Identification of Self-Potential Anomalies of a Diffusion–Absorption Origin

Diffusion and adsorption (DA) potentials are frequently the sources of self-potential (SP) anomalies, but they do not arouse practical interest in contrast to anomalies of oxidation–reduction and filtration origins. DA anomalies are common and geophysicists sometimes mistakenly consider DA anomalies as examples of filtration anomalies. Identification of DA anomalies is based on correlation of SP and apparent resistivity values along the same profiles. During the student geophysical training workshop for students of the Moscow State University (Aleksandrovka village, Kaluga Region) we obtained profiles with SP and resistivity anomalies with good correlation between them. This makes it possible to consider such SP anomalies as a result of DA processes.     

Ecological–Biogeochemical Monitoring of a Linden Avenue in a Megapolis

Ecological–biogeochemical monitoring of a linden avenue on Kosygin Street, Moscow, has revealed that soils at sites regarded as contaminated contain elevated Mn, Fe, Sr, and Se concentrations and lower Zn contents. Linden leaves at the assumed contaminated sites typically contain higher Cu and Fe concentrations and not as much higher Zn, As, and Cr concentrations but much lower Mn and Sr concentrations. Water leachates of soils at sites regarded as background have slightly lower pH and lower Ca, Mg, K, and Na concentrations and total mineralization. Test for phytochelatins in the leaves proved to be rather ineffective, as also were estimates of the fluctuating asymmetry of the leaf laminas. The greatest differences were detected in the degree of leaf pathology and the contents of pigments.     

Numerical analysis of a pile–slab-supported railway embankment

This paper presents a numerical analysis of a well-monitored pile–slab-supported embankment for the Beijing–Tianjin high-speed railway in China. Cement–fly ash–gravel piles were used in this project. A coupled two-dimensional mechanical and hydraulic numerical model was used for this analysis and the results are compared with the field measurements including settlement, load distribution between soil and pile, and excess pore pressure. The numerical model calculated the settlement profile close to that measured in the field. The proportion of the load carried by the soil was small thus significantly reducing the settlement. The stress transfer from the soil to the piles reduced the excess pore pressure effectively. A parametric study was conducted to investigate the influence of three key factors on the performance of the embankment. The parametric study indicated that the existence of a cushion reduced the shear force in the slab. The increase in slab thickness and pile stiffness increased the shear force and bending moment in the slab. An increase in pile stiffness reduced the settlement and lateral displacement of the embankment.     

Hornblende–garnet–plagioclase thermobarometry: a natural assemblage calibration of the thermodynamics of hornblende

Calibrations are presented for an independent set of four equilibria between end-members of garnet, hornblende, plagioclase and quartz. Thermodynamic data from a large internally-consistent thermodynamic dataset are used to determine the ΔG° of the equilibria. Then, with the known mixing properties of garnet and plagioclase, the non-ideal mixing in amphibole is derived from a set of 74 natural garnet–amphibole–plagioclase–quartz assemblages crystallised in the range 4–13 kbar and 500–800 °C. The advantage of using known thermodynamic data to calculate ΔG° is that correlated variations of composition with temperature and pressure are not manifested in fictive derived entropies and volumes, but are accounted for with non-ideal mixing terms. The amphibole is modelled using a set of ten independent end-members whose mixing parameters are in good agreement with the small amount of data available in the literature. The equilibria used to calibrate the amphibole non-ideal mixing reproduce pressures and temperatures with average absolute deviations of 1.1 kbar and 35 °C using an average pressure–temperature approach, and 0.8 kbar with an average pressure approach. The mixing data provide not only a basis for thermobarometry involving additional phases, but also for calculation of phase diagrams in complex amphibole-bearing systems. Received: 8 November 1999 / Accepted: 7 July 2000     

