Molecular and stable carbon isotopic characterization of PAH contaminants at McMurdo Station, Antarctica

The molecular and stable carbon isotopic compositions of contaminant polycyclic aromatic hydrocarbons (PAHs) at McMurdo Station, Antarctica were analyzed in samples collected from land and sub-tidal area. PAHs in the study areas were characterized by high amounts of naphthalene and alkylated naphthalenes from petroleum products introduced by human activities in the area. Principal component analysis (PCA) of PAH composition data identified multiple sources of PAH contamination in the study area. Compositional assignments of origins were confirmed using compound specific stable carbon isotopic analysis.     

CO2 measurements on 1-cm3 ice samples with an IR laserspectrometer (IRLS) combined with a new dry extraction device

A new dry gas extraction and analysis method for small (1 cm³) ice samples is presented. The extraction device, cooled to ?20°C, contains two movable steel needle matrices for crushing the ice. During the crushing process the gas escaping from the ice sample is continuously analyzed for CO₂ with an infrared laserspectrometer. This method enables a fast measurement (few minutes) of the CO₂ concentration in the air bubbles with high spatial resolution in the ice core and a minimum potential contamination. An important CO₂ contamination source due to an interaction of water vapour with surfaces is shortly discussed.The reproducibility of extraction and analysis is ±2%. We analyzed CO₂ concentrations in the trapped air from different ice cores originating from the Greenland ice sheet and from Antarctica.     

Halogen contamination in Antarctic H5 and H6 chondrites and relation to sites of recovery

The distribution of the elements F, Cl, Br and I was analysed in layers removed stepwise from Antarctic H5 and H6 chondrites. All meteorites show higher concentrations of these elements on their surfaces than in their interiors. The degree of halogen enrichment cannot be correlated with the degree of visual weathering and is proportional to the time the meteorites were residing on the surface of the Antarctic ice. During this period, aerosols, salts and gaseous components are deposited on the surfaces of the meteorites and diffuse into their interior. The observed contamination level of the meteorites is influenced by leaching properties and diffusion behaviour of the individual halogens. The major contamination source for F, Cl and probably Br is air-borne seaspray; for I it is the gaseous compound methyl iodide (CH₃I) produced by biological processes in the sea. Methyl iodide and its oxidation products formed in the Antarctic atmosphere (e.g., I₂) can be transported over longer distances to the interior of Antarctica than air-borne seaspray. Therefore, the ratio of the halogen contamination is related to the collection site of the meteorites. All meteorites that were found in the Antarctic interior are contaminated to a lesser degree by F, Cl and Br relative to I than those found near the coast. The measured enrichment ratio of I/F is a function of the distance between the collection site and the open sea, and increases from the Allan Hills to the Thiel Mountains. By revealing the degree of contamination of a meteorite it is possible to determine its maximum surface residence time on the Antarctic ice.     

Reconstructions of the Campbell Plateau and the Lord Howe Rise

Reconstructions of the southeastern margin of Gondwanaland require either a separation of East and West Antarctica or movement between the Lord Howe Rise and the Campbell Plateau. Previous plate tectonic reconstructions based on sea-floor spreading data eliminated the Lord Howe Rise-Campbell Plateau separation prior to 36 m.y. ago because of overlap. This conclusion is dependent on the reconstruction of Australia and Antarctica, interpretation of magnetic anomalies between Antarctica and the Campbell Plateau and the nature of the plate boundary in New Zealand. Revised reconstructions of the fit between Australia and Antarctica, and a reinterpretation of the magnetic anomalies between the Campbell Plateau and Antarctica suggest that there is no problem of overlap between the Lord Howe Rise and the Campbell Plateau, and that continued motion between these plates prior to 36 m.y. ago is a more plausible alternative to separation between East and West Antarctica.     

