班公湖-怒江洋早-中侏罗世洋内俯冲:来自洞错蛇绿岩的证据

本文在班公湖-怒江缝合带中段洞错蛇绿岩中新厘定一套洋内俯冲成因的岩石组合,岩性以橄榄岩、堆晶岩(包括堆晶辉长岩和斜长花岗岩)、辉长岩墙、枕状熔岩和辉绿岩脉等为主。堆晶辉长岩、辉长岩墙和辉绿岩脉锆石U-Pb测年显示,它们形成于中侏罗世(172～165Ma)。辉长岩墙和辉绿岩脉地球化学和锆石Lu-Hf同位素分析显示,它们兼具N-MORB和岛弧玄武岩地球化学特征,且均来自亏损地幔源区,形成过程中受到了俯冲流体的影响。结合区域上同时期的玻安岩、高镁安山岩和钙碱性岩浆岩等资料,我们得出班公湖-怒江缝合带内保存了一套相对完整的早-中侏罗世洋内弧岩石层序,记录了班公湖-怒江洋早-中侏罗世时期的洋内俯冲事件。早-中侏罗世是班公湖-怒江洋快速消减期,洋内俯冲和洋-陆俯冲同时存在。     

西藏东巧蛇绿岩中辉长岩锆石SHRIMP定年及其地质意义

东巧蛇绿岩位于分割羌塘地块和拉萨地块的班公湖—怒江缝合带中段,是该带最著名的产铬铁矿床的蛇绿岩残片之一。该蛇绿岩遭受构造肢解,恢复后的蛇绿岩剖面各岩石单元齐全。本文应用SHRIMPⅡ锆石UPb法,对东巧蛇绿岩中堆晶辉长岩进行了测年,获得辉长岩年龄为187.8±3.7 Ma。该年龄代表了东巧洋盆的形成时代,为确定研究区特提斯洋盆的古构造格局及其发育演化过程等提供了重要的年代学制约。     

青藏高原班公湖-怒江结合带中段那曲县觉翁地区发现完整的蛇绿岩剖面

在位于班公湖-怒江结合带中段的那曲县觉翁地区首次发现较完整的蛇绿岩剖面，由下到上见有变质橄榄岩、辉橄岩、堆晶岩、块状辉长岩、岩墙群、碳酸盐岩、枕状熔岩、放射虫硅质岩等，被晚白垩世竟柱山组角度不整合覆盖，在堆晶岩中获同位素年龄值128Ma，从而证实蛇绿岩的时代为早白垩世。这一发现填补了班公湖-怒江结合带中段无完整蛇绿岩剖面的空白，并证实除侏罗纪蛇绿岩外还存在白垩纪蛇绿岩，为班公湖-怒江结合带中段最终闭合时间的确定提供了依据。     

班公湖中特提斯洋向南俯冲的时限:来自SSZ型辉长岩的制约

班公湖-怒江中特提斯洋的俯冲极性和俯冲时间一直存在争议。作者通过野外地质调查、岩相学、锆石U-Pb年代学及岩石地球化学研究,从西藏班公湖蛇绿混杂岩带中识别出一套早白垩世SSZ型蛇绿岩,岩石组合上主要由辉长岩和玄武岩组成,还有少量的硅质岩和超基性岩。本文对辉长岩进行了全岩主、微量元素地球化学及LA-ICP-MS锆石U-Pb年代学研究。地球化学组成特征显示,辉长岩富集轻稀土元素,重稀土元素平坦,相对富集大离子亲石元素,高场强元素存在一定亏损;Th/Ta比值与岛弧玄武岩相似(Th/Ta1.6),Ta/Hf比值较高(0.1),显示其既保留了俯冲环境的地球化学特征,也提供了伸展构造环境的信息。辉长岩中锆石U-Pb加权平均年龄为129.2±0.4 Ma(MSWD=0.36),该年龄是班公湖-怒江缝合带中迄今报道的最年轻蛇绿岩年龄。结合区域地质背景,认为这套蛇绿岩形成于班公湖-怒江古洋盆西段向南俯冲形成的弧前盆地,而班公湖-怒江古洋盆北向俯冲可能始于早侏罗世,晚侏罗世形成双向俯冲格局,直到早白垩世洋盆关闭,晚白垩世进入陆内构造环境。     

