Seasonal connections between meteoric water and streamflow generation along a mountain headwater stream

In snowmelt-driven mountain watersheds, the hydrologic connectivity between meteoric waters and stream flow generation varies strongly with the season, reflecting variable connection to soil and groundwater storage within the watershed. This variable connectivity regulates how streamflow generation mechanisms transform the seasonal and elevational variation in oxygen and hydrogen isotopic composition (δ¹⁸O and δD) of meteoric precipitation. Thus, water isotopes in stream flow can signal immediate connectivity or more prolonged mixing, especially in high-relief mountainous catchments. We characterized δ¹⁸O and δD values in stream water along an elevational gradient in a mountain headwater catchment in southwestern Montana. Stream water isotopic compositions related most strongly to elevation between February and March, exhibiting higher δ¹⁸O and δD values with decreasing elevation. These elevational isotopic lapse rates likely reflect increased connection between stream flow and proximal snow-derived water sources heavily subject to elevational isotopic effects. These patterns disappeared during summer sampling, when consistently lower δ¹⁸O and δD values of stream water reflected contributions from snowmelt or colder rainfall, despite much higher δ¹⁸O and δD values expected in warmer seasonal rainfall. The consistently low isotopic values and absence of a trend with elevation during summer suggest lower connectivity between summer precipitation and stream flow generation as a consequence of drier soils and greater transpiration. As further evidence of intermittent seasonal connectivity between the stream and adjacent groundwaters, we observed a late-winter flush of nitrate into the stream at higher elevations, consistent with increased connection to accumulating mineralized nitrogen in riparian wetlands. This pattern was distinct from mid-summer patterns of nitrate loading at lower elevations that suggested heightened human recreational activity along the stream corridor. These observations provide insights linking stream flow generation and seasonal water storage in high elevation mountainous watersheds. Greater understanding of the connections between surface water, soil water and groundwater in these environments will help predict how the quality and quantity of mountain runoff will respond to changing climate and allow better informed water management decisions.     

The stable isotopes of natural waters at the Marcell Experimental Forest

We present a new data set from the Marcell Experimental Forest (MEF) that compiles water isotope measurements from multiple research catchments, some of which have been studied since the 1960s. The MEF is located in northern Minnesota, USA, and is home to heavily studied and monitored forests, streams, bogs, and fens. Peat-forming systems (bogs and fens) are an important component of the MEF landscape and have a profound impact on the water cycle in these catchments. Within the last decade, analysis of stable isotopes of water (expressed as δD and δ¹⁸O) has been implemented to characterize the different components of the water budget, and to allow researchers to look at catchment and peatland-specific hydrologic effects in the watershed. This δD and δ¹⁸O data set of natural waters from MEF catchments is primarily composed of measurements from three peatlands (S1, S2, S6) during an 11-year period. More recently collection and analysis were expanded to also include samples from the Spruce and Peatland Responses Under Changing Environments (SPRUCE) project in the S1 bog, peatlands S3, S4, S5, as well as nearby lakes. We establish a local meteoric water line by analyzing the isotopic composition of precipitation, which fills a void in regional meteoric water lines for Minnesota. Furthermore, we establish baseline isotopic composition for bog outlet streams, bog porewater, aquifer groundwater, overland flow, subsurface stormflow, and snowpack, as well as runoff from the SPRUCE experimental chambers. These data are publicly available and will be expanded upon in the future.     

Inter‐comparison of hydro‐climatic regimes across northern catchments: synchronicity,resistance and resilience

