Inorganic bedded cherts from the Magadi area,Kenya

The High Magadi beds can be divided into a lower and an upper sequence, separated by a bed rich in Tilapia nilotica remains. The lower sequence contains one or more magadiite horizons. Through digging of trenches it has been possible to establish that the cherts of the Chert Series are stratigraphically equivalent to the magadiite horizons. The transition magadiite-chert has been observed in many places and may occur over a distance of less than 50 cm. It is accomplished by removal of sodium by percolating waters. The resulting bedded chert may preserve the fine lamination present in magadiite. The conversion is accompanied by many textural and structural features such as large desiccation polygons, buckling, reticulation, extrusion, casts of mud-cracks and calcite.The precipitation of magadiite is postulated to have taken place in annual increments in a stratified lake at the brine-epilimnion interface. The maximum duration is estimated at 4,000–6,000 years. Solubility measurements indicate that most Magadi waters at the present time are supersaturated with respect to magadiite and kenyaite, though no precipitation has been observed. The presence of chert chips in intraformational gravels indicates that the conversion to chert was already initiated during the magadiite precipitation interval.The inorganic mechanism for the formation of bedded chert observed at Magadi is suggested to apply also to the Dales Gorge Member of the Precambrian Brockman Iron Formation of W. Australia. Evidence for magadiite as chert precursor is found in the depositional rates, the presence of riebeckite and in textures such as macules and cross-pods. The proposed model is extended to include Precambrian banded iron formations in general and the restriction of these formations to the early history of the earth is explained by the likely compositions of waters from closed basins.     

A Brine Evolution Model and Mineralogy of Chemical Sediments in a Volcanic Crater,Lake Kitagata,Uganda

Lake Kitagata, Uganda, is a hypersaline crater lake with Na–SO₄–Cl–HCO₃–CO₃ chemistry, high pH and relatively small amounts of SiO₂. EQL/EVP, a brine evaporation equilibrium model (Risacher and Clement 2001), was used to model the major ion chemistry of the evolving brine and the order and masses of chemically precipitated sediments. Chemical sediments in a 1.6-m-long sediment core from Lake Kitagata occur as primary chemical mud (calcite, magadiite [NaSi₇O₁₃(OH)₃·3H₂O], burkeite [Na₆(CO₃)(SO₄)₂]) and as diagenetic intrasediment growths (mirabilite (Na₂SO₄·10H₂O)). Predicted mineral assemblages formed by evaporative concentration were compared with those observed in salt crusts along the shoreline and in the core from the lake center. Most simulations match closely with observed natural assemblages. The dominant inflow water, groundwater, plays a significant role in driving the chemical evolution of Lake Kitagata water and mineral precipitation sequences. Simulated evaporation of Lake Kitagata waters cannot, however, explain the large masses of magadiite found in cores and the formation of burkeite earlier in the evaporation sequence than predicted. The masses and timing of formation of magadiite and burkeite may be explained by past groundwater inflow with higher alkalinity and SiO₂ concentrations than exist today.     

Geomorphic,hydroclimatic and hydrothermal controls on the formation of lithium brine deposits in the Qaidam Basin,northern Tibetan Plateau,China

