阿尔泰造山带南缘镁铁质岩体的地球化学特征及铜镍硫化物型矿床找矿前景

对阿尔泰造山带南缘锡泊渡、阿拉托别和托斯巴斯陶等镁铁质岩体的主量元素和微量元素地球化学特征进行研究，并与喀拉通克岩体进行了对比。结果表明，这些岩体的形成过程与喀拉通克岩体不同，进而评价了这些岩体的找矿前景，提出锡泊渡北岩体具有较好的成矿条件，其他几个岩体成矿条件不十分理想。     

秦岭造山带西段三叠纪透辉石岩-二长岩杂岩体的成因研究及其构造意义北大核心CSCD

镁铁质-长英质杂岩体的成因研究对探讨秦岭造山带在三叠纪时期的地球动力学背景具有重要的意义。对位于秦岭造山带西段的安王山透辉石岩-二长岩杂岩体进行了系统的锆石U-Pb定年和原位Hf同位素分析、全岩主元素和微量元素分析及全岩Sr-Nd同位素分析。透辉石岩-二长岩杂岩体主要由透辉石岩、辉长岩和二长岩组成。锆石U-Pb定年显示二长岩形成于(233±1)Ma。该杂岩体具有非常高的Ba(1395~5500μg/g)和Sr(652~2560μg/g)含量、平行且分馏的稀土元素分布模式、弱的Eu异常及相似且富集的Sr((^(87)Sr/^(86)Sr)i=0.70587)和Nd(εNd(t)=−1.85~−3.89)同位素组成。来自杂岩体的二长岩具有中度解耦的Hf-Nd同位素系统和负的ΔεHf(t)(−2.41~−4.90)值,这说明透辉石岩-二长岩杂岩体起源于被大陆碎屑沉积物熔体交代的富集地幔,并且在上升、侵位至地壳过程中经历了分离结晶作用。透辉石岩-二长岩杂岩体的成因研究表明,剪刀式大陆碰撞过程中出现的南东向板片撕裂导致了秦岭造山带内三叠纪镁铁质-长英质岩浆作用的形成。     

四顶黑山镁铁质—超镁铁质岩Sm-Nd等时线年龄及其意义

四顶黑山岩体主要由超镁铁质岩和镁铁质岩组成。超镁铁质岩由橄榄岩、角闪橄榄岩、辉橄岩、辉石岩等组成;镁铁质岩由辉长岩、角闪辉长岩、橄榄辉长岩等组成。本次对辉长岩进行了全岩Sm-Nd同位素分析,得到的等时线年龄为327±9.0Ma,初始εNd（t）=＋3.97,表明镁铁质—超镁铁质岩中辉长岩形成于早石炭世末。属于富集地幔向亏损地幔过渡类型。这一年龄的确定,为探讨北山—天山结合部晚古生代镁铁质—超镁铁质岩的成因机制和该区的区域地质演化提供了有效的年代学依据。     

赣中早第三纪镁铁质岩石的地质地球化学及其地质意义

赣中吉安-泰和白垩纪红盆中发育有大量的镁铁质岩石，呈岩墙、岩瘤等多种产状，野外穿插关系和全岩K-Ar法年龄(为49—65Ma，相当于古新世)均表明它们形成于早第三纪，微量元素以明显富集大离子亲石元素、中度富集高场强元素和轻稀土元素为特征，无明显的Nb和Ta负异常，同位素具有相对较低^87Sr／^86Sr(0．7041～0．7064)和较高^143Nd／^144Nd(εNd(T)= 0．8- 6．2)的特征。赣中古新世镁铁质岩石的地球化学特征表明它们与岛弧玄武岩明显不同，类似于洋岛玄武岩(OIB)。结合岩石的地质地球化学特征和区域地质发展史，认为赣中古新世镁铁质岩石的源区是EMⅡ型富集地幔和亏损地幔(DMM)混合，暗示古新世时太平洋板块对中国东南部的影响很弱，中国东南部自古新世初期进入大陆边缘的板内岩石圈伸展环境，岩石圈伸展与软流圈上涌有关。     

