Simultaneous water and vapour transfer in an unsaturated mudstone in badlands terrain,southwestern Taiwan

The simultaneous transfer of pore fluid and vapour was studied in the unsaturated shallow subsurface of a Plio-Pleistocene marine mudstone badland slope in southwestern Taiwan during the dry season using field monitoring data and numerical simulations. Data from field monitoring show mass-basis water contents of ~0.05 to ~0.10 that decrease towards the unsaturated ground surface and were invariant during the middle part of the dry season, except for daily fluctuations. In addition, the observed daily fluctuations in water content correlate with fluctuations in bedrock temperature, especially at depths of 2.5–5.0 cm. Periodic increases in water content occurred most notably during the day, when the bedrock temperature showed the greatest increase. Water contents then decreased to the previous state as bedrock temperature decreased during the night. Calculated vapour fluxes within the mudstone during the day increased up to 6 × 10⁻⁶–1 × 10⁻⁵ kg m⁻² s⁻¹, deriving a 0.01–0.02 increase in mass-basis water content at 2.5 cm depth for a 12-h period. This agrees with field monitoring data, suggesting that increases in water content occurred due to vapour intrusions into the bedrock. Pore water electrical conductivity (EC) showed periodic variations due to vapour intrusion, and gradually increased between the ground surface and depths of 2.5–5.0 cm. In contrast, pore water EC gradually decreased between 15 and 40 cm depth. Calculated water fluxes at depths of 2.5–40.0 cm varied from −4 × 10⁻⁶ to −2 × 10⁻⁹ kg m⁻² s⁻¹. These fluxes generated an increase in solute concentrations at the ground surface, with negative values of water flux indicating an upwards movement of water towards the surface. We show that the increase in solute content due to solute transfer from depth is highly dependent on variations in water flux with depth. © 2020 John Wiley & Sons, Ltd.     

An isotopic calibration study of precipitation,cave dripwater,and climate in west‐central Florida

A calibration study of oxygen and hydrogen isotopic composition from precipitation and cave dripwater was conducted in west‐central Florida at Legend Cave during 2007–2008. This study was performed to better understand how modern precipitation patterns can be discerned through examination of cave dripwater and speleothem calcite for paleoclimate reconstruction. The ‘amount effect’ was shown to be a dominant control on the oxygen isotopic composition of precipitation for the study area. A meteoric water line with a slope of 6·7 suggests evaporative effects occur either during precipitation or subsequent hydrological processes. However, δ¹⁸O values of cave dripwater averaged near the mean annual amount‐weighted average of precipitation, suggesting that the isotopic composition of dripwater tracks the long‐term average of rainfall. An observed weak seasonal influence occurred in the d‐excess values, with summer precipitation being more enriched due to increased evaporative effects. Comparison of precipitation δ¹⁸O values to synoptic weather data shows the dominant amount effect influence occurs due to strong convective storms producing highly ¹⁸O‐depleted rainfall at greater amounts during the year. Constant δ¹⁸O values of the dripwater indicate that paleoclimate reconstructions using speleothems from this area would record changes in annual to interannual shifts in precipitation amount above the cave. Copyright © 2011 John Wiley & Sons, Ltd.     

Anomalous drip in the Punkva caves (Moravian Karst): relevant implications for paleoclimatic proxies

The anomalous drip in the Punkva caves (Moravian Karst) shows specific hydrogeochemical properties such as low SI_calcite ~ 0.14 ± 0.11 (standard deviation), low mineralization (4.53 ± 0.42) × 10^?3 mol l^?1, and enhanced values of δ¹³C (?7.85 to ?8.35‰ VPDB), Mg/Ca × 1000 ratio (45.7 ± 3.3), and Sr/Ca × 1000 ratio (0.65 ± 0.06). By these properties, the anomalous drip significantly differs from other regular drips in the same cave and other caves in the region. The study suggests that the anomalous drip properties are a consequence of prior calcite precipitation or/and water mixing along the water flow path. As the former processes are spatially controlled, the knowledge of dripwater flow path seems to be necessary for correct paleoclimatic/paleoenvironmental reconstructions. Copyright © 2015 John Wiley & Sons, Ltd.     

