http://www.sciencedirect.com/science/article/pii/S1674987111000387

Fluid flow is an integral part of hydrothermal mineralization,and its analysis and characterization constitute an important part of a mineralization model.The hydrodynamic study of mineralization deals with analyzing the driving forces,fluid pressure regimes,fluid flow rate and direction,and their relationships with localization of mineralization.This paper reviews the principles and methods of hydrodynamic studies of mineralization,and discusses their significance and limitations for ore deposit studies and mineral exploration. The driving forces of fluid flow may be related to fluid overpressure,topographic relief,tectonic deformation, and fluid density change due to heating or salinity variation,depending on specific geologic environments and mineralization processes.The study methods may be classified into three types,megascopic(field) observations, microscopic analyses,and numerical modeling.Megascopic features indicative of significantly overpressured (especially lithostatic or supralithostatic) fluid systems include horizontal veins,sand injection dikes,and hydraulic breccias.Microscopic studies,especially microthermometry of fluid inclusions and combined stress analysis and microthermometry of fluid inclusion planes(FIPs) can provide important information about fluid temperature,pressure,and fluid-structural relationships,thus constraining fluid flow models.Numerical modeling can be carried out to solve partial differential equations governing fluid flow, heat transfer,rock deformation and chemical reactions,in order to simulate the distribution of fluid pressure, temperature,fluid flow rate and direction,and mineral precipitation or dissolution in 2D or 3D space and through time.The results of hydrodynamic studies of mineralization can enhance our understanding of the formation processes of hydrothermal deposits,and can be used directly or indirectly in mineral exploration.     

http://www.sciencedirect.com/science/article/pii/S1674987111000466

The Ordos Basin of North China is not only an important uranium mineralization province, but also a major producer of oil,gas and coal in China.The genetic relationship between uranium mineralization and hydrocarbons has been recognized by a number of previous studies,but it has not been well understood in terms of the hydrodynamics of basin fluid flow.We have demonstrated in a previous study that the preferential localization of Cretaceous uranium mineralization in the upper part of the Ordos Jurassic section may have been related to the interface between an upward flowing,reducing fluid and a downward flowing,oxidizing fluid.This interface may have been controlled by the interplay between fluid overpressure related to disequilibrium sediment compaction and which drove the upward flow,and topographic relief,which drove the downward flow.In this study,we carried out numerical modeling for the contribution of oil and gas generation to the development of fluid overpressure,in addition to sediment compaction and heating.Our results indicate that when hydrocarbon generation is taken into account,fluid overpressure during the Cretaceous was more than doubled in comparison with the simulation when hydrocarbon generation was not considered.Furthermore,fluid overpressure dissipation at the end of sedimentation slowed down relative to the no-hydrocarbon generation case.These results suggest that hydrocarbon generation may have played an important role in uranium mineralization,not only in providing reducing agents required for the mineralization,but also in contributing to the driving force to maintain the upward flow.     

Mantle convection modeling of the supercontinent cycle： Introversion,extroversion, or a combination？

The periodic assembly and dispersal of continental fragments,referred to as the supercontinent cycle,bear close relation to the evolution of mantle convection and plate tectonics.Supercontinent formation involves complex processes of"introversion"(closure of interior oceans),"extroversion"(closure of exterior oceans),or a combination of these processes in uniting dispersed continental fragments.Recent developments in numerical modeling and advancements in computation techniques enable us to simulate Earth’s mantle convection with drifting continents under realistic convection vigor and rheology in Earth-like geometry(i.e.,3D spherical-shell).We report a numerical simulation of 3D mantle convection,incorporating drifting deformable continents,to evaluate supercontinent processes in a realistic mantle convection regime.Our results show that supercontinents are assembled by a combination of introversion and extroversion processes.Small-scale thermal heterogeneity dominates deep mantle convection during the supercontinent cycle,although large-scale upwelling plumes intermittently originate under the drifting continents and/or the supercontinent.     

http://www.sciencedirect.com/science/article/pii/S1674987111000508

This paper presents the results of a set of numerical models focussing on structural controls on hydrothermal mineralization.We first give an overview of natural phenomena of structurally-controlled ore formation and the background theory and mechanisms for such controls. We then provide the results of a group of simple 2D numerical models validated through comparison with Cu-vein structure observed near the Shilu Copper deposit(Yangchun,Guangdong Province, China) and finally a case study of 3D numerical modelling applied to the Hodgkinson Province in North Queensland(Australia).Two modelling approaches,discrete deformation modelling and continuum coupled deformation and fluid flow modelling,are involved.The 2D model-derived patterns are remarkably consistent with the Cu-vein structure from the Shilu Copper deposit,and show that both modelling approaches can realistically simulate the mechanical behaviours of shear and dilatant fractures.The continuum coupled deformation and fluid flow model indicates that pattern of the Cuveins near the Shilu deposit is the result of shear strain localization,development of dilation and fluid focussing into the dilatant fracture segments.The 3D case-study models(with deformation and fluid flow coupling) on the Hodgkinson Province generated a number of potential gold mineralization targets.     