藏北羌塘中部果干加年山早古生代堆晶辉长岩的锆石SHRIMP U-Pb年龄——兼论原-古特提斯洋的演化

位于羌塘中部龙木错-双湖缝合带中的果干加年山早古生代堆晶岩,主要由辉石橄榄岩、堆晶辉石岩、堆晶辉长岩、斜长岩等岩石类型组成.对堆晶辉长岩中锆石的矿物学与年代学研究表明.堆晶辉长岩中发育3种内部结构特征的锆石晶体,锆石Th、U含量和Th/U值揭示了同一岩浆系统中结晶形成的岩浆锆石.获得堆晶辉长岩SHRIMP锆石U-Pb谐和年龄461Ma±7Ma(MSWD=1.3)、431.7Ma±6.9Ma(MSWD=0.54),分别代表了青藏高原中部地区原一古特提斯洋扩张过程中早期(中奥陶世Darriwilian阶晚期)、晚期(早志留世Telychian阶中期)的岩浆作用事件.果干加年山早古生代堆晶岩具有MORB.的特征,代表了龙木错-双湖缝合带中残存的早古生代蛇绿岩,也是青藏高原中南部地区目前为止认知时代最早的原一古特提斯洋壳的残迹.羌塘中部早古生代蛇绿岩的确定及其年代学的约束,使得龙木错-双湖特提斯洋盆的形成时代至少可以追溯到中奥陶世-早志留世,并推论龙木错-双湖缝合带、南羌塘古生代增生楔及其中生代盆地和班公湖-怒江缝合带共同构成了青藏高原特提斯大洋最终消亡的巨型缝合带,晚古生代原-古特提斯洋向南的俯冲消减导致了冈底斯带石炭纪-二叠纪岛孤型火山岩、二叠纪花岗闪长岩和大洋俯冲型榴辉岩的形成.     

西藏班公湖-怒江缝合带中段江错蛇绿岩岩石学、地球化学、年代学及地质意义

江错蛇绿岩位于班公湖-怒江缝合带中段, 位于切里湖蛇绿岩亚带的最东端, 南邻蓬湖西蛇绿岩.江错蛇绿岩岩石组合相对较全, 主要由变质橄榄岩、辉长岩和辉绿岩等组成.江错蛇绿岩辉长岩-辉绿岩与N-MORB相比具有较高的Mg#、低Ti、K、Na和P的特征, 富集大离子亲石元素Sr、Rb、Ba和亏损高场强元素Th、Hf、Ta、Nb, REE配分图总体显示为平坦型分布模式.通过地球化学元素分析认为江错蛇绿岩是形成于SSZ之上的弧后盆地扩张脊环境.对其进行辉长岩锆石SHRIMP U-Pb定年, 得出加权平均年龄为189.8±3.3 Ma(MSWD=0.97), 该结果代表了班公湖怒江缝合带中段江错地区特提斯洋的扩张时代, 与中段东巧地区蛇绿岩年龄一致, 但晚于东段洋盆发育时代且早于西段洋盆发育时代, 表明整个班公湖-怒江洋盆发育时代存在东早西晚的特点.      

北天山巴音沟蛇绿岩形成于早石炭世:来自辉长岩LA-ICPMS锆石U-Pb年龄的证据

北天山巴音沟蛇绿岩中堆晶辉长岩的LA-ICPMS锆石U-Pb测年结果确定:巴音沟蛇绿岩中辉长岩形成的同位素地质年代为344.0±3.4Ma。表明巴音沟蛇绿岩所代表的洋盆形成于早石炭世。综合前人天山石炭纪蛇绿岩及构造演化的研究成果,笔者认为巴音沟蛇绿岩是大陆板内强烈拉张的产物。     