南极地震学研究进展

归纳总结了在南极开展地震学研究中的各种主要方法及其研究成果,较全面地介绍了南极地震学研究的现状与进展．首先对南极地震活动性作了简单的介绍,然后分别介绍了利用面波和体波研究地壳上地幔结构的主要成果,最后从地震各向异性的角度归纳介绍了南极大陆部分区域面波方位各向异性及剪切波分裂研究的主要成果．研究表明,南极大陆地震活动性较低、地震强度较小,仅在横贯南极山脉区域、维多利亚地、阿黛利地、威尔克斯地等有较明显的地震活动; 横贯南极山脉将南极大陆分为东南极和西南极两个不同的地质构造区域,东南极地壳和上地幔地震波速度偏高,西南极则偏低;上地幔各向异性较为明显并普遍存在,且西南极各向异性强度稍高于东南极克拉通．     

Baseline metal concentrations in Paramoera walkeri from East Antarctica

Remediation of the Thala Valley waste disposal site near Casey Station, East Antarctica was conducted in the austral summer of 2003/2004. Biomonitoring of the adjacent marine environment was undertaken using the gammaridean amphipod Paramoera walkeri as a sentinel species [Stark, J.S., Johnstone, G.J., Palmer, A.S., Snape, I., Larner, B.L., Riddle, M.J., in press, . Monitoring the remediation of a near shore waste disposal site in Antarctica using the amphipod Paramoera walkeri and diffusive gradients in thin films (DGTs). Marine Pollution Bulletin and references therein]. Determination of uptake of metals and hypothesis testing for differences that could be attributed to contamination required the establishment of baseline metal concentrations in P. walkeri. Baseline metal concentrations from two reference locations in the Windmill Islands are presented here. P. walkeri was a found to be a sensitive bioaccumulating organism that recorded spatial and temporal variability at the reference sites. Measurement of metals in P. walkeri required the development of a simple digestion procedure that used concentrated nitric acid. For the first time, rare earth metals were determined with additional clean procedures required to measure ultra low concentrations using magnetic sector ICP-MS. Certified and in-house reference materials were employed to ensure method reliability.     

Heavy metal contamination in coastal sediments and soils near the Brazilian Antarctic Station, King George Island

This paper investigates the natural and anthropogenic processes controlling sediment chemistry in Admiralty Bay, King George Island, Antarctica, emphasizing the area affected by the Brazilian Antarctic Station Comandante Ferraz (Ferraz). Total and bioavailable concentrations of sixteen elements were determined in 32 sediment and 14 soils samples. Factor analysis allowed us to distinguish three groups of samples: (1) Ferraz sediments, with higher content of total trace metals and organic matter; (2) control sediments, with intermediate characteristics; (3) Ferraz soils, with higher bioavailability of most metals due to its oxidizing condition and low organic matter content. Major elements such as Fe, Al, Ca and Ti presented similar levels in all three groups. Enrichment factor calculations showed that paints, sewage and petroleum contamination enhanced metal concentrations in Ferraz surface sediments as follows: B, Mo, and Pb (>90%); V and Zn (70-80%); Ni, Cu, Mg, and Mn (30-40%). Despite evidence of contamination in these sediments, the low bioavailability, probably caused by iron-sulfide, indicates small environmental risks.     

Biodegradation of petroleum products in experimental plots in Antarctic marine sediments is location dependent

Clean sediment collected from O'Brien Bay, East Antarctica, was artificially contaminated with a mix of Special Antarctic Blend diesel fuel and lubricating oil and deployed in two uncontaminated locations (O'Brien and Sparkes Bays) and a previously contaminated bay (Brown Bay) to evaluate whether a history of prior contamination would influence the biodegradation process. Detailed analysis of the hydrocarbon composition in the sediment after 11 weeks revealed different patterns of degradation in each bay. Biodegradation indices showed that hydrocarbon biodegradation occurred in all three bays but was most extensive in Brown Bay. This study shows that even within a relatively small geographical area, the longevity of hydrocarbons in Antarctic marine sediments can be variable. Our results are consistent with faster natural attenuation of spilt oil at sites with previous exposure to oil but further work is needed to confirm this. Such information would be useful when evaluating the true risk and longevity of oils spills.     

