Geomorphic influences on the distribution and accumulation of pyrogenic carbon (PyC) following a low severity wildfire in northern New Mexico

The distribution, transport, and accumulation of wildfire‐generated pyrogenic carbon (PyC) has important consequences for contaminant transport and carbon cycling, but a conceptual model for PyC accumulation and loss that includes geomorphic processes is lacking. In this study we quantified PyC concentration in soil samples collected from the Jemez Mountains of New Mexico before and after the 2013 Thompson Ridge (TR) fire, and developed a conceptual model describing PyC redistribution. Pre‐fire samples were fortuitously collected 4 years before the TR burn and post‐fire samples were collected at the same locations 15 months following the TR fire. Samples were collected from the O and A horizon, with sites representing a range of slope angle, aspect, burn severity, and geomorphic setting. PyC was determined by a modified chemo‐thermal oxidation method to compare PyC to total organic carbon (TOC). The mean PyC/TOC ratio was significantly higher post‐fire than pre‐fire (0.14 vs 0.12), indicating increased PyC sequestration. O horizon PyC concentrations were more variable and more responsive to fire than the A horizon. Soil horizon, watershed, and geomorphic setting proved to be the most influential factors in predicting PyC concentration changes. PyC concentrations increased most on hillslopes and in low‐severity burn areas, suggesting higher rates of PyC production or post‐fire accumulation. Burn patchiness appears to facilitate PyC accumulation, with lower severity patches trapping PyC mobilized from high severity patches. While PyC content had greater point scale variance following the fire, the fire also homogenized pre‐fire PyC differences between soil horizons and among watersheds within the burn perimeter, differences that appear to develop over time between fires. The O horizon is a larger sink for PyC in the short term following fire, but based on pre‐fire concentrations the A horizon appears to be a more stable sink for PyC. Copyright © 2018 John Wiley & Sons, Ltd.     

Total organic carbon fluxes of the Red River system (Vietnam)

Riverine transport of organic carbon from terrestrial ecosystems to the oceans plays an important role in the global carbon cycle. The Red River is located in Southeast Asia where river discharge, sediment loads and fluxes of elements (carbon, nitrogen and phosphorus) associated with suspended solids have been dramatically altered over past decades as a result of reservoir impoundment and land use, population, and climate change. Dissolved organic carbon (DOC) and particulate organic carbon (POC) concentrations were measured monthly at four stations of the Red River system from January 2008 to December 2010. The results reveal that POC changed synchronically with total suspended solids (TSS) concentration and with the river discharge, whereas no clear trend was observed for DOC concentration. The mean value of total organic carbon (TOC = DOC + POC) flux in the delta of the Red River was 31.5 × 10¹³ ± 4.0 × 10¹³ MgC.yr^?1 (range 27.9–35.8 × 10¹³ MgC.yr^?1 which leads to a specific TOC flux of 2012 ± 255 kgC.km^?2.yr^?1 during this 2008–2010 period. About 80% of the TOC flux was transferred to the estuary during the rainy season as a consequence of the higher river water discharge. The high mean value of the POC:Chl‐a ratio (1585 ± 870 mgC.mgChl‐a^?1) and the moderate C:N ratio (7.3 ± 0.1) in the water column system suggest that organic carbon in the Red River system is mainly derived from erosion and soil leaching in the basin. The effect of two new dam impoundments in the Red River was also observable with lower TOC fluxes in 2010 compared with 2008. Copyright © 2017 John Wiley & Sons, Ltd.     