Limestone Dissolution Processes in Beke Doline Aggtelek National Park,Hungary

Aggtelek National Park, Hungary, is a limestone karst upland characterized by karren, dolines and river caves. For a period of two years, climatic and carbonate dissolution variables were monitored at four depths in a 7·5 m shaft through the soil fill in the floor of a typical large (150 m diameter) doline. Results are compared to other monitoring stations in the shallow soils on side slopes. Runoff and groundwater flow are focused into the base of the doline soil fill, where moisture is maintained at 70–90 per cent field capacity and temperatures permit year-round production of soil CO₂. The capacity to dissolve calcite (limestone) ranges from c. 3 g m⁻² per year beneath thin soils on the driest slopes to 17–30 g m⁻² per year in the top 1–2 m of doline fill and at its base 5–7 m below. © 1997 John Wiley & Sons, Ltd.     

Quantification of the hydraulic diffusivity of a bentonite-sand mixture using the water head decrease measured upon sudden flow interruption

This paper presents a new modelling approach to quantify the hydraulic diffusivity of low-permeability unconsolidated porous media under confined saturated-flow conditions in the laboratory. The derived analytical solution for the transient variation of the hydraulic head after flow interruption was applied to experimental data obtained from continuous measurements of the water pressure at two locations in the soil column. Three soil samples made of a mixture of natural bentonite (at different mass fractions) and medium sand were studied during a series of stepwise constant flow rates of water. The numerical results well fit the experimentally measured decrease of the dimensionless hydraulic head. The study shows that the increase of the mass fraction of bentonite in the soil sample from 10 to 30% is accompanied by a strong decrease of the hydraulic diffusivity from 2.4 × 10⁻² to 1.1 × 10⁻³ m² s⁻¹, which is clearly due to the decrease of the hydraulic conductivity of the soil sample. The specific storages obtained for each of the three samples are in the same order of magnitude and seem to decrease with the increase of mass fraction of bentonite. However, they clearly reflect the predominant portion of the compressibility of the porous medium compared with that of water. Compared with reported literature values for clayey soils, the specific storage values in this study are slightly higher, varying within the range of 2 × 10⁻³ to 8.1 × 10⁻³ m⁻¹._. The experimental results also give insight into the limitations of the modelling approach. In the case of low-permeability soils (K < 2 × 10⁻⁶ ms⁻¹) and steady-flow conditions with low Reynolds numbers, for example, Re < 0.003, it is recommended to choose a time duration for flow interruption between subsequent flow rate steps of longer than 5 s. For high-permeability porous media, to increase the precision of the quantified hydraulic diffusivity, it might be useful to select a measuring frequency significantly higher than 1 Hz.     

Temporal variation in properties of an uncropped,ploughed Miamian soil in relation to seasonal erodibility

Knowledge of seasonal variation in soil structural and related properties is important for the determination of critical periods during which soil is susceptible to accelerated erosion and other degradative processes. The purpose of this research was to evaluate the magnitude of seasonal variations in selected soil and deposited sediment properties in relation to soil erodibility for a Miamian silt-loam soil (Typic Hapludalf) in central Ohio. Erosion plots (USLE-type) were established on a 4·5% slope and maintained under bare, ploughed conditions from 1988 to 1991. Particle size distribution, bulk density(ρ_b), percentage water stable aggregates (WSA), soil organic carbon (SOC), and total soil nitrogen (TSN) of both soil and sediment samples were monitored between Autumn 1989 and Spring 1991. The soil and sediment particle size distributions followed no clear seasonal trends. Soil ρ_b increased following tillage (1·20 Mg m⁻³) and was highest (1·45 Mg m⁻³) during the autumn owing to soil slumping and consolidation upon drying. Low winter and spring values of ρ_b and %WSA (20–50% lower than in autumn) were attributed to excessive wetness and freeze–thaw effects. Both SOC and soil TSN contents progressively declined (from 2·18 to 1·79% and 1·97 to 1·75 g kg⁻¹, respectively) after ploughing owing to maintenance of plots under bare, fallow conditions. Spring highs and autumn lows of sediment SOC (3·12 vs. 2·44%) and TSN (2·70 vs. 1·96 g kg⁻¹) contents were a result of the combined effects of soil microbial activity and rainfall erosivity. Soil properties such as bulk density, SOC and WSA, which vary seasonally, can potentially serve as predictors of seasonal soil erodibility, which, in turn, could improve the predictive capacity of soil erosion prediction models. © 1998 John Wiley & Sons, Ltd.     

