淮南采煤沉陷区积水水文地球化学及氢氧稳定同位素特征

以安徽淮南采煤沉陷积水为研究对象,通过样品采集与测试,研究不同沉陷年限及类型积水水文地球化学和氢氧稳定同位素组成特征及影响因素.结果表明：（1）研究区水化学类型主要为Cl-Na、HCO₃·Cl-Na型,沉陷积水中常量离子主要来源于蒸发岩溶解和硅酸盐风化,受蒸发作用和人为活动的影响明显,水化学组成随沉陷时间和类型变化不大.（2）淮南大气降水线方程为：δD=8.85δ¹⁸O+18.73,沉陷区积水氢氧稳定同位素值在淮南大气降水线右下方依次分布并接近降水线,表明沉陷积水主要来源于大气降水.（3）在降水稀释、水体蒸发及地下水补给的作用下,随着沉陷年限的增加,积水中重同位素越来越贫化,同一年限不同类型的积水同位素值变化较小.     

A study on the spatial variations in stable isotopic composition of precipitation in a semiarid region of Southern India

The stable isotope analysis of all major rain events from Moinabad (MB), Rajendranagar (RN) and Osmanasagar (OS) reservoir, three closely placed locations in Hyderabad, India, were carried out during the 2005 to 2008 period. The OS station recorded the highest amount of rainfall with an average value of 1000 mm, whereas the MB station recorded the lowest average rainfall of 790 mm. The stable isotope (δ¹⁸O) values of the precipitation samples during these period varied from ?11.43‰ to ?0.03‰ for the MB station, ?8.21‰ to 0.54‰ for the RN station and ?11.47‰ to 0.72‰ for the OS station. The d‐excess of precipitation at the three stations also showed considerable variations and revealed that the precipitation in the region undergoes significant modification through secondary evaporation during its fall. The possible causes for these observed spatial and temporal variations in amount and the isotopic composition of precipitation in a small geographical area within the city were studied. The observed variations may be attributed to the regional scale differences in water budget induced by rapid urbanisation activities in the city coupled with the differences in secondary effects undergone by the falling drops. This study elucidating changes in precipitation patterns in the city and its possible causes may largely help in its water balance calculation. Copyright © 2011 John Wiley & Sons, Ltd.     

Dual effects of precipitation and evaporation on lake water stable isotope composition in the monsoon region

We present the results of a 3‐year monitoring programme of the stable isotope composition of lake water and precipitation at Taozi Lake, in the East Asian monsoon region of China. Our aims were to reveal the spatiotemporal pattern of variation of stable isotopes in a small closed‐basin lake and to quantitatively determine the impacts of precipitation and evaporation on the stable isotope composition of lake water under a humid monsoon climate. In the time domain, the stable oxygen isotopic ratio of the lake water (δ¹⁸O_L) exhibited substantial seasonal and interannual variations, but the isotope variations between different precipitation events substantially exceeded seasonal and interannual variations. Compared with the stable isotopes in precipitation, δ¹⁸O_L was substantially positive and d_L was negative. In the space domains, the lake water was homogeneously mixed. Indicated by statistic analyses, precipitation plays a dominant role in dynamic of the lake stable isotope during precipitation events of relatively large magnitude, whereas the effect of evaporation is dominant during smaller precipitation events. Results advance our understanding of the stable isotope change rule in the process of lake water evaporation, and it is helpful to identify the climatic significance recorded in stable isotopic compositions of lake bottom sediments.     

极端降水条件下白洋淀主淀区水化学特征及水质变化

极端降水是影响水环境质量的重要气象因素之一,随着全球气候变暖,极端降水事件的频率和量级呈显著上升的趋势,对湖泊水化学和水环境产生了深刻的影响.白洋淀是华北地区重要的湖泊型湿地和生态功能区,为查明极端降水条件下白洋淀主淀区的水化学和水质特征,本研究利用Piper三线图、Gibbs图和多元统计方法阐明了白洋淀极端降雨后的水化学特征、氢氧稳定同位素特征和水质空间变化,揭示了极端降水条件对白洋淀主淀区水化学和水质的影响.结果表明：(1)在极端降水条件下,白洋淀主淀区湖水呈弱碱性,水化学类型主要为Ca-HCO₃·SO₄型,极端降水减弱了蒸发结晶作用和人类活动等因素对白洋淀主淀区湖水水化学组成的影响.极端降水是导致白洋淀主淀区pH、电导率和总溶解性固体发生大幅度变化的原因之一.(2)极端降水条件下白洋淀主淀区湖水的δ²H和δ¹⁸O值的范围分别为-60.86‰～-35.01‰和-8.84‰～-3.45‰,其值均与水深呈显著负相关.极端降水使得白洋淀主淀区湖水的氢、氧稳定同位素贫化,但对其空间分布的影响不大,湖水氢...     

