Environmental isotopic study on the recharge and residence time of groundwater in the Heihe River Basin, northwestern China

The recharge and origin of groundwater and its residence time were studied using environmental isotopic measurements in samples from the Heihe River Basin, China. δ¹⁸O and δD values of both river water and groundwater were within the same ranges as those found in the alluvial fan zone, and lay slightly above the local meteoric water line (δD=6.87δ¹⁸O+3.54). This finding indicated that mountain rivers substantially and rapidly contribute to the water resources in the southern and northern sub-basins. δ¹⁸O and δD values of groundwater in the unconfined aquifers of these sub-basins were close to each other. There was evidence of enrichment of heavy isotopes in groundwater due to evaporation. The most pronounced increase in the δ¹⁸O value occurred in agricultural areas, reflecting the admixture of irrigation return flow. Tritium results in groundwater samples from the unconfined aquifers gave evidence for ongoing recharge, with mean residence times of: less than 36 years in the alluvial fan zone; about 12–16 years in agricultural areas; and about 26 years in the Ejina oasis. In contrast, groundwater in the confined aquifers had ¹⁴C ages between 0 and 10 ka BP.     

The hydrochemical characteristics and evolution of groundwater and surface water in the Heihe River Basin, northwest China

A combination of isotopic and chemical indicators has been used to characterize rainfall, surface water and groundwater in the Heihe River Basin, China. Surface- vs. groundwater chemistry data enabled geographical zones and chemical types to be differentiated. The dissolution of halite, Glauber’s salt, gypsum, dolomite and calcite determine Na⁺, Cl^?, Mg²⁺, Ca²⁺, $ {\text{SO}}^{{2 - }}_{4} A combination of isotopic and chemical indicators has been used to characterize rainfall, surface water and groundwater in the Heihe River Basin, China. Surface- vs. groundwater chemistry data enabled geographical zones and chemical types to be differentiated. The dissolution of halite, Glauber’s salt, gypsum, dolomite and calcite determine Na⁺, Cl⁻, Mg²⁺, Ca²⁺, and chemistry, but other processes such as evaporation, ion exchange, and deposition also influence the water composition. The majority of deep confined groundwaters are tritium-free and less mineralized than in the shallow aquifer. Radiocarbon values in the deeper groundwaters range from 18.8 to 38.9 pmc, and 80 pmc probably represents the upper limit of initial ¹⁴C activity; this yields ages of approximately 5,960–11,971 years BP, which is about 3,000 years older than those calculated by models in previous work. The shallow aquifer exhibits fairly high and variable tritium activities (4–75 TU), evidence of recent recharge and low residence time (<60 years), which is in line with estimates from previous work. Isotopic signatures indicate formation of deeper groundwaters in a colder and wetter climate during the late Pleistocene and Holocene. The results suggested that significant changes are urgently needed in water-use strategy to achieve sustainable development.

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Résumé Une combinaison de plusieurs indicateurs isotopiques et chimiques a été utilisée dans le but de caractériser les précipitations, les eaux de surface et les eaux souterraines dans le Bassin de la Rivière Heihe, en Chine. La confrontation des chimies des eaux souterraines et de surface a permis de différentier plusieurs secteurs géographiques et faciès chimiques. Les compositions chimiques en Na⁺, Cl⁻, Mg²⁺, Ca²⁺, et sont déterminées par la dissolution de la halite, du sel de Glauber, du gypse, de la dolomite et de la calcite, mais d’autres processus peuvent également avoir une influence, comme l’évaporation, les échanges de bases et la sédimentation. La majorité des eaux souterraines captives profondes ne contiennent pas de tritium, et sont moins minéralisées que dans l’aquifère superficiel. Les valeurs de carbone 14 dans l’aquifère le plus profond sont comprises entre 18.8 et 38.9 pcm, pour une valeur maximum probable d’activité initiale de 80 pcm; les ages estimés correspondants sont compris entre 5,960 et 11,971 ans, soit environ 3,000 ans de plus que ceux calculés auparavant par les modèles. L’aquifère superficiel présente des activités tritium plut?t élevées et variables (4 à 75 UT), démontrant l’existence d’une alimentation récente et d’un temps de résidence faible (<60 ans), ce qui concorde avec les études antérieures. Les signatures isotopiques indiquent une alimentation des eaux souterraines les plus profondes au cours d’épisodes climatiques plus froids et plus humides qu’actuellement, à la fin du Pléistocène et à l’Holocène. Les résultats suggèrent que des changements significatifs dans la planification des usages de l’eau sont nécessaires et urgents dans des perspectives d’exploitation durable.