Landscape influences on aluminium and dissolved organic carbon in streams draining the Hubbard Brook valley,New Hampshire,USA

Concentrations of both aluminium (Al) and dissolved organic carbon (DOC) in stream waters are likely to be regulated by factors that influence water flowpaths and residence times, and by the nature of the soil horizons through which waters flow. In order to investigate landscape‐scale spatial patterns in streamwater Al and DOC, we sampled seven streams draining the Hubbard Brook valley in central New Hampshire. We observed considerable variation in stream chemistry both within and between headwater watersheds. Across the valley, concentrations of total monomeric aluminium (Al_m) ranged from below detection limits (<0·7 µmol l⁻¹) to 22·3 µmol l⁻¹. In general, concentrations of Al_m decreased as pH increased downslope. There was a strong relationship between organic monomeric aluminium (Al_o) and DOC concentrations (R² = 0·92). We observed the highest Al_m concentrations in: (i) a watershed characterized by a steep narrow drainage basin and shallow soils and (ii) a watershed characterized by exceptionally deep forest floor soils and high concentrations of DOC. Forest floor depth and drainage area together explained much of the variation in ln Al_m (R² = 0·79; N = 45) and ln DOC (R² = 0·87; N = 45). Linear regression models were moderately successful in predicting ln Al_m and ln DOC in streams that were not included in model building. However, when back‐transformed, predicted DOC concentrations were as much as 72% adrift from observed DOC concentrations and Al_m concentrations were up to 51% off. This geographic approach to modelling Al and DOC is useful for general prediction, but for more detailed predictions, process‐level biogeochemical models are required. Copyright © 2005 John Wiley & Sons, Ltd.     

Effect of subsurface water level on gully headcut retreat in tropical highlands of Ethiopia

Gully erosion is a major cause of soil loss and severe land degradation in sub-humid Ethiopia. The objective of this study was to investigate the role and the effect of subsurface water level change on gully headcut retreat, gully formation and expansion in high rainfall tropical regions in the Ethiopian highlands. During the rainy seasons of 2017–2019, the expansion rate of 16 fixed gullies was measured and subsurface water levels were measured by piezometers installed near gully heads. During the study period, headcut retreats ranged from 0.70 to 2.35 m, with a mean value of 1.49 ± 0.56 m year⁻¹, and average depth of the surface water level varied between 1.12 and 2.82 m, with a mean value of 2.62 m. Gully cross-section areas ranged from 2.90 to 20.90 m², with an average of 9.31 ± 4.80 m². Volumetric retreat of gully headcuts ranged from 4.49 to 40.55 m³ and averaged 13.34 ± 9.10 m³. Soil loss from individual gullies ranged from 5.79 to 52.31 t year⁻¹ and averaged 17.21 ± 11.74 t year⁻¹. The headcut retreat rate and sediment yield were closely related over the three study seasons. Elevated subsurface water levels facilitated the slumping of gully banks and heads, causing high sediment yield. When the soil was saturated, bank collapse and headcut retreat were favoured by the combination of elevated subsurface water and high rainfall. This study indicates that area exclosures are effective in controlling subsurface water level, thus reducing gully headcut retreat and associated soil loss.     

An integrated water balance model for assessing water scarcity in a data-sparse interfluve in eastern India

Abstract

The objective of this study is to measure the balance of water demand versus water resource availability in an interfluve of West Bengal, India to support water resource planning, particularly of inter-basin transfers. Surface water availability was modelled using the US Soil Conservation Service curve number (SCS-CN) approach, whilst groundwater availability was modelled based on water-level fluctuations and the rainfall infiltration method. Water use was modelled separately for the agricultural, industrial, and domestic sectors using a predominantly normative approach and water use to availability ratios calculated for different administrative areas within the interfluve. Overall, the approach suggested that the interfluve receives 327 × 10⁶ m³ year^-1 of excess water after satisfying these sectoral demands, but that the eastern part of the study area is in deficit. However, a sensitivity analysis carried on the approach to several assumptions in the model suggested changed circumstances would produce surplus/deficit ranging from ?215 × 10⁶ to 435 × 10⁶ m³ year^-1 . The approach could have potential for localised water balance modelling in other Indian catchments.