Influence of below-cloud evaporation on stable isotopes of precipitation in the Yellow River source region

The study of below-cloud evaporation effects under clouds in the Yellow River source region is of great significance for regional water resource generation as well as for water resource security in the arid and semi-arid regions of northern China. In this study, we quantitatively assessed the evapotranspiration effect in the Yellow River source region from March to November based on the improved Stewart model. The study concluded that: (1) below-cloud evaporation was slightly higher in summer than in other seasons (residual fractions of raindrop evaporation were 80.57% in summer, 81.12% in spring, and 84.2% in autumn, respectively); and (2) sub-cloud evaporation diminishes with increasing altitude (residual fractions of raindrop evaporation were 83.09% in the western part of the area, 81.82% in the central part of the area, and 81.36% in the eastern part of the area, respectively). (3) The total linear index between study areas f and ∆d is 2.24, where f > 95%, it is 1.19; that is, the evaporation of raindrops increases by 1% and the reduction in the excess of mercury by about 2‰. (4) Local meteorological factors (temperature, precipitation, and relative humidity) and raindrop diameter have a cross-influence on below-cloud evaporation, with relative humidity having the most significant effect, with the highest correlation coefficient of 3.03 when relative humidity is less than 70%. The results of the study can provide a parameter basis for hydrological and climatic models in the Yellow River Basin.     

Mechanisms of isotopic control of precipitation in the Yellow River source region

The study of water vapour sources and water cycle patterns in the Yellow River source region is of great significance for ensuring water resource security in the arid and semi-arid regions of northern China. We established a precipitation stable isotope observation system in the Yellow River source region for three consecutive years (2020–2022), systematically analysed the spatial and temporal distribution characteristics of precipitation stable isotopes ²H and ¹⁸O in the Yellow River source region and their interrelationships with environmental factors and topography, and explored the regional water vapour transport pathways by using the HYSPLIT model and combining with the global reanalysis data. The results show that: (1) the δ¹⁸O and δ²H values of precipitation in the Yellow River source region follow the seasonal pattern, with the first half of the year being richer than the second half of the year; (2) the spatial variations of δ¹⁸O of precipitation in the Yellow River source region show a low in the southwest and a high in the northeast; (3) the water vapour source in the source area is basically stable, and the complex transport paths and the cross-effects of the local factors determine the stable isotope characteristics of the water, and the stable isotope characteristics of the water are determined by the cross-effects of the local factors, because the source of the water vapour and the local factors such as the height will not change significantly in the short term. Since the source of water vapour and local elevation factors will not change significantly in the short term, the precipitation pattern in the source area of the Yellow River can be considered to be basically stable.     

Hydroclimatic significance of stable isotopes in precipitation from glaciers of Garhwal Himalaya,Upper Ganga Basin (UGB), India

Stable isotopic composition of precipitation as preserved in continental proxy climate archives (e.g., ice cores, lacustrine sediments, tree rings, groundwater, and organic matter) can sensitively record fluctuations in local meteorological variables. These are important natural climatic tracers to understand the atmospheric circulation patterns and hydrological cycle and to reconstruct past climate from archives. Precipitation was collected at Dokriani Glacier to understand the response of glaciers to climate change in the Garhwal Central Himalaya, Upper Ganga Basin. The local meteoric water line deviates from the global meteoric water line and is useful for the identification of moisture source in the region. The data suggest different clusters of isotopic signals, that is, summer (June–September) and winter (November–April); the mean values of δ¹⁸O, δD, and d ‰ during summer are ?13.03‰, ?84.49‰, and 19.78 ‰, respectively, whereas during winter, the mean values of δ¹⁸O, δD, and d ‰ are ?7.59‰, ?36.28‰, and 24.46 ‰, respectively. Backward wind trajectory analysis ascertains that the major source of precipitation during summer is from the Indian Summer Monsoon and during winter from the westerlies. Regression analysis has been carried out in order to establish interrelationship between the precipitation isotopic signatures and meteorological variables such as air temperature, relative humidity, and precipitation. Temperature and precipitation have good correlation with the isotopic signatures of precipitation with R² values >.5, suggesting that both temperature and amount effects prevail in the study region. Multiple regression analysis found strong relationships for both the seasons. The relationship of deuterium excess with δ¹⁸O, relative humidity, and precipitation are significant for the winter season. No significant relationships of deuterium excess were found with other meteorological variables such as temperature and radiation. The correlation and regression analysis performed are significant and valuable for interpretation of processes in the hydrological cycle as well as for interpretation of palaeoclimate records from the region.     

