Structures associated with inversion of the Donbas Foldbelt (Ukraine and Russia)

The Donbas Foldbelt is part of the Prypiat–Dnieper–Donets intracratonic rift basin (Belarus–Ukraine–southern Russia) that developed in Late Devonian times and was reactivated in Early Carboniferous. To the southeast, the Donbas Foldbelt joins the contiguous, deformed Karpinsky Swell. Basin “inversions” led first to the uplift of the Palaeozoic series (mainly Carboniferous but also syn-rift Devonian strata in the southwesternmost part of the Donbas Foldbelt, which are deeply buried in the other parts of the rift system), and later to the formation of the fold-and-thrust belt. The general structural trend of the Donbas Foldbelt, formed mainly during rifting, is WNW–ESE. This is the strike of the main rift-related fault zones and also of the close to tight “Main Anticline” of the Donbas Foldbelt that developed along the previous rift axis. The Main Anticline is structurally unique in the Donbas Foldbelt and its formation was initiated in Permian times, during a period of (trans) tensional reactivation, during which active salt movements occurred. A relief inversion of the basin also took place at this time with a pronounced uplift of the southern margin of the basin and the adjacent Ukrainian Shield. Subsequently, Cimmerian and Alpine phases of tectonic inversion of the Donbas Foldbelt led to the development of flat and shallow thrusts commonly associated with folds into the basin. A fan-shaped deformation pattern is recognised in the field, with south-to southeast-vergent compressive structures, south of the Main Anticline, and north- to northwest-vergent ones, north of it. These compressive structures are clearly superimposed onto the WNW–ESE structural grain of the initial rift basin. Shortening structures that characterise the tectonic inversion of the basin are (regionally) orientated NW–SE and N–S. Because of the obliquity of the compressive trends relative to the WNW–ESE strike of inherited structures (major preexisting normal faults and the Main Anticline), in addition to reverse displacements, right lateral movements occurred along the main boundary fault zones and along the faulted hinge of the Main Anticline. The existence of preexisting structures is also thought to be responsible for local deviations in contractional trends (that are E–W in the southwesternmost part of the basin).     

Geological controls on soil parent material geochemistry along a northern Manitoba–North Dakota transect

As a pilot study for mapping the geochemistry of North American soils, samples were collected along two continental transects extending east–west from Virginia to California, and north–south from northern Manitoba to the US–Mexican border and subjected to geochemical and mineralogical analyses. For the northern Manitoba–North Dakota segment of the north–south transect, X-ray diffraction analysis and bivariate relations indicate that geochemical properties of soil parent materials may be interpreted in terms of minerals derived from Shield and clastic sedimentary bedrock, and carbonate sedimentary bedrock terranes. The elements Cu, Zn, Ni, Cr and Ti occur primarily in silicate minerals decomposed by aqua regia, likely phyllosilicates, that preferentially concentrate in clay-sized fractions; Cr and Ti also occur in minerals decomposed only by stronger acid. Physical glacial processes affecting the distribution and concentration of carbonate minerals are significant controls on the variation of trace metal background concentrations.     

A comparison of selective extraction soil geochemistry and biogeochemistry in the Cobar area, New South Wales