The higher mid‐latitudes of the Northern Hemisphere are particularly sensitive to climate change as small differences in temperature determine frozen ground status, precipitation phase, and the magnitude and timing of snow accumulation and melt. An international inter‐catchment comparison program, North‐Watch, seeks to improve our understanding of the sensitivity of northern catchments to climate change by examining their hydrological and biogeochemical responses. The catchments are located in Sweden (Krycklan), Scotland (Mharcaidh, Girnock and Strontian), the United States (Sleepers River, Hubbard Brook and HJ Andrews) and Canada (Catamaran, Dorset and Wolf Creek). This briefing presents the initial stage of the North‐Watch program, which focuses on how these catchments collect, store and release water and identify ‘types’ of hydro‐climatic catchment response. At most sites, a 10‐year data of daily precipitation, discharge and temperature were compiled and evaporation and storage were calculated. Inter‐annual and seasonal patterns of hydrological processes were assessed via normalized fluxes and standard flow metrics. At the annual‐scale, relations between temperature, precipitation and discharge were compared, highlighting the role of seasonality, wetness and snow/frozen ground. The seasonal pattern and synchronicity of fluxes at the monthly scale provided insight into system memory and the role of storage. We identified types of catchments that rapidly translate precipitation into runoff and others that more readily store water for delayed release. Synchronicity and variance of rainfall–runoff patterns were characterized by the coefficient of variation (cv) of monthly fluxes and correlation coefficients. Principal component analysis (PCA) revealed clustering among like catchments in terms of functioning, largely controlled by two components that (i) reflect temperature and precipitation gradients and the correlation of monthly precipitation and discharge and (ii) the seasonality of precipitation and storage. By advancing the ecological concepts of resistance and resilience for catchment functioning, results provided a conceptual framework for understanding susceptibility to hydrological change across northern catchments. Copyright © 2010 John Wiley & Sons, Ltd.     

Oxygen‐18 dynamics in precipitation and streamflow in a semi‐arid agricultural watershed,Eastern Washington,USA

Understanding flow pathways and mechanisms that generate streamflow is important to understanding agrochemical contamination in surface waters in agricultural watersheds. Two environmental tracers, δ¹⁸O and electrical conductivity (EC), were monitored in tile drainage (draining 12 ha) and stream water (draining nested catchments of 6‐5700 ha) from 2000 to 2008 in the semi‐arid agricultural Missouri Flat Creek (MFC) watershed, near Pullman Washington, USA. Tile drainage and streamflow generated in the watershed were found to have baseline δ¹⁸O value of ?14·7‰ (VSMOW) year round. Winter precipitation accounted for 67% of total annual precipitation and was found to dominate streamflow, tile drainage, and groundwater recharge. ‘Old’ and ‘new’ water partitioning in streamflow were not identifiable using δ¹⁸O, but seasonal shifts of nitrate‐corrected EC suggest that deep soil pathways primarily generated summer streamflow (mean EC 250 µS/cm) while shallow soil pathways dominated streamflow generation during winter (EC declining as low as 100 µS/cm). Using summer isotopic and EC excursions from tile drainage in larger catchment (4700‐5700 ha) stream waters, summer in‐stream evaporation fractions were estimated to be from 20% to 40%, with the greatest evaporation occurring from August to October. Seasonal watershed and environmental tracer dynamics in the MFC watershed appeared to be similar to those at larger watershed scales in the Palouse River basin. A 0·9‰ enrichment, in shallow groundwater drained to streams (tile drainage and soil seepage), of δ¹⁸O values from 2000 to 2008 may be evidence of altered precipitation conditions due to the Pacific Decadal Oscillation (PDO) in the Inland Northwest. Copyright © 2009 John Wiley & Sons, Ltd.     

Influence of lowland aquifers and anthropogenic impacts on the isotope hydrology of contrasting mesoscale catchments

We examined the isotope hydrology of eight, contrasting mesoscale (104–488 km²) catchments characterized by a systematic change in the relative importance of upland and lowland areas that reflects the relative distribution of metamorphic and sedimentary rocks. Precipitation and stream water were monitored over a 12‐month period, and stable isotopes were used to examine spatial variations in the hydrometric and tracer dynamics of the catchments. Isotopic tracers were used to examine the temporal dynamics of different runoff sources, and geochemical tracers (alkalinity) were used to identify the geographic sources of runoff. Input–output relationships of isotopic tracers were explored using a gamma function to fit a transit time distribution, which was used to test the hypothesis that the length of mean transit times increased systematically with the cover of sandstone aquifers in the catchments. However, in three catchments, the increased influence of anthropogenic factors, notably reservoir storage, urban runoff and agricultural abstraction for irrigation, prevented reliable transit time estimation. For sites where tentative mean transit time estimates were possible, these varied from around 1.6 years in upland catchments dominated by metamorphic rocks (>75%) and responsive soils to around 4 years in catchments with 34% sandstone cover and freely draining soils. These preliminary results were consistent with inferences of geochemical tracers on the increased role of sedimentary aquifers as runoff sources in lowland areas, but observation from a larger number of sites is needed to confirm this. Copyright © 2012 John Wiley & Sons, Ltd.     