Combined Gravimetric–Seismic Crustal Model for Antarctica

The latest seismic data and improved information about the subglacial bedrock relief are used in this study to estimate the sediment and crustal thickness under the Antarctic continent. Since large parts of Antarctica are not yet covered by seismic surveys, the gravity and crustal structure models are used to interpolate the Moho information where seismic data are missing. The gravity information is also extended offshore to detect the Moho under continental margins and neighboring oceanic crust. The processing strategy involves the solution to the Vening Meinesz-Moritz’s inverse problem of isostasy constrained on seismic data. A comparison of our new results with existing studies indicates a substantial improvement in the sediment and crustal models. The seismic data analysis shows significant sediment accumulations in Antarctica, with broad sedimentary basins. According to our result, the maximum sediment thickness in Antarctica is about 15 km under Filchner-Ronne Ice Shelf. The Moho relief closely resembles major geological and tectonic features. A rather thick continental crust of East Antarctic Craton is separated from a complex geological/tectonic structure of West Antarctica by the Transantarctic Mountains. The average Moho depth of 34.1 km under the Antarctic continent slightly differs from previous estimates. A maximum Moho deepening of 58.2 km under the Gamburtsev Subglacial Mountains in East Antarctica confirmed the presence of deep and compact orogenic roots. Another large Moho depth in East Antarctica is detected under Dronning Maud Land with two orogenic roots under Wohlthat Massif (48–50 km) and the Kottas Mountains (48–50 km) that are separated by a relatively thin crust along Jutulstraumen Rift. The Moho depth under central parts of the Transantarctic Mountains reaches 46 km. The maximum Moho deepening (34–38 km) in West Antarctica is under the Antarctic Peninsula. The Moho depth minima in East Antarctica are found under the Lambert Trench (24–28 km), while in West Antarctica the Moho depth minima are along the West Antarctic Rift System under the Bentley depression (20–22 km) and Ross Sea Ice Shelf (16–24 km). The gravimetric result confirmed a maximum extension of the Antarctic continental margins under the Ross Sea Embayment and the Weddell Sea Embayment with an extremely thin continental crust (10–20 km).     

Benthic marine pollution around McMurdo Station, Antarctica: A summary of findings

McMurdo Station is the United States Antarctic Research Program's (USARP) centre for scientific and logistical support for most of the continent and is the largest settlement in Antarctica. Over 30 years of human presence with shipping, air-transport, scientific, and municipal activities have resulted in severe but localized nearshore marine benthic pollution. This review will summarize the results of 3 years of research which has documented concentrations of chemical contaminants, changes in community patterns, and the toxicity of sediments to invertebrate species and infaunal communities. The primary contaminants are petroleum hydrocarbons in the sediments of Winter Quarters Bay, the site of shipping activities and a former dumpsite. Total hydrocarbon levels in sediments in Winter Quarters Bay were comparable to the most polluted harbours in temperate latitudes. However, a steep gradient of pollution existed: stations less than 1 km away were nearly pristine. Benthic invertebrate communities changed dramatically along this contamination gradient. The results of both field and laboratory bioassay experiments with contaminated sediments found that biological changes observed in benthic communities around McMurdo Station were most likely caused by hydrocarbons, PCBs, and PCTs. A primary goal of polar pollution research is to determine the response and tolerance of Antarctic biota to physical and chemical anthropogenic disturbance, and the mitigation of negative effects. To this end, future work should include continued monitoring of changes in chemical and community patterns, studies of the physiological responses of Antarctic invertebrates to chemical contamination, and further comparisons of anthropogenic and natural disturbances to benthic communities.     

