Reconstruction of composition of the earth’s primary aqueous phase. Part 1: Formation from carbonaceous chondrite matter

The equilibrium composition was modeled for the water-carbonaceous chondrite matter system open to CO₂ and CH₄. It was shown that at 25°C, total pressure of 1 bar, and definite proportions between partial pressures of CO₂ (10⁻⁵–10⁻⁸ bars) and CH₄ (10⁻⁴–10⁻⁸ bar), the aqueous phase is characterized by a K/Na ratio of 4–12, which corresponds to the ratios of these elements in the cellular liquid of organisms. Aqueous phase has pH = 8−9, Eh = −450 ± 50 mV, and ammonia nitrogen, and K, Na, and Mg concentrations close to those in the cellular liquid.     

The red‐beds of the Triassic Narrabeen group

The closure of the Brisbane River to extractive dredging and the exhaustion or limitation of other sand sources have caused an industry shift to manufactured sand for concrete fine aggregates. Manufactured sand is generated in a purpose‐designed process; it is not recycled waste‐crusher dust. At present it is produced in 12 of the major hardrock quarries in southeast Queensland. To date companies have achieved only partial replacement of natural sands, to around 40% of the fine aggregate component in their concrete mixes. While improved technology and management will further reduce the amount of natural blend sand required, it is unlikely to be fully replaced in the foreseeable future. Although providing a solution to one problem, manufactured sand raises new environmental issues. The management of fine wastes is likely to become an important issue, as will the increased demand for natural fine sands to improve mix grading and workability. Diminishing supply from land‐based sources has resulted in increased applications for dredging of Moreton Bay, where enormous resources occur and low impact extraction may be possible. However, this prospect raises difficult environmental and land‐access issues for government decision makers.     

On the protonation of oxo- and hydroxo-groups of the goethite (α-FeOOH) surface: A FTIR spectroscopic investigation of surface O-H stretching vibrations

The O-H stretching region of goethite particles evaporated at different levels of acidity was investigated by Attenuated Total Reflectance (ATR)-Fourier Transform InfraRed (FTIR) spectroscopy. Two-dimensional IR Correlation Spectroscopy was used to identify correlations between different sets of discrete surface OH stretches and a Multivariate Curve Resolution analysis was used to resolve the predominant spectral components. Two dominant groups of hydroxyls were identified on the basis of their differences in proton affinity. Group I hydroxyls appear as two 3698/3541 and 3660/3490 cm⁻¹ band pairs. Group II hydroxyls are manifested through the 3648 and 3578 cm⁻¹ bands at greater levels of surface proton loading. There is consequently no correlation between O-H stretching frequencies and proton affinity. Groups I and II were assigned to mostly singly- (-OH) and doubly- (μ-OH) coordinated hydroxyls, respectively. Stretches arising from triply-coordinated (μ₃-OH) are proposed to be embedded within the dominant O-H band of bulk goethite. The possibility that these sites contribute to Group I and II hydroxyls should, however, not be entirely dismissed without further investigations.A reexamination of Temperature Programmed Desorption (TPD)-FTIR data of one goethite sample evaporated from alkaline conditions [Boily J.-F., Szanyi J., Felmy A. R. (2006) A combined FTIR and TPD study on the bulk and surface dehydroxylation and decarbonation of synthetic goethite. Geochim. Cosmochim. Acta70, 3613-3624] provided further constraints to this band assignment by providing clues to the network of surface hydrogen bonds. Important cooperative effects between hydrogen-bonded surface hydroxyls are suggested to play a crucial role on the variations of the position and intensity of discrete O-H stretching bands as a function of protonation level and temperature.     

Distribution and concentrations of anthropogenic platinum group elements in the surface environment of Hong Kong

Ecotourism environmental impact assessment is a traveling activity relevant influence prediction and appraisal. And the setting-up of the index system is very important to implement the appraisal of environmental impact of ecological travel. According to the index system, natural ecological environment, humane social environment, the environment of tourist resources and the atmosphere of capacity of tourist environment, four major systems form the first index. Each system formed the second index of several key elements. In addition, it is a key step to appraise the sureness of the factor weight, which influences the rationality of the result directly. Daily method of weighting has the Delphi＇s and the AHP. According to ＂Grade form of characteristic value of Standard of rating for quality of tourist attractions＂ which the National Tourism Administration issues, the paper takes the Jingshan mountains ecological tourist zone as an example and adopts AHP to weight the factors mainly, assisted with the Delphi＇s by the help of computer. The Jingshan ecological tourist zone is good. The result of calculation, comprehensive value of 8.35 after establishment, shows that it doesn＇t change dramatically, attributing to the index of natural ecological environment like atmosphere, quality of surface water, acoustics environment and vegetation coverage. Improvement of traffic states and sanitation caused by the project in the region increases the comprehensive value, while the water and soil loss in partial area caused by construction decrease.     