Use of stable water isotopes to identify hydrological processes of meteoric water in montane catchments

This study analyzes the stable isotopic compositions of hydrogen and oxygen (δ²H, δ¹⁸O) in montane meteoric waters including precipitation and stream water of central Taiwan to identify hydrological processes in montane catchments. Results of precipitation demonstrate that monsoon and altitude effects are two principal processes affecting δ and deuterium excess (d^E) values of inland precipitation in central Taiwan. Furthermore, slope and intercept values of summer and winter local meteoric water line are modified by secondary evaporation effects such as moisture recycling and raindrop evaporation. Additionally, stream water's results indicate that differences in δ values among stream waters reflect isotopic altitude effect whereby lower values are more evident in stream water originating from high‐elevation catchments than low‐elevation catchments. Comparison of the isotopic results between precipitation and stream water indicates that summer precipitation containing recycled moisture is the most important water source for the studied stream waters and indicates that catchment effect and base flow contribution are the two major hydrological processes affecting mountain stream hydrology. The hydrological processes identified by the isotopic study re‐stress the important role of forests in mountain hydrology. Copyright © 2015 John Wiley & Sons, Ltd.     

Precipitation induced stream flow: An event based chemical and isotopic study of a small stream in the Great Plains region of the USA

A small stream in the Great Plains of USA was sampled to understand the streamflow components following intense precipitation and the influence of water storage structures in the drainage basin. Precipitation, stream, ponds, ground-water and soil moisture were sampled for determination of isotopic (D, ¹⁸O) and chemical (Cl, SO₄) composition before and after two intense rain events. Following the first storm event, flow at the downstream locations was generated primarily through shallow subsurface flow and runoff whereas in the headwaters region – where a pond is located in the stream channel – shallow ground-water and pond outflow contributed to the flow. The distinct isotopic signatures of precipitation and the evaporated pond water allowed separation of the event water from the other sources that contributed to the flow. Similarly, variations in the Cl and SO₄ concentrations helped identify the relative contributions of ground-water and soil moisture to the streamflow. The relationship between deuterium excess and Cl or SO₄ content reveals that the early contributions from a rain event to streamflow depend upon the antecedent climatic conditions and the position along the stream channel within the watershed. The design of this study, in which data from several locations within a watershed were collected, shows that in small streams changes in relative contributions from ground water and soil moisture complicate hydrograph separation, with surface-water bodies providing additional complexity. It also demonstrates the usefulness of combined chemical and isotopic methods in hydrologic investigations, especially the utility of the deuterium excess parameter in quantifying the relative contributions of various source components to the stream flow.     

Using hydrogeochemical data to trace groundwater flow paths in a cold alpine catchment