Geomorphic controls on floodplain sediment and soil organic carbon storage in a Scottish mountain river

River floodplains constitute an important element in the terrestrial sediment and organic carbon cycle and store variable amounts of carbon and sediment depending on a complex interplay of internal and external driving forces. Quantifying the storage in floodplains is crucial to understand their role in the sediment and carbon cascades. Unfortunately, quantitative data on floodplain storage are limited, especially at larger spatial scales. Rivers in the Scottish Highlands can provide a special case to study alluvial sediment and carbon dynamics because of the dominance of peatlands throughout the landscape, but the alluvial history of the region remains poorly understood. In this study, the floodplain sediment and soil organic carbon storage is quantified for the mountainous headwaters of the River Dee in eastern Scotland (663 km²), based on a coring dataset of 78 floodplain cross-sections. Whereas the mineral sediment storage is dominated by wandering gravel-bed river sections, most of the soil organic carbon storage can be found in anastomosing and meandering sections. The total storage for the Upper Dee catchment can be estimated at 5.2 Mt or 2306.5 Mg ha^-1 of mineral sediment and 0.7 Mt or 323.3 Mg C ha^-1 of soil organic carbon, which is in line with other studies on temperate river systems. Statistical analysis indicates that the storage is mostly related to the floodplain slope and the geomorphic floodplain type, which incorporates the characteristic stream power, channel morphology and the deposit type. Mapping of the geomorphic floodplain type using a simple classification scheme shows to be a powerful tool in studying the total storage and local variability of mineral sediment and soil organic carbon in floodplains. © 2019 John Wiley & Sons, Ltd.     

Evaluating the impact of soil redistribution on the in situ mineralization of soil organic carbon

Soil erosion, transport and deposition by water drastically affect the distribution of soil organic carbon (SOC) within a landscape. Moreover, soil redistribution may have a large impact on the exchange of carbon (C) between the pedosphere and the atmosphere. One of the large information gaps within this research domain, concerns the fate of SOC after erosion by water. According to different (mainly laboratory) studies, soil redistribution leads to aggregate breakdown, thereby exposing the contained SOC to mineralization. Our study aims to quantify the extent to which such increased mineralization occurs in a real field situation. Carbon dioxide (CO₂)‐efflux was measured in the field after an important erosion event for a continuous period of 112 days. The specific situation on the field ensured that almost none of eroded SOC was exported from the field. Measurements of CO₂‐efflux were done in areas with sediment deposition, as well as in comparable areas without sedimentation. Comparison of these measurements allowed the net effect of soil deposition on CO₂‐efflux to be assessed. Field data were complemented by measurements on incubated, undisturbed soil core samples, in order to disentangle the contribution of environmental factors (moisture, temperature) from any erosional effect on CO₂‐efflux. Results of these measurements on the field showed that CO₂‐efflux was regulated by a complex interplay of different factors (mostly soil porosity, soil moisture and soil temperature). In combination with the incubation measurements, it could be concluded that the processes of erosion and transport indeed led to an increased mineralization of SOC, as a result of aggregate breakdown and exposure of previously encapsulated SOC. This effect was, however, much smaller than observed in previous laboratory studies. Moreover, it was only important in the first weeks, immediately after the erosion event. The calculated net erosional effect on CO₂‐efflux represented a mere 1·6% of total SOC, originally present in the soil. Copyright © 2010 John Wiley & Sons, Ltd.     

Modelling the effect of soil burn severity on soil erosion at hillslope scale in the first year following wildfire in NW Spain

Fire severity is recognized as a key factor in explaining post‐fire soil erosion. However, the relationship between soil burn severity and soil loss has not been fully established until now. Sediment availability may also affect the extent of post‐fire soil erosion. The objective of this study was to determine whether soil burn severity, estimated by an operational classification system based on visual indicators, can significantly explain soil loss in the first year after wildfire in shrubland and other areas affected by crown fires in northwest (NW) Spain. An additional aim was to establish indicators of sediment availability for use as explanatory variables for post‐fire soil loss. For these purposes, we measured hillslope‐scale sediment production rates and site characteristics during the first year after wildfire in 15 experimental sites using 65 plots. Sediment yields varied from 0.2 Mg ha^?1 to 50.1 Mg ha^?1 and soil burn severity ranged from low (1.8) to very high (4.5) in the study period. A model that included soil burn severity, annual precipitation and a land use factor (as a surrogate for sediment availability) as explanatory variables reasonably explained the erosion losses measured during the first year after fire. Model validation confirmed the usefulness of this empirical model. The proposed empirical model could be used by forest managers to help evaluate erosion risks and to plan post‐fire stabilization activities. Copyright © 2015 John Wiley & Sons, Ltd.     