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Resumen Se ha utilizado una combinación de indicadores isotópicos y químicos para caracterizar la precipitación, el agua superficial y el agua subterránea en la Cuenca del Río Heihe, China. Los datos químicos de aguas superficiales frente a las subterráneas no permiten diferenciar zonas geográficas y tipos químicos. La disolución de halita, sal de Glauber, yeso, dolomita y calcita determina la química de Na⁺, Cl⁻, Mg²⁺, Ca²⁺, y , pero otros procesos, como evaporación, intercambio de iones y precipitación influyen también en la composición del agua. La mayoría de las aguas subterráneas profundas confinadas no tienen Tritio y están menos mineralizados que el acuífero superficial. Los valores de radiocarbono en las aguas subterráneas más profundas oscilan entre 18.8 y 38.9 pmc, y el valor de 80 pmc representa probablemente el límite superior de la actividad inicial de ¹⁴C; proporcionando edades de aproximadamente 5,960–11,971 a?os BP, que son unos 3,000 a?os más antiguas de las calculadas mediante modelización en trabajos previos. El acuífero superficial tiene actividades de tritio bastante más altas y variables (4–75 UT), evidenciando una recarga reciente y unos tiempos de residencia bajos (<60 a?os), lo cual está en la línea de lo estimado en trabajos previos. Los datos isotópicos apuntan a la formación de aguas subterráneas más profundas en un clima más frío y húmedo durante el Pleistoceno superior y el Holoceno. Los resultados sugieren que se necesita hacer cambios significativos en la estrategia de uso del agua para alcanzar un desarrollo sostenible.

     

Sources of groundwater recharge at the confluence of the Niles, Sudan

 Due to the rapid expansion of the Sudanese capital city far away from its three Niles, it has become a necessity to estimate the sustainability of the groundwater resources in this arid area. The purpose of this study – based on the stable-isotopic composition of groundwater – is to identify the sources of recharge and their relative contribution. The results show that groundwater infiltrated from the Niles under the present prevailing arid climate, with greater contribution from the White Nile compared to the Blue Nile, occupies an extension of 12 km from the Niles within the two main aquifers. Paleogroundwater of meteoric origin, infiltrated in the cooler pluvial earlier Holocene, occupies the outer zones beyond the Niles' effect. A rational utilization policy is recommended to preserve the finite groundwater resources. Received: 27 August 1998 · Accepted: 2 March 1999     

Use of chloride-mass balance and environmental isotopes for evaluation of groundwater recharge in the alluvial aquifer, Wadi Tharad, western Saudi Arabia

Groundwater recharge estimation has become a priority issue for humid and arid regions, especially in regions like Saudi Arabia, where the precipitation varies over space and time as a result of topography and seasonality. Wadi Tharad is a typical arid area in western Saudi Arabia. Within its drainage area of 400 km², the groundwater system shows a graded hydrochemical zonation from the hydrocarbonate in the upper reach to the chloride zone in the lower reach. The saturation index (SI) varies depending on the concentrations of carbonate minerals; the mean for calcite and dolomite is about in equilibrium (e.g., zero value). As halite and gypsum indices are negative, it is undersaturated. Isotopic compositions of H and O in the groundwater show that the groundwater recharge resources are mainly from meteoric water. The chloride-mass balance method was refined to estimate the amount of recharge, which is probably 11% of the effective annual rainfall. These results can be used to improve the accuracy of future groundwater management and development schemes.     

Analysis of the exchange of groundwater and river water by using Radon-222 in the middle Heihe Basin of northwestern China

In arid regions of western China, water resources come from mountain watersheds and disappear in the desert plain. The exchange of surface water and groundwater takes place two or three times in a basin. It is essential to analyze the interaction of groundwater with surface water to use water resources effectively and predict the change in the water environment. The conventional method of analysis, however, measures only the flow of a stream and cannot determine groundwater seepage accurately. As the concentration of Radon-222 (²²²Rn) in groundwater is much higher than in surface water, the use of ²²²Rn was examined as an indicator for the analysis of the interaction between surface water and groundwater. Measurement of the ²²²Rn concentration in surface water was conducted to detect groundwater seepage into a stream in the middle Heihe Basin of northwestern China. Furthermore, the simultaneous groundwater flow into and out of a stream from the aquifers was quantified by solving the ²²²Rn mass balance equation, in which the losses of gas exchange and radioactive decay of ²²²Rn are considered. Meanwhile, river runoff was gauged to determine the exchange rates between surface water and groundwater. The result shows that ²²²Rn isotope can be used as a good environmental tracer with high sensitivity for the interaction between surface water and groundwater, especially in the fractured aquifer system, karst aquifer system and discharge basins.     