Qaidam Basin is a hyperarid inland basin with an area of 121 × 10³ km² located on the northern Tibetan Plateau. Today, one fourth of the basin is covered by playas and hypersaline lakes. Nearly 80% of brine lithium found in China is contained in four salt lakes: Bieletan (BLT), DongTaijinaier (DT), XiTaijinaier (XT) and Yiliping (YLP). In the past decade, great attention was paid to improving the technology for the extraction of lithium from the brine deposits, but studies on origin and mode of formation of the brine deposits remained limited. Our recent investigations found that: (1) ~ 748.8 t of lithium was transported annually into the lower catchment of the four salt lakes via the Hongshui–Nalinggele River (H–N River), the largest river draining into the Qaidam Basin, (2) Li⁺-rich brines are formed only in salt lakes associated with inflowing rivers with Li⁺ concentrations greater than 0.4 mg/L, and (3) the water Li⁺ concentration is positively correlated with both the inflowing river and the associated subsurface brine, including saline lakes with low lithium concentrations. These findings clearly indicate that long-term input of Li⁺ from the H–N River controls the formation of lithium brine deposits. Here we determine that the source of the lithium is from hydrothermal fields where two active faults converge in the upper reach of the Hongshui River. The hydrothermal fields are associated with a magmatic heat source, as suggested by the high Li⁺ and As^3 + content water from geysers. Based on the assumption of a constant rate of lithium influx, we estimate that the total reserves of lithium were likely formed since the postglacial period. Our data indicate that lithium reserves in each of the four salt lakes depend on the influx of Li⁺-bearing water from the H–N River. The data also suggest that during the progradation of the alluvial Fan I, the H–N River drained mostly into the BLT salt lake until the Taijinaier River shifted watercourse to the north and began to feed the salt lakes of the DT, XT and YLP, alongside with the Fan II progradation. The inference is consistent with stratigraphic evidence from the sediment cores of the four salt lakes. One of the major findings of our work is the importance of the contrasting hydroclimatic conditions between the high mountains containing ice caps and the terminal salt lakes. The greater than 4000 m of relief in the watershed enables a massive amount of ions, such as K⁺, to be weathered and transported together with detrital material from the huge, relatively wet alpine regions to the hyperarid terminal basins, where intense evaporation rapidly enriches the lake water, resulting in evaporite deposition and associated K⁺- and Li⁺-rich brine deposits.     

内陆湖盆"深水成盐"形成条件和识别标志:以东濮凹陷与现代盐湖为例

位于我国东部的许多新生代盆地,在地质历史时期发育了巨厚的岩盐沉积。尽管这些盆地的成盐模式研究已经历了40多年,但由于缺乏“深水成盐”的现代沉积模式,到底是“深盆-深水”还是“深盆-浅水”成盐,一直难以定论。为了理解“深水成盐”的控制因素,很多现代盐湖开展了水文学和水化学调查,然而这些湖盆的矿物组合各不相同,“深水成盐”的形成条件和控制因素尚不清楚。本文对死海、佛瑞湖等“深水成盐”的现代盐湖以及我国东濮凹陷沙三段的成盐特征进行了解剖,从盐度、水深、湖平面波动以及卤水分层等角度探讨了“深水成盐”的形成条件,对比分析了“深水成盐”的相对位置以及沉积物特征,总结了“深水成盐”的识别标志。研究表明,盐岩层系在岩心和测井资料上显示出多尺度的旋回性。“深水成盐”为水深较大的洼陷中心成盐,与盆缘的“浅水成盐”同盆共存。沉积相对岩盐层系的结构和组成有明显的控制作用,其中洼陷带的“深水成盐”,主要在洼陷带的卤水-湖底沉积物界面附近,析出和增生粗晶的盐类矿物,常与富含有机质和黄铁矿的暗色泥岩共存;而湖滨附近的“浅水成盐”,单层厚度薄,结晶粒度细小,通常含有较多的陆源碎屑。死海为代表的现代盐湖以及东濮凹陷等古代成盐盆地的沉积特征表明,“深水成盐”发生于湖平面的下降期,而且卤水剖面的厚度对蒸发岩的形成分布有明显的控制作用,同时具有“深水”和“深盆”特征的内陆盐湖更容易形成单层厚度大、横向稳定的岩盐沉积。本研究有助于改变人们以往对内陆湖盆成盐机理的认知,尤其是现代盐湖的卤水分层析盐特征,对解读地质历史中的其他成盐事件具有重要启示。基于现代沉积实例的“深水成盐”识别标志,可以为古代岩盐沉积模式的建立提供限定条件。     

Petrology and geochemistry of chert on the marginal zone of Yangtze Platform,western Hunan,South China,during the Ediacaran–Cambrian transition