The NGC 1023 galaxy group: An anti-hubble flow?

We discuss recently published data indicating that the nearby galaxy group NGC 1023 includes an inner, virialized, quasi-stationary component together with an outer component comprising a flow of dwarf galaxies falling toward the center of the system. The inner component is similar to the Local Group of galaxies, but the Local Group is surrounded by a receding set of dwarf galaxies forming the local Hubble flow, rather than a system of approaching dwarfs. This clear difference in the structures of these two systems, which are very similar in other respects, may be associated with the dark energy in which they are immersed. Self-gravity dominates in the inner component of the Local Group, while the anti-gravity created by the cosmic dark-energy background dominates in the surrounding Hubble flow. In contrast, self-gravity likewise dominates throughout the NGC 1023 Group, both in its central component and in the surrounding “anti-Hubble” flow. NGC 1023 as a whole is apparently in an ongoing state of formation and virialization. We expect that there exists a receding flow similar to the local Hubble flow at distances of 1.4–3 Mpc from the center of the group, where anti-gravity should become stronger than the gravity of the system.     

Estimation of the composition of the Earth’s primary aqueous phase. 2. Synthesis from the mantle and igneous rock material. Comparison with synthesis from the carbonaceous chondrite material

Simulation results of the equilibrium state of systems water-carbonaceous chondrite material, water-primary mantle material, water-ultramafic rock material, and water-mafic rock material open with respect to carbon dioxide and methane at 25°C, 1 bar indicate that highly alkaline reduced aqueous solutions with K/Na > 1 can be formed only if water is in equilibrium with compositions close to those of continental crust and primitive mantle. Yu.V. Natochin’s hypothesis that the living cell can be formed only in an aqueous environment with K/Na > 1 leads to the conclusion that terrestrial life could arise and further evolve on the Earth during the differentiation of primary chondritic material into the Earth’s core and mantle (during the first few million years of the planet’s lifetime) in an alkaline (pH 9–10) reduced (Eh = −400–500 mV) aqueous solution at a temperature of 50–60°C, in equilibrium with an N₂-bearing atmosphere, which also contained CH₄ (partial pressure from 10⁻² to 10⁻⁸ bar), CO₂ (partial pressure from 10⁻⁵ to 10⁻⁸ bar), NH₃, H₂, H₂S, CO, and other gases.     

The Geochemistry of the Arabian Lithospheric Mantle--a Source for Intraplate Volcanism?

We present trace element and Sr–Nd–Hf–Pb isotopecompositions for clinopyroxenes from anhydrous spinel peridotiteand garnet ± spinel pyroxenite xenoliths of Pan-Africanlithospheric mantle from Jordan, including the first high-precisiondouble-spike Pb isotope measurements of mantle clinopyroxene.Clinopyroxenes from the peridotites are variably Th–U–LILE–LREEenriched and display prominent negative Nb, Zr and Ti anomalies.MREE–HREE abundances can generally be modelled as partialmelting residues of spinel lherzolite with primitive-mantle-likecomposition after extraction of 5–10% melt, whereas theenrichments in Th–U–LILE–LREE require a Pan-Africanor later metasomatic event. The large range of Nd, Sr, Pb andHf isotope ratios in both peridotites and pyroxenites (e.g.Nd 1·4–17·5; ²⁰⁶Pb/²⁰⁴Pb 17·2–20·4;Hf 0·6–164·6) encompasses compositionsmore radiogenic than mid-ocean ridge basalt (MORB), and Pb isotopescover almost the entire range of oceanic basalt values. Hf valuesare some of the highest ever recorded in mantle samples andare decoupled from Nd in the same samples. Marked correlationsbetween Sr–Nd–Pb isotopes, LILE–LREE enrichmentsand HFSE depletion suggest that the metasomatizing agent wasa carbonatitic-rich melt and isotopic data suggest that metasomatismmay have been related to Pan-African subduction. The metasomaticmelt permeated depleted upper mantle (<16 kbar) during Pan-Africansubduction at 600–900 Ma, and the variably metasomatizedmaterial was then incorporated into the Arabian lithosphericmantle. There is no evidence for recent metasomatism (<30Ma) related to the Afar plume like that postulated to have affectedsouthern Arabian lithospheric mantle. Hf isotopes in the mantleclinopyroxenes are unaffected by metasomatism, and even somestrongly overprinted lithologies record ancient (>1·2Ga) pre-metasomatic Lu–Hf signatures of the depleted uppermantle that was the protolith of the Arabian lithospheric mantle.The ‘resistance’ of the Lu–Hf isotopic systemto later metasomatic events resulted in the development of extremelyheterogeneous Hf isotopic signatures over time that are decoupledfrom other isotopic systems. No mantle sample in this studyexactly matches the chemical and isotopic signature of the sourceof Jordanian intraplate basalts. However, the xenolith compositionsare broadly similar to those of the source of Arabian intraplatebasalts, suggesting that the numerous Cenozoic intraplate volcanicfields throughout Arabia may be the product of melting uppermantle wedge material fertilized during Pan-African subductionand incorporated into the Arabian lithospheric mantle. We proposea model whereby the proto-Arabian lithospheric mantle underwenta major melting event in early Proterozoic–late Archeantimes (at the earliest at 1·2 Ga). Island-arc volcanismand major crust formation occurred during the Pan-African orogeny,which liberated fluids and possibly small-degree melts thatmigrated through the mantle creating zones of enrichment forcertain elements depending upon their compatibility. Immobileelements, such as Nb, were concentrated near the base of themantle wedge providing the source of the Nb-rich Jordanian volcanicrocks. More mobile elements, such as LILE and LREE, were transportedup through the mantle and fertilized the shallow mantle sourceof the Jordanian xenoliths. Following subduction, the mantlewedge became fossilized and preserved distinct enriched anddepleted zones. Lithospheric rifting in the Miocene triggeredpartial melting of spinel-facies mantle in the lower lithosphere,which mixed with deeper asthenospheric garnet-facies melts asrifting evolved. These melts entrained segments of variablycarbonatite-metasomatized shallow lithospheric mantle en routeto the surface. KEY WORDS: Arabian lithospheric mantle; Jordan; mantle xenoliths; Sr–Nd–Hf–Pb isotopes     