Response of soil aggregate disintegration to the different content of organic carbon and its fractions during splash erosion

Aggregate disintegration is a critical process in soil splash erosion. However, the effect of soil organic carbon (SOC) and its fractions on soil aggregates disintegration is still not clear. In this study, five soils with similar clay contents and different contents of SOC have been used. The effects of slaking and mechanical striking on splash erosion were distinguished by using deionized water and 95% ethanol as raindrops. The simulated rainfall experiments were carried out in four heights (0.5, 1.0, 1.5 and 2.0 m). The result indicated that the soil aggregate stability increased with the increases of SOC and light fraction organic carbon (LFOC). The relative slaking and the mechanical striking index increased with the decreases of SOC and LFOC. The reduction of macroaggregates in eroded soil gradually decreased with the increase of SOC and LFOC, especially in alcohol test. The amount of macroaggregates (>0.25 mm) in deionized water tests were significantly less than that in alcohol tests under the same rainfall heights. The contribution of slaking to splash erosion increased with the decrease of heavy fractions organic carbon. The contribution of mechanical striking was dominant when the rainfall kinetic energy increased to a range of threshold between 9 J m⁻² mm⁻¹ and 12 m⁻² mm⁻¹. This study could provide the scientific basis for deeply understanding the mechanism of soil aggregates disintegration and splash erosion.     

The persistence of beaver-induced geomorphic heterogeneity and organic carbon stock in river corridors

Beavers are widely recognized as ecosystem engineers for their ability to shape river corridors by building dams, digging small canals, and altering riparian vegetation. Through these activities, beavers create beaver meadows, which are segments of river corridor characterized by high geomorphic heterogeneity, attenuation of downstream fluxes, and biodiversity. We examine seven beaver meadows on the eastern side of the Rocky Mountain National Park, Colorado, USA with differing levels of beaver activity. We divide these sites into the four categories of active, partially active, recently abandoned (< 20 years), and long abandoned (> 30 years). We characterize geomorphic units within the river corridor and calculate metrics of surface geomorphic heterogeneity relative to category of beaver activity. We also use measures of subsurface geomorphic heterogeneity (soil moisture, soil depth, percent clay content, organic carbon concentration) to compare heterogeneity across beaver meadow categories. Finally, we calculate organic carbon stock within the upper 1.5 m of each meadow and compare these values to category of beaver activity. We find that surface geomorphic heterogeneity and mean soil moisture differ significantly only between active and long abandoned meadows, suggesting a non-linear decrease with time following beaver abandonment of a meadow. Soil depth and organic carbon stock do not differ consistently in relation to category of beaver meadow, suggesting that larger-scale geologic controls that foster deep floodplain soils can continue to maintain substantial organic carbon stocks after beavers abandon a meadow. These results also indicate that the effects of beaver ecosystem engineering can persist for nearly three decades after the animals largely abandon a river corridor. © 2018 John Wiley & Sons, Ltd.     

Towards constraining the magnitude of global agricultural sediment and soil organic carbon fluxes