In parts of the deeply weathered and semi-arid environments of the Cobar area (NSW, Australia), detection of mineralisation using conventional soil sampling and total metal analysis is impeded. This is due to the intense leaching of trace elements within the weathered profile, discontinuous coverage of transported materials and the existence of diffuse regional geochemical anomalies of ill-defined source. Selective chemical extractions, applied to various regolith components, and biogeochemistry offer a means of isolating localised geochemical patterns related to recent dispersion of trace elements through the overburden. Lag geochemical patterns across the McKinnons deposit (Au) and Mrangelli prospect (Pb–Zn–As) reflect mechanical dispersion processes and minor hydromorphic effects. Concentrations of more mobile elements tend to be higher in the non-magnetic fraction, due to higher proportions of goethite and poorly crystalline hematite than in the magnetic fraction. The subdued soil geochemical responses for metals extractable by cold 40% hydrochloric acid (CHX) and for total element concentration reflect the leached nature of the residual profile, low grade of mineralisation, dilution by aeolian components and disequilibrium of fine fractions with coarser, relict Fe-oxides. The stronger contrast for CHX for most metals, compared with total extraction, indicates surface accumulation of trace elements derived from underlying mineralisation. Enzyme leach element anomalies are intense but generally located directly over bedrock sources or major structural breaks, irrespective of the nature of the overburden. Though mechanisms for the dispersion of trace elements extracted by enzyme leaching are not well established, the lack of lateral transport suggests vertical migration of volatile metal species (atmimorphic dispersion). The strong, multi-element response to mineralisation in cypress pine needles indicates significant metal recycling during the present erosional cycle. However, a comparison of the trace element concentrations in vegetation (cypress pine needles) and selective extractions of soils indicates that recycling by the plants is not the dominant mechanism for transportation of metals through the overburden. The vegetation may be responding to hydromorphic dispersion patterns at depth. The use of selective extractions may be useful in detecting mineralisation through deeply leached profiles, but offers even greater potential when integrated with biogeochemistry to detect targets buried by significant thickness of transported cover.     

The geochemical features of terrigenous host rocks at massive sulfide deposits in the eastern Caucasus

Based on a great body of factual data, geochemical peculiarities in the distribution of rare, noble, radioactive, and other trace components in the Lower-Middle Jurassic terrigenous ore-enclosing (hereafter, host) rocks at massive sulfide deposits in the Vostochnyi (eastern) segment of the Greater Caucasus are high-lighted. Study of the Filizchai base metal massive sulfide deposit made it possible to define general regularities of element distribution in the ore body and altered wall rocks that reflect the general geochemical zonality. Concentrations of most components depend on the lithology and wall-rock alteration, distribution of rocks in the section, proximity of the contacting ore, and its mineral composition. Contents of typical elements in host rocks are closely associated with their concentrations in the ore bodies.     

Geochemical evolution of the Capim River kaolin, Northern Brazil

The Capim River kaolin, located in the eastern Brazilian Amazon, constitutes one of the most important kaolin deposits in the world. Known for its high whiteness, its noble application is in the paper industry. Studies were carried out on samples from the six facies of the deposit (sand kaolin, soft kaolin, lower transition facies, ferruginous crust, upper transition facies and flint kaolin) in order to trace its geochemical evolution. The kaolin developed at the expense of Cretaceous sandy–clayey sediments of the Ipixuna Formation. Intense lateritic processes characterized by ferruginization and deferruginization mechanisms led to the distinction of the different facies.     

Arsenic as an indicator element for gold exploration in the region of the Xiangxi Au–Sb–W deposit, NW Hunan, PR China

The Xiangxi Au–Sb–W deposit, the largest of its type in northwestern Hunan, China, is a sulfide-dominated ore body hosted by low grade metamorphic red slates of the Neoproterozoic Madiyi Formation. Three stages of mineralization, quartz–scheelite, quartz–gold–pyrite, quartz–gold–stibnite, and one metal-barren stage of veining, quartz–calcite, are recognized. Arsenopyrite occurs only as a minor mineral phase in the second stage. Analyses for 21 trace elements show that the enrichment factors of As in the metal deposit (EC [=element concentration of sample/average content of an element in the upper crust]: 190; 43 samples) in ore veins and in the Guanzhuang and Yuershan reference sections (3.7 km and 2.7 km away from the Xiangxi mine, EC: 3.5; 96 samples) are much smaller than those of Sb (52855 [in ore veins], 117 [in the sections]), W (5665, 7.5) and Au (2727, 5.3). The background concentrations of Au and As in the two sections were 1.4 ppb and 1.4 ppm, respectively. Arsenic (with an anomaly coefficient [AC = number of anomalous samples/total number of samples] of 76%) forms a larger geochemical halo than W (AC: 8%) and Au (AC: 32%). Gold and As in the deposit were transported mainly as metal complexes such as Au(HS)⁻₂, H_nAs₃S⁻⁽³⁻ⁿ⁾₆ (n=1, 2 or 3) and HAsS⁰₂. Au(HS)⁻₂ is rapidly precipitated by a geochemical oxidation barrier — the red slates of the Madiyi Formation. As–S complexes in the stratigraphic horizon can be transformed into As–O complexes (e.g., H₃AsO⁰₃) under oxidizing conditions, and are continuously transported. Therefore, they can be widely distributed in the red slate units, thus forming extensive geochemical haloes, so that As can be used as an indicator element for Au exploration in the Xiangxi region.     