新疆坡北杂岩体西端镁铁-超镁铁质岩体成因的稀有气体同位素制约

新疆坡北镁铁-超镁铁质杂岩体由一个辉长岩体以及二十多个超镁铁质侵入体组成,其中坡一超镁铁质岩体稀有气体同位素组成揭示存在地幔柱的贡献。坡北杂岩体西端的坡一、坡四、坡十和坡十四等几个超镁铁质岩体的稀有气体同位素对比分析结果表明,岩浆矿物的³He/⁴He值（0.26~2.79Ra）分布于地壳与地幔值之间,较高的²⁰Ne/²²Ne和较低的²¹Ne/²²Ne值分布于Ne质量分馏线（MFL）和L-K线之间,⁴⁰Ar/³⁶Ar=295~598。³He/⁴He与⁴⁰Ar/³⁶Ar比值揭示坡北杂岩体西端不同超镁铁质岩体形成过程中地幔（柱）、地壳和大气组分的贡献不同,岩体成因也可能不同。其中,坡一岩体具有地幔柱作用的贡献,其他三个岩体的岩石圈地幔及地壳流体组分的贡献较大。岩浆地幔源区由深部地幔柱物质叠加俯冲流体交代的岩石圈地幔物质所组成,大气与地壳物质组分可能由俯冲再循环洋壳带入到岩浆地幔源区以及围岩物质的混入。     

新疆北部镁铁-超镁铁质岩的PGE成矿问题

铂族元素(PGE)矿化主要与镁铁-超镁铁杂岩有关,成矿类型主要为岩浆型矿床,这类PGE矿床的形成主要依赖两个条件:一是岩浆中富含PGE;二是具备PGE从岩浆中分离和富集的机制,主要是在岩浆演化过程中硫达到饱和。新疆北部镁铁-超镁铁质杂岩发育,并产有喀拉通克、黄山、黄山东、图拉尔根4个大型铜镍矿床和香山、土墩、葫芦、白石泉等中、小型铜镍矿,以及香山西、尾亚等中型钒钛磁铁矿矿床,但迄今尚未发现成型的PGE矿床。文中通过对PGE矿床的形成机制与镁铁-超镁铁杂岩源区特征研究,探讨了北疆地区PGE矿床的成矿问题。综合分析认为,新疆北部后碰撞镁铁-超镁铁质岩的岩石类型为经过了分离结晶形成的铁质岩石系列,是PGE矿床的有利容矿岩石;矿床的Sr、Nd、Pb、O、Os和S同位素和含矿岩石地球化学特征表明,铜镍硫化物矿床含矿岩浆在岩浆演化和成矿过程中有地壳物质加入并可导致硫化物熔离作用,说明在成矿机制上也存在形成岩浆型PGE矿化的条件。新疆北部PGE矿化微弱的原因可能在于该区广泛发育的亏损型地幔源(具正的εNd值特征),这一亏损型地幔可能部分源于洋壳熔融,与产于后碰撞造山带环境、发育于"洋壳"或"不成熟"陆壳基底之上有关,由此决定了原始岩浆为贫PGE的源区,因此不利于PGE的富集成矿。     

一个开放的岩浆房系统：攀西新街镁铁-超镁铁质层状岩体

新街镁铁-超镁铁岩体是与峨眉山溢流玄武岩同期共生的层状岩体之一，可分为三个火成堆积旋回，包括六个岩相带，各旋回下部主要由超镁铁岩组成，上部主要由辉长岩、橄长岩等组成。对第一旋回和第二旋回下部主量元素、微量元素和同位素分析结果表明，其总体特征与峨眉山玄武岩中的低钛玄武岩特征相似，其^87Sr/^86Sr,εNd（t）,^206Pb/^204Pb,^207Pb/^204Pb和^208Ph/^204Pb分别为0.70610-0.70636,1.01-1.75,17.895-18.935,15.563-15.639,38.345-39.037,这种相似性显示了新街岩体与峨眉山玄武岩具有成因联系，并且其同位素比值和高场强元素的原始地幔标准化图解和洋岛玄武岩（OIB）的相似性说明岩浆的源区可能为地幔柱。MgO和其它氧化物的相关性指示了橄榄石、斜方辉石和少量磁铁矿的分离结晶作用。另外，部分样品的（La/Nb）PM和（Th/Ta）PM大于1说明有地壳物质的混染或岩石圈地幔的混染。同时对O同位素值的测定结果表明，第二旋回和第一旋回上部的样品具有高δ^18O的特征（〉6‰），说明岩浆房的上部遭受了地壳物质的混染，而下部则没有受到地壳物质的混染。另外δ^18O与SiO2不存在正相关关系，指示了混染物不是上地壳，而是SiO2较低的下地壳。其Nd同位素和O同位素模拟计算结果表明，其平均混染程度大约为12％-15％。可能正是由于下地壳物质的混染导致了岩浆中FeO含量的降低，从而导致硫化物发生熔离作用，并由此导致铂族元素的富集。     