The Ediacaran–Cambrian transition was one of the most critical intervals in Earth history. During this interval, widespread chert was precipitated, commonly as a stratal wedge in carbonates, along the southern margin of the Yangtze Platform, South China. The chert wedge passes into a full chert succession further basinward to the south‐east. Four lithotypes of chert are identified across the marginal zone in western Hunan: mounded, vein, brecciated and bedded chert. The mounded chert is characterized by irregular to digitiform internal fabrics, generally with abundant original vesicles and/or channels that mostly are lined by botryoidal chalcedony cements with minor quartz and barite crystals. The host chert (or matrix) of these mounds is dominated by amorphous cryptocrystalline silica, commonly disseminated with pyrite. The vein chert, with minor quartz locally, generally cross‐cuts the overlying dolostone and chert horizons and terminates under the mounded and/or bedded chert bodies. The brecciated chert commonly occurs as splayed ‘intrusions’ or funnel‐shaped wedges and cross‐cuts the topmost dolostones. The bedded chert, the most common type, generally is thin to medium‐bedded and laminated locally; it is composed of amorphous silica with minor amounts of black lumps. Microthermometry of fluid inclusions from vein and void‐lining minerals (mainly quartz and barite) revealed homogenization temperatures from 120 to 180°C for the trapped primary fluids. Compositionally, these chert deposits generally are pure, with SiO₂ > 92 wt%, and only minor Fe₂O₃ and Al₂O₃ contents, most of which show positive Europium anomalies in rare earth element patterns, especially for the mounded chert. All these data suggest that the marginal zone chert deposits resulted from a low‐temperature, silica‐rich hydrothermal system, in which the mounded chert was precipitated around the releasing vents, i.e. as silica chimneys. The vein and splayed brecciated chert, however, was formed along the syndepositional fault/fracture conduits that linked downward, while the bedded chert was precipitated in the quieter water column from the fallout of hydrothermal plumes onto the sea floor. These petrological and geochemical data provide compelling evidence and a new clue to the understanding of the extensive silica precipitation; rapid tectono‐depositional and oceanic changes during the Ediacaran–Cambrian transition in South China.     

Radiolarian Age of Chert-hosted Bedded Manganese Deposits from the Gen-otani Mine in the Tamba District, Northern Kyoto City, Japan

Abstract. Numerous bedded manganese deposits sporadically distributed throughout the Tamba district, southwestern Japan are intercalated within chert sequence. It is well known that radiolarian remains are commonly included in both bedded manganese deposits and host cherts. The Gen‐otani mine, one of these deposits, is located at Otani, Keihoku‐Shimonaka, northern Kyoto City. Chemical composition and age of the chert sequence at the mine were examined. Mainly according to SiO₂ and MnO contents together with lithology, the chert sequence is divided into three sections; lower massive chert, middle bedded manganese deposit and upper bedded chert sections. Radiolarian faunas consisting of middle Jurassic species such as Eucyrtidiellum unumaense, Dictyomitrella(?) kamoensis, Parvicingula dhimenaensis, Sethocapsa aitai, Sethocapsa kodrai, Transhsuum brevicostatum, Tricolocapsa plicarum, Unuma echinatus and others were extracted from both the middle manganese section and overlying bedded chert of the upper section. This examination reveals that the bedded manganese deposit at the Gen‐otani mine formed until Bajocian to early Bathonian (middle Middle Jurassic) in age.     