Zn, Pb, Cu and As distribution patterns in overbank and medium-order stream sediment samples: their use in exploration and environmental geochemistry

Overbank and medium-order stream sediment samples were collected in Belgium and Luxembourg from 66 sampling locations (area of about 33,000 km²) and analysed for major and trace elements among which Zn, Pb, Cu and As. At each sampling location large bulk samples were taken, namely in the lower (normally at ≥1.5 m depth, over an interval of about 20–40 cm) and upper (normally upper 5–25 cm) parts of the overbank profiles and from the stream sediments. Furthermore, at a number of these sites, a detailed geochemical analysis of vertical overbank sediment profiles (sampling intervals of 10–20 cm) was subsequently carried out to unravel element variations through time and to help in the overall evaluation. For most sampled sections evidences such as ¹⁴C-dating and the absence of anthropogenic particles point towards a pre-industrial and often pristine origin of the lower overbank sediment samples. From the latter bulk samples, mean background concentrations were deduced. They reveal the existence of significant differences between the northern and southern part of Belgium (incl. Luxembourg) which relate to the difference in geological substrate. In the north dominantly non-lithified Quaternary and Tertiary sands, marls and clays occur while in the south Palaeozoic sandstones, shales and carbonate rocks outcrop. Consequently separate mean background values were calculated for the two areas. In the southern study area, some anomalous metal concentrations have been recorded in pre-industrial sediments. They are derived from mineralised Palaeozoic rocks, a feature which could be of interest for base metal exploration. In the upper overbank and stream sediments, in general, higher heavy metal and As contents were recorded with highest values in areas with metal mining, metal melting and cokes treatment industries. By comparing the trace element concentrations of the upper overbank or stream sediment samples with the concentrations detected in the lower overbank samples at each of the sampling locations, and by evaluating the vertical distribution patterns where available, the degree of pollution of the alluvial plain and the present-day stream sediments can be assessed. From this exercise, it is clear that highest pollution occurs in the northern part of Belgium, which relates to its high population density and industrial development.     

A concise analytical strategy applied to waste treatment technology

Studying the mechanisms at work in waste technologies, such as waste-immobilisation, reactive barriers for waste containment, waste–waste neutralisation, etc., requires an integral characterization of materials. Materials before and after processing should be characterised in terms of (a) proportions of phases (liquids and solids), (b) composition and homogeneity of phases, (c) grain-size distribution (ideally per phase), and (d) large-scale compositional gradients within the system. Novel techniques can be applied successfully such as Rietveld-analysis of powder-XRD patterns to determine the modal proportions of fine-grained solids and laser-ablation–ICP–MS to determine trace element distributions on a ≈10-μm scale. Mathematical mass-balance and diffusion models provide checks for consistency in the characterization of materials. A case study is presented on a geochemical engineering treatment of red mud, the waste product of bauxite processing.     

Contribution to a geodynamic reconstruction of the Anti-Atlas (Morocco) during Pan-African times with the emphasis on inversion tectonics and metallogenic activity at the Precambrian–Cambrian transition