Moisture source diagnostics and isotope characteristics for precipitation in east Hungary: implications for their relationship

Knowledge relating to the relationship between the characteristics of precipitation and sources of moisture is essential to improve our understanding of the global water cycle. This study presents the first quantitative estimation of the moisture source regions combined with stable isotope analyses for precipitation at K-puszta, east Hungary. The contributions of the following moisture sources were diagnosed according to the sector analysis of 4-day backward trajectories together with the calculation of evaporation and precipitation fluxes based on the specific humidity: Mediterranean region (57.0%), local moisture (14.8%), Atlantic region (14.2%), Northern Europe (7.4%) and Eastern Europe (6.6%). The δD and δ¹⁸O values of daily precipitation were measured and the deuterium excess (d-excess) was calculated. The d-excess showed systematic differences among the marine sources, reflecting the characteristics of the moisture source area. The results suggest that the stable isotope composition of precipitation preserves information regarding the origin of the water vapour.     

Spatial and temporal variability in the stable isotope systematics of modern precipitation in China: implications for paleoclimate reconstructions

The stable isotopic composition of materials such as glacial ice, tree rings, lake sediments, and speleothems from low-to-mid latitudes contains information about past changes in temperature (T) and precipitation amount (P). However, the transfer functions which link δ¹⁸O_p to changes in T or P, dδ¹⁸O_p/dT and dδ¹⁸O_p/dP, can exhibit significant temporal and spatial variability in these regions. In areas affected by the Southeast Asian monsoon, past variations in δ¹⁸O and δD of precipitation have been attributed to variations in monsoon intensity, storm tracks, and/or variations in temperature. Proper interpretation of past δ¹⁸O_p variations here requires an understanding of these complicated stable isotope systematics. Since temperature and precipitation are positively correlated in China and have opposite effects on δ¹⁸O_p, it is necessary to determine which of these effects is dominant for a specific region in order to perform even qualitative paleoclimate reconstructions. Here, we evaluate the value of the transfer functions in modern precipitation to more accurately interpret the paleorecord. The strength of these transfer functions in China is investigated using multiple regression analysis of data from 10 sites within the Global Network for Isotopes in Precipitation (GNIP). δ¹⁸O_p is modeled as a function of both temperature and precipitation. The magnitude and signs of the transfer functions at any given site are closely related to the degree of summer monsoon influence. δ¹⁸O_p values at sites with intense summer monsoon precipitation are more dependent on the amount of precipitation than on temperature, and therefore exhibit more negative values in the summer. In contrast, δ¹⁸O_p values at sites that are unaffected by summer monsoon precipitation exhibit strong relationships between δ¹⁸O_p and temperature. The sites that are near the northern limit of the summer monsoon exhibit dependence on both temperature and amount of precipitation. Comparison with simple linear models (δ¹⁸O_p as a function of T or P) and a geographic model (δ¹⁸O_p as a function of latitude and altitude) shows that the multiple regression model is more successful at reproducing δ¹⁸O_p values at sites that are strongly influenced by the summer monsoon. The fact that the transfer function values are highly spatially variable and closely related to the degree of summer monsoon influence suggests that these values may also vary temporally. Since the Southeast Asian monsoon intensity is known to exhibit large variations on a number of timescales (annual to glacial–interglacial), and the magnitude and sign of the transfer functions is related to monsoon intensity, we suggest that as monsoon intensity changes, the magnitude and possibly even the sign of the transfer functions may vary. Therefore, quantitative paleoclimate reconstructions based on δ¹⁸O_p variations may not be valid.     