http://www.sciencedirect.com/science/article/pii/S1674987114000334

The Musgrave Province developed at the nexus of the North,West and South Australian cratons and its Mesoproterozoic evolution incorporates a 100 Ma period of ultra-high temperature(UHT) metamorphism from ca.1220 to ca.1120 Ma.This was accompanied by high-temperature A-type granitic magmatism over an 80 Ma period,sourced in part from mantle-derived components and emplaced as a series of pulsed events that also coincide with peaks in UHT metamorphism.The tectonic setting for this thermal event(the Musgrave Orogeny) is thought to have been intracontinental and the lithospheric architecture of the region is suggested to have had a major influence on the thermal evolution.We use a series of two dimensional,fully coupled thermo-mechanical-petrological numerical models to investigate the plausibility of initiating and prolonging UHT conditions under model setup conditions appropriate to the inferred tectonic setting and lithospheric architecture of the Musgrave Province.The results support the inferred tectonic framework for the Musgrave Orogeny,predicting periods of UHT metamorphism of up to 70 Ma,accompanied by thin crust and extensive magmatism derived from both crustal and mantle sources.The results also appear to be critically dependent upon the specific location of the Musgrave Province,constrained between thicker cratonic masses.     

http://www.sciencedirect.com/science/article/pii/S1674987113000832

The Sinus Iridum region, the first choice for China＇s＂Lunar Exploration Project＂is located at the center of the lunar LQ-4 area and is the site of Chang＇e-3 （CE-3）＇s soft landing. To make the scientific exploration of Chang＇e-3 more targeted and scientific, and to obtain a better macro-level understanding of the geotectonic environment of the Sinus Iridum region, the tectonic elements in LQ-4 region have been studied and the typical structures were analyzed statistically using data from CE-1, Clementine, LRO and Lunar Prospector missions. Also, the mineral components and periods of mare basalt activities in the study area have been ascertained. The present study divides the tectonic units and establishes the major tectonic events and sequence of evolution in the study area based on morphology, mineral constituents, and tectonic element distribution.     

http://www.sciencedirect.com/science/article/pii/S1674987112001521

The Tarim Basin is a representative example of the basins developed in the northwest China that are characterized by multiple stages of heating and cooling.In order to better understand its complex thermal history,apatite fission track （AFT） thermochronology was applied to borehole samples from the Tazhong Uplift Zone （TUZ）.Twelve sedimentary samples of Silurian to Triassic depositional ages were analyzed from depths coinciding with the apatite partial annealing zone （～60-120 ℃）.The AFT ages,ranging from 132 ± 7 Ma （from a Triassic sample） to 25 ± 2 Ma （from a Carboniferous sample）,are clearly younger than their depositional ages and demonstrate a total resetting of the AFT thermometer after deposition.The AFT ages vary among different tectonic belts and decrease from the No.Ten Faulted Zone （133-105 Ma） in the northwest,the Central Horst Zone in the middle （108-37 Ma）,to the East Buried Hill Zone in the south （51 25 Ma）.Given the low magnitude of post-Triassic burial heating evidenced by low vitrinite reflectance values （Ro ＜ 0.7％）,the total resetting of the AFT system is speculated to result from the hot fluid flow along the faults.Thermal effects along the faults are well documented by younger AFT ages and unimodal single grain age distributions in the vicinity of the faults.Permian-early Triassic basaltic volcanism may be responsible for the early Triassic total annealing of those samples lacking connectivity with the fault.The above arguments are supported by thermal modeling results.     

http://www.sciencedirect.com/science/article/pii/S167498711400070X

We investigated the relationships among slab geometry,obliquity,and the thermal regime associated with the subduction of oceanic plates using a three-dimensional(3D) parallelepiped thermal convection model.Various models with convex and concave slab shapes were constructed in the numerical simulation,and the temperature and mantle flow distributions were calculated.The results revealed that when the slab dip angle increases,or the obliquity of subduction becomes steeper,the interplate temperature decreases remarkably.Cooler(warmer) zones on the plate interface were identified from the modeling where there was a larger(smaller) subduction angle.Consequently,the interplate temperature distribution is partly controlled by the true subduction angle(TSA),which is a function of the slab dip angle and the obliquity of subduction.The rate of change of the interface temperature for the TSA was10-50 ℃(10°TSA 20°) at depths ranging from(TSA- 10) × 5 km to 60 +(TSA- 10) × 5 km for a flat slab after a subduction history of 7 Myrs.The along-arc slab curvature affects the variation in TSA.The slab radius also appeared to influence the radius of induced mantle flow.     