Nodular chert from the Arbuckle Group, Slick Hills, SW Oklahoma: a combined field, petrographic and isotopic study

Nodular chert from the middle and upper Arbuckle Group (Early Ordovician) in the Slick Hills, SW Oklahoma, was formed by selective replacement of grainstones, burrow fillings, algal structures, and evaporite nodules. Chert nodules are dominantly microquartz with minor fibrous quartz (both quartzine and chalcedony), megaquartz, and microflamboyant quartz. Lepisphere textures of an opal-CT precursor are preserved in many (especially in finely-crystalline) chert nodules. The δ¹⁸O values of microquartz chert range from +23.4 to + 28.8^0/00 (SMOW), significantly lower than those of Cenozoic and Mesozoic microquartz chert formed both in the deep sea and from near-surface sea water. The δ¹⁸O values of chert decrease with increasing quartz crystal size. Silicification in the Arbuckle Group occurred during early diagenesis, with the timing constrained by the relative temporal relationships among silicification, burial compaction, and early dolomite stabilization. Silica for initial chert nucleation may have been derived from both dissolution of sponge spicules and silica-enriched sea water. Chert nucleation appears to have been controlled by the porosity, permeability, and organic matter content of precursor sediments. This conclusion is based on the fact that chert selectively replaced both porous grainstones and burrows and algal structures enriched in organic matter. Growth of chert probably occurred by a maturation process from opal-A(?), to opal-CT, to quartz, as indicated by the presence of opal-CT precursor textures in many chert nodules. Although field and petrographic evidence argues for an early marine origin for chert in the Arbuckle Group, the light δ¹⁸O values are inconsistent with this origin. Meteoric resetting of the δ¹⁸O values of the chert during exposure of the carbonate platform best explains the light δ¹⁸O values because: (i) the δ¹⁸O values of chert nodules decrease with decreasing δ¹⁸O values of host limestones, and (ii) chert nodules from early dolomite, which underwent more extensive meteoric modification than associated limestones, have lighter δ¹⁸O values than chert nodules from limestones. Increasing recrystallization of chert nodules by meteoric water resulted in progressive ¹⁸O depletion and (quartz) crystal enlargement.     

Spatial and temporal geochemical variability in lacustrine sedimentation in the East African Rift System: Evidence from the Kenya Rift and regional analyses

Many previous studies on lacustrine basins in the East African Rift System have directed their attention to climatic controls on contemporary sedimentation or climate change as part of palaeoenvironmental reconstruction. In contrast, this research focuses on the impact of tectonism and volcanism on rift deposition and develops models that help to explain their roles and relative importance. The study focuses on the spatial and temporal variability in bulk sediment geochemistry from a diverse range of modern and ancient rift sediments through an analysis of 519 samples and 50 major and trace elements. The basins examined variously include, or have contained, wetlands and/or shallow to deep, fresh to hypersaline lakes. Substantial spatial variability is documented for Holocene to modern deposits in lakes Turkana, Baringo, Bogoria, Magadi and Malawi. Mio‐Pleistocene sediments in the Central Kenya Rift and Quaternary deposits of the southern Kenya Rift illustrate temporal variability. Tectonic and volcanic controls on geochemical variability are explained in terms of: (i) primary controlling factors (faulting, subsidence, uplift, volcanism, magma evolution and antecedent lithologies and landscapes); (ii) secondary controls (bedrock types, rift shoulder and axis elevations, accommodation space, meteoric and hydrothermal fluids and mantle CO ₂); and (iii) response factors (catchment area size, orographic rains, rain shadows, vegetation densities, erosion and weathering rates, and spring/runoff ratios). The models developed have, in turn, important implications for palaeoenvironmental interpretation in other depositional basins.     