Variations of stable isotopic compositions in precipitation on the Tibetan Plateau and its adjacent regions

There is no temperature effect in the southern Tibetan Plateau and South Asia to the south of the Tanggula Mountains. Amount effect has been observed at a few sampling stations accounting for about a half of the statistical stations. There is notable temperature effect in the middle and northern Tibetan Plateau and its adjacent Central Asia to the north of the Tanggula Mountains. Because vapor directly originates from low-latitude oceans, the relative heavy δ¹⁸O with small variation characterizes the rainfall in South Asia. A sharp depletion of the stable isotopic compositions in precipitation takes place from Kyangjin on the southern slope of the Himalayas to the Tanggula Mountains in the middle plateau. From the Tanggula Mountains to the northern Tibetan Plateau, the δ¹⁸O in precipitation increases with increasing latitude.     

Spatial and temporal variations of stable isotopes in precipitation in midlatitude coastal regions

Spatial and temporal variations of the isotopic composition of precipitation were investigated to better understand their controlling factors. Precipitation was collected from six locations in Hokkaido, Japan, and event‐based analyses were conducted for a period from March 2010 to February 2013. Relatively low δ values and a high d‐excess for annual averages were observed at three sites located along the Japan Sea compared to the three sites at Pacific Ocean side. Lower δ values in spring and fall and higher d‐excess in winter were observed for the region along the Japan Sea. In total, 264 precipitation events were identified. Precipitation originated predominantly from low‐pressure system (LPS) events, which were classified as northwest (LPS‐NW) and southeast (LPS‐SE) events according to the routes of the low‐pressure center, that passed northwest and southeast of Hokkaido, respectively. LPS‐SE events showed lower δ¹⁸O than LPS‐NW events, which is attributable to the lower δ¹⁸O of water vapor resulting from heavy rainfalls in the upstream region of the LPS air mass trajectories over the Pacific Ocean. This phenomenon observed in Hokkaido can be found in other midlatitude coastal regions and applied for hydrological, atmospheric, and paleoclimate studies. A characteristic spatial pattern was found in LPS‐NW events, in which lower δ¹⁸O was observed on the Japan Sea side than on the Pacific Ocean side in each season. This is likely due to the location of the sampling sites and their distance from the LPS: Precipitation with lower δ¹⁸O in the region along the Japan Sea occurs in a well‐developed cloud system near the low‐pressure center in cold and warm sectors of LPS, whereas precipitation with higher δ¹⁸O on the Pacific side mainly occurs in a warm sector away from the low‐pressure center. Air mass from the north does not always cause low δ in precipitation, and the precipitation process in the upstream region is another important factor controlling the isotopic composition of precipitation, other than the local temperature and precipitation amount.     

Using stable isotopes to understand seasonal and interannual dynamics in moisture sources and atmospheric circulation in precipitation

Stable isotopes in precipitation are useful tracers to strengthen understanding of climate change and hydrological processes. In this study, the moisture sources of 190 precipitation events in Beijing were analysed using the Hybrid Single‐particle Lagrangian Integrated Trajectory model, based on which we studied the relation between variations in precipitation δ¹⁸O and dynamics in moisture sources and atmospheric circulation in seasonal and interannual timescales. Categorization of 7 groups of moisture sources was performed, among which oceanic moisture sources presented lower δ¹⁸O in precipitation than continental moisture sources. The results show that seasonal variations of precipitation δ¹⁸O were caused by changes of moisture sources. In summer, moisture from proximal oceans dominated vapour transport to Beijing due to increasing monsoon strength and resulted in a relatively small variation of precipitation δ¹⁸O. At the interannual timescale, the variations of δ¹⁸O in summer precipitation were related to dynamics in oceanic moistures, showing depleted values when the contribution of oceanic moistures, especially the proportion of long‐distance oceanic moisture, was high. Further analysis indicated that changes of oceanic moisture sources were controlled by the strength of summer monsoons. These findings address the complexity of moisture sources in midlatitude monsoon areas and suggest that isotopic signals in precipitation have the potential to deduce changes in moisture sources and atmospheric circulation and can therefore serve for palaeoclimate reconstruction.     