南极验潮站对全球地震海啸的响应

现有对南极潮汐的研究主要聚焦在海平面变化、高程转换和常规调和分析,针对南极验潮站的潮位异常分析还很少见.本文聚焦南极验潮站数据中的异常潮位记录,提取到达南极的全球地震海啸事件,并分析南极不同验潮站对全球地震海啸的响应能力.本文首先利用潮汐调和分析去除验潮数据中的趋势项,分析余水位中较大幅度的潮位异常信号,然后通过对比不同方法,选取2.5倍标准差作为阈值提取到达南极的全球地震海啸事件.得出潮位异常信息点后,本文对比了各个验潮站点对地震海啸事件响应的敏感性与地理位置的关系,发现东南极威尔克斯地和南极半岛及其附近岛屿的验潮站更能响应全球地震海啸事件,长城站等8个站点适合开展全球地震海啸事件的响应和记录研究.

     

Greenland and Antarctica Ice Sheet Mass Changes and Effects on Global Sea Level

Thirteen years of GRACE data provide an excellent picture of the current mass changes of Greenland and Antarctica, with mass loss in the GRACE period 2002–2015 amounting to 265 ± 25 GT/year for Greenland (including peripheral ice caps), and 95 ± 50 GT/year for Antarctica, corresponding to 0.72 and 0.26 mm/year average global sea level change. A significant acceleration in mass loss rate is found, especially for Antarctica, while Greenland mass loss, after a corresponding acceleration period, and a record mass loss in the summer of 2012, has seen a slight decrease in short-term mass loss trend. The yearly mass balance estimates, based on point mass inversion methods, have relatively large errors, both due to uncertainties in the glacial isostatic adjustment processes, especially for Antarctica, leakage from unmodelled ocean mass changes, and (for Greenland) difficulties in separating mass signals from the Greenland ice sheet and the adjacent Canadian ice caps. The limited resolution of GRACE affects the uncertainty of total mass loss to a smaller degree; we illustrate the “real” sources of mass changes by including satellite altimetry elevation change results in a joint inversion with GRACE, showing that mass change occurs primarily associated with major outlet glaciers, as well as a narrow coastal band. For Antarctica, the primary changes are associated with the major outlet glaciers in West Antarctica (Pine Island and Thwaites Glacier systems), as well as on the Antarctic Peninsula, where major glacier accelerations have been observed after the 2002 collapse of the Larsen B Ice Shelf.     

Deglacial hypsometry of Antarctica

A new and more detailed analysis of the hypsometry of the Antarctic continent, based upon 1° digital data on ice thickness and surface and subglacial elevations, shows that Antarctica, even when deglaciated according to a simple Airy-isostatic model, is an unusual continent. It is the only one with a markedly bimodal hypsometric curve, and separation of the two modes shows that they are the single modes of West Antarctica (at ?450 m a.s.1.) and East Antarctica (at 950 m a.s.1.) respectively; the two parts of the continent are probably distinct tectonic entities. The modal height of East Antarctica is 700 m higher than that of the global ensemble of continents, suggesting that hotspot epeirogeny or a less well-known mechanism has affected its recent history. The age of this modal-height anomaly has important tectonic and especially climatic implications: it is equivalent to a 4–6°C cooling of the continental surface. The area of dry land after deglaciation is 10.5 × 10⁶ km²; the volume of ice in Antarctica is estimated at 26.9 × 10⁶ km³, and of ice in the Northern Hemisphere at 2.5 × 10⁶ km³; these figures lead to a eustatic sea-level equivalent for present-day glacier ice of 68 m or somewhat less.     