Editor D. Koutsoyiannis; Associate editor D. Hughes     

Estimation methods of eco-environmental water requirements: Case study

With the enhancement of knowledge on the rela- tionship between water resources and ecological environment, the eco-environmental water require- ments have become an important factor in the alloca-tion of water resources[1―4]. Because of different un-derstandings on the concept, there are many estimation methods for ecological water requirements[5―7], envi-ronmental flows[8―12], instream flows[13,14], and low flows[15―17]. Most of those methods are identical in the intrinsic contents and a…     

Soil detachment by overland flow on steep cropland in the subtropical region of China

Accurate prediction of soil detachment capacity is fundamental to establish process-based erosion models and improve soil loss assessment. Few studies were conducted to reveal the mechanism of detachment process for yellow soil on steep cropland in the subtropical region of China using field experiments. This study was performed to determine soil detachment characteristics and explore the relationships between soil detachment capacity (D _c) and flow rate, slope gradient, mean velocity, shear stress, stream power and unit stream power. Field experiments were conducted on intact soil with flow rates ranging from 0.2 × 10⁻³ to 0.5 × 10⁻³ m⁻³ s⁻¹ and slope gradients varying from 8.8 to 42.4%. The results showed the following. (a) D _c of yellow soil was smaller than other soils because of its high clay content. (b) D _c was more susceptible to flow than to slope gradient. Power functions were derived to depict the relationship between D _c and the flow rate and slope gradient (R² = 0.91). (c) D _c was better simulated by power functions of the stream power (R² = 0.83) than functions of the shear stress or the unit stream power. (d) Considering its accuracy, simplicity and accessibility, the power function based on flow rate and slope gradient is recommended to predict D _c of yellow soil in the field. The results of this study provide useful support for revealing soil detachment mechanism and developing process-based soil erosion models for the subtropical region of China.     

Variation and attribution of water use efficiency in sunflower and maize fields in an irrigated semi-arid area

Water use efficiency (WUE) links carbon and water exchanges between farmlands and the atmosphere. Understanding the variation and attribution of WUE is essential to reveal the physiological and ecological adaptation mechanisms of crops to the changing environment, and to better allocate, regulate and conserve water resources. However, few studies on the variation and attribution of WUE have been conducted in irrigated arid or semi-arid farmlands. Therefore, in this study, water and carbon fluxes were measured using eddy covariance systems in two farmlands (one sunflower field and one maize field) in a semi-arid irrigation district in China. It was found that the average WUE of sunflower during its full growth period was 1.72 g C kg⁻¹ H₂O, much lower than that of maize (4.07 g C kg⁻¹ H₂O). At each growth stage, the WUE of both crops were negatively correlated with vapour pressure deficit (VPD), net radiation (R_n) and soil water content (SWC). The negative correlations could be attributed to the arid meteorological condition and the relatively abundant soil moisture due to irrigation and shallow groundwater levels. VPD was the main factor affecting WUE, followed by R_n and SWC. It was also found that the response of WUE to crop leaf area index (LAI) and to canopy conductance (g_c) depended on the VPD ranges: when VPD increased, the response of WUE to LAI and to g_c decreased. Our findings could improve the understanding of the coupling effect of water and carbon fluxes over farmland ecosystems in arid and semi-arid irrigation areas and help improve agricultural production and save water resources in such areas.     

Water quality and hydrogeochemical characteristics of the River Buyukmelen,Duzce, Turkey