Spatial distribution and seasonal variation in 18O/16O of modern precipitation and river water across the conterminous USA

We report a quantitative analysis of regional differences in the the oxygen isotope composition of river water and precipitation across the USA because data are now available to undertake a more geographically and temporally extensive analysis than was formerly possible. Maps of modern, mean annual δ¹⁸O values for both precipitation (δ¹⁸O_PPT) and river water (δ¹⁸O_RIV) across the 48 contiguous states of the USA have been generated using latitude and elevation as the primary predictors of stable isotope composition while also incorporating regional and local deviations based on available isotopic data. The difference between these two maps was calculated to determine regions where δ¹⁸O_RIV is significantly offset from local δ¹⁸O_PPT. Additional maps depicting seasonal and extreme values for δ¹⁸O_RIV and δ¹⁸O_PPT were also constructed. This exercise confirms the presence of regions characterized by differences in δ¹⁸O_RIV and δ¹⁸O_PPT and specifically identifies the magnitude and regional extent of these offsets. In particular, the Great Plains has δ¹⁸O_RIV values that are more positive than precipitation, while much of the western USA is characterized by significantly lower δ¹⁸O_RIV values in comparison with local δ¹⁸O_PPT. The most salient feature that emerged from this comparison is the ‘catchment effect’ for the rivers. Because river water is largely derived from precipitation that fell upstream of the sample locality (i.e. at higher elevations) δ¹⁸O_RIV values are often lower than local δ¹⁸O_PPT values, particularly in catchments with high‐elevation gradients. Seasonal patterns in the isotopic data substantiate the generally accepted notion that amplitudes of δ¹⁸O variation are greatly dampened in river water relative to those of local precipitation. Copyright © 2005 John Wiley & Sons, Ltd.     

Spatial and temporal distributions of stable isotopes in precipitation over Thailand

Spatial and temporal variations of the isotopic composition of precipitation over Thailand were investigated. The local meteoric water line for Thailand deviates slightly from the global meteoric water line, with lower slopes (7.62 ± 0.07, 7.59 ± 0.08) and intercepts (6.42 ± 0.39, 6.22 ± 0.42) using ordinary and precipitation weighted methods. Differences in spatial and temporal δ¹⁸O distributions between the tropical monsoon and tropical savanna climate zones were found due to differing moisture source contributions and seasonal precipitation patterns. The temporal data reveals that the northeast monsoon rains originate from isotopically-enriched local moisture with isotope values of −9.36 to −0.09‰ (mean − 3.73 ± 0.42‰), whereas the southwest monsoon clouds had a more significant rainout effect from Rayleigh distillation, with isotope values of −9.56 to −1.78‰ (mean − 5.40 ± 0.38‰). The precipitation amount at each site was negatively correlated with δ¹⁸O (−0.24 to −3.20‰ per 100 mm, R² = 0.1–0.9). Furthermore, δ¹⁸O was negatively correlated with geography (latitude, altitude) for the southwest monsoon periods, as expected based on other observed correlations. However, an inverse correlation was seen in the northeast monsoon due to differing moisture transportation as part of the continental effect. The correlation coefficient (R) was higher in the southwest monsoon (−0.84 for latitude effect, −0.64 for altitude effect) than the northeast monsoon (0.67 for latitude effect, 0.35 for altitude effect). The spatial pattern of isotopic composition reflects the southwest monsoon more clearly than the northeast monsoon, but the two monsoons also have a cancelling impact on orographic patterns. An agreement of the δ¹⁸O and deuterium excess (d-excess) was a negative correlation and found to reflect precipitation sources and re-evaporation processes. The d-excess was slightly higher for the northeast monsoon, bringing moisture from the Pacific Ocean and travelling across the continent before reaching the observed stations. By contrast, the d-excess was relatively lower for the Indian Ocean's moisture in the southwest monsoon.     