1994-2014年南极沿岸验潮站海平面绝对变化确定与分析

鉴于卫星测高技术在南极周边海域会受到海面浮冰影响,且在利用测高序列分析海平面周期性动态变化时还会受到潮汐周期混叠效应的影响,为此,本文开展了基于GPS和验潮数据联合的南极大陆附近海域从1994-2014年间海平面的绝对变化研究.研究结果显示：在围绕南极大陆及附近海域的15个验潮站中,海平面绝对变化速度最大的是Diego Ramirez验潮站,达到11.10±0.04 mm·a-1;在西南极南极半岛的德雷克海峡,海平面变化最为活跃,变化均值在8.31±0.05 mm·a-1;在东南极,从Syowa站依次到Casey站,海平面的绝对变化速度相对平稳,四个潮位站海平面变化均值为3.35±0.04 mm·a-1;在罗斯冰架右下侧的罗斯岛附近,由于冰川崩解入海导致Scott Base站处的海平面上升速度较快,达到了9.61±0.07 mm·a-1.综合15个验潮站计算结果可得南极半岛德雷克海峡和罗斯岛附近海域,海平面绝对变化速度要高于同期南大洋海平面绝对变化速度,而东南极4个潮位站海平面绝对变化均值则与其相当.这也进一步反映了南极不同海域间海平面变化的差异性,相比较于对南大洋海平面变化的一个整体研究,分区研究海平面变化更具针对性,能更好地了解南极不同区域冰盖、冰架崩解和消融的情况.     

ANNUAL SEA LEVEL VARIABILITY INDUCED BY CHANGES IN SEA ICE EXTENT AND ACCUMULATION ON ICE SHEETS: AN ASSESSMENT BASED ON REMOTELY SENSED DATA

Changes of mean annual net accumulation at the surface on the grounded ice sheets of East Antarctica, West Antarctica and Greenland in response to variations in sea ice extent are estimated using grid-point values 100 km apart. The data bases are assembled principally by bilinear interpolation of remotely sensed brightness temperature (Nimbus-5 ESMR, Nimbus-7 SMMR), surface temperature (Nimbus-7 THIR), and surface elevation (ERS-1 radar altimeter). These data, complemented by field data where remotely sensed data are not available, are used in multivariate analyses in which mean annual accumulation (derived from firn emissivity) is the dependent variable; the independent variables are latitude, surface elevation, mean annual surface temperature, and mean annual distance to open ocean (as a source of energy and moisture). The last is the shortest distance measured between a grid point and the mean annual position of the 10% sea ice concentration boundary, and is used as an index of changes in sea ice extent as well as of mean concentration. Stepwise correlation analyses indicate that variations in sea ice extent of ± 50 km would lead to changes in accumulation inversely of ± 4% on East Antarctica, ± 10% on West Antarctica, and ±4% on Greenland. These results are compared with those obtained in a previous study using visually interpolated values from contoured compilations of field data; they substantiate the findings for the Antarctic ice sheets (±4% on East Antarctica, ±9% in West Antarctica), and suggest a reduction by one half of the probable change of accumulation on Greenland (from ±8%). The results also suggest a reduction of the combined contribution to sea level variability to ±0.19 mm a-1 (from ±0.22 mm a-1).     

利用ICESat数据解算南极冰盖冰雪质量变化

南极冰盖冰雪质量变化反映了全球气候变化,并且直接影响着全球海平面变化.ICESat测高卫星的主要任务之一就是要确定南北两极冰盖的质量变化情况并评估其对全球海平面变化的影响.本文利用2003年10月至2008年12月的ICESat测高数据,针对南极DEM分辨率有限的特殊性,通过求解坡度改正值,解决重复轨道地面脚点不重合的问题,计算了南极大陆(86°S以北区域,后文所述南极冰盖均不包括86°S以南区域)在这5年里的冰雪质量变化情况,得到东南极冰盖的质量变化为-18±20 Gt/a,西南极-26±6 Gt/a,南极冰盖的冰雪质量变化为-44±21 Gt/a,对全球海平面上升的影响约为0.12 mm·a-1.解算结果表明,南极冰盖质量亏损主要集中在西南极阿蒙森海岸附近冰川以及东南极波因塞特角区域.     