Using CRD method for quantification of groundwater recharge in the Gaza Strip, Palestine

Rainfall is the main source of groundwater recharge in the Gaza Strip area in Palestine. The area is located in the semi-arid zone and there is no source of recharge other than rainfall. Estimation of groundwater recharge from rainfall is not an easy task since it depends on many uncertain parameters. The cumulative rainfall departure (CRD) method, which depends on the water balance principle, was used in this study to estimate the net groundwater recharge from rainfall. This method does not require much data as is the case with other classical recharge estimation methods. The CRD method was carried out using optimisation approach to minimise the root mean square error (RMSE) between the measured and the simulated groundwater head. The results of this method were compared with the results of other recharge estimation methods from literature. It was found that the results of the CRD method are very close to the results of the other methods, but with less data requirements and greater ease of application. Based on the CRD method, the annual amount of groundwater recharge from rainfall in the Gaza Strip is about 43 million m³. An erratum to this article can be found at     

Tracing infiltration and recharge using stable isotope in Taihang Mt., North China

The groundwater in headwater region is an important recharge source for the adjacent mountain-front plain. In order to reveal the relationship among precipitation, soil water and groundwater, from June to September in 2004, stable isotopes (deuterium and oxygen-18) in precipitation and soil waters at the depths of 10, 20, 30, 50, 70, 90, and 110 cm were analyzed at two sites covered by black locust (Robinia Pseudoacia L.) (Site A) and grass predominated by Themeda triandra (T. japonica (Willd.) Tanaka) and Bothriochloa ischaemum (B. ischaemum (L.) Keng) (Site B) in an experimental catchment at Taihang Mt., North China, respectively. The δ¹⁸O of precipitation in daily rain events shows large variations (−13.3 to −4.3‰) with a mean of 8.1‰. The δ¹⁸O and δ D of soil waters along profiles in two sites suggest that the influence of canopy cover was just up to 10 cm in top soil water. The soil water moved over the zero flux plane at 70 cm in-depth is expected to escape the evaporative effect at the end of September in both sites. The results show that the stable isotope, instead of tritium as tradition, can be used to trace the soil water behaviors based on the movement of isotopic peak along the vertical profiles in this semi-arid and semi-humid mountainous region. The infiltration depths of soil water in Taihang Mt. are 12 and 10 mm/day from June to September in 2004 in Site A and Site B, respectively. Tracing by stable isotope, recharge fluxes of soil water to local groundwater are of 3.8 and 3.2 mm/day in Site A and Site B, respectively. The results provide desirable information for assessment of local groundwater resources. An erratum to this article can be found at     

Use of multiple age tracers to estimate groundwater residence times and long-term recharge rates in arid southern Oman

Multiple age tracers were measured to estimate groundwater residence times in the regional aquifer system underlying southwestern Oman. This area, known as the Najd, is one of the most arid areas in the world and is planned to be the main agricultural center of the Sultanate of Oman in the near future. The three isotopic age tracers ⁴He, ¹⁴C and ³⁶Cl were measured in waters collected from wells along a line that extended roughly from the Dhofar Mountains near the Arabian Sea northward 400 km into the Empty Quarter of the Arabian Peninsula. The wells sampled were mostly open to the Umm Er Radhuma confined aquifer, although, some were completed in the mostly unconfined Rus aquifer. The combined results from the three tracers indicate the age of the confined groundwater is < 40 ka in the recharge area in the Dhofar Mountains, > 100 ka in the central section north of the mountains, and up to and > one Ma in the Empty Quarter. The ¹⁴C data were used to help calibrate the ⁴He and ³⁶Cl data. Mixing models suggest that long open boreholes north of the mountains compromise ¹⁴C-only interpretations there, in contrast to ⁴He and ³⁶Cl calculations that are less sensitive to borehole mixing. Thus, only the latter two tracers from these more distant wells were considered reliable. In addition to the age tracers, δ²H and δ¹⁸O data suggest that seasonal monsoon and infrequent tropical cyclones are both substantial contributors to the recharge. The study highlights the advantages of using multiple chemical and isotopic data when estimating groundwater travel times and recharge rates, and differentiating recharge mechanisms.     