Petrology of palagonite tuffs of Koko Craters,Oahu, Hawaii

Tuff deposits of the Koko Crater group consist largely of alkali basalt glass, either fresh or palagonitized. Most of the deposits are progressively palagonitized at depth, and topographic relations of palagonite on Koko Crater indicate that the palagonite was formed after the cone had been deeply eroded.The principal authigenic minerals in the palagonite tuffs were deposited in following sequence: phillipsite, chabazite, analcime, montmorillonite together with opal, and calcite. The amount of authigenic minerals in a given sample is generally proportional to the amount of palagonite, indicating that the authigenic minerals are produced in palagonitization of glass.Chemical analyses of sideromelane and associated palagonite by the electron microprobe show that about a quarter of the SiO₂, half of the Al₂O₃ and MgO, and three quarters or more of the CaO, Na₂O, and K₂O are lost in converting sideromelane to an equal volume of palagonite. A substantial proportion of these components lost from the sideromelane are precipitated nearby in zeolites, montmorillonite, opal, and calcite.Reaction of sideromelane with percolating ground water at low temperatures accounts for the vertical zoning from relatively fresh tuffs down into palagonite tuffs. The pH and ionic strength of percolating water probably increased with depth by solution and hydrolysis of glass, and where the pH and ionic strength became sufficiently high, the glass reacted to form palagonite and zeolites. Palagonite was formed by a microsolution-precipitation mechanism rather than by hydration or devitrification.     

The role of hydrothermal fluids in sedimentation in saline alkaline lakes: Evidence from Nasikie Engida,Kenya Rift Valley

Saline alkaline lakes that precipitate sodium carbonate evaporites are most common in volcanic terrains in semi‐arid environments. Processes that lead to trona precipitation are poorly understood compared to those in sulphate‐dominated and chloride‐dominated lake brines. Nasikie Engida (Little Magadi) in the southern Kenya Rift shows the initial stages of soda evaporite formation. This small shallow (<2 m deep; 7 km long) lake is recharged by alkaline hot springs and seasonal runoff but unlike neighbouring Lake Magadi is perennial. This study aims to understand modern sedimentary and geochemical processes in Nasikie Engida and to assess the importance of geothermal fluids in evaporite formation. Perennial hot‐spring inflow waters along the northern shoreline evaporate and become saturated with respect to nahcolite and trona, which precipitate in the southern part of the lake, up to 6 km from the hot springs. Nahcolite (NaHCO₃) forms bladed crystals that nucleate on the lake floor. Trona (Na₂CO₃·NaHCO₃·2H₂O) precipitates from more concentrated brines as rafts and as bottom‐nucleated shrubs of acicular crystals that coalesce laterally to form bedded trona. Many processes modify the fluid composition as it evolves. Silica is removed as gels and by early diagenetic reactions and diatoms. Sulphate is depleted by bacterial reduction. Potassium and chloride, of moderate concentration, remain conservative in the brine. Clastic sedimentation is relatively minor because of the predominant hydrothermal inflow. Nahcolite precipitates when and where pCO₂ is high, notably near sublacustrine spring discharge. Results from Nasikie Engida show that hot spring discharge has maintained the lake for at least 2 kyr, and that the evaporite formation is strongly influenced by local discharge of carbon dioxide. Brine evolution and evaporite deposition at Nasikie Engida help to explain conditions under which ancient sodium carbonate evaporites formed, including those in other East African rift basins, the Eocene Green River Formation (western USA), and elsewhere.     

内蒙古伊克昭盟现代碱湖区矿层的矿物组成及分布特征

内蒙伊克昭盟是我国现代碱湖分布最集中的地区,各碱湖矿层的主要盐类矿物是泡碱,其次是芒硝,天然碱和石盐及少量单斜钠钙石,氯碳钠镁石,钙水碱和水碱。泡碱普遍存在于各个碱湖的矿层中,芒硝主要存在于西部碱湖的矿层中,天然碱集中分嘏于碱湖区西南部的几个碱湖中,且只分布于矿层的某些部位,碱湖矿层剖面上,天然碱与芒硝呈互为消长关系,天然碱和石盐则呈正相关。     

Antidune and chute and pool structures in the base surge deposits of the Laacher See area, Germany