Seasonal variations of stable isotope in precipitation and moisture transport at Yushu,eastern Tibetan Plateau

Precipitation δ 18O at Yushu, eastern Tibetan Plateau, shows strong fluctuation and lack of clear seasonality. The seasonal pattern of precipitation stable isotope at Yushu is apparently different from either that of the southwest monsoon region to the south or that of the inland region to the north. This different seasonal pattern probably reflects the shift of different moisture sources. In this paper, we present the spatial comparison of the seasonal patterns of precipitation δ 18O, and calculate the moisture transport flux by using the NCAR/NCEP reanalysis data. This allows us to discuss the relation between moisture transport flux and precipitation δ 18O. This study shows that both the southwest monsoon from south and inland air mass transport from north affected the seasonal precipitation δ 18O at Yushu, eastern Tibetan Plateau. Southwest monsoon brings the main part of the moisture, but southwest transport flux is weaker than in the southern part of the Tibetan Plateau. However, contribution of the inland moisture from north or local evaporation moisture is enhanced. The combined effect is the strong fluctuation of summer precipitation δ 18O at Yushu and comparatively poor seasonality.     

Orographic distillation and spatio‐temporal variations of stable isotopes in precipitation in the North Atlantic

Little is known about the spatial and temporal variability of the stable isotopic composition of precipitation in the North Atlantic and its relationship to the North Atlantic Oscillation (NAO) and anthropogenic climate change. The islands of the Azores archipelago are uniquely positioned in the middle of the North Atlantic Ocean to address this knowledge gap. A survey of spatial and temporal variability of the stable isotope composition of precipitation in Azores is discussed using newly presented analyses along with Global Network of Isotopes in Precipitation data. The collected precipitation samples yield a new local meteoric water line (δ²H = 7.1 * δ¹⁸O + 8.46) for the Azores region and the North Atlantic Ocean. The annual isotopic mean of precipitation shows a small range for the unweighted and precipitation mass‐weighted δ¹⁸O‐H₂O values. Results show an inverse relation between the monthly δ¹⁸O‐H₂O and the amount of precipitation, which increases in elevation and into the interior of the island. Higher amounts of precipitation (from convective storm systems) do not correspond to the most depleted values of stable isotopes in precipitation. Precipitation shows an orographic effect with depleted δ¹⁸O‐H₂O values related to the Rayleigh effect. Monthly δ¹⁸O‐H₂O values for individual precipitation sampling stations show little relationship to air temperature. Results show a local source of moisture during the summer with the characteristics of the first vapour condensate. The stable isotope composition of precipitation is strongly correlated to the NAO index, and δ¹⁸O‐H₂O values show a statistically significantly trend towards enrichment since 1962 coincident with the increased air temperature and relative humidity due to climate change. Results are in line with observations of increasing sea surface temperature and relative humidity.     

Seasonal variations of deuterium and oxygen‐18 isotopes and their response to moisture source for precipitation events in the subtropical monsoon region

Deuterium and oxygen‐18 are common environmental tracers in water used to investigate hydrological processes such as evaporation and groundwater recharge, and to trace moisture source. In this study, we collected event precipitation from 01 January 2010 to 28 February 2011 at a site in Changsha, Yangtze River Basin to estimate the influence of moisture source and atmospheric conditions on stable isotope compositions. The local meteoric water line, established as δD = (8.45 ± 0.13) δ¹⁸O + (17.7 ± 0.9) (r² = 0.97, n = 189), had a higher slope and intercept than global meteoric water line. Temperature–δ¹⁸O exhibited complex correlations, with positive correlations during Nov.–Apr. superior to during Jun.–Sep., which was attributed to distinctive moisture sources, but vague the overall period; amount effect examined throughout the year. Linear regressions between δ¹⁸O and δD value in different precipitation event size classes revealed progressively decreasing slope and intercept values with decreasing precipitation amount and increasing vapour pressure deficit, indicating that small rainfall events (0–5 mm) were subject to secondary evaporation effects during rainwater descent. In contrast, snowfall and heavy precipitation events exhibited high slope and intercepts for the regression equation between δ¹⁸O and δD. High concentrations of heavy isotopes were associated with precipitation events sourced from remote westerly air masses, degenerated tropical marine air masses from the Bay of Bengal (BoB), and inland moisture in the pre‐monsoon period, as determined from backward trajectories assessed in the HYSPLIT model. Meanwhile, low concentrations of heavy isotopes were found to correspond with remote maritime moisture from BoB, the South China Sea, and the west Pacific at three different air pressures in summer monsoon and post‐monsoon using HYSPLIT and records of typhoon paths. These findings suggest that stable isotope compositions in precipitation events are closely associated with the meteorological conditions and respond sensitively to moisture source in subtropical monsoon climates. Copyright © 2013 John Wiley & Sons, Ltd.     