利用稳定同位素识别黑河流域地上水的补给来源

本文利用稳定同位素(2H和18O)及水化学方法识别黑河流域地下水的补给来源,估算黑河水与地下水的转化数量.研究结果表明,黑河流域地下水的主要补给来自山区出山河流,山前戈壁带是地下水快速补给区,中下游盆地地下水补给来源为引河灌溉和河流侧渗.黑河干流出山河水在张掖以上河段约4.4×108 m3/a渗漏补给地下水,约占出山迳流量的27%.张掖一正义峡河段道地下水向河道平均排泄量为11.4×108 m3/a,占该段河流迳流量的69%.研究成果不仅对黑河流域地下水的开发管理有着重要意义,对我国西北类似的内陆盆地地下水的开发管理有着借鉴意义.     

黑河流域地下水同位素年龄及可更新能力研究

通过对黑河流域地下水的放射性同位素如氚(T)和¹⁴C的测定, 对该流域浅层和深层地下水的年龄以及其更新速率进行了估算. 结果表明: 整体上看, 从黑河流域的上游、中游至下游, 浅层和深层地下水年龄逐渐增加, 地下水更新速率也逐渐增大. 其中, 黑河上游浅层和深层地下水平均更新速率分别为1.96%·a^-1和1.76%·a^-1, 可更新能力最强; 中游浅层和深层地下水平均更新速率为1.25%·a^-1和0.68%·a^-1, 可更新能力次之; 下游浅层和深层地下水平均更新速率分别为0.74%·a^-1和0.18%·a^-1, 可更新能力最差. 黑河流域不同地带地下水由于循环条件的不同, 浅层和深层地下水年龄存在较大的差异. 其中, 中游山前平原补给条件较好, 浅层和深层地下水年龄较小; 中、下游远离河道地区浅层和深层地下水补给条件差, 显示了更老的年龄. 黑河流域埋深40 m以上的浅层地下水平均更新速率(1.13%·a^-1)高于埋深40~100 m之间的中层地下水(0.65%·a^-1)以及埋深100 m以下深层地下水(0.55%·a^-1). 因此, 在黑河流域地下水开发过程中要合理开发浅层地下水, 适当缩减开发深层地下水.     

A catchment water balance model for estimating groundwater recharge in arid and semiarid regions of south-east Iran

This paper presents a new model of the rainfall-runoff-groundwater flow processes applicable to semiarid and arid catchments in south-east Iran. The main purpose of the model is to assess the groundwater recharge to aquifers in these catchments. The model takes into account main recharge mechanisms in the region, including subsurface flow in the valley alluvium in mountainous areas and recharge from the bed of ephemeral rivers. It deals with the effects of spatial variation in the hydrological processes by dividing the catchment into regions of broad hydrologic similarity named as highland, intermediate and aquifer areas. The model is based on the concept of routing precipitation within and through the catchment. The model has been applied to the Zahedan catchment and the results indicate that the groundwater level estimated by the recharge model generally is in agreement with the behaviour of groundwater levels in observation wells. The sensitivity analysis indicates that when the rainfall in the aquifer area is used to replace the values recorded in the intermediate area and the highland area, the recharge estimates are reduced by 42-87%. This result supports the division of the catchment into different zones of hydrological similarity to account for spatial variability of hydrological processes. Electronic Publication     

Occurrence of soluble salts and moisture in the unsaturated zone and groundwater hydrochemistry along the middle and lower reaches of the Heihe River in northwest China

Deforestation, over-development of water resources and population growth have contributed to degeneration of vegetation in the Heihe River Basin in northwest China. Salts and water contents are the most important factors affecting the growth of vegetation in this arid area. This study was conducted to determine soluble salt levels of soils in the unsaturated zone and the hydrochemistry of groundwater at 14 sites in this region. Concentrations of soluble ions in the soils deceased with depth. Soil ion contents increased at depths below the root system of native plants. Sulfate was the dominant anion in both the unsaturated zone and the groundwater. Total dissolved solids (TDS) in groundwater ranged from less than 1 g/L in the middle reaches of the watershed to about 10 g/L in the arid lower reaches. In the middle and upper reaches of the watershed, salinity in soil and groundwater decreased. Groundwater was highly variable in hydrochemistry. The lower reaches was predominated by SO₄–Na•Mg and SO₄–Mg•Na type water, whereas in the middle reaches groundwater is characterized by lower TDS and HCO₃-dominated type water. Evapotranspiration is responsible for occurrence of the soluble salts in the soil profiles. Dissolution is the dominant chemical process in the middle reaches, whereas evapotranspiration prevails in the lower reaches of the Heihe River.     