http://www.sciencedirect.com/science/article/pii/S1674987114001297

The southern boundary of the Singhbhum Craton witnessed multiple orogenies that juxtaposed thin slice of granulite suite of the Rengali Province against the low-grade granite-greenstone belt of the cra...     

http://www.sciencedirect.com/science/article/pii/S1674987114000218

Fluid infiltration into retrograde granulites of the Southern Marginal Zone(Limpopo high grade terrain)is exemplified by hydration reactions.shear zone hosted metasomatism,and lode gold mineralisation.Hydration reactions include the breakdown of cordierite and orthopyroxene to gedrite kyanite,and anthophyllite,respectively.Metamorphic petrology,fluid inclusions,and field data indicate that a low H_2O-activity carbon-saturated CO_2-rich and a saline aqueous fluid infiltrated the Southern Marginal Zone during exhumation.The formation of anthophyllite after orthopyroxene eslablished a regional retrograde anthophyllite-in isograd and occurred at P-T conditions of- 6 kbar and 610 C,which fixes the minimum mole fraction of II.0 in the CO_2-rich fluid phase at- 0.1.The maximum H_2O mole fraction is hxed by the lower temperature limit(~800℃) for partial melting at ~0.3.C-O-H fluid calculations show that the CO_2-rich fluid had an oxygen fugacity that was 0.6 log10 units higher than that of the fayalite-magnetitequartz buffer and that the CO_2/(CO_2+CH_4) mole ratio of this fluid was 1.The presence of dominantly relatively low density CO_2-rich fluid inclusions in the hydrated granulites indicates that the fluid pressure was less than the lithostatic pressure.This can be explained by strike slip faulting and/or an increase of the rock permeability caused by hydration reactions.     

http://www.sciencedirect.com/science/article/pii/S1674987112001570

The supercontinent cycle,by which Earth history is seen as having been punctuated by the episodic assembly and breakup of supercontinents,has influenced the rock record more than any other geologic phenomena,and its recognition is arguably the most important advance in Earth Science since plate tectonics.It documents fundamental aspects of the planet’s interior dynamics and has charted the course of Earth’s tectonic,climatic and biogeochemical evolution for billions of years.But while the widespread realization of the importance of supercontinents in Earth history is a relatively recent development,the supercontinent cycle was first proposed thirty years ago and episodicity in tectonic processes was recognized long before plate tectonics provided a potential explanation for its occurrence.With interest in the supercontinent cycle gaining momentum and the literature expanding rapidly,it is instructive to recall the historical context from which the concept developed.Here we examine the supercontinent cycle from this perspective by tracing its development from the early recognition of long-term episodicity in tectonic processes,through the identification of tectonic cycles following the advent of plate tectonics,to the first realization that these phenomena were the manifestation of episodic supercontinent assembly and breakup.     

http://www.sciencedirect.com/science/article/pii/S1674987111000831

The IAPWS-95 formulation explicit in Helmholtz free energy proposed by Wagner and Proβ(2002) is the best equation of state of water,from which all thermodynamic properties can be obtained over a wide T—p range from 273.16 to 1273 K and from 0 to 1000 MPa with experimental accuracy.This paper reports the applications of the IAPWS-95 formulation in fluid inclusion and mineral-water phase equilibria. A reliable and highly efficient calculation method is presented for the saturated properties of water so that the formulation can be conveniently applied in the study of fluid inclusion,such as calculating homogenization pressures,homogenization densities(or molar volumes),volume fractions and isochores.Meanwhile,the univariant curves of some mineral-dehydration reactions are calculated based on the IAPWS-95 formulation.The computer code of the IAPWS-95 formulation can be obtained from the corresponding author.     

http://www.sciencedirect.com/science/article/pii/S1674987114000231

The possibility of a net rotation of the lithosphere with respect to the mantle is generally overlooked since it depends on the adopted mantle reference frames,which are arbitrary.We review the geological and geophysical signatures of plate boundaries,and show that they are markedly asymmetric worldwide.Then we compare available reference frames of plate motions relative to the mantle and discuss which is at best able to fit global tectonic data.Different assumptions about the depths of hotspot sources(below or within the asthenosphere,which decouples the lithosphere from the deep mantle) predict different rates of net rotation of the lithosphere relative to the mantle.The widely used no-net-rotation(NNR) reference frame,and low(0.2°-0.4° /Ma) net rotation rates(deep hotspots source) predict an average net rotation in which some plates move eastward relative to the mantle(e.g.,Nazca).With fast(1° /Ma) net rotation(shallow hotspots source),all plates,albeit at different velocity,move westerly along a curved trajectory,with a tectonic equator tilted about 30° relative to the geographic equator.This is consistent with the observed global tectonic asymmetries.     