Numerical modeling of soil–structure interface of a concrete-faced rockfill dam

Concrete-faced rockfill dams (CFRD) are widely used in large-scale hydraulic projects. The face slab, the key seepage-proof structure of great concern, has a strong interaction with the neighboring gravel cushion layer due to a significant difference in their stiffness. An elasto-plasticity damage interface element, a numerical format of the EPDI model, is described for numerical analysis of a CFRD that can trace the separation and re-contact between the face slab and the cushion layer at the interface. As verified by simulating slide block and direct shear interface tests, this element was confirmed to capture effectively the primary monotonic and cyclic behaviors of the interface. This element can easily be extended to the finite element method (FEM) programs that involve the Goodman interface element. The analysis of a typical CFRD showed that the interface model describes a significant effect on the stress response of the face slab under different conditions, including dam construction, water storage, and earthquake. Treatments of the cushion layer, such as an asphalt layer, changed the behavior of the interface between it and the face slab, which resulted in a significant effect on the stress response of the face slab. The top of the face slab exhibited a significant separation from the cushion layer during construction, induced mainly by construction of the neighboring dam body.     

Geochemical modelling of a Zn–Pb skarn: Constraints from LA–ICP–MS analysis of fluid inclusions

The Bismark deposit (northern Chihuahua, Mexico) is one of several base metal-rich high-temperature, carbonate-replacement deposits hosted in northern Mexico. Previous fluid inclusion studies based on microthermometry and PIXE have shown that the Zn-rich, Pb-poor Bismark deposit formed from a moderate salinity magmatic fluid [Baker, T. and Lang, J.R., 2003. Reconciling fluid inclusion types, fluid processes, and fluid sources in skarns: an example from the Bismark Deposit, Mexico. Mineralium Deposita 38(4), 474–495; Baker, T., van Achterberg, E., Ryan, C.G. and Lang, J.R., 2004. Composition and evolution of ore fluids in a magmatic-hydrothermal skarn deposit. Geology 32(2), 117–120]. The exact precipitation mechanisms are unclear and may have due to cooling, salinity decrease and wall rock reaction. Furthermore, PIXE data suggested that Pb and Zn concentrations were comparable and inconsistent with the Zn-rich nature of the ore. However, Pb was commonly below the limit of detection for PIXE and the data presented by Baker et al. [Baker, T., van Achterberg, E., Ryan, C.G. and Lang, J.R., 2004. Composition and evolution of ore fluids in a magmatic-hydrothermal skarn deposit. Geology 32(2), 117–120] are regarded as the maximum concentrations of Pb in the fluid. In this study new LA ICP MS analysis was carried out on the same fluid inclusion population to compare with the PIXE data in order to constrain the uncertainty related to the Pb data and the new results are used to model possible ore deposition mechanisms. The new laser ablation data reveal overall lower concentrations of Pb in the ore fluid (average value ~ 285 ppm) than previously indicated by PIXE analysis (average value ~ 713 ppm). Chemical modelling using the new laser ablation data tested the following ore deposition processes: 1) cooling; 2) fluid–rock reaction at constant temperature; 3) cooling and simultaneous fluid–rock interaction. Modelling results show that the gangue and ore minerals observed at Bismark are best reproduced by fluid–rock interaction and simultaneous cooling. Results from the simulations strongly indicate that ore deposition was mainly driven by a pH increase due to the neutralization of the acidic ore fluid (pH = 3.9) as the result of the reaction with the limestone. Modelling results also suggest that the deposit likely formed under cooling conditions, but do not support the hypothesis of a temperature decrease as the principal ore-forming process.     

Cyclic Swell–Shrink Behaviour of a Compacted Expansive Soil

Laboratory cyclic swell–shrink tests were carried out on compacted expansive soil specimens to study in detail the effect of changes in shrinkage pattern on the swell–shrink behaviour of compacted expansive soils. Compacted soil specimens were allowed to swell and either shrank fully or partially shrank to several predetermined heights in each cycle. The tests were carried out at a surcharge pressure of 50 kPa. The test results revealed that shrinkage of compacted saturated soil specimens to predetermined height in each shrinkage cycle provides similar conditions as that of the controlled suction tests with an increasing number of swell–shrink cycles. The water content of soil specimens and hence soil suction was found to remain nearly constant for each pattern of shrinkage. For soil specimens equilibrated to a given swell–shrink pattern, suction at the end of shrinkage cycles was changed from a higher suction to a lower suction, and also from a lower to a higher suction. The experimental results showed that there may be an immediate equilibrium state attained by the soil in terms of swell–shrink potential if suction at the shrinkage cycles was less than the past suction; otherwise, the equilibrium state was accompanied by fatigue of swelling. The volumetric deformation of the soil specimen subjected greater shrinkage was found to be much larger than the corresponding vertical deformation. The compressibility index of microstructure, κ_m, was determined for several shrinkage patterns. It is shown that κ_m is heavily influenced by suction at the end of shrinkage cycles.     