New geochronological analyses (U–Pb SIMS zircon ages) have yielded ages of 552 ± 5 Ma for the Bou Madine rhyolitic dome (Ougnat, eastern Anti-Atlas), 543 ± 9 Ma for the Tachkakacht rhyolitic dyke (Saghro–Imiter, eastern Anti-Atlas), and 531 ± 5 Ma for the Aghbar trachytic sill (Bou Azzer, central Anti-Atlas). Inherited zircon cores from the Aghbar trachytic sill and from the Bou Madine rhyolitic dome have been shown to be of Statherian age (ca. 1600–1800 Ma) and Palæoproterozoic (>2100 Ma) age, respectively, suggesting that a significantly older protolith underlies the Pan-African rocks in the Central and Eastern Anti-Atlas. Granodiorites and rhyolites from the Saghro–Imiter area have similar low ⁸⁷Sr/⁸⁶Sr (0.702–0.706) and ¹⁴³Nd/¹⁴⁴Nd (0.5116–0.5119) initial ratios, suggesting a mixture of mantle and lower crust sources. This can also be inferred from the low ¹⁸⁷Os/¹⁸⁸Os ratios obtained on pyrite crystals from the rhyolites.A recently published lithostratigraphic framework has been combined with these new geochemical and geochronological data, and those from the literature to produce a new reconstruction of the complex orogenic front that developed at the northern edge of the Eburnian West African craton during Pan-African times. Three Neoproterozoic magmatic series can be distinguished in the Anti-Atlas belt, i.e., high-K calc-alkaline granites, high-K calc-alkaline to shoshonitic rhyolites and andesites, and alkaline-shoshonitic trachytes and syenites, which have been dated at 595–570, 570–545 and 530 Ma, respectively.The accretion of the Pan-African Anti-Atlas belt to the West African super continent (WAC) was a four-stage event, involving extension, subduction, moderate collision and extension. The calc-alkaline magmatism of the subduction stage was associated with large-scale base metal and gold mineralisation. Metallogenic activity was greatest during the final extensional stage, at the Precambrian–Cambrian boundary. It is characterised by world-class precious metal deposits, base–metal porphyry and SEDEX-type occurrences.     

Petrology and geochemistry of the Salma dike, Raniganj coalfield (Lower Gondwana), eastern India: linkage with Rajmahal or Deccan volcanic activity?

The Gondwana (Early Permian to Early Cretaceous) basins of eastern India have been intruded by ultramafic–ultrapotassic (minette, lamproite and orangeite) and mafic (dolerite) rocks. The Salma dike is the most prominent among mafic intrusives in the Raniganj basin. This dike is tholeiitic in composition; MgO varies from 5.4 to 6.3% and the mg number from 54 to 59. In general, the major and trace element abundances are uniform both along and across the strike. There is geochemical and mineralogical evidence for fractional crystallization. The chondrite normalized REE pattern of the Salma dike (La/Yb_n=3.5) is similar to that of Deccan dikes of the Son–Narmada rift zone, western India. ⁸⁷Sr/⁸⁶Sr varies from 0.70552 to 0.70671 suggesting assimilation of crustal material. Some trace element abundances (e.g. Ti, Zr, Y) of the Salma dike are comparable to Group I Rajmahal basalts. The ⁴⁰Ar–³⁹Ar whole rock age of 65 Ma for the Salma dike is less than the ca. 114 Ma age for the Rajmahal basalt, but is similar to the generally accepted age for Deccan volcanic rocks. Despite geographical proximity with the Rajmahal basalt, the Salma dike is believed to be related to late phase of Deccan volcanic activity.     

Geochemical characteristics of lava-field basalts from eastern Australia and inferred sources: Connections with the subcontinental lithospheric mantle?

 A large new database of major, trace elements and Sr-Nd isotopic ratios from 11 lava-field provinces in New South Wales and Queensland, eastern Australia allows detailed interpretation of the origin of these basaltic magmas. Isotopic signatures and trace element patterns identify an OIB-type (oceanic island basalt) source as a dominant component for most of these and some provinces appear to have additional significant components derived from the subcontinental lithospheric mantle (SCLM). The SCLM components have geochemical characteristics that overlap those observed in spinel lherzolite xenoliths (samples of shallow lithospheric mantle) from eastern Australia. These SCLM components show geochemical provinciality that indicates the occurrence of distinct geochemical lithospheric domains reflecting the timing and style of tectonic evolution of different regions. One component reflects modification by subduction-related processes during the late Paleozoic and Mesozoic, one records enrichment by fluids during old metasomatic events and another suggests a metasomatic event involving a distinctive amphibole and apatite-style enrichment. The composition and age distribution of volcanic lava-field provinces older than 10 Ma are consistent with a model involving a regional upwelling (elongated N–S along eastern Australia) of deep hot mantle related to marginal rifting and with OIB-type source geochemical characteristics. Thermal inhomogeneities within this plume swath resulted in small diapirs which may have undergone melt segregation at about 100 km and incorporated varying amounts of SCLM components there or from higher levels of the SCLM during ascent. Subsequent hot-spot generated central volcanoes overprinted this lava-field volcanism, tapped a similar OIB-type source component and truncated the thermal events. Accepted: 15 March 1995     