Reliable quantitative data on the extent and rates of soil erosion are needed to understand the global significance of soil‐erosion induced carbon exchange and to underpin the development of science‐based mitigation strategies, but large uncertainties remain. Existing estimates of agricultural soil and soil organic carbon (SOC) erosion are very divergent and span two orders of magnitude. The main objective of this study was to test the assumptions underlying existing assessments and to reduce the uncertainty associated with global estimates of agricultural soil and SOC erosion. We parameterized a simplified erosion model driven by coarse global databases using an empirical database that covers the conterminous USA. The good agreement between our model results and empirical estimates indicate that the approach presented here captures the essence of agricultural erosion at the scales of continents and that it may be used to predict the significance of erosion for the global carbon cycle and its impact on soil functions. We obtained a global soil erosion rate of 10.5 Mg ha^‐1 y^‐1 for cropland and 1.7 Mg ha^‐1 y^‐1 for pastures. This corresponds to SOC erosion rates of 193 kg C ha^‐1 y^‐1 for cropland and 40.4 kg C ha^‐1 y^‐1 for eroding pastures and results in a global flux of 20.5 (±10.3) Pg y^‐1 of soil and 403.5 (±201.8) Tg C y^‐1. Although it is difficult to accurately assess the uncertainty associated with our estimates of global agricultural erosion, mainly due to the lack of model testing in (sub‐)tropical regions, our estimates are significantly lower than former assessments based on the extrapolation of plot experiments or global application of erosion models. Our approach has the potential to quantify the rate and spatial signature of the erosion‐induced disturbance at continental and global scales: by linking our model with a global soil profile database, we estimated soil profile modifications induced by agriculture. This showed that erosion‐induced changes in topsoil SOC content are significant at a global scale (an average SOC loss of 22% in 50 years) and agricultural soils should therefore be considered as dynamic systems that can change rapidly. Copyright © 2011 John Wiley & Sons, Ltd.     

Characterizing the dynamics of soil organic carbon in grasslands on the Qinghai-Tibetan Plateau

Carbon dynamics of grasslands on the Qinghai-Tibetan Plateau may play an important role in regional and global carbon cycles. The CENTURY model (Version 4.5) is used to examine temporal and spatial variations of soil organic carbon (SOC) in grasslands on the Plateau for the period from 1960 to 2002. The model successfully simulates the dynamics of aboveground carbon and soil surface SOC at the soil depth of 0-20 cm and the simulated results agree well to the measurements. Examination of SOC for eight typical grasslands shows different patterns of temporal variation in different ecosystems in 1960-2002. The extent of temporal variation increases with the increase of SOC of ecosystem. SOC increases first and decreases quickly then during the period from 1990 to 2000. Spatially, SOC density obtained for the equilibrium condition declines gradually from the southeast to the northwest on the plateau and showed a high heterogeneity in the eastern plateau. The results suggest that (i) SOC den-sity in the alpine grasslands shows remarkable response to climate change during the 42 years, and (ii) the net carbon exchange rate between the alpine grassland ecosystems and the atmosphere increases from 1990 to 2000 as compared with that before 1990.     

Erosion,deposition, and the persistence of soil organic matter: mechanistic considerations and problems with terminology

The effect of erosional detachment, transport, and deposition of topsoil on the stock of soil organic matter (SOM) and its association with soil minerals has been a focus of a growing number of studies. A particularly lively debate is currently centered on the questions of whether terrestrial sedimentation of previously eroded SOM may constitute a relevant sink for atmospheric carbon dioxide (CO₂), and how ‘stable’ such carbon (C) might be on multidecadal timescales. In this commentary, we illustrate how redistribution of eroded SOM within a landscape can create situations that are not adequately described by the jargon commonly used to characterize C turnover dynamics. We argue that more quantitative and scientifically rigorous categories are needed to describe soil C turnover and to promote the development of innovative, numerical models of C dynamics in landscapes characterized by significant mass movement. Copyright © 2013 John Wiley & Sons, Ltd.     

The fluvial flux of particulate organic matter from the UK: the emission factor of soil erosion