The effects of intensive rainfalls (flash floods) on the development on the landforms in the K?szeg Mountains (Hungary)

The effects of the intensive rainfall episodes in the years 2009 and 2010 in the K?szeg Mountains were investigated. Channel profiles were constructed at various times during these periods, which were used to describe the channel changes. We measured the length of the incised and filled sections on multiple occasions. We could establish the degree and the direction of the changes using this data. The sediment veneer that developed in the area of K?szeg town was mapped and its conditions of development were examined. The erosion and accumulation landforms developed during these years were classified and described. These forms are the following: rills, gullies, alluvial fans and sediment veneer. We distinguished and characterised those which had previously formed, but they were changed or increased (the channels). We established the conditions under which the sediment veneer can develop, furthermore those conditions which can increase the chance of the formation of this landform. These conditions are the following: the high density of roads in the catchment areas of valleys leading to settlements, the great thickness of superficial deposit, and the steep slope of the surface of the catchment area. We created theoretical classification of the morphological environment where the development of sediment veneer may happen and identified settlements with structures which promote or prevent the development of the sediment veneer. We determined the probability of the development of the sediment veneer at some settlements in K?szeg, and suggestions have been given to decrease the chance of the development of this sediment veneer.     

The westward drift of the lithosphere: A tidal ratchet?

Is the westerly rotation of the lithosphere an ephemeral accidental recent phenomenon or is it a stable process of Earth's geodynamics? The reason why the tidal drag has been questioned as the mechanism determining the lithospheric shift relative to the underlying mantle is the apparent too high viscosity of the asthenosphere. However, plate boundaries asymmetries are a robust indication of the ‘westerly’ decoupling of the entire Earth's outer lithospheric shell and new studies support lower viscosities in the low-velocity layer (LVZ) atop the asthenosphere. Since the solid Earth tide oscillation is longer in one side relative to the other due to the contemporaneous Moon's revolution, we demonstrate that a non-linear rheological behavior is expected in the lithosphere mantle interplay. This may provide a sort of ratchet favoring lowering of the LVZ viscosity under shear, allowing decoupling in the LVZ and triggering the westerly motion of the lithosphere relative to the mantle.     

Contrasting rock permeability in the aureole of the Ballachulish igneous complex, Scottish Highlands: the influence of surface energy?