西藏改则县拉果错蛇绿岩构造属性:来自岩石学、地球化学、年代学及Lu-Hf同位素的制约

拉果错蛇绿岩是狮泉河-阿索-嘉黎蛇绿岩带中出露最完整的蛇绿岩组合之一,对恢复和反演该缝合带所代表洋盆演化具有重要意义。然而,目前拉果错蛇绿岩的成因及构造环境还不清楚,时代也存在争议。选择拉果错蛇绿岩中的斜长花岗岩和堆晶辉长岩作为研究对象,开展了野外勘查及剖面的测制,以及地球化学、LA-ICP-MS锆石U-Pb定年及Lu-Hf同位素研究,并结合区域地层、岩浆岩等相关资料,探讨了拉果错蛇绿岩的构造属性。拉果错斜长花岗岩和辉长岩野外呈整合接触,地球化学特征表明二者具有同源性,具有与E-MORB(富集大洋中脊玄武岩)相似的稀土元素配分形式和微量特征;Lu-Hf同位素显示岩浆源区为亏损地幔,由多种组分组成,可能来源于亏损地幔和Ⅱ型富集地幔二组分混合的地幔源区;斜长花岗岩和辉长岩LA-ICP-MS锆石U-Pb定年分别获得184.1±0.79Ma和183.5±2.2Ma的谐和年龄,代表了拉果错蛇绿岩的形成时代。研究表明,拉果错蛇绿岩形成于具有强烈大洋中脊玄武岩特征的弧后盆地环境。     

金沙江缝合带西段蛇绿岩与弧火山岩成对性关系——来自地球化学和LA-ICP-MS锆石U-Pb年龄证据

对金沙江缝合带西段青海治多地区的多彩蛇绿混杂岩和当江荣中酸性岛弧火山岩进行了研究,野外地质剖面显示,蛇绿岩主要由辉长岩、堆晶辉长岩和玄武岩组成,缺少地幔橄榄岩单元。通过对蛇绿岩内部细粒辉长岩、基性熔岩的地球化学测试及堆晶辉长岩的LA-ICP-MS锆石U-Pb测年发现,基性熔岩可分为2种类型,即洋岛玄武岩OIB型和MORB-IAT型。前者并非蛇绿岩组分,为构造就位时带入;后者为过渡类型,具有典型洋中脊—岛弧蛇绿岩地球化学特征。辉长岩具有明显的TNT槽等岛弧信号,与类型二均属于蛇绿岩成分。测得的堆晶辉长岩中锆石U-Pb年龄为252.50Ma±0.58Ma(MSWD=0.95),是蛇绿岩的形成年龄。研究认为,多彩蛇绿岩与当江荣火山岩具有成对性关系,结合造山带沟—弧—盆体系构造格局,认为前者形成于岛弧偏海沟的弧前构造背景,是晚二叠世金沙江洋持续俯冲的产物。     

西藏班公湖-怒江缝合带西段洞错蛇绿岩中的辉长岩锆石U-Pb年代学及地质意义

洞错蛇绿岩位于班公湖-怒江缝合带西段阿里地区,前人对其空间展布、构造环境及成因有过一定的探讨,但研究程度薄弱.选择洞错蛇绿岩中的辉长岩为研究对象,对其开展详细的岩相学、地球化学、年代学等工作,解读洋盆的形成时间及构造环境.结果表明,辉长岩与N-MORB相比具有较高的Mg#,低K、Na、P和Ti的元素特征,亏损Hf、Zr、Nb等高场强元素（HFSE）,具有轻稀土亏损型配分模式,表明可能源于N-MORB型亏损地幔源区.地球化学元素研究表明辉长岩岩浆源自亏损的尖晶石二辉橄榄岩~30%部分熔融,可能形成于与洋内俯冲相关的岛弧或者弧前构造环境,属于SSZ型蛇绿岩.辉长岩锆石的U-Pb测年指示其结晶年龄为222±4.8 Ma（MSWD=0.5,n=28）,代表了辉长岩的形成年龄,佐证了洞错蛇绿岩形成于晚三叠世,表明班公湖-怒江特提斯洋盆从晚三叠世开始存在洋内俯冲消减地质作用.      

Wavelength-dispersive X-ray fluorescence spectrometric determination of Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites

Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.     

高压微波消解法测定醋酸纤维过滤器采集的微尘粒子中的砷镉钴铬铜铁锰镍铅钒锌

最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提     

Isotopic systematics of He,Ar, S,Cu, Ni,Re, Os,Pb, U,Sm, Nd,Rb, Sr,Lu, and Hf in the rocks and ores of the Norilsk deposits

This paper reports the first results of a study of 11 isotope systems (³He/⁴He, ⁴⁰Ar/³⁶Ar, ³⁴S/³²S, ⁶⁵Cu/⁶³Cu, ⁶²Ni/⁶⁰Ni, ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ^206–208Pb/²⁰⁴Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.     