Trace element geochemistry of altered volcanic ash layers (tonsteins) in Late Permian coal-bearing formations of eastern Yunnan and western Guizhou Provinces, China

Trace element compositions were determined (by instrumental neutron activation analysis; INAA) in 30 samples of synsedimentary volcanic ash-derived tonsteins and detrital claystones from coal seams within the late Permian coal-bearing formation of eastern Yunnan and western Guizhou Provinces, China. The characteristics of trace-element geochemistry in the tonsteins can be distinguished from those of detrital claystones because of the former's unique volcanic-ash origin. The detrital claystones are characterized by their relatively high content of V, Ti, Sc, Cr, Co and Ni, relatively low content of Th and U, Th/U ratio, and small negative Eu anomaly (Eu/Eu* 0.63–0.93). Overall, these trace element characteristics are consistent with a mafic source similar to the composition of basalt rocks in the erosional region on the western edge of the study area. In contrast, the tonsteins are low in V, Ti, Sc, Cr, Co and Ni contents and have a high Th/U ratio with a distinct negative Eu anomaly (Eu/Eu* normally in the range of 0.2–0.4), consistent with a silicic magmatic source.Within the group of tonsteins, those from the lower section (P_2.1) of the coal-bearing formation are relatively high in Ti, Zr, Hf, Nb, Ta and rare earth elements (REE), as compared to those from the middle and upper sections (P_2.2+3). In trace-element discrimination diagrams (scatter plots) of Hf–Ta, Ti–Ta, Ti–V, Hf–Sc, Lu–Hf and Lu–Th, tonsteins from the P_2.1 horizon always fall in isolated distribution areas, separate from the tonsteins of the P_2.2+3 horizon. These results suggest that the source materials of tonsteins from the two separate horizons were probably derived from volcanic ash falls of two distinctly different natures. Based on a comparison of the concentrations and assemblages of trace elements between various magmatic rocks, the source materials of tonsteins from P_2.1 horizon were mostly composed of calc-alkalic, silica-poor volcanic ash (similar to rhyodacitic magma), whereas those from P_2.2+3 were apparently more siliceous and K-rich (rhyolitic magma). Thus, tonsteins from the two different horizons are characterized by unique geochemical properties, which remain constant over a wide lateral extent. Integration of trace-elemental compositions with mineralogical and textural observations makes possible the establishment of tonstein stratigraphy, thus, facilitating more precise and reliable coal-seam correlations.     

Geological features and origin of the Huize carbonate-hosted Zn–Pb–(Ag) District, Yunnan, South China