The River Buyukmelen is located in the province of Duzce in northwest Turkey and its water basin is approximately 470 km². The Aksu, Kucukmelen and Ugursuyu streams flow into the River Buyukmelen. It flows into the Black Sea with an output of 44 m³ s⁻¹. The geological succession in the basin comprises limestone and dolomitic limestone of the Yılanlı formation, sandstone, clayey limestone and marls of the Akveren formation, clastics and volcano‐clastics of the Caycuma formation, and cover units comprised of river alluvium, lacutrine sediments and beach sands. The River Buyukmelen is expected to be a water source that can supply the drinking water needs of Istanbul until 2040; therefore, it is imperative that its water quality be preserved. The samples of rock, soil, stream water, suspended, bed and stream sediments and beach sand were collected from the Buyukmelen river basin. They were examined using mineralogical and geochemical methods. The chemical constituents most commonly found in the stream waters are Na⁺, Mg²⁺, SO²⁻₄, Cl⁻ and HCO₃⁻ in the Guz stream water, Ca²⁺ in the Abaza stream water, and K⁺ in the Kuplu stream water. The concentrations of Na⁺, K⁺, Ca²⁺, Mg²⁺, SO²⁻₄, HCO⁻₃, Cl⁻, As, Pb, Ni, Mn, Cr, Zn, Fe and U in the Kuplu and Guz stream waters were much higher than the world average values. The Dilaver, Gubi, Tepekoy, Maden, Celik and Abaza streams interact with sedimentary rocks, and the Kuplu and Guz streams interact with volcanic rocks. The amount of suspended sediment in the River Buyukmelen in December 2002 was 120 mg l⁻¹. The suspended and bed sediments in the muddy stream waters are formed of quartz, calcite, plagioclase, clay (kaolinite, illite and smectite), muscovite and amphibole minerals. As, Co, Cd, Cr, Pb, Ni, Zn and U have all accumulated in the Buyukmelen river‐bed sediments. The muddy feature of the waters is related to the petrographic features of the rocks in the basin and their mineralogical compositions, as most of the sandstones and volcanic rocks (basalt, tuffite and agglomerate) are decomposed to a clay‐rich composition at the surface. Thus, the suspended sediment in stream waters increases by physical weathering of the rocks and water–rock interaction. Owing to the growing population and industrialization, water demand is increasing. The plan is to bring water from the River Buyukmelen to Istanbul's drinking‐water reservoirs. According to the Water Pollution Regulations, the River Buyukmelen belongs to quality class 1 based on Hg, Cd, Pb, As, Cu, Cr, Zn, Mn, Se, Ba, Na⁺, Cl⁻, and SO²⁻₄; and to quality class 3 based on Fe concentration. The concentration of Fe in the River Buyukmelen exceeds the limit values permitted by the World Health Organization and the Turkish Standard. Because water from the River Buyukmelen will be used as drinking water, it will have an adverse effect on water quality and humans if not treated in advance. In addition, the inclusion of Mn and Zn in the Elmali drinking‐water reservoir of Istanbul and Fe in the River Buyukmelen water indicates natural inorganic contamination. Mn, Zn and Fe contents in the waters are related to geological origin. Moreover, the River Buyukmelen flow is very muddy in the rainy seasons and it is inevitable that this will pose problems during the purification process. Copyright © 2005 John Wiley & Sons, Ltd.     

Hydrogeology of Wadi Al-Yammaniyah, Saudi Arabia

Quaternary alluvium, ranging in thickness from a few to 100 meters underlain by Precambrian rocks of metamor-phic and igneous origin, constitutes an important source of ground water in Wadi Al-Yammaniyah, Saudi Arabia. The purpose of this report is to assess the hydraulic properties, quality of water, and estimated change in storage in waterbearing rocks in the area. The results of eight pumping tests carried out in hand-dug, large-diameter wells, indicate that the hydraulic conductivity of the alluvial aquifer ranges from 5.6 × 10⁻⁵ to 1.85 × 10⁻³ cm/second (3.36 × 10⁻⁵ to 1.11 × 10⁻³ m/minute) and that its storativity varies from 8.23 × 10⁻² to 1.17 × 10⁻¹. The aquifer is replenished by sporadic but intensive rainfall of short duration. The present withdrawal is only about 10 percent of the annual recharge which is estimated at 52 × 10⁶ m³. It is shown that there is a substantial potential for the future development of potable ground water which would be required for the development of the area.     

Snow-distribution and melt modelling for glaciers in Zackenberg river drainage basin,north-eastern Greenland