Grey tuffs of late Pleistocene age form broad fans radiating from the Laacher See basin. They were derived from phreatomagmatic outbursts, and transported in turbulent pyroclastic flows, in contrast with the underlying white pumice tuffs of air fall origin. Flow origin of the grey tuffs is inferred from the well-bedded plane parallel to cross-bedded tephra characteristic of base surge deposits, and a variety of other sedimentary structures, as well as grain size distributions. We recognize a tentative sequence of five main kinds of dune structures or cross-bedded strata. With some reservations these may be compared with the high flow-regime alluvial bedforms produced experimentally in flumes. Most of the cross-bedded structures in the Laacher See deposits resemble antidunes, with steep stoss sides and very low-dipping lee sides. Upcurrent migration of antidune crests is dominant close to the source, but changes to downcurrent migration at greater distances, presumably because of decay in flow energy. The most spectacular cross-bedding is somewhat similar to chute and pool structures formed under experimental condition in alluvial flumes, but not recognized in ancient sedimentary rocks. We suggest that these structures of the Laacher See tuffs formed during deposition from phreatic pyroclastic flows of very high flow energy and high sediment concentration. The antidunes apparently formed at lesser flow velocity than chute and pool structures, although interpretation of velocity conditions by examination of the deposits is difficult because of other factors such as the cohesiveness of wet material erupted by explosive phreatic volcanic activity. The large wave lengths of the dune-like structures, however, suggest unusually high velocities. The Laacher See magmas were of phonolitic to tephritic composition, and may have erupted with greater explosive energy and in greater volume than comparable basaltic eruptions.     

Kaolin deposits in the lower cretaceous Baqueró formation (Santa Cruz Province, Patagonia, Argentina)

Sedimentary kaolin deposits in the Lote 18 area (Santa Cruz Province, Patagonia, Argentina) have been mined since 1951. They constitute 30% of the country's production and are mainly used in the ceramic whiteware industry. The deposits belong to the Baqueró Formation (Lower Cretaceous) and unconfomably overlie either the ash-flow tuffs of the Chon-Aike Formation (Middle Jurassic), which are altered to kaolinite and minor illite, or the ash-fall tuffs of Bajo Grande Formation (Upper Jurassic-Lower Cretaceous), which are altered mainly to smectites. The presence of illite or smectite, as well as the kaolinite crystallinity, depends on the stratigraphic position of the kaolin horizons within the Lower Member of the Baqueró Formation and on the lithology of the underlying rocks. Kaolin beds composed of well-crystallized kaolinite at the base of the sequence overlaying Chon-Aike rocks are the purest. Kaolinite becomes less well cystallized with transport. Edge-to-face and swirl SEM textural patterns indicate the compaction of flocculated clays and clay movement during drainage and compaction. Mineralogical, petrological, and physico-structural evidence (i.e., form, extent, thickness) indicates that the kaolin deposits are sedimentary, formed by the transportation and deposition of previously formed kaolinite. Kaolin beds are ovoidal in plan and lenticular in profile, with thickness ranging from centimeters to 11 meters, and the culmination of fining-upward clastic sequences. Sedimentary facies analysis indicates that the kaolin deposits were formed in a fluvial environment from currents with a high suspended-load/bed-load ratio, as would result from deposition in ox-bow lakes.     

Origin of spheroidal chert nodules, Drunka Formation (Lower Eocene), Egypt

Chert nodules of the Drunka Formation (Lower Eocene) are mostly spherical, have diameters from 40 to 120 cm, are quasi-uniformly spaced 2–3 m apart in the plane of bedding, have concentric internal structure and, except for rare small (<6 cm) solid chert nodules, are less than 85% chertified. Nodules formed after moderate alteration of limestone by meteoric water (δ¹⁸O_calcite = –4 to –8‰) at shallow (<100 m) burial depths; more extensive alteration of limestone (δ¹⁸O = –10 to –16‰) by meteoric water followed nodule growth. Chertification was by low-temperature meteoric water (δ¹⁸O_quartz = +18‰ in margins to +22‰ in nuclei) at shallow burial depths. Meteoric water may have invaded the Drunka Formation in association with shelf progradation during the Early Eocene, or during the development of a Middle Eocene unconformity. Replacement of carbonate mud by microcrystalline quartz was the dominant chertification process, but fossils were replaced in part by fine-grained equant megaquartz, quartzine and chalcedony; the last of these occurs in places as beekite. Opal A-secreting marine organisms are the inferred source of silica, but none are preserved. There is no compelling evidence of an opal-CT precursor, so quartz may have formed by direct precipitation. Self-organization processes of enigmatic character established the spacing pattern of the nodules and also the Liesegang-banded internal structure of the chert nodules. Nodules grew chiefly by diffusive supply of silica, although one locality has elongate nodules that grew when there was some porewater advection. Chertification patterns and δ¹⁸O values of both calcite and quartz indicate that nodule growth was complex and variable. Some nodules probably grew from the centre outwards. Many nodules, however, initially grew simultaneously across the entire nodule, but late-stage growth was predominantly at the outer margins or at selective internal sites.     