Relations between basal condition,subglacial hydrological networks and geothermal flux in Antarctica

When modelling the Antarctic ice sheet, the velocity of the ice flow is linked to its temperature. Depending on the thermal rate, the flow rate may vary between deformation and sliding. In this study, we focus on the geothermal flux because it is the least well-known component of the heat equation, and because it constrains the temperature at the bottom of the ice sheet. We used available geological data to build a map of the geothermal flux, which was found to increase from 51 mW/m² in East Antarctica to 68 mW/m² in West Antarctica. These values were integrated in the computation of a basal temperature map. The available map of hydrological networks clearly shows more melted areas in West Antarctica than in the earlier results. So we suggest that the model should be forced with higher geothermal flux values, over 85 mW/m² in this sector. This increase is in good agreement with published results which found a geothermal flux three times higher in West Antarctica. Finally, we computed the bottom melt rate over the ice sheet area which has a mean value of 3.5 mm/yr resulting in a lost of melted ice equal to 1% of the total mass balance.     

基于多源遥感数据的南极冰架与海岸线变化监测

综合使用光学与微波遥感数据,提出了南极冰架变化连续监测的系统方法,包括基于MOA的冰架基准图生成,基于相似性测度的影像匹配,及基于阈值与分水岭变换的图像分割方法.使用该方法获取了2002—2011年初全南极18个主要冰架的变化数据,并归纳了南极冰架变化的三种类别.进一步得出,近年间崩解变化为主的冰架均处于西南极,并主要集中在南极半岛;扩展变化为主的冰架集中在东南极;南极三大冰架的扩展变化明显,其中Amery冰架将在近年发生较大崩解.本研究首次获取了2002年初至2011年初每年一幅的动态的全南极海岸线数据,并得出近10年间南极海岸线扩展增加总量为5878 km2.     

Crustal structure in the Mizuho Plateau, East Antarctica, by a two-dimensional ray approximation

Studies on the crustal and upper-mantle structure in Antarctica have been one of the major contributions to Antarctic research since the International Geophysical Year of 1957–1958. Many refraction surveys with small charge size have been conducted in Antarctica, but long-range experiments were also made in 5 regions on the margin of the Antarctic continent.In 1979–1981, the scientific program of the Japanese Antarctic Research Expedition was focused on the earth sciences, and in particular, an explosion seismic experiment along a long survey line was the major item during these years. An experiment along a 300 km-long line with three shots and 27 observation stations was successfully made in the northern Mizuho Plateau, East Antarctica.From the analysis of travel times and the amplitude study of synthetic seismograms, the crustal structure of the northern Mizuho Plateau was determined. The depths of the Conrad and the Moho discontinuties were determined as 31 km and 42 km, respectively. The P-wave velocity and depth relation was determined as 6.0 km/s on the surface of the bedrock, 6.3 km/s at a depth of 2 km, 6.8 km/s at the Conrad and 7.9 km/s at the Moho. The velocity in the crust increases gradually. The crustal structure obtained is representative of East Antarctica.     

Palaeomagnetism and KAr age of Mesozoic and Cenozoic igneous rocks from Antarctica

A new analysis of palaeomagnetic data for igneous rocks from Deception Island, 25 de Mayo Island (King George Island) and Cape Spring, are given.K-Ar age determinations indicate that most of the igneous samples from 25 de Mayo Island included in the palaeomagnetic study are of Late Mesozoic/Early Tertiary age. The significance of these palaeomagnetic-radiometric data on the hypothesis of oroclinal bending of the Antarctic Peninsula and on the apparent polar movement of Antarctica is discussed.The positions of palaeomagnetic poles for the Andean igneous complex indicate that there has not been any apparent post-Late Cretaceous/Early Tertiary oroclinal bending in the Antarctic Peninsula from 74°S to 62°S.A comparison of the positions of palaeomagnetic poles for Antarctica and Australia suggests that the direction of apparent polar movement relative to Antarctica reversed after the Miocene.