Soil erosion has been identified as a potential global carbon sink since eroded organic matter is replaced at source and eroded material is readily buried. However, this argument has relied on poor estimates of the total fate of in‐transit particulates and could erroneously imply soil erosion could be encouraged to generate carbon stores. These previous estimates have not considered that organic matter can also be released to the atmosphere as a range of greenhouse gases, not only carbon dioxide (CO₂), but also the more powerful greenhouse gases methane (CH₄) and nitrous oxide (N₂O). As soil carbon lost by erosion is only replaced by uptake of CO₂, this could represent a considerable imbalance in greenhouse gas warming potential, even if it is not significant in terms of overall carbon flux. This work therefore considers the flux of particulate organic matter through UK rivers with respect to both carbon fluxes and greenhouse gas emissions. The results show that, although emissions to the atmosphere are dominated by CO₂, there are also considerable fluxes of CH₄ and N₂O. The results suggest that soil erosion is a net source of greenhouse gases with median emission factors of 5.5, 4.4 and 0.3 tonnes CO_2eq/yr for one tonne of fluvial carbon, gross carbon erosion and gross soil erosion, respectively. This study concludes that gross soil erosion would therefore only be a net sink of both carbon and greenhouse gases if all the following criteria are met: the gross soil erosion rate were very low (<91 tonnes/km²/yr); the eroded carbon were completely replaced by new soil organic matter; and if less than half of the gross erosion made it into the stream network. By establishing the emission factor for soil erosion, it becomes possible to properly account for the benefits of good soil management in minimizing losses of greenhouse gases to the atmosphere as a by‐product of soil erosion. Copyright © 2015 John Wiley & Sons, Ltd.     

Fluvial transport of coarse particulate organic matter in a coastal mountain stream of a rainy-temperate evergreen broadleaf forest in southern Chile

Coarse particulate organic matter (CPOM, i.e. particles such as leaves, wood fragments, twigs, branches, flowers, seeds and fruits) in aquatic systems influences the flow, provides an important food source, and at the catchment scale, may significantly contribute to total carbon export. CPOM exports have rarely been quantified in subtropical, broadleaf forest streams. We captured CPOM in Bunte traps in the rainfall-dominated Vuelta de Zorra stream in southern Chile to (a) propose a novel classification to characterize the different CPOM components, (b) analyze the frequency of each matter class (i.e. leaves, wood fragments, and ‘others’) and its seasonal variability, (c) quantify the CPOM transported, (d) derive a model to quantify CPOM transport rates, and (e) compare the transported CPOM data with those from a unique long-term (> seven years) large wood monitoring dataset. Results showed that leaves were significantly more abundant than other types of CPOM in all seasons. The dry CPOM transport rate ranged over three orders of magnitude, and there was a significant relationship with mean discharge. Mean dry CPOM yield for the study period 2015–2017 was 4.6 kg/ha/yr when normalizing to the total forested catchment area. The 2009–2018 decadal average yield was 6.8 kg/ha/yr when normalizing to the total forested catchment area. These values are similar to measurements from deciduous and coniferous forests in streams in the United States and the Brazilian Mato Grosso and ~1/10 of the yields obtained in a Swiss torrent. Over a three-year period, the CPOM exports in Vuelta de Zorra ranged between 13 and 36% of the exported large wood (particles with diameters ≥ 100 mm and length ≥ 1 m) exports. Our data collected from an underrepresented area improve the understanding of global carbon budgets and cycling. © 2020 John Wiley & Sons, Ltd.     

Soil organic carbon enrichment of dust emissions: magnitude,mechanisms and its implications for the carbon cycle

Soil erosion is an important component of the global carbon cycle. However, little attention has been given to the role of aeolian processes in influencing soil organic carbon (SOC) flux and the release of greenhouse gasses, such as carbon dioxide (CO₂), to the atmosphere. Understanding the magnitude and mechanisms of SOC enrichment in dust emissions is necessary to evaluate the impact of wind erosion on the carbon cycle. This research examines the SOC content and enrichment of dust emissions measured using Big Spring Number Eight (BSNE) wind‐vane samplers across five land types in the rangelands of western Queensland, Australia. Our results show that sandy soils and finer particulate quartz‐rich soils are more efficient at SOC emission and have larger SOC dust enrichment than clay‐rich aggregated soils. The SOC enrichment ratios of dusts originating from sites with sand‐rich soil ranged from 2·1–41·9, while the mean enrichment ratio for dusts originating from the clay soil was 2·1. We hypothesize that stronger inter‐particle bonds and the low grain density of the aggregated clay soil explain its reduced capacity to release SOC during saltation, relative to the particulate sandy soils. We also show that size‐selective sorting of SOC during transport may lead to further enrichment of SOC dust emissions. Two dust samples from regional transport events were found to contain 15–20% SOC. These preliminary results provide impetus for additional research into dust SOC enrichment processes to elucidate the impact of wind erosion on SOC flux and reduce uncertainty about the role of soil erosion in the global carbon cycle. Copyright © 2013 John Wiley & Sons, Ltd.     