Synthesis and nutrient release patterns of a biochar-based N–P–K slow-release fertilizer

Biochar has excellent solute adsorption capacity, yet few studies have investigated its application as a nutrient carrier in the development of slow-release fertilizers. The current study developed a biochar-based N–P–K fertilizer (BSRF) and evaluated its nutrient release patterns relative to a conventional fertilizer. SEM and EDX analyses confirmed the coarse and highly porous microstructure of the biochar (SBC) that enabled it to effectively sorb NO₃ ^?, PO₄ ^3?, and K⁺ and form a nutrient-impregnated BSRF. BSRF had lower NO₃ ^?, PO₄ ^3?, and K⁺ release than the conventional chemical fertilizer, demonstrating its low release behavior. BSRF-amended sandy soil had higher water retention capacity than that amended with a conventional chemical fertilizer. BSRF has potential to reduce nutrient leaching, improve water retention, and hence increase crop nutrient and water use efficiencies. Future research should focus on understanding nutrient release mechanisms, synchronization of nutrient release with plant uptake, and applications of the BSRF in environmental remediation.     

Experimental modeling of native carbon formation in a C–O–H fluid system

Integrated data are presented on structure–morphology features, as well as on the material and phase composition, of a fluid-produced carbonaceous substance (CS) formed under known thermodynamic conditions of the experiment (C–O–H system, 500–800°C, and 500–1000 atm). Solid products of the synthesis were examined by means of X-ray phase and thermal analyses, scanning electron microscopy combined with microprobe analysis, transmission electron microscopy, high-resolution Raman spectroscopy, IR spectroscopy, and CHN-analysis. The characteristics of the experimental CS may be applicable in genetic modeling of natural ore-bearing fluidal carbonaceous systems.     

Magnetic–hydrophobic coagulation of paramagnetic minerals: a correlation of theory with experiments

A simple theoretical model of magnetic–hydrophobic coagulation considering the total interaction potential energy between two spheres exposed to an external magnetic field as a sum of the van der Waals, electrostatic, magnetic, and hydrophobic components is proposed. The model was used to interpret experiments on coagulation of fine siderite particles in distilled water and 10⁻² M KCl, hydrophobized by sodium oleate. In the experiments, a relative extent of the coagulation/stability equilibrium of the siderite suspension was evaluated photoelectrically. To estimate the model parameters, the ζ-potential and hydrophobicity of siderite particles were measured.A qualitative agreement was obtained between the model predictions (energy maximum and secondary minimum) and the experimental results (voltage changes after a selected interval of sedimentation) of the siderite suspensions. Moreover, a statistically significant correlation was found between the experimental voltages and the calculated energy maximum (a crucial factor of theories on the fine particle coagulation kinetics), which can be represented by a linear regression equation with the correlation coefficient of 0.979.     

Formation of the Olyutorsky–Kamchatka foldbelt: a kinematic model

The Olyutorsky–Kamchatka foldbelt formed as a result of two successive collisions of the Achaivayam–Valaginsky and Kronotsky–Commander island arcs with the Eurasian margin where the two terranes docked after a long NW transport. We model their motion history from the Middle Campanian to Present and illustrate the respective plate margin evolution with ten reconstructions. In this modeling the arcs are assumed to travel on the periphery of the large plates of Eurasia, North America, Pacific, and Kula, for which the velocities and directions of motion are known from published data. The model predicts that the Achaivayam–Valaginsky arc was the leading edge of the Kula plate from the Middle Campanian to the Middle Paleocene and then moved slowly with the Pacific plate as long as the Middle Eocene when it accreted to Eurasia. The Kronotsky arc initiated in the Middle Campanian on the margin of North America and was its part till the latest Paleocene when the terrane changed polarity to move northwestward with the Pacific plate and eventually to collide with Eurasia in the Late Miocene. The predicted paleolatitudes of the Achaivayam–Valaginsky and Kronotsky–Commander island arcs for the latest Cretaceous and Paleogene are consistent with nine (out of eleven) reliable paleomagnetic determinations for samples from the two arcs. Additional changes imposed on the initial model parameters (kinematics of the large plates, relative position of the Kula–Pacific Ridge and the Emperor seamount chain, or time of active volcanism within the arcs) worsen the fit of the final reconstructions to available geological and paleomagnetic data. Therefore, the suggested model appears to be the most consistent one at this stage of knowledge.     