Use of hydrogeochemistry and environmental isotopes for evaluation of groundwater in Qingshuihe Basin,northwestern China

Hydrogeochemistry and environmental isotope data were utilized to understand origin, geochemical evolution, hydraulic interconnection, and renewability of groundwater in Qingshuihe Basin, northwestern China. There are four types of groundwater: (1) shallow groundwater in the mountain front pluvial fans, originating from recent recharge by precipitation, (2) deep paleo-groundwater of the lower alluvial plains, which was formed long ago, (3) shallow groundwater in the lower alluvial plains, which has undergone evaporation during the recharge process, and (4) mixed groundwater (shallow and deep groundwater in the plain). The main water types are Na–HCO₃, which dominates type (1), and Na–SO₄, which dominates types (2) and (3). Geochemical evolution in the upper pluvial fans is mainly the result of CO₂ gas dissolution, silicates weathering and cation exchange; in the lower alluvial plains, it is related to mineral dissolution. The evaporative enrichment only produces significant salinity increases in the shallow groundwater of the lower alluvial plains. Shallow groundwater age in the upper plain is 10 years or so, showing a strong renewability. Deep groundwater ages in the lower plain are more than 200 years, showing poor renewability. In the exploitation areas, the renewability of groundwater evidently increases and the circulation period is 70–100 years.     

黑河流域走廊平原地下水补给源组成及其变化

通过环境同位素、水文分割法和相关分析研究表明,祁连山区降水、冰川雪融水和基岩裂隙水通过出山口地表径流补给构成黑河流域走廊平原地下水主要补给源,具有年际和年内丰枯动态变化规律,与祁连山区降水量和气温的关联度分别为0.97和0.79,与平原张掖站降水量和气温的关联度分别为0.43和0.60。在自然径流条件下,祁连山区降水量变化是改变走廊平原地下水补给的主导因素,约占91%权重;气温变化是重要影响因素,约占9%权重。20世纪80年代以来祁连山区各补给源处于偏丰期。因此,近年来走廊平原地下水补给量相对50年代减少27.1%,人类活动是重要影响因素,急需加强科学调控。     

A simple daily soil–water balance model for estimating the spatial and temporal distribution of groundwater recharge in temperate humid areas

Quantifying the spatial and temporal distribution of natural groundwater recharge is usually a prerequisite for effective groundwater modeling and management. As flow models become increasingly utilized for management decisions, there is an increased need for simple, practical methods to delineate recharge zones and quantify recharge rates. Existing models for estimating recharge distributions are data intensive, require extensive parameterization, and take a significant investment of time in order to establish. The Wisconsin Geological and Natural History Survey (WGNHS) has developed a simple daily soil–water balance (SWB) model that uses readily available soil, land cover, topographic, and climatic data in conjunction with a geographic information system (GIS) to estimate the temporal and spatial distribution of groundwater recharge at the watershed scale for temperate humid areas. To demonstrate the methodology and the applicability and performance of the model, two case studies are presented: one for the forested Trout Lake watershed of north central Wisconsin, USA and the other for the urban-agricultural Pheasant Branch Creek watershed of south central Wisconsin, USA. Overall, the SWB model performs well and presents modelers and planners with a practical tool for providing recharge estimates for modeling and water resource planning purposes in humid areas.

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Resumen La cuantificación de la distribución espacial y temporal de la recarga natural de agua subterránea es un requisito previo para una modelación y una gestión efectivas de las aguas subterráneas. Dado que se está incrementando el uso de los modelos de flujo para la toma de decisiones de gestión, existe una necesidad creciente de métodos simples y prácticos para delimitar las zonas de recarga y cuantificar los rangos de la misma. Los modelos existentes para la estimación de la distribución de la recarga requieren datos intensivos, una parametrización extensiva y una inversión de tiempo significativa para ser establecidos. El Servicio Geológico y de Historioa Natural de Wisconsin (WGNHS) ha desarrollado un modelo simple de balance diario de agua en el suelo (SWB) que usa de forma sencilla datos disponibles de suelo, de cobertera, topográficos y climáticos conjuntamente con un Sistema de Información Geográfica (GIS) para estimar la distribución espacial y temporal de la recarga de aguas subterráneas a escala de cuenca para zonas templadas húmedas. Para demostrar la metodología, aplicabilidad y el comportamiento del modelo, se presentan dos casos: uno en la cuenca boscosa de Trout Lake, en la zona Norte-Central de Wisconsin, USA y el otro en la Cuenca urbano-agrícola de Pheasant Branch Creek, Sur-Centro de Winconsin, USA. En conjunto, el modelo SWB funciona bien y presenta a los modeladores y planificadores una herramienta práctica para llevar a cabo una estimación de la recarga para propósitos de modelación y planificación de los recursos de agua en zonas húmedas.