The Huize Zn–Pb–(Ag) district, in the Sichuan–Yunnan–Guizhou Zn–Pb–(Ag) metallogenic region, contains significant high-grade, Zn–Pb–(Ag) deposits. The total metal reserve of Zn and Pb exceeds 5 Mt. The district has the following geological characteristics: (1) high ore grade (Zn + Pb ≥ 25 wt.%); (2) enrichment in Ag and a range of other trace elements (Ge, In, Ga, Cd, and Tl), with galena, sphalerite, and pyrite being the major carriers of Ag, Ge, Cd and Tl; (3) ore distribution controlled by both structural and lithological features; (4) simple and limited wall-rock alteration; (5) mineral zonation within the orebodies; and (6) the presence of evaporite layers in the ore-hosting wall rocks of the Early Carboniferous Baizuo Formation and the underlying basement.Fluid-inclusion and isotope geochemical data indicate that the ore fluid has homogenisation temperatures of 165–220 °C, and salinities of 6.6–12 wt.% NaCl equiv., and that the ore-forming fluids and metals were predominantly derived from the Kunyang Group basement rocks and the evaporite-bearing rocks of the cover strata. Ores were deposited along favourable, specific ore-controlling structures. The new laboratory and field studies indicate that the Huize Zn–Pb–(Ag) district is not a carbonate-replacement deposit containing massive sulphides, but rather the deposits can be designated as deformed, carbonate-hosted, MVT-type deposits. Detailed study of the deposits has provided new clues to the localisation of concealed orebodies in the Huize Zn–Pb–(Ag) district and of the potential for similar carbonate-hosted sulphide deposits elsewhere in NE Yunnan Province, as well as the Sichuan–Yunnan–Guizhou Zn–Pb–(Ag) metallogenic region.     

Continental-scale patterns in soil geochemistry and mineralogy: Results from two transects across the United States and Canada

In 2004, the US Geological Survey (USGS) and the Geological Survey of Canada (GSC) initiated a pilot study that involved collection of more than 1500 soil samples from 221 sites along two continental transects across Canada and the United States. The pilot study was designed to test and refine protocols for a soil geochemical survey of North America. The two transects crossed a wide array of soil parent materials, soil ages, climatic conditions, landforms, land covers and land uses. Sample sites were selected randomly at approximately 40-km intervals from a population defined as all soils of the continent. At each site, soils representing 0 to 5 cm depth, and the O, A, and C horizons, if present, were collected and analyzed for their near-total content of over 40 major and trace elements. Soils from 0–5 cm depth were also collected for analysis of organic compounds. Results from the transects confirm that soil samples collected at a 40-km spacing reveal coherent, continental- to subcontinental-scale geochemical and mineralogical patterns that can be correlated to aspects of underlying soil parent material, soil age and climate influence. The geochemical data also demonstrate that at the continental-scale the dominance of any of these major factors that control soil geochemistry can change across the landscape. Along both transects, soil mineralogy and geochemistry change abruptly with changes in soil parent materials. However, the chemical influence of a soil’s parent material can be obscured by changing climatic conditions. For the transects, increasing precipitation from west to east and increasing temperature from north to south affect both soil mineralogy and geochemistry because of climate effects on soil weathering and leaching, and plant productivity. Regional anomalous metal concentrations can be linked to natural variations in soil parent materials, such as high Ni and Cr in soils developed on ultramafic rocks in California or high P in soils formed on weathered Ordovician limestones in central Kentucky. On local scales, anomalous metal concentrations recognized in soil profiles, such as high P in soils from animal confinement sites, are consistent with local anthropogenic disturbances. At a larger scale, the distribution of Hg across the west to east transect demonstrates that it can be difficult to distinguish between natural or anthropogenic contributions and that many factors can contribute to an element’s spatial distribution.Only three samples in a subset of seventy-three 0–5 cm depth soil samples from the north to south transect had organochlorine pesticides values above the method detection limit, apparently related to historic usage of the pesticides DDT and dieldrin.     

Delineation of geochemical blocks for undiscovered large ore deposits using deep-penetrating methods in alluvial terrains of eastern China

Many large ore deposits have been discovered in eastern China along the Circum-Pacific Rim. However, alluvium, which covers most of the terrain, prevents a complete assessment of the mineralization potential by geological and conventional geochemical approaches. Two deep-penetrating geochemical methods—collection of nanoscale metals in earthgas (NAMEG) and selective leaching of mobile forms of metals in overburden (MOMEO) have been used to investigate the possibility to delineate geochemical blocks generated from large ore deposits buried by alluvial terrains. A wide-spaced sampling was carried out in an area of approximately 250 000 km² at density of one sample per 400–800 km². The soil samples were subjected to MOMEO leaching and were analyzed for Au, Ag, Cu, Pb, Zn, Fe, and Mn by atomic absorption spectrometry (AAS). The earthgas samples were analyzed for 17 elements by INNA. The results show that water-extractable metals by MOMEO processing can give prominent expression to concealed deposits and can delineate large-scale geochemical anomalies in the alluvial terrains. The distribution of gold in earthgas is situated along the largest deep fault systems and the concentration centers distribute in the secondary faults on the both sides of the deep fault systems.     