Identification of a Holocene aquifer–lagoon system using hydrogeochemical data

The hydrogeochemical characteristics of the Cabo de Gata coastal aquifer (southeastern Spain) were studied in an attempt to explain the anomalous salinity of its groundwater. This detritic aquifer is characterised by the presence of waters with highly contrasting salinities; in some cases the salinity exceeds that of seawater. Multivariate analysis of water samples indicates two groups of water (G1 and G2). Group G1 is represented in the upper part of the aquifer, where the proportion of seawater varies between 10 and 60%, whilst G2 waters, taken from the lower part of the aquifer, contain 60−70% seawater. In addition, hydrogeochemical modelling was applied, which reveals that the waters have been subject to evaporation between 25 and 35%. There was a good agreement between the modelled results and the observed water chemistry. This evaporation would have occurred during the Holocene, in a coastal lagoon environment; the resulting brines would have infiltrated into the aquifer and, due to their greater density, sunk towards the impermeable base. The characteristics of this water enabled us to reconstruct the interactions that must have occurred between the coastal aquifer and the lagoon, and to identify the environmental conditions that prevailed in the study area during the Middle Holocene.     

Collapse of granular–cohesive soil mixtures on a horizontal plane

Acta Geotechnica - The collapse test with granular or cohesive materials known as ‘slump test’ is a simple, small-scale experiment. It can be used to study the rheology of soil masses...     

Soil–projectile interaction during penetration of a transparent clay simulant

Visualization of soil structure interaction during projectile penetration of clay is made possible by use of a surrogate composed of magnesium lithium phyllosilicate combined with high-speed photography and digital image correlation. A free-falling penetrator striking at 5.5 m/s simulated a projectile. Penetration resistance was constant within the resolution of the experiment; it was mainly due to the bearing resistance of the soil in contact with the nose, rather than skin friction. Bearing resistance in dynamic penetration for a hemispherical-nose rod was about 20% higher than quasi-static tests using a sphere. Bearing resistance was also about 20% higher for a hemispherical nose compared to a conical nose. Cavitation behind the nose is dependent on its shape with soils rebounding toward the projectile for conical noses but not hemispherical ones.

     

Preparation and Characterization of a New Layered Double Hydroxide, Mg–Fe–Ce

正1 Introduction In the present paper,MgCl2·6H2O,FeCl3·6H2O,and CeCl3·6H2O were used as raw materials in the precipitationhydrothermal method to synthesize MgF eC e hydrotalcite.The effects of the Fe:Ce molar ratio on the composition,crystal structure,and thermal stability of hydrotalcite are examined.Energy-dispersive X-ray spectroscopy(EDS),X-     

Solid phase iron–sulfur geochemistry of a reactive barrier for treatment of mine drainage