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Résumé Quantifier les distributions temporelle et spatiale de la réalimentation naturelle des eaux souterraines est en règle générale un préalable à une modélisation et une gestion efficaces des eaux souterraines. Etant donné que les modèles numériques sont utilisés de manière croissante dans les prises de décisions en matière de gestion, il existe un besoin accru pour des méthodes simples et pratiques, afin de délimiter les zones d’alimentation et de quantifier les recharges associées. Les modèles existants, destinés à l’estimation de la répartition des réalimentations, demandent énormément de données, un paramétrage long, et un investissement conséquent en temps de mise en œuvre. Le Wisconsin Geologic and Natural History Survey (WGNHS) a développé un modèle simple basé sur un bilan en eau quotidien dans les sols (SWB); il utilise les données directement disponibles sur les sols, l’occupation des sols, la topographie et le climat, en conjonction avec un Système d’Information Géographique, afin d’estimer les distributions temporelle et spatiale de la réalimentation des eaux souterraines à l’échelle du bassin versant, pour les zones humides tempérées. Afin de démontrer la méthodologie, l’applicabilité et les performances du modèle, deux applications sont présentées: la première sur le bassin versant boisé de Trout Lake au centre-nord du Wisconsin (Etats-Unis), et le second sur le bassin versant agricole et urbanisé de Pheasant Branch Creek au centre-sud du Wisconsin. Le modèle SWB se comporte globalement bien, et offre aux modélisateurs un outil fonctionnel pour estimer les réalimentations, dans le cadre de modélisations et de plans de gestion des ressources en eau souterraine dans les zones humides.

     

Determining the seasonality of groundwater recharge using water isotopes: a case study from the upper North Han River basin,Korea

The stable isotopes of oxygen and hydrogen were used to determine the seasonal contributions of precipitation to groundwater recharge at a forested catchment area in the upper North Han River basin, Korea. A comparison of the stable isotopic signatures of groundwater and precipitation indicates that the precipitations which occurred during both the dry and rainy seasons are the important source of groundwater recharge in this region. A stable isotopic signature shown in the stream waters at the upstream reaches is similar to that of groundwaters, indicating that stream waters are mostly fed by groundwater discharge. Reservoir waters in the downstream flood control dams have lower deuterium excess values or d-values compared with those of the upstream waters, indicating a secondary evaporative enrichment. These results can provide a basis for the effective management of groundwater and stream water resources in the North Han River basin.     

Hydrochemical tracers in the middle Rio Grande Basin,USA: 1. Conceptualization of groundwater flow

Chemical and isotopic data for groundwater from throughout the Middle Rio Grande Basin, central New Mexico, USA, were used to identify and map groundwater flow from 12 sources of water to the basin, evaluate radiocarbon ages, and refine the conceptual model of the Santa Fe Group aquifer system.Hydrochemical zones, representing groundwater flow over thousands to tens of thousands of years, can be traced over large distances through the primarily siliciclastic aquifer system. The locations of the hydrochemical zones mostly reflect the modern predevelopment hydraulic-head distribution, but are inconsistent with a trough in predevelopment water levels in the west-central part of the basin, indicating that this trough is a transient rather than a long-term feature of the aquifer system. Radiocarbon ages adjusted for geochemical reactions, mixing, and evapotranspiration/dilution processes in the aquifer system were nearly identical to the unadjusted radiocarbon ages, and ranged from modern to more than 30 ka. Age gradients from piezometer nests ranged from 0.1 to 2 year cm^–1 and indicate a recharge rate of about 3 cm year^–1 for recharge along the eastern mountain front and infiltration from the Rio Grande near Albuquerque. There has been appreciably less recharge along the eastern mountain front north and south of Albuquerque.