南岭东段燕山期镁铁质岩石Nd-Sr同位素研究及意义

南岭东段燕山期镁铁质岩浆活动可划分为4个阶段(中侏罗世、晚侏罗世、早白垩世和晚白垩世),分别对应4次重要的伸展拉张作用时期。镁铁质岩石具有基本类似的Nd—Sr同位素特征,ISr较高(一般介于0．705～0．710之间),εNd值变化范围较大(介于-7．90～5．16之间),表明其岩浆源为壳-幔混合源性质。镁铁质岩石具有板内拉斑玄武岩特征,系形成于板内拉张环境,表明该区在燕山早期的中侏罗世即已进入后造山演化阶段。岩石的成因模式为地幔镁铁质岩浆在上升至地壳底部过程中,受到地壳组分的混染,在岩石圈伸展的深部背景和浅部拉张状态下形成。     

大别造山带中镁铁质——超镁铁质岩石和榴辉岩有关问题的讨论

根据近年来积累的文献资料及研究讨论指出：（１）大别山造带镁铁质－－超镁铁质岩石可分成两大类;一类以任家湾、童家冲、祝家铺道士冲、青山、沙河等辉石辉长岩类为代表,它们具有相同的牲和成岩年龄,可能与华北、华南地块聚敛碰产生的岛弧或大陆岩浆岩有关;另一类以铙拔寨,大化坪、碧溪岭和毛屋岩体为代表,虽然它们的成岩年龄均在前寒武纪,但却有着不同的成岩时代和成岩环境。（２）大别造山带榴辉岩等多属异地来源,具有不     

内蒙古中部地区镁铁质-超镁铁质岩形成时代及地质意义

为探讨内蒙古中部地区镁铁质-超镁铁质岩形成时代及地球化学特征,完善区域成岩成矿年代学格架,本文对克布、黄花滩和小南山岩体进行了锆石U-Pb年代学及全岩地球化学分析。LA-ICP-MS锆石U-Pb测年获得克布和黄花滩镁铁质-超镁铁质岩结晶年龄分别为258±2 Ma(MSWD=2.3)和262±1 Ma(MSWD=0.51),属于中-晚二叠世,小南山辉长岩应形成于中-晚二叠世(～273 Ma)。全岩地球化学分析表明,三个岩体样品m/f值介于0.96～3.54之间,主要为镁铁质-超镁铁质岩,其稀土和微量元素曲线基本表现为轻稀土元素(LREE)和大离子亲石元素(LILE)相对富集,高场强元素(HFSE)相对亏损的相似性特征,但也有明显的区别,显示各岩体岩浆演化或分异程度可能不尽相同。综合区域研究资料表明,内蒙古中部地区晚古生代镁铁质-超镁铁质岩浆活动可能至少始于早二叠世(294Ma),持续至中-晚二叠世(273～258Ma),且二叠纪时期中亚造山带南缘较大范围内均发育较为活跃的幔源岩浆活动。克布、黄花滩和小南山岩体应形成于后碰撞伸展环境,其岩浆源区可能混染了俯冲流体交代改造的地幔楔物质,使3个岩体的岩石样品均显示具有富含大离子亲石元素和轻稀土元素,贫高场强元素等部分岛弧岩浆特征的信号。     

南秦岭下地壳组成及岩石圈的拆离俯冲作用

根据新提供的Pb同位素组成及岩石地球化学研究成果，本文进一步证实了位于北秦岭北界的明港地区发育的早中生代安山玄武质火山角砾岩岩筒所携带的下地壳捕虏体属于南秦岭。所恢复的南秦岭下地壳剖面自下而上为：底侵成因的变辉长岩-基性麻粒岩(其中含有榴辉岩及辉石岩的透镜体)-酸性麻粒岩。秦岭造山带总体的岩石因模型为：南秦岭(扬子块体)向北拆离俯冲，北秦岭地壳向华北仰冲，华北岩石因呈楔状插入秦岭造山带，拆离面约在中、下地壳之间。南秦岭俯冲岩片延伸的范围在平面上有可能达到400km。     