蓝藻水华衰亡对沉积物碳库有机碳组分的影响

湖泊沉积物碳库作为湖泊生态系统的重要组成部分,对湖泊碳循环起重要作用,而蓝藻水华衰亡过程对湖泊碳库稳定性影响研究较少本研究采集太湖蓝藻、湖水、沉积物样品,建立蓝藻水沉积物室内模拟实验系统,分析蓝藻水华衰亡过程中沉积物碳库易氧化有机碳(EOC)、惰性有机碳(ROC)、微生物量碳(MBC)、轻组有机碳(LFOC)和重组有机碳(HFOC)的变化规律,探究蓝藻水华衰亡过程对湖泊碳库稳定性的影响结果表明,蓝藻水华衰亡前期(1～9天),ROC缓慢下降,EOC和LFOC快速下降,MBC有所增加;衰亡中期(10～45天),沉积物TOC和ROC含量升高;衰亡末期(46～63天),HFOC和ROC等稳定有机碳进入一个从缓慢分解逐渐趋于稳定的阶段周期性的蓝藻水华暴发、衰亡和湖泊稳定性有机碳的日渐累积,最终会对沉积物碳库有机碳组分及其稳定造成显著影响.     

Model‐based evaluation of impact of soil redistribution on soil organic carbon stocks in a temperate hedgerow landscape

Agroforestry systems are promoted for providing a number of ecosystem services and environmental benefits, including soil protection and carbon sequestration. This study proposes a modelling approach to quantify the impact of soil redistribution on soil organic carbon (SOC) storage in a temperate hedgerow landscape. Evolution of SOC stocks at the landscape scale was examined by simulating vertical and horizontal SOC transfers in the 0–105 cm soil layer due to soil redistribution by tillage and water processes. A spatially explicit SOC dynamics model (adapted from RothC‐26.3) was used, coupled with a soil‐redistribution model (LandSoil). SOC dynamics were simulated over 90 years in an agricultural hedgerow landscape dedicated to dairy farming, with a mix of cropping and grasslands. Climate and land use were simulated considering business‐as‐usual scenarios derived from existing information on the study area. A net decrease in SOC stocks was predicted at the end of the simulation period. Soil redistribution induced a net SOC loss equivalent to 2 kg C ha^?1 yr^?1 because of soil exportation out of the study site and an increase in SOC mineralization. Hedgerows and woods were the only land use in which soil redistribution induced net SOC storage. Soil tillage was the main process that induced soil redistribution within cultivated fields. Soil exportation out of the study area was due to erosion by water, but remained low because of the protective role of the hedgerow network. These soil transfers redistributed SOC stocks in the landscape, mostly within cultivated fields. Copyright © 2016 John Wiley & Sons, Ltd.     

太湖浮游植物群落的有机碳生产及其影响因子分析

2007年1-12月对中国科学院太湖湖泊生态系统站栈桥附近进行了每月1次以及太湖4个典型湖区每季度1次的有机碳生产实验,分析了太湖浮游植物群落的有机碳生产情况及其影响因子.结果表明,浮游植物有机碳生产与光照、温度以及浮游植物的群落组成有着密切的关系.舂、夏季浮游植物光合效率比秋、冬季高,空间上蓝藻占优势的湖区较高,水草区较低.     