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Resumen Se utilizaron datos químicos e isotópicos de agua subterránea a lo largo de la cuenca central del río Grande, Nuevo México, EEUU, para identificar y mapear el flujo de agua subterránea de 12 fuentes de agua a la cuenca para evaluar edades por medio de radio carbon y para refinar el modelo conceptual del sistema acuífero del Grupo Santa Fé. Se puede establecer zonas hidrotérmicas que representan el flujo de agua subterránea a lo largo de miles a miles de decenas de años en grandes distancias a través del sistema acuífero principalmente siliclástico. Las ubicaciones de las zonas hidroquímicas mayormente reflejan la distribucion de la cabeza hidráulica pre-desarollo moderna pero son inconsistentes con una depresión en los niveles de agua pre-desarollo en la zona central oeste de la cuenca. Esto indica que esta depresión es un rasgo transitorio y no un rasgo de largo plazo del sistema acuífero. Las edades de radio carbon ajustadas para los procesos de reaciones geoquímicas, de mezclado y de evapotranspiración-dilución son casi idénticas a los edades de radio carbon no ajustadas oscilan en un rango desde la modernidad a 30 mil años. Las gradientes de edad de nidos de piezometros van de 0.1 a 2 años cm^–1 e indican un sitio de recarga de aproximadamente 3 cm/yr para la recarga a lo largo del frente montañoso oriental e infiltración del río Grande cerca de Albuquerque. Se aprecia una recarga menor a lo largo del frente oriental de montañas al norte y al sur de Albuquerque.

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Résumé Des données sur les éléments chimiques et les isotopes présents dans leau souterraine prélevée à divers endroits dans le bassin moyen du Rio Grande, au centre du Nouveau-Mexique (É-U), ont permis de déterminer lexistence et létendue de douze sources deau régionales dans le bassin, dévaluer les âges radiocarbones et de raffiner le modèle conceptuel du système aquifère du groupe de Santa Fe. Des zones hydro-chimiques qui représentent lécoulement de leau souterraine depuis des dizaines de milliers dannées peuvent être suivies sur de longues distances à travers laquifère principalement siliclastique. La position des zones hydro-chimiques reflète principalement la distribution moderne des charges hydrauliques mais est incohérente avec une dépression dans le niveau deau dans la partie centre-ouest du bassin, ce qui indique que cette dépression est un élément transitoire du système aquifère plutôt quun élément à long terme. Les âges radiocarbones ajustés aux réactions géochimiques et aux processus de mélange et dévapotranspiration/dilution qui ont lieu dans laquifère sont presque identiques aux âges non ajustés et varient de la période moderne jusquà 30 ka. Les gradients dâge établis à partir des nids de piézomètres sétendent de 0.1 à 2 a cm^–1 et suggèrent un taux de recharge denviron 3 cm a^–1 le long du front des montagnes à lest et pour linfiltration provenant du Rio Grande près dAlbuquerque. Il y a eu substantiellement moins de recharge le long du front des montagnes à lest, au nord et au sud dAlbuquerque.

     

Application of environmental groundwater tracers at the Sulphur Bank Mercury Mine, California, USA

Boron, chloride, sulfate, δD, δ¹⁸O, and ³H concentrations in surface water and groundwater samples from the Sulphur Bank Mercury Mine (SBMM), California, USA were used to examine geochemical processes and provide constraints on evaporation and groundwater flow. SBMM is an abandoned sulfur and mercury mine with an underlying hydrothermal system, adjacent to Clear Lake, California. Results for non-³H tracers (i.e., boron, chloride, sulfate, δD, and δ¹⁸O) identify contributions from six water types at SBMM. Processes including evaporation, mixing, hydrothermal water input and possible isotopic exchange with hydrothermal gases are also discerned. Tritium data indicate that hydrothermal waters and other deep groundwaters are likely pre-bomb (before ~1952) in age while most other waters were recharged after ~1990. A boron-based steady-state reservoir model of the Herman Impoundment pit lake indicates that 71–79% of its input is from meteoric water with the remainder from hydrothermal contributions. Results for groundwater samples from six shallow wells over a 6–month period for δD and δ¹⁸O suggests that water from Herman Impoundment is diluted another 3% to more than 40% by infiltrating meteoric water, as it leaves the site. Results for this investigation show that environmental tracers are an effective tool to understand the SBMM hydrogeologic regime.

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Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users.