The Ballachulish igneous complex in the Scottish Highlands, part of a widespread group of late Caledonian calcalkaline intrusions, was emplaced at a depth of 10 km into Dalradian metasediments resulting in melting of the country rocks near the intrusive contact. The greatest extent of melting occurred in the Leven schist in the 400 m wide so-called Chaotic Zone which experienced infiltration of aqueous fluids from the pluton. In contrast, adjacent to the Chaotic Zone, the feldspar-bearing Appin quartzite underwent significant melting only within a few metres of the intrusion, despite both being in contact with the same fluid source as the Leven schist and having a similar (wet) melting point. The permeability of the Appin quartzite and quartz horizons in the Leven schist to pervasive grain-edge infiltration of aqueous fluids was determined by measuring the equilibrium quartz-H₂O dihedral angle for the P-T conditions of contact metamorphism. Addition of powdered samples of both rock types to the pure quartz-H₂O system results in a linear decrease of the quartz-H₂O dihedral angle with increasing temperature. The rate of this decrease for the Leven schist is greater than that for the Appin quartzite, and the angle decreases below 60° some 30 °C below the wet solidus (670 °C at 0.3 GPa). Charges bearing Appin quartzite had dihedral angles greater than 60° at all temperatures below the wet solidus (690 °C at 0.3 GPa). These results demonstrate that quartz-rich horizons in the Leven schist would have been permeable to infiltration of aqueous fluids close to the solidus, permitting extensive H₂O-fluxed melting to occur. The Appin quartzite would have remained impermeable to grain-edge flow, consistent with the observed differences in the extent of partial melting of the two lithologies. Received: 25 November 1996 / Accepted: 29 October 1997     

ATR-FTIR spectroscopic study of the adsorption of desferrioxamine B and aerobactin to the surface of lepidocrocite (γ-FeOOH)

The adsorption of two model siderophores, desferrioxamine B (DFOB) and aerobactin, to lepidocrocite (γ-FeOOH) was investigated by attenuated total reflection infrared spectroscopy (ATR-FTIR). The adsorption of DFOB was investigated between pH 4.0 and 10.6. The spectra of adsorbed DFOB indicated that two to three hydroxamic acid groups of adsorbed DFOB were deprotonated in the pH range 4.0-8.2. Deprotonation of hydroxamic acid groups of adsorbed DFOB at pH values well below the first acid dissociation constant of solution DFOB species (pK_a = 8.3) and well below the point of zero charge of lepidocrocite (pH_PZC = 7.4) suggested that the surface speciation at the lower end of this pH range (pH 4) is dominated by a surface DFOB species with inner-sphere coordination of two to three hydroxamic acids groups to the surface. Maximum adsorption of DFOB occurred at approximately pH 8.6, close to the first pK_a value of the hydroxamic acid groups, and decreased at lower and higher pH values.The spectra of adsorbed aerobactin in the pH range 3-9 indicated at least three different surface species. Due to the small spectral contributions of the hydroxamic acid groups of aerobactin, the interactions of these functional groups with the surface could not be resolved. At high pH, the spectral similarity of adsorbed aerobactin with free aerobactin deprotonated at the carboxylic acid groups indicated outer-sphere complexation of the carboxylate groups. With decreasing pH, a significant peak shift of the asymmetric carboxylate stretch vibration was observed. This finding suggested that the (lateral) carboxylic acid groups are coordinated to the surface either as inner-sphere complexes or as outer-sphere complexes that are strongly stabilized at the surface by hydrogen bonding at low pH.     

The Mazafran river (western Sahel of Algiers): superimposition or antecedence?

At the western Sahel of Algiers, the watercourse of the Mazafran river is perpendicular to the Sahel fold, forming a gorge that has developed in a tectono-eustatic context characteristic of the Sahel region. This gorge has formed in a regime of superimposition which involves the evolution of antecedence in relation to the Sahel uplift. This deduction is the result of multiple analyses that are based on a stratigraphic study which characterizes the succession of continental and marine deposits and the analyses of lineament map of tectonic evolution during the Quaternary which is marked by the Sahel folding. In order to correlate the chronology between the fluvial and marine sedimentary dynamics, a geomorphological study of the Mazafran alluvial terraces associated with the paleoshorelines was realized. The obtained results reveal that the development of the Mazafran river gorge is complex.     

Why did life develop on the surface of the Earth in the Cambrian?

Life was limited for most of Earth's history, remaining at a primitive stage and mostly marine until about 0.55 Ga. In the Paleozoic, life eventually exploded and colonized the continental realm. Why had there been such a long period of delayed evolution of life? Early life was dominated by Archaea and Bacteria,which can survive ionizing radiation better than other organisms. The magnetic field preserves the atmosphere, which is the main shield of UV radiation. We explore the hypothesis that the Cambrian explosion of life could have been enabled by the increase of the magnetic field dipole intensity due to the solidification of the inner core, caused by the cooling of the Earth, and the concomitant decrease with time of the high-energy solar flux since the birth of the solar system. Therefore, the two phenomena could be responsible for the growth and thickening of the atmosphere and the development of land surface life.