http://www.sciencedirect.com/science/article/pii/S1674987114000395

The study of fluid inclusions in high-grade rocks is especially challenging as the host minerals have been normally subjected to deformation, recrystallization and fluid-rock interaction so that primary in- clusions, formed at the peak of metamorphism are rare. The larger part of the fluid inclusions found in metamorphic minerals is typically modified during uplift. These late processes may strongly disguise the characteristics of the ＂original＂ peak metamorphic fluid. A detailed microstructural analysis of the host minerals, notably quartz, is therefore indispensable for a proper interpretation of fluid inclusions. Cathodoluminescence （CL） techniques combined with trace element analysis of quartz （EPMA, LA- [CPMS） have shown to be very helpful in deciphering the rock-fluid evolution. Whereas high-grade metamorphic quartz may have relatively high contents of trace elements like Ti and A1, low- temperature re-equilibrated quartz typically shows reduced trace element concentrations. The result- ing microstructures in CL can be basically distinguished in diffusion patterns （along microfractures and grain boundaries）, and secondary quartz formed by dissolution-reprecipitation. Most of these textures are formed during retrograde fluid-controlled processes between ca. 220 and 500 ℃, i.e. the range of semi-brittle deformation （greenschist-facies） and can be correlated with the fluid inclusions. In this way modified and re-trapped fluids can be identified, even when there are no optical features observed under the microscope.     

The genesis of the slab window-related Arzular low-sulfidation epithermal gold mineralization （eastern Pontides, NE Turkey）

The Arzular mineralization is one of the best examples of epithermal gold deposits in the eastern Pontides orogenic belt.The mineralization is hosted by the subduction-related basaltic andesites and is mainly controlled by E-W and NE-SW trending fracture zones.The main ore minerals are galena, sphalerite,pyrite.chalcopyrite.tetrahedrite and gold.Homogenization temperatures of fluid inclusions are between 130 and 295℃ for quartz and between 90 and 133℃ for sphalerite.Sulphur isotope values obtained from pyrite,galena and sphalerite vary between 1.2‰ and 3‰.indicating that sulphur belongs to magmatic origin and was derived from the Lutetian non-adakitic granitic intrusions in the region.Oxygen isotope values are between 15.0‰ and 16.7‰ and hydrogen isotope values are between -87‰ and -91‰ The sulphur isotope thermometer yielded temperatures in the range of 244-291℃ for the ore formation.Our results support the hypothesis that the Arzular mineralization is a low-sulfidation epithermal gold deposit associated with non-adakitic subduction- related granitic magmas that were generated by slab window-related processes in a south-dipping subduction zone during the Lutetian.     

http://www.sciencedirect.com/science/article/pii/S1674987111000429

The three most crucial factors for the formation of large and super-large magmatic sulfide deposits are: (1) a large volume of mantle-derived mafic-ultramafic magmas that participated in the formation of the deposits; (2) fractional crystallization and crustal contamination, particularly the input of sulfur from crustal rocks, resulting in sulfide immiscibility and segregation; and (3) the timing of sulfide concentration in the intrusion. The super-large magmatic Ni-Cu sulfide deposits around the world have been found in small mafic-ultramafic intrusions, except for the Sudbury deposit. Studies in the past decade indicated that the intrusions hosting large and super-large magmatic sulfide deposits occur in magma conduits, such as those in China, including Jinchuan (Gansu), Yangliuping (Sichuan), Kalatongke (Xinjiang), and Hongqiling (Jilin). Magma conduits as open magma systems provide a perfect environment for extensive concentration of immiscible sulfide melts, which have been found to occur along deep regional faults. The origin of many mantle-derived magmas is closely associated with mantle plumes, intracontinental rifts, or post-collisional extension. Although it has been confirmed that sulfide immiscibility results from crustal contamination, grades of sulfide ores are also related to the nature of the parental magmas, the ratio between silicate magma and immiscible sulfide melt, the reaction between the sulfide melts and newly injected silicate magmas, and fractionation of the sulfide melt. The field relationships of the ore-bearing intrusion and the sulfide ore body are controlled by the geological features of the wall rocks. In this paper, we attempt to demonstrate the general characteristics, formation mechanism,tectonic settings, and indicators of magmatic sulfide deposits occurring in magmatic conduits which would provide guidelines for further exploration.     