硅酸盐中铁、锰、钛、钙、钾、磷、硅、铝、镁、钠、锶、铷、钡的X-射线荧光光谱定量测定

本文介绍样品经四硼酸锂熔融制成玻璃小饼。采用Lachance模式和理论a系数来校正元素间的效应,由3080E型X-射线荧光谱仪和DF-350B数据处理系统完成硅酸盐中十三个项目的测定。     

硅酸盐类样品中硅、铁、铝、钛、锰、钙、镁、钾、钠和磷的x射线荧光光谱测定

本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。     

Viscous, cohesive, non-Newtonian, depositing, radial slurry flow

Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.     

Mountains,nations, parks,and conservation

Between 1985 and 1991, two new mountain protected areas (MTNPA) covering more than 35,000 km² and based on participatory management models — the Makalu-Barun National Park and Conservation Area, Nepal, and Qomolangma Nature Preserve, Tibet Autonomous Region — were successfully established through the collaborative efforts of Woodlands Mountain Institute and conservationists in China and Nepal. Characteristics common to both projects include the importance of establishing (1) effective rationales, (2) local support constituencies, (3) a senior advisory group, (4) a task force, (5) linkages between conservation and development, and (6) fund raising mechanisms. The lessons derived from the experiences of Woodlands Mountain Institute are of significant value to others in preserving MTNPA. Increased collaboration and communication between all interested in conservation, however, will remain a critical component for expanding mountain protected area coverage to throughout the world.     

Regional distribution of Al,B, Ba,Ca, K,La, Mg,Mn, Na,P, Rb,Si, Sr,Th, U and Y in terrestrial moss within a 188,000 km2 area of the central Barents region: influence of geology,seaspray and human activity

Five hundred and ninety-eight samples of terrestrial moss (Hylocomium splendens and Pleurozium schreberi) collected from a 188,000 km² area of the central Barents region (NE Norway, N Finland, NW Russia) were analysed by ICP-AES and ICP-MS. Analytical results for Al, B, Ba, Ca, K, La, Mg, Mn, Na, P, Rb, Si, Sr, Th, U and Y concentrations are reported here. Graphical methods of data analysis, such as geochemical maps, cumulative frequency diagrams, boxplots and scatterplots, are used to interpret the origin of the patterns for these elements. None of the elements reported here are emitted in significant amounts from the smelting industry on the Kola Peninsula. Despite the conventional view that moss chemistry reflects atmospheric element input, the nature of the underlying mineral substrate (regolith or bedrock) is found to have a considerable influence on moss composition for several elements. This influence of the chemistry of the mineral substrate can take place in a variety of ways. (1) It can be completely natural, reflecting the ability of higher plants to take up elements from deep soil horizons and shed them with litterfall onto the surface. (2) It can result from naturally increased soil dust input where vegetation is scarce due to harsh climatic conditions for instance. Alternatively, substrate influence can be enhanced by human activity, such as open-cast mining, creation of ‘technogenic deserts’, or handling, transport and storage of ore and ore products, all of which magnify the natural elemental flux from bedrock to ground vegetation. Seaspray is another natural process affecting moss composition in the area (Mg, Na), and this is most visible in the Norwegian part of the study area. Presence or absence of some plant species, e.g., lichens, seems to influence moss chemistry. This is shown by the low concentrations of B or K in moss on the Finnish and Norwegian side of the (fenced) border with Russia, contrasting with high concentrations on the other side (intensive reindeer husbandry west of the border has selectively depleted the lichen population).     

NEW SET OF LOW CONCENTRATION STANDARDS FOR LA, CE, SM, YB, LU, Y, SC, V, NB AND TA IN SILICATES

We have developed a set of four synthetic standards for the rare earth and high field strength elements designed for use in the determination of those elements in silicates. The base material is a glass nominally at the eutectic of the MgO-Al₂O₃-SiO₂ ternary system. The nominal doping level was 2 wt% of the elements as oxides. To avoid problems associated with peak interference, the elements were doped in four separate glasses.