Significant uncertainty remains in understanding the groundwater flow pathways in the northeastern Qinghai–Tibet Plateau. Hydrogeochemical and isotopic data as well as hydrogeological data were combined to explore the groundwater flow path in a representative cold alpine catchment in the headwater region of the Heihe River. The results indicate that the suprapermafrost groundwater chemical components were mainly affected by calcite dissolution and evaporation, whereas the geochemistry of subpermafrost groundwater was controlled by dolomite and gypsum dissolution, calcite precipitation, and albite and halite dissolution. Distinct hydrogeochemical characteristics and controlling processes suggest a poor hydraulic connectivity between the suprapermafrost and subpermafrost groundwater. The hydraulic connectivity between permafrost groundwater and groundwater in the seasonally frozen area was confirmed by their similar hydrogeochemical features. In the seasonally frozen area, a silty clay layer with low permeability separates the aquifer into the deep (depth >20 m) and shallow (depth <20 m) flow paths. The deep groundwater was characterized by the enhanced dedolomitization and enhanced cation exchange processes compared with the shallow groundwater. Groundwater in the seasonally frozen area finally discharges as base flow into the stream. These results provide useful information about the groundwater flow systems in the unique alpine gorge catchments in Qinghai–Tibet Plateau. The above findings suggest that the permafrost distribution and the aquifer structures within the seasonally frozen area have significant impact on groundwater flow paths. Cross‐validation by drilling work and hydrograph data confirms that the hydrogeochemical and isotopic tracers combined with field investigations can be relatively low‐cost tools in interpreting the groundwater flow paths in similar alpine catchments.     

Understanding hydrological processes in glacierized catchments: Evidence and implications of highly variable isotopic and electrical conductivity data

The spatial and temporal characterization of geochemical tracers over Alpine glacierized catchments is particularly difficult, but fundamental to quantify groundwater, glacier melt, and rain water contribution to stream runoff. In this study, we analysed the spatial and temporal variability of δ²H and electrical conductivity (EC) in various water sources during three ablation seasons in an 8.4‐km² glacierized catchment in the Italian Alps, in relation to snow cover and hydro‐meteorological conditions. Variations in the daily streamflow range due to melt‐induced runoff events were controlled by maximum daily air temperature and snow covered area in the catchment. Maximum daily streamflow decreased with increasing snow cover, and a threshold relation was found between maximum daily temperature and daily streamflow range. During melt‐induced runoff events, stream water EC decreased due to the contribution of glacier melt water to stream runoff. In this catchment, EC could be used to distinguish the contribution of subglacial flow (identified as an end member, enriched in EC) from glacier melt water to stream runoff, whereas spring water in the study area could not be considered as an end member. The isotopic composition of snow, glacier ice, and melt water was not significantly correlated with the sampling point elevation, and the spatial variability was more likely affected by postdepositional processes. The high spatial and temporal variability in the tracer signature of the end members (subglacial flow, rain water, glacier melt water, and residual winter snow), together with small daily variability in stream water δ²H dynamics, are problematic for the quantification of the contribution of the identified end members to stream runoff, and call for further research, possibly integrated with other natural or artificial tracers.     

The influence of lithology on surface water sources

Understanding the temporal and spatial variability of water sources within a basin is vital to our ability to interpret hydrologic controls on biogeochemical processes and to manage water resources. Water stable isotopes can be used as a tool to determine geographic and seasonal sources of water at the basin scale. Previous studies in the Coastal Range of Oregon reported that the variation in the isotopic signatures of surface water did not conform to the commonly observed “elevation effect,” which exhibits a trend of increasing isotopic depletion with rising elevation. The primary purpose of this research is to investigate the mechanisms governing seasonal and spatial variations in the isotopic signature of surface waters within the Marys River Basin, located in the leeward side of the Oregon Coastal Range. Surface water and precipitation samples were collected every 2–3 weeks for isotopic analysis for 1 year. Our results confirmed the lack of elevational variation of surface water isotopes within this leeward basin. Although we find elevational variation in precipitation in the eastern portion of the watershed, this elevation effect is counteracted by rainout with distance from the Pacific coast. In addition, we found significant variation in surface water isotope values between catchments underlain predominantly by basalt or sandstone. The degree of separation was strongest during the summer when low flows reflect deeper groundwater sources. This indicates that baseflow within streams drained by each lithology is being supplied from two distinctly separate water sources. In addition, the flow of the Marys River is dominated by water originating from the sandstone water source, particularly during the low‐flow summer months. We interpreted that the difference in water source results from sandstone catchments having highly fractured geology or locally tipping to the east facilitating cross‐basin water exchange from the windward to the leeward side of the Coast Range. Our results challenge topographic derived watershