较高，铌占有率为5．71％～17．2％，钽为2．33％～12．52％。     

金红石和锡石的喇曼光谱研究

对我国不同地区和不同成因类型矿床的金红石和锡石及人工合成的金红石样品进行了室温下的喇曼光谱测定。每一粉末样品的喇曼图谱中都见有群论所预言的四条本征喇曼谱带。对于每一谱带的归属进行了说明。对单晶体的喇曼光谱测定说明,不同的入射和接受方向只对谱带的相对强度产生影响。     

天然及优化处理翡翠的拉曼光谱鉴定法

拉曼光谱是一种鉴定宝玉石的无损检测新技术,具有方便、快捷、准确的特点.本文通过测定和分析一系列翡翠样品的拉曼光谱,给出一种仅用拉曼光谱即可鉴定翡翠品质的方法:根据翡翠的拉曼特征峰,同时辅助拉曼光谱中反映的荧光信息来鉴别翡翠是否是天然翡翠、漂白-填充处理翡翠、有机染料染色处理翡翠、漂白-填充 有机染料处理翡翠(即商业上俗称的A货、B货、C货、B C货).     

新疆阿拉尔重熔型花岗岩的地球化学特征及构造意义

西天山地区广泛分布地壳重熔型的花岗岩,年龄多集中于300Ma左右,在时代上属于晚石炭世,阿拉尔花岗岩具有高硅低铝、富钾贫钠、准铝质,A/CNK介于0.79～1.05之间,σ在1.55～1.83之间。明显富集Rb、Th、K等大离子不相容元素,亏损Ba、Sr、P、Ti等元素,并具有弱Nb亏损,稀土元素分布曲线呈明显的＂海鸥＂型。由早侵入次到晚侵入次,有向酸碱性增强方向演化,显示重熔型花岗岩特征,形成于挤压向拉张过渡构造背景下。     

中国天山花岗岩类的时空分布及构造意义

天山花岗岩类具明显的时空分带特征,以古生代最为明显.它们可分为:1.中天山南缘中加里东期花岗岩带:2.中天山北缘晚加里东期花岗岩带;3.中天山南缘早华力西期花岗岩带;4.中天山北缘中华力西期花岗岩带;5.马宗山南缘晚华力西期花岗岩带;6.南天山南坡晚华力西期花岗岩带.在时空上,花岗岩类在中天山陆壳南、北缘呈交替分布的格局,显示出与天山陆壳南、北张合呼应、交替演化的和谐一致关系.中天山花岗岩类是几个地槽主旋回的产物.天山花岗岩带与蛇绿岩带成“对”分布,沿“中天山南缘深断裂”,及“中国天山主干断裂”两侧延伸,二者互相平行.天山花岗岩类是多成因的.分为洋壳重熔型、陆壳重熔型及洋壳陆壳混合重熔型花岗岩.     

西秦岭柴家庄、八卦山和天子山花岗岩体地球化学特征

柴家庄、八卦山和天子山花岗岩体空间上紧密共生,岩性均为二长花岗岩,岩石具富硅、过铝、贫钙的地球化学特征,属钙碱性系列。3个岩体的大离子亲石元素蛛网图和稀土元素配分曲线相关性均较好。3个岩体受印支晚期断裂构造控制,成岩时代相近,是同源岩浆演化不同期次的产物,应统称为柴家庄—八卦山—天子山岩浆带。     

湖南柿竹园钨-钼-铋-锡矿床中锡石的产状与成因

笔者通过电子探针观察在湖南省柿竹园夕卡岩型钨—钼—铋—锡矿床中找到了大量微米粒级的锡石。这些锡石在空间上与磁铁矿共生,在成因上却与早期含锡夕卡岩的交代蚀变作用有关。本文根据矿物组合特征和锡石产出形式讨论了锡石的形成过程,并且提出了本区含锡磁铁矿夕卡岩中锡石的成因模式。     

四川乡城-稻城地区花岗岩地球化学特征及构造背景探讨

四川乡城-稻城地区发育4套花岗岩体：包括石英闪长玢岩、花岗细晶岩、二长花岗（细晶）岩和花岗闪长岩,形成时代为印支期到燕山晚期。花岗岩的地球化学研究表明：w（SiO2）=57．82％～81．66％,σ=0．06～2．45,w（K2O＋Na2O）=1．38％～7．76％,AR=1．26～2．93,属于亚碱性岩体;EREE含量较低,轻稀土相对富集,δEu=0．09～1．28,（La／Yb）N=1．88～11．96,总体表现为右倾型。各套花岗岩微量元素地球化学特征差异明显,相对富集大离子亲石元素,贫化高场强元素,Rb／Sr=0．04～6．18。根据花岗岩的R1-R2,Rb—Yb＋Ta,Ta—Yb构造判别图解和区域构造演化史研究,认为二长花岗岩形成于板内构造环境,花岗细晶岩、闪长玢岩和花岗闪长岩形成于岛弧构造环境,其形成与义敦岛弧带碰撞造山活动有关。     

胶辽地块古元古代花岗岩类型及成因

据辽东半岛古元古代花岗岩详细的岩石化学、地球化学研究，表明三类古元古代花岗岩的形成环境不同，属该区古元古代构造演化不同阶段的产物，即早期花岗岩（二长花岗岩）代表造山期前裂谷化阶段的产物，中期花岗岩（斜长花岗岩）代表造山期收缩碰撞阶段的产物，晚期花岗岩（环斑花岗岩）属造山期后伸展塌隐阶段的结果。