This paper discusses the solid phase Fe–S geochemistry of a reactive barrier at the Nickel Rim mine site (Ontario, Canada). The barrier, designed to treat groundwater contaminated by acid mine drainage, is composed of leaf and municipal compost and wood chips. This study shows that S is accumulating in the organic material as primarily acid volatile sulfides, at concentrations up to 195 μmol S g⁻¹ d.w. (0.63 wt% S) in a zone of preferential flow. Pyrite and/or S⁰ account for only a small fraction of the total reduced inorganic S, as oxidants are probably present at only low concentrations in the barrier system. The results of the solid phase analyses, the formation of disordered mackinawite (Fe_1+xS) on piezometer tubing, and thermodynamic calculations indicate that the precipitation of poorly crystalline Fe monosulfides is the primary sink for Fe and S in the barrier. Siderite (FeCO₃) formation is proposed as an additional Fe sink in areas of high Fe flux. Minor accumulations of acid-soluble, organically-bound S in the reactive barrier occur in zones of low aqueous Fe concentration. After 23 months of operation, the average rate of S accumulation at the up-gradient edge of the barrier is calculated to be 87 μmol S g⁻¹ a⁻¹ (d.w. organic material), or 47 mol S m⁻² a⁻¹ in the direction of groundwater flow. Solid phase analyses from samples collected 3 and 14 months after installation indicate that the S accumulation rate declined by a factor of 3 over that time period.     

A review of the pressure–temperature–time evolution of the Limpopo Belt: Constraints for a tectonic model

Published literature argues that the Limpopo Belt can be subdivided into three zones, each with a distinctive geological character and tectono-metamorphic fingerprint. There are currently two contrasting schools of thought regarding the tectono-metamorphic evolution of the CZ. One camp argues that geochronological, structural and prograde pressure–temperature (P–T) evidence collectively indicate that the CZ underwent tectono-metamorphism at ca. 2.0 Ga which followed a clockwise P–T evolution during a transpressive orogeny that was initiated by the collision of the Kaapvaal and Zimbabwe cratons. Deformation and metamorphism consistent with this scenario are observed in the southern part of the NMZ but are curiously absent from the whole of the SMZ. The opposing view argues that the peak metamorphism associated with the collision of the Kaapvaal and Zimbabwe cratons occurred at ca. 2.6 Ga and the later metamorphic event is an overprint associated with reactivation along Archean shear zones. Post-peak-metamorphic conditions, which at present cannot be convincingly related to either a ca. 2.6 or 2.0 Ga event in the CZ reveal contrasting retrograde paths implying either near-isothermal decompression and isobaric cooling associated with a ‘pop-up’ style of exhumation or steady decompression–cooling linked to exhumation controlled by erosion. Recent data argue that the prograde evolution of the ca. 2.0 Ga event is characterised by isobaric heating prior to decompression–cooling. Contrasting P–T paths indicate that either different units exist within the CZ that underwent different P–T evolutions or that some P–T work is erroneous due to the application of equilibrium thermobarometry to mineral assemblages that are not in equilibrium. The morphology of the P–T path(s) for the ca. 2.6–2.52 Ga event are also a matter of dispute. Some workers have postulated an anticlockwise P–T evolution during this period whilst others regard this metamorphic event as following a clockwise evolution. Granitoid magmatism is broadly contemporaneous in all three zones at ca. 2.7–2.5 suggesting a possible causal geodynamic link. P–T contrasts between and within the respective zones prevent, at present, the construction of a coherent and inter-related tectonic model that can account for all of the available evidence. Detailed and fully-integrated petrological and geochronological studies are required to produce reliable P–T–t paths that may resolve some of these pertinent issues.     

Analysis of the evolution of road tunnels equilibrium conditions with a convergence–confinement approach

Since both lining structure and rock mass exhibit delayed behaviour, tunnel equilibrium conditions evolve with time. After discussing existing work done on different aspects of long-term tunnel behaviour, the aim of this paper is to “understand” the influence of rock mass and lining degradations on the long-term stability conditions of the tunnel by means of the convergence–confinement method. In order to represent the effects of degradation on tunnel long-term conditions, specific degradation models are selected according to the disorders identified during principal inspections of road tunnels in Switzerland. By simulating the reduction of the mechanical properties of both the rock mass and the lining or by using creep models, it is possible to assess the influence of the main degradation processes on tunnel stability. The results are interpreted in terms of tunnel safety factor. The presented approach for the determination of the long-term behaviour of tunnels, although valid for simple tunnel geometry and field stress conditions, allows to roughly estimate the influence of significant degradation processes that affect the rock mass and the supporting structure. Though this approach results in some simplification, it may be generalised and adopted with more refined numerical analyses for improving the assessment of tunnel long-term conditions.