A giant late Precambrian chert-bearing olistostrome discovered in the Bohemian Massif: A record of Ocean Plate Stratigraphy (OPS) disrupted by mass-wasting along an outer trench slope

An intriguing example of chert–graywacke olistostrome is exceptionally well preserved within the late Neoproterozoic to early Cambrian Blovice accretionary wedge, Bohemian Massif. The olistostrome exhibits a block-in-matrix fabric defined by chert blocks isolated within the graywacke matrix. The major and trace element composition indicates two distinct types of cherts that formed either in a hydrothermal pelagic or hemipelagic environment supplied with a distal terrigenous material. The former is documented by elevated contents of Fe, Co, Zn, Ni, and Ti whereas the latter by high Al₂O₃ contents, relatively lower La_N/Ce_N ratios, and higher Eu/Eu* and Ce/Ce* values. Based on these geochemical data integrated with field observations and detrital zircon U–Pb ages of the host graywackes (determined using laser ablation ICP-MS), a new model for the origin of chert–graywacke association is proposed. The cherts are interpreted as representing pelagic and hemipelagic members of the Ocean Plate Stratigraphy (OPS) that formed in a sedimentary basin, carried on top of a subducting plate towards the trench. While moving over the outer swell (rise), the chert basin was intensely fractured and disrupted into large blocks or slabs. Subsequent motion of the plate brought the blocks onto an outer trench slope where they became gravitationally unstable to slide down and mix in the trench with distal, ca. 580–570 Ma turbidites derived from the overriding plate. Finally, this chert–graywacke olistostrome was covered by younger, ca. 560–547 Ma trench-fill turbidites (devoid of chert blocks) and accreted to the accretionary wedge toe, deformed, buried, and exhumed back to the wedge surface. We propose that such an olistostrome composed of pelagic/hemipelagic chert blocks and terrigenous, arc-derived graywacke matrix represents a rarely documented case of submarine, outer trench slope mass-wasting deposits and may be considered a new type of subduction-related mélanges. We coin the term outer-trench-slope mélange.     

新疆库车盆地康村地区砂岩型铜矿成矿模式研究

新疆库车盆地分布着一系列砂岩型铜矿床和矿点,文章在野外调查的基础上开展康村地区铜矿沉积环境和成矿模式研究,总结了区内沉积环境、沉积相与铜矿化体的配置关系,进而探讨了矿化成因和成矿模式。结果表明：康村地区新近系中可以识别出主要的沉积相类型有冲积扇相、扇三角洲相和湖泊相,以及5种亚相和7种微相。砂岩型铜矿化与沉积环境相关,矿(化)体主要分布在扇三角洲平原相和扇三角洲前缘相。2件样品LA-ICP-MS测年数据分别为427.4±6.6 Ma、387.3±3.3 Ma和424.6±2.3 Ma、279.9±6.8 Ma,表明康村地区中新统吉迪克组(N₁j)含铜砂砾岩的物源主要来自于库车盆地北西南天山造山带古生代晚志留世至早二叠世地质演化所形成的地层和岩浆岩产物。康村地区的矿化类型为砂岩型铜矿化,深部铜富集为硫酸盐热化学还原作用(TSR)型矿化成因,近地表矿化为后期盆地地上和地下卤水改造成因。库车盆地康村地区的铜矿化形成于新近系砂岩成岩之后,为后生富集,主要受新近纪后期断裂构造及后生卤水控制。     