青藏高原综合观测研究站的回顾与展望

中国科学院青藏高原综合观测研究站从１９８８年建站到１９９８年以来,在各个方面均取得了长足的发展,横向生产性项目的开展和完成不仅解决了部队和地方的实际问题,而且缓和了观测研究站在运行过程中所面临的经费严重不足的问题,同时也为我所冻土专业研究人员提供了在生产中实践的机会,在基础理论研究方面,承担了国家攀登计划项目,国家基金项目,中国科学院重点项目和中国科学院冰冻圈专项项目等的研究工作,在多年冻土变化,     

铀钍的地球化学及对地壳演化和生物进化的影响

本文论述了在含挥发份和贫挥发份条件下Ｕ、Ｔｈ的迁移行为及其对地球和行星演化的影响,并阐述了造成地球独特地质演化历史的原因。提出了Ｕ、Ｔｈ在地球中的迁移模式以及该模式对地壳形成、演化的控制作用和对生物发展演化的可能影响。     

Wavelets and the Generalization of the Variogram

The experimental variogram computed in the usual way by the method of moments and the Haar wavelet transform are similar in that they filter data and yield informative summaries that may be interpreted. The variogram filters out constant values; wavelets can filter variation at several spatial scales and thereby provide a richer repertoire for analysis and demand no assumptions other than that of finite variance. This paper compares the two functions, identifying that part of the Haar wavelet transform that gives it its advantages. It goes on to show that the generalized variogram of order k=1, 2, and 3 filters linear, quadratic, and cubic polynomials from the data, respectively, which correspond with more complex wavelets in Daubechies's family. The additional filter coefficients of the latter can reveal features of the data that are not evident in its usual form. Three examples in which data recorded at regular intervals on transects are analyzed illustrate the extended form of the variogram. The apparent periodicity of gilgais in Australia seems to be accentuated as filter coefficients are added, but otherwise the analysis provides no new insight. Analysis of hyerpsectral data with a strong linear trend showed that the wavelet-based variograms filtered it out. Adding filter coefficients in the analysis of the topsoil across the Jurassic scarplands of England changed the upper bound of the variogram; it then resembled the within-class variogram computed by the method of moments. To elucidate these results, we simulated several series of data to represent a random process with values fluctuating about a mean, data with long-range linear trend, data with local trend, and data with stepped transitions. The results suggest that the wavelet variogram can filter out the effects of long-range trend, but not local trend, and of transitions from one class to another, as across boundaries.     

共和盆地层状地貌系统与青藏高原隆升及黄河发育

利用卫星遥感影像,结合实地调查和测年结果,对共和盆地层状地貌系统进行了解译、分析。研究表明,共和盆地层状地貌系统由山麓剥蚀面、洪积扇面、盆地面以及黄河阶地面构成,其空间结构、物质组成对发生于早更新世早期的青藏运动C幕和中更新世末期的共和运动反映清晰。青藏运动C幕使青藏高原主夷平面在高原差异性隆升中彻底解体,垂直变形量高达1700m。共和运动使黄河在0.11Ma进入共和盆地,其后黄河平均以3.5mm/a的侵蚀速率下切盆地,同时在盆地边部的山前古冲洪积扇以大致相近的速率被抬升,最终导致高差在2000m左右的层状地貌系统的出现。     

从榴辉岩与围岩的关系论苏鲁榴辉岩的形成与折返

位于华北和扬子两板块碰撞带中的苏鲁榴辉岩形成的温压条件不但是超高压，而且是高温。榴辉岩的PTt轨迹表明其为陆-陆磁撞俯冲带的产物。榴辉岩的区域性围岩花岗质片麻岩为新元古代同碰撞期花岗岩，榴辉岩及其他直接围岩皆呈包体存在于其中，并见新元古代花岗岩呈脉状侵入榴辉岩包体中。区域性围岩新元古代花岗岩的锆石中发现有柯石英、绿辉石等包裹体，表明新元古代花岗岩的组成物质也经受过超高压变质作用，且榴辉岩与围岩新元古代花岗岩的锆石U-Pb体系同位素年龄基本相同。但新元古代花岗岩所记录的变质作用和变形作用期次（或阶段）却少于榴辉岩。椐上述可得如下推断：超高压榴辉岩与新元古代花岗岩岩浆是同时在碰撞带底部（俯冲板块前部）形成的；榴辉岩的第一折返阶段是由新元古代花岗岩岩浆携带上升的，其第二折返阶段是和新元古代花岗岩一起由逆冲及区域性隆起而上升，遭受剥蚀。     