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Résumé Les concentrations en bore, chlorure, sulfate, δD, δ¹⁸O, et ³H d’échantillons d’eaux de surface et souterraine prélevés dans le banc de soufre de la mine de mercure (SBMM en anglais) en Californie, USA, ont été utilisées pour étudier les processus géochimiques et pour fournir des contraintes à l’évaporation et à l’écoulement des eaux souterraines. La SBMM est une mine de soufre et de mercure abandonnée, adjacente au lac Clear en Californie et sous laquelle se trouve un système hydrothermal.Les résultats des traceurs autres que le tritium (bore, chlorure, sulfate, δD, et δ¹⁸O) ont permis d’identifier des contributions de six types d’eaux à SBMM. Des processus tels que l’évaporation, le mélange, l’entrée d’eau hydrothermale et de possibles échanges isotopiques avec des gaz hydrothermaux ont également été identifiés. Les données de tritium montrent que les eaux hydrothermales et d’autres eaux profondes sont probablement d’age antérieure à la bombe (avant ~1952), alors que la plupart des autres eaux sont issues de la recharge après ~1990. Un modèle de réservoir représentant le lac situé dans la partie Herman Impoundment de l’ancienne mine, en régime permanent et basé sur le bore, montre que 71–79% de l’eau provient des précipitations, le reste provenant de contributions hydrothermales. Les résultats de δD et δ¹⁸O pour des échantillons d’eau souterraine de six puits peu profonds sur une période de 6 mois suggèrent que l’eau de Hermann Impoundment est encore diluée entre 3% jusqu’à plus de 40% lorsqu’elle quitte le site du fait de l’infiltration d’eau météorique. Les résultats de cette étude montrent que les traceurs environnementaux constituent un outil efficace pour comprendre le régime hydrogéologique de la SBMM.

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Resumen Se han utilizado datos de concentraciones de boro, cloruros, sulfatos, δD, δ¹⁸O, y ³H en muestras de aguas superficiales y subterráneas procedentes de la Mina de Mercurio Sulphur Bank (SBMM), California, USA, para estudiar los procesos geoquímicos y caracterizar la evaporación y el flujo del agua subterránea. SBMM es una mina abandonada de azufre y mercurio con un sistema hidrotermal subyacente, cercano al Lago Clear, California.Los resultados de los trazadores que no son ³H (por ejemplo, boro, cloruros, sulfatos δD, y δ¹⁸O) identifican las contribuciones de seis tipos de agua en la SBMM. Se han identificado diversos procesos, como evaporación, mezcla, entrada de agua hidrotermal y la posibilidad de intercambios isotópicos con gases hidrotermales. Los datos de tritio indican que las aguas hidrotermales y otras aguas subterráneas profundas son probablemente pre-bombas (previas a ~1952) en edad mientras que la mayoría de las otras aguas se han recargado después de ~1990. Un modelo estacionario basado en el boro de la fosa del lago Herman Impoundment indica que el 71–79% de su entrada procede de agua meteórica con restos de contribución hidrotermal. Los resultados para las muestras de aguas subterráneas procedentes de seis pozos superficiales en un periodo de 6 meses para δD y δ¹⁸O sugieren que el agua procedente de Herman Impoundment se diluye en otro 3% hasta más del 40% debido a la infiltración de agua meteórica., que sale del sitio. Los resultados de esta investigación muestran que los trazadores ambientales son una herramienta efectiva para entender el régimen hidrogeológico de la SBMM.

     

Groundwater recharge and discharge processes in the Jakarta groundwater basin, Indonesia

Proper management of groundwater resources requires knowledge of the processes of recharge and discharge associated with a groundwater basin. Such processes have been identified in the Jakarta groundwater basin, Indonesia using a theory that describes the simultaneous transfer of heat and fluid in a porous medium. Temperature-depth profiles in monitoring wells are used to determine the geothermal gradient. To examine the rules of groundwater flow in the distortion of the isotherms in this area, several methods are compared. Subsurface temperature distribution is strongly affected by heat advection due to groundwater flow. Under natural flow conditions, the recharge area is assumed to occur in the hills and uplands, which are located on the periphery of the Jakarta basin, and the discharge area is located in the central and northern part of the Jakarta groundwater basin. A transition area, which could act as local recharge and discharge areas, occupies the middle of the lowland. Subsurface temperatures show good correlation with the groundwater flow conditions, and the data yield important information on the location of recharge and discharge areas.     

Nitrate pollution of groundwater in the Yellow River delta,China

Nitrate pollution of groundwater in the Yellow River delta, China is an important issue related not only to nitrate dispersion and health concerns but also to mass transport and interactions of groundwater, sea, and river waters in the coastal area. The spatial distribution of nitrate, nitrate sources, and nitrogen transformation processes were investigated by field surveys and geochemical methods. Nitrate occurred mainly in shallow layers and had a spatial distribution coinciding with geomorphology and land/water use. Irrigation water from the Yellow River and anthropogenic waste are two main nitrogen sources of nitrate in the delta, and both denitrification and mixing processes could take place according to characteristics identified by ionic and isotopic data.