Geochemie und Petrogenese der Intrusivgesteine von Ağören in Ostanatolien/Türkei

The bulk mass of the intrusive rocks found in the surroundings of Ağören/East Anatolia is composed mainly of K-feldspar, quartz and plagioclase. Moreover the minerals biotite, muscovite and rarely amphiboles are present as minor components and apatite, zircon, chlorite, sericite, tourmaline as well as titanite are found as accessory components. The intrusives can be defined as granites and qaurtzmonzonites by plotting within the QAP diagram. They show a clearly prealuminous character (A/CNK ratio >1.1) and typical geochemical attributes of S-type granites.The distribution pattern of trace – and rare earth elements in various diagrams indicate that the initial magma was generated by collision processes and accompanyed crust thickening and consequently a partial melting of the underlying Akdağ metamorphics and Hinis metaophiolites.     

Multiple generations of forearc mafic–ultramafic rocks in the Timor–Tanimbar ophiolite, eastern Indonesia

We investigated mafic–ultramafic rocks distributed in the Timor–Tanimbar region as a possible modern analogue for the Mediterranean-type ophiolites in the Tethyan system. The geological occurrence suggests that the buoyant subduction of Australian continent uplifted the fragments of newly formed mantle–crust section, which extends to the neighboring preemplaced forearc marginal basins. However, we recognized a large variety of igneous features, which is consistent with the lack of complete succession and the presence of abundant crosscutting structures. All peridotite masses in Timor (Mutis, Atapupu and Dili) are mostly fertile (lherzolitic) in compositions. In addition, we found depleted harzburgite, highly refractory dunite and olivine websterite to occur as minor constituents, which display compositional contrast to those of the lherzolites. Structurally overlying Ocussi volcanics resemble island–arc tholeiite in terms of trace element characteristics, apparently inconsistent with genetic relationship with Timor lherzolite masses. In eastern small islands (Moa and Dai), all types of ophiolitic rocks display varying degrees of island–arc affinities. Cumulate origin of wehrlite and gabbroic rocks in Dai is marked by early crystallization of clinopyroxene and common occurrence of high-calcic plagioclase. Dikes cutting the gabbro sequence have weak island–arc signatures relative to those of Ocussi volcanics. Mildly depleted lherzolite–harzburgite in Moa was intruded by high-Mg andesitic magma, which crystallized hornblende gabbro containing high-Mg orthopyroxene. These petrological and geochemical variations can be best explained by the combination of (1) a temporal change of igneous activity possibly associated with development of forearc basin and (2) the emplacement of spatially different forearc regions in each locality. Unusual occurrence of fertile lherzolite in the forearc setting, generation of high-Mg andesite magmatism, inverted metamorphic grade recorded from associated metamorphic rocks, and formation of marginal basins may be linked to the injection of high-temperature asthenospheric materials into the mantle wedge.     

Application of the Pt–Re–Os isotopic systems to mantle geochemistry and geochronology

The Re–Os system has now been applied to a wide variety of problems in the solid earth sciences. This review concentrates on applications of the Re–Os system to understanding the age and composition of the mantle and the role that various materials in the mantle play in generating surface magmas. The progress in understanding Re–Os systematics in natural materials has accompanied dramatic advances in the understanding of the geochemical behavior of Re and the platinum group elements. This group of elements and the two isotopic systems (Pt–Os and Re–Os) they contain provide a view of Earth processes that are controlled not by the silicate phases the make up most of the outer portion of Earth, but by sulfide, oxide and metal phases that constitute but a trace of the mantle and crust. These phases are sensitive to oxygen and sulfur fugacities in ways that silicates are not. Consequently, the Re–Os and Pt–Os systems provide a new view into the geochemical evolution of the solid Earth that is complementary to that obtained through the study of traditional radiometric systems that are based on lithophile elements.