山西晋中盆地晚新生代地层划分、沉积环境及其先秦以来气候和湖泊演化

【研究目的】晋中盆地位于汾渭断陷盆地带的中部,新生代最大沉积厚度超过3800 m,建立晋中盆地精确地层年代框架和高分辨率沉积层序对于理解汾渭断陷盆地带的演化、华北地区气候变化具有重要意义。【研究方法】本文对晋中盆地东北部晚新生代标准孔ZK01（钻孔深度870.5 m）岩心开展了年代学和沉积学研究。【研究结果】将ZK01孔揭示的松散沉积物分为6个岩性组。首次通过磁性地层学研究,划分出13个正极性时段和12个负极性时段,建立了ZK01孔地层年代框架。晋中盆地新生代沉积物底部最老年龄约8.1 Ma,将晋中盆地活动的起始时间从前人一般认为的上新世初期,确定为中新世晚期,提前了约3 Ma。区内晚新生代地层划分为新近系中新统灞河阶（N₁⁴）和保德阶（N₁⁵）,上新统高庄阶（N₂¹）和麻则沟阶（N₂²2）,第四系下更新统泥河湾阶（Qp¹）,中、上更新统和全新统。【结论】构造活动与气候变化是盆地沉积环境的主要控制因素,共同导致了上新世早期和早更新世中晚期的两次湖泊大规模发育。全新世时期,早中期即先秦（约2.5 ka以前）,盆地中仍是河湖共存阶段;晚期（2.5 ka以来）,出现湖消河长的局面,直至明、清时期湖泊全部消失,气候变化和人类活动影响是盆地中湖泊最终消失的主要原因。创新点：首次通过磁性地层学将晋中盆地发育时间确定为中新世晚期约8.1 Ma;盆地的湖泊发育早期主要受构造和气候控制,全新世以来气候变化和人类活动造成湖泊最终消亡。     

The evolution of a silicic magma system: isotopic and chemical evidence from the Woods Mountains volcanic center,eastern California

The isotopic compositions of Nd and Sr and concentrations of major and trace elements were measured in flows and tuffs of the Woods Mountains volcanic center of eastern California to assess the relative roles of mantle versus crustal magma sources and of fractional crystallization in the evolution of silicic magmatic systems. This site was chosen because the contrast in isotopic composition between Precambrian-to-Mesozoic country rocks and the underlying mantle make the isotope ratios sensitive indicators of the proportions of crustal- and mantle-derived magma. The major eruptive unit is the Wild Horse Mesa tuff (15.8 m.y. old), a compositionally zoned rhyolite ignimbrite. Trachyte pumice fragments in the ash-flow deposits provide information on intermediate composition magma types. Crustal xenoliths and younger flows of basalt and andesite (10 m.y. old) provide opportunities to confirm the isotopic compositions of potential mantle and crustal magma sources inferred from regional patterns. The trachyte and rhyolite have _Nd values of -6.2 to -7.5 and initial ⁸⁷Sr/⁸⁶Sr ratios mostly between 0.7086 and 0.7113. These magmas cannot have been melted directly from the continental basement because the _Nd values are too high. They also cannot have formed by closed system fractional crystallization of basalt because the ⁸⁷Sr/⁸⁶Sr ratios are higher than likely values for parental basalt. Both major and trace element variations indicate that crystal fractionation was an important process. These results require that the silicic magmas are end products of the evolution of mantle-derived basalt that underwent extensive fractional crystallization accompanied by assimilation of crustal rock. The mass fraction of crustal components in the trachyte and rhyolite is estimated to be between 10% and 40%, with the lower end of the range considered more likely. The generation of magmas with SiO₂ contents greater than 60% appears to be dominated by crystal fractionation with minimal assimilation of upper crustal rocks.