A physically based snow-evolution modelling system (SnowModel) that includes four sub-models: MicroMet, EnBal, SnowPack, and SnowTran-3D, was used to simulate eight full-year evolutions of snow accumulation, distribution, sublimation, and surface melt from glaciers in the Zackenberg river drainage basin, in north-east Greenland. Meteorological observations from two meteorological stations were used as model inputs, and spatial snow depth observations, snow melt depletion curves from photographic time lapse, and a satellite image were used for model testing of snow and melt simulations, which differ from previous SnowModel tests methods used on Greenland glaciers. Modelled test-period-average end-of-winter snow water equivalent (SWE) depth for the depletion area differs by a maximum of 14 mm w.eq., or ∼6%, more than the observed, and modelled test-period-average snow cover extent differs by a maximum of 5%, or 0·8 km², less than the observed. Furthermore, comparison with a satellite image indicated a 7% discrepancy between observed and modelled snow cover extent for the entire drainage basin. About 18% (31 mm w.eq.) of the solid precipitation was returned to the atmosphere by sublimation. Modelled mean annual snow melt and glacier ice melt for the glaciers in the Zackenberg river drainage basin from 1997 through 2005 (September–August) averaged 207 mm w.eq. year⁻¹ and 1198 mm w.eq. year⁻¹, respectively, yielding a total averaging 1405 mm w.eq. year⁻¹. Total modelled mean annual surface melt varied from 960 mm w.eq. year⁻¹ to 1989 mm w.eq. year⁻¹. The surface-melt period started between mid-May and the beginning of June and lasted until mid-September. Annual calculated runoff averaged 1487 mm w.eq. year⁻¹ (∼150 × 10⁶ m³) (1997–2005) with variations from 1031 mm w.eq. year⁻¹ to 2051 mm w.eq. year⁻¹. The model simulated a total glacier recession averaging − 1347 mm w.eq. year⁻¹ (∼136 × 10⁶ m³) (1997–2005), which was almost equal to previous basin average hydrological water balance storage studies − 244 mm w.eq. year⁻¹ (∼125 × 10⁶ m³) (1997–2003). Copyright © 2007 John Wiley & Sons, Ltd.     

Soil organic carbon storage and soil CO<Subscript>2</Subscript> flux in the alpine meadow ecosystem

High-resolution sampling, measurements of organic carbon contents and ¹⁴C signatures of selected four soil profiles in the Haibei Station situated on the northeast Tibetan Plateau, and application of ¹⁴C tracing technology were conducted in an attempt to investigate the turnover times of soil organic carbon and the soil-CO₂ flux in the alpine meadow ecosystem. The results show that the organic carbon stored in the soils varies from 22.12×10⁴ kg C hm⁻² to 30.75×10⁴ kg C hm⁻² in the alpine meadow ecosystems, with an average of 26.86×10⁴ kg C hm⁻². Turnover times of organic carbon pools increase with depth from 45 a to 73 a in the surface soil horizon to hundreds of years or millennia or even longer at the deep soil horizons in the alpine meadow ecosystems. The soil-CO₂ flux ranges from 103.24 g C m⁻² a⁻¹ to 254.93 gC m⁻² a⁻¹, with an average of 191.23 g C m⁻² a⁻¹. The CO₂ efflux produced from microbial decomposition of organic matter varies from 73.3 g C m⁻² a⁻¹ to 181 g C m⁻² a⁻¹. More than 30% of total soil organic carbon resides in the active carbon pool and 72.8%281.23% of total CO₂ emitted from organic matter decomposition results from the topsoil horizon (from 0 cm to 10 cm) for the Kobresia meadow. Responding to global warming, the storage, volume of flow and fate of the soil organic carbon in the alpine meadow ecosystem of the Tibetan Plateau will be changed, which needs further research. Supported by the National Natural Science Foundation of China (Grant Nos. 40231015, 40471120 and 40473002) and the Guangdong Provincial Natural Science Foundation of China (Grant No. 06300102)     

Mercury cycling during acid rain recovery at the forested Lesní potok catchment,Czech Republic

From 2011 to 2019, mercury (Hg) stores and fluxes were studied in the small forested catchment Lesní potok (LES) in the central Czech Republic using the watershed mass balance approach together with internal measurements. Mean input fluxes of Hg via open bulk deposition, beech throughfall and spruce throughfall during the periodwere 2.9, 3.9 and 7.6 μg m⁻² year⁻¹, respectively. These values were considerably lower than corresponding deposition Hg fluxes reported in the early years of the 21st century from catchments in Germany. Current bulk precipitation inputs at unimpacted Czech mountainous sites were lower than those in Germany. The largest Hg inputs to the catchment were via litterfall, averaging 22.6 and 17.8 μg m⁻² year⁻¹ for beech and spruce stands. The average Hg input, based on the sum of mean litterfall and throughfall deposition, was 23.0 μg m⁻² year⁻¹, compared to the estimated Hg output in runoff of 0.5 μg m⁻² year⁻¹, which is low compared to other reported values. Thus, only ~2% of Hg input is exported in stream runoff. Stream water Hg was only weakly related to dissolved organic carbon (DOC) but both concentrations were positively correlated with water temperature. The estimated total soil Hg pool averaged 47.5 mg m⁻², only 4% of which was in the O-horizon. Thus Hg in the O-horizon pool represents 72 years of deposition at the current input flux and 3800 years of export at the current runoff flux. Age-dating by ¹⁴C suggested that organic soil contains Hg from recent deposition, while mineral soil at 40–80 cm depth contained 4400-year old carbon, suggesting the soil had accumulated atmospheric Hg inputs through millennia to reach the highest soil Hg pool of the soil profile. These findings suggest that industrial era intensification of the Hg cycle is superimposed on a slower-paced Hg cycle during most of the Holocene.     