南海的形成演化与新特提斯在南海的重新活化

南海位于印度板块、欧亚板块和太平洋板块之间,是世界上最大的边缘海,其构造位置处于太平洋构造域和特提斯构造域,地质构造复杂.关于南海形成演化的动力学机制存在有多种不同观点,其中最重要的一个观点是印度板块与欧亚板块的碰撞致使华南地块和印支地块地幔物质沿东南方向蠕动,从而导致南海的海底扩张.从特提斯的演化规律,以及新特提斯的闭合过程来看,南海并不是特提斯洋的残留海,而是新特提斯在闭合过程中配合印度板块与欧亚板块碰撞导致华南地块和印支地块地幔物质东南方向蠕动的动力学机制下,在南海重新活化的结果.     

Principles of spatial organization and evolution of the biosphere and the noosphere

In his last lifetime essay, “A Few Words about the Noosphere”, Academician V.I. Vernadsky (1944) wrote that all living organisms on the planet, including man, are integral to the biosphere of the Earth, its material and energy structure and cannot be physically independent of it even for a minute. However, the substrate that generates all living beings and is no less tightly bound to the biosphere has always been characterized by a significant geochemical heterogeneity, traced both in the vertical and in the lateral structure of all geospheres.

The present work is devoted to three most important aspects of modern geochemistry and biogeochemistry:

• — evolution of the ecological and geochemical state of the environment under conditions of a virgin (anthropogenically untouched) biosphere;
• — structural features of the geochemical organization of the modern noosphere;
• — specificity of the interaction of living matter with the environment under increasing anthropogenic load.

On the basis of theoretical concepts of biogeochemistry and geochemical ecology, formulated in the works of V.I. Vernadsky, A.P. Vinogradov, A.E. Fersman, B.B. Polynov, A.I. Perel’man, M.A. Glazovskaya, V.V. Kovalsky, E. Odum, B. Commoner, E.I. Kolchinskii and others, the author puts forward a hypothesis that there exist two qualitatively different stages in the evolution of the biosphere.The first stage is recognized as the period of natural evolution of the biosphere during which it evolves successively into a more complex and more biogeochemically specialized object. In the course of the geological time, this constantly results, on the one hand, in an increase in species diversity and the perfection of individual species, and, on the other hand, to directed improvement and a greater differentiation of the geochemical conditions of the environment. At this stage, the evolution of all systems of the biosphere that were controlled by the mechanisms of self-organization and self-regulation resulted in the establishment of a dynamic equilibrium, which was responsible for the cycling of all essential chemical elements and therefore providing ecologically optimal geochemical conditions in all ecological niches and for all species and biocenoses inhabiting the biosphere at any given moment.The beginning of the second stage is related to the appearance of reason and qualitative changes in the biosphere caused by the goal-directed activity of the human mind, as an entirely new geological force that appeared to be able not only to disrupt the functioning of natural mechanisms of self-regulation and selforganization, but also to transform the environment in the intersts of a single biological species, Homo sapiens. A direct consequence of this change was the uncontrolled transformation of the natural environment, during which the primary structure (geochemical background) created in the course of billions of years was eventually superimposed by a qualitatively new layer of anthropogenically-derived chemical elements and compounds, thus building an interference pattern of a new geochemical field with which practically all modern living organisms are now forced to interact.An outstanding feature of the new evolutionary stage of the natural environment, called by Vernadsky the noosphere, is that biogeochemical changes at this stage proceed at a rate which exceeds that required for the living matter to adapt to these changes. The result is the disruption of the existing parameters of the biological cycle, leading to the emergence of a significant number of endemic diseases of geochemical nature.The proposed approach was used to prove the anthropogenic genesis of existing geochemical endemic diseases and explain the mechanisms of their appearance. In addition, this approach allowed us to develop a new methodology for mapping zones of ecological and geochemical risk and noticeably simplify the procedure of monitoring distribution and prevention of all diseases of geochemical nature.