Influence of topographic,geomorphic, and hydrologic variables on beaver dam height and persistence in the intermountain western United States

Stream ecosystems can be dramatically altered by dam-building activities of North American beaver (Castor canadensis). The extent to which beavers’ ecosystem engineering alters riverscapes is driven by the density, longevity, and size (i.e. height and length) of the dams constructed. In comparison to the relative ubiquity of beaver dams on the landscape, there is a scarcity of data describing dam heights. We collected data describing dam height and dam condition (i.e. damaged or intact) of 500 beaver dams via rapid field survey, differentiating between primary and secondary dams and associating each dam with a beaver dam complex. With these data, we examined the influence of beaver dam type (primary/secondary), drainage area, streamflow, stream power, valley bottom width, and HUC12 watershed on beaver dam height with linear regression and the probability that a beaver dam was damaged with logistic regression. On average, primary dams were 0.46 m taller than secondary dams; 15% of observed dams were primary and 85% secondary. Dam type accounted for 21% of dam height variation (p <0.0001). Slope (p = 0.0107), discharge (p = 0.0029), and drainage area (p = 0.0399) also affected dam height, but each accounted for less than 3% of dam height variation. The average number of dams in a dam complex was 6.1 (SD ± 4.5) and ranged from 1 to 21. The watershed a beaver dam was located in accounted for the most variability (17.8%) in the probability that a beaver dam was damaged, which was greater than the variability explained by any multiple logistic regression model. These results indicate that temporally dynamic variables are important influencers of dam longevity and that beaver dam ecology is a primary factor influencing beaver dam height. © 2020 John Wiley & Sons, Ltd.     

Soil organic carbon and nitrogen content of density fractions and effect of meadow degradation to soil carbon and nitrogen of fractions in alpine Kobresia meadow

This research was conducted on the non-disturbed native alpine Kobresia meadow(YF) and the severely degraded meadow(SDL) of Dari County of Qinghai Province.By a density fractionation approach,each soil sample was divided into two fractions:light fraction(LF) and heavy fraction(HF).The obtained fractions were analyzed for organic carbon(OC) and nitrogen(N) concentrations.The results showed:(1) the OC concentration in HF and LF was 3.84% and 28.63% respectively while the nitrogen concentration in HF and LF wa...     

Using Rock‐Eval 6 pyrolysis for tracking fossil organic carbon in modern environments: implications for the roles of erosion and weathering

This work relates to the debate on the fossil organic carbon (FOC) input in modern environments and its possible implication for the carbon cycle, and suggests the use of Rock‐Eval 6 pyrolysis as a relevant tool for tracking FOC in such environments. Considering that such a delivery is mainly due to supergene processes affecting the continental surface, we studied organic matter in different reservoirs such as bedrocks, alterites, soils and rivers in two experimental catchments at Draix (Alpes de Haute Provence, France). Samples were subjected to geochemical (Rock‐Eval 6 pyrolysis) investigations and artificial bacterial degradations. After comparing the geochemical fingerprint of samples, geochemical markers of FOC were defined and tracked in the different reservoirs. Our results confirm the contribution of FOC in modern soils and rivers and display the various influences of weathering and erosional processes on the fate of FOC during its exchange between these pools. In addition, the contrasting behaviour of these markers upon the supergene processes has also highlighted the refractory or labile characters of the fossil organic matter (FOM). Bedrock to river fluxes, controlled by gully erosion, are characterized by a qualitative and quantitative preservation of FOM. Bedrock to alterite fluxes, governed by chemical weathering, are characterized by FOC mineralization without qualitative changes in deeper alterites. Alterite to soils fluxes, controlled by (bio)chemical weathering, are characterized by strong FOC mineralization and qualitative changes of FOM. Thus weathering and erosional processes induce different FOM evolution and affect the fate of FOC towards the global carbon cycle. In this study, gully erosion would involve maintenance of an ancient sink for the global carbon cycle, while (bio)chemical processes provide a source of CO₂. Finally, this study suggests that Rock‐Eval 6 pyrolysis can be considered as a relevant tool for tracking FOC in modern environments. Copyright © 2006 John Wiley & Sons, Ltd.