Spatial patterns of soil nitrate in Japanese forested watersheds: importance of the near-stream zone as a source of nitrate in stream water

Spatial patterns of N dynamics in soil were evaluated within two small forested watersheds in Japan. These two watersheds were characterized by steep slopes (>30°) and high stream NO⁻₃ drainage rates (8·4 to 25·1 kg N ha⁻¹ yr⁻¹) that were greater than bulk precipitation N input rates (7·5 to 13·5 kg N ha⁻¹ yr⁻¹). Higher rates of nitrification potential at near-stream zones were reflected in greater NO⁻₃ contents for soil at the near-stream zones compared with ridge zones. Both stream discharge rates and NO⁻₃ concentrations in deep unsaturated soil at the near-stream zones were positively correlated to NO⁻₃ concentrations in stream water. These relationships, together with high soil NO⁻₃ contents at the near-stream zones, suggest that the near-stream zone was an important source of NO⁻₃ to stream water. Nitrate flux from these near-stream zones was also related to the drainage of cations (K⁺, Ca²⁺ and Mg²⁺). The steep slope of the watersheds resulted in small saturated areas that contributed to the high NO⁻₃ production (high nitrification rates) in the near-stream zone. © 1998 John Wiley & Sons, Ltd.     

Response of soil aggregate disintegration to the different content of organic carbon and its fractions during splash erosion

Aggregate disintegration is a critical process in soil splash erosion. However, the effect of soil organic carbon (SOC) and its fractions on soil aggregates disintegration is still not clear. In this study, five soils with similar clay contents and different contents of SOC have been used. The effects of slaking and mechanical striking on splash erosion were distinguished by using deionized water and 95% ethanol as raindrops. The simulated rainfall experiments were carried out in four heights (0.5, 1.0, 1.5 and 2.0 m). The result indicated that the soil aggregate stability increased with the increases of SOC and light fraction organic carbon (LFOC). The relative slaking and the mechanical striking index increased with the decreases of SOC and LFOC. The reduction of macroaggregates in eroded soil gradually decreased with the increase of SOC and LFOC, especially in alcohol test. The amount of macroaggregates (>0.25 mm) in deionized water tests were significantly less than that in alcohol tests under the same rainfall heights. The contribution of slaking to splash erosion increased with the decrease of heavy fractions organic carbon. The contribution of mechanical striking was dominant when the rainfall kinetic energy increased to a range of threshold between 9 J m⁻² mm⁻¹ and 12 m⁻² mm⁻¹. This study could provide the scientific basis for deeply understanding the mechanism of soil aggregates disintegration and splash erosion.     

Hydrological flow paths controlling stream chemistry in Japanese forested watersheds

Water sources and flow paths contributing to stream chemistry were evaluated in four Japanese forested watersheds with steep topography (slopes ≥30°). Stream chemistry during periods without rainfall and during events with less than 100 mm of precipitation was similar to seepage water chemistry, but markedly different from that of soil water which had higher concentrations of NO⁻₃ and Ca²⁺ and lower concentrations of Na⁺ and HCO⁻₃. Also, stream Cl⁻ concentrations in a Cl⁻‐treated watershed did not increase either during events with less than 100 mm of total rainfall or at baseflow conditions, even three years after the Cl⁻ treatment. These results suggest that groundwater within bedrock fissures of Paleozoic strata had a long residence time and was a major contributor to steam water under baseflow conditions and even during small precipitation events (≤100 mm). In contrast, for large precipitation events (≥100 mm), stream chemistry became more similar to soil water chemistry, especially within the steepest watershed. Also, for large precipitation events, stream Cl⁻ concentrations in the Cl⁻‐treated watershed increased markedly. These results suggest that soil water was a major contributor to stream waters only during these large events. Copyright © 1999 John Wiley & Sons, Ltd.