http://www.sciencedirect.com/science/article/pii/S1674987111000582

The Central India Tectonic Zone(CITZ) marks the trace of a major suture zone along which the south Indian and the north Indian continental blocks were assembled through subduction-accretioncollision tectonics in the Mesoproterozoic.The CITZ also witnessed the major,plume-related,late Cretaceous Deccan volcanic activity,covering substantial parts of the region with continental flood basalts and associated magmatic provinces.A number of major fault zones dissect the region,some of which are seismically active.Here we present results from gravity modeling along five regional profiles in the CITZ, and combine these results with magnetotelluric(MT) modeling results to explain the crustal architecture. The models show a resistive(more than 2000Ω·m) and a normal density(2.70 g/cm~3) upper crust suggesting\ dominant tonalite-trondhjemite-granodiorite(TTG) composition.There is a marked correlation between both high-density(2.95 g/cm~3) and low-density(2.65 g/cm~3) regions with high conductive zones (<80Ω·m) in the deep crust.We infer the presence of an interconnected grain boundary network of fluids or fluid-hosted structures,where the conductors are associated with gravity lows.Based on the conductive nature,we propose that the lower crustal rocks are fluid reservoirs,where the fluids occur as trapped phase within minerals,fluid-filled porosity,or as fluid-rich structural conduits.We envisage that substantial volume of fluids were transferred from mantle into the lower crust through the younger plume-related Deccan volcanism,as well as the reactivation,fracturing and expulsion of fluids transported to depth during the Mesoproterozoic subduction tectonics.Migration of the fluids into brittle fault zones such as the Narmada North Fault and the Narmada South Fault resulted in generating high pore pressures and weakening of the faults,as reflected in the seismicity.This inference is also supported by the presence of broad gravity lows near these faults,as well as the low velocity in the lower crust beneath regions of recent major earthquakes within the CITZ.     

http://www.sciencedirect.com/science/article/pii/S1674987112000618

The Moyar Shear Zone(MSZ) of the South Indian granulite terrain hosts a prominent syenite pluton (～560 Ma) and associated NW-SE to NE-SW trending mafic dyke swarm(～65 Ma and 95 Ma). Preliminary magnetic fabric studies in the mafic dykes,using Anisotropy of Magnetic Susceptibly(AMS) studies at low-field,indicate successive emplacement and variable magma flow direction.Magnetic lineation and foliation in these dykes are identical to the mesoscopic fabrics in MSZ mylonites,indicating shear zone guided emplacement.Spatial distribution of magnetic lineation in the dykes suggests a common conduit from which the source magma has been migrated.The magnetic foliation trajectories have a sigmoidal shape to the north of the pluton and curve into the MSZ suggesting dextral sense of shear.Identical fabric conditions for magnetic fabrics in the syenite pluton and measured field fabrics in mylonite indicate syntectonic emplacement along the Proterozoic crustal scale dextral shear zone with repeated reactivation history.     

http://www.sciencedirect.com/science/article/pii/S1674987111000806

Zoned tourmaline（schorl-dravite） in the matrix of hydrothermal explosive breccia and ore veins in gold deposits,Chita region.Eastern Transbaikalia.Russia,are associated with Na- and K-rich porphyry-type subvolcanic intrusives.δ¹⁸O values of tourmaline from three gold deposits（Darasun. Talatui,Teremkinskoye） are +8.3‰,+7.6‰,and +6.0‰and calculatedδ¹⁸O values of fluids responsible for the tourmalinization are +7.3‰,+7.7‰,and +4.2‰,respectively.These data imply an igneous fluid source,except at the Teremkin deposit where mixing with meteoric water is indicated.Wide ranges of Fe³⁺/Fe_tot,and the presence of vacancies characterize the Darasun deposit tourmaline indicating wide ranges of f（O₂） and pH of mineralizing fluids.Initial stage tourmalines from the gold deposits of the Darasun ore district are dravite or high mg schorl.Second stage tourmaline is characterized by oscillatory zoning but with Fe generally increasing towards crystal rims indicating decreasing temperature.Third stage tourmaline formed unzoned crystals with x_Mg（mole fraction of Mg） close to that of the hrst stage tourmaline,due to a close association with pyrite and arsenopyrite.From Fe³⁺/Fe_tot values,chemical composition and crystallization temperatures.logf（O₂） of mineralizing fluids ranged from ca.—25 to—20. much higher than for the gold-bearing beresite—listvenite association,indicating that tourmalinization was not related to gold mineralization.