Factors controlling stable oxygen,hydrogen and carbon isotope ratios in regional groundwater of the eastern United Arab Emirates (UAE)

Increasing groundwater salinity and depletion of the aquifers are major concerns in the UAE. Isotopes of oxygen, hydrogen, and carbon concentrations in groundwater were used to estimate evaporation loss using the isotopes of oxygen and hydrogen, and using a carbon isotope to trace inorganic carbon cycling in two main aquifers in the eastern part of the United Arab Emirates. The δD‐δ¹⁸O of groundwater samples plotted on a line given by: δD = 4 δ¹⁸O + 4 ·4 (r² = 0·4). In comparison, the local meteoric water line (LMWL) has been defined by the line: δD = 8 δ¹⁸O + 15. In order to better understand the system investigated, samples were separated into two groups based on the δD‐δ¹⁸O relationship. These are (1) samples that plot above the LMWL (δD = 6·1 δ¹⁸O + 12·4, r² = 0·8) and which are located predominantly in the north of the study area, and (2) samples that plot below the LMWL (δD = 5·6 δ¹⁸O + 6·2, r² = 0·8) and which are mostly distributed in the south. Slopes for both the groups are similar and lower than that for LMWL indicating potential evaporation of recharging water. However, the y‐intercept, which differs between the two groups, suggests evaporation of return flow and evapotranspiration in the unsaturated zone to be more significant in the south. This is attributed to intense agricultural activities in the region. Samples from the eastern Gravel Plain aquifer have δ¹³C and dissolved inorganic carbon (DIC) values in the range from ? 10 to 17‰, and 12–100 mg C/l, respectively, while the range for those from the Ophiolite aquifer is from ? 11 to ? 16.4‰, and 16–114 mg C/l respectively. This suggests the control of C‐3 and C‐4 plants on DIC formation, an observation supported by the range δ¹³C of soil organic matter (from ? 18·5 to ? 22·1‰.) Copyright © 2007 John Wiley & Sons, Ltd.     

基于氢氧同位素分析南昌地震台流体观测井水补给来源

在地震地下流体研究中,地下水补给及循环过程是重要的研究内容之一,氢氧同位素示踪技术是目前研究该过程的常用手段。南昌地震台流体观测井自2013年8月22日投入观测以来,其基础数据未进行有效分析,通过对南昌井水样数据进行氢氧同位素及水化学实验分析,结果表明：井水主要补给源为直接大气降雨,补给前经历了一定蒸发作用;水—岩反应不充分,属于未成熟水;水样中无明显优势阳离子,Ca²⁺、Na⁺占主体,优势阴离子为HCO₃^－,表明井水属重碳酸型水;水源补给高程约582 m。南昌地震台流体观测井总体受大气降水影响较大。     

Spatial,seasonal, and source variability in the stable oxygen and hydrogen isotopic composition of tap waters throughout the USA

To assess spatial, seasonal, and source variability in stable isotopic composition of human drinking waters throughout the entire USA, we have constructed a database of δ¹⁸O and δ²H of US tap waters. An additional purpose was to create a publicly available dataset useful for evaluating the forensic applicability of these isotopes for human tissue source geolocation. Samples were obtained at 349 sites, from diverse population centres, grouped by surface hydrologic units for regional comparisons. Samples were taken concurrently during two contrasting seasons, summer and winter. Source supply (surface, groundwater, mixed, and cistern) and system (public and private) types were noted. The isotopic composition of tap waters exhibits large spatial and regional variation within each season as well as significant at‐site differences between seasons at many locations, consistent with patterns found in environmental (river and precipitation) waters deriving from hydrologic processes influenced by geographic factors. However, anthropogenic factors, such as the population of a tap's surrounding community and local availability from diverse sources, also influence the isotopic composition of tap waters. Even within a locale as small as a single metropolitan area, tap waters with greatly differing isotopic compositions can be found, so that tap water within a region may not exhibit the spatial or temporal coherence predicted for environmental water. Such heterogeneities can be confounding factors when attempting forensic inference of source water location, and they underscore the necessity of measurements, not just predictions, with which to characterize the isotopic composition of regional tap waters. Published 2013. This article is a U.S. Government work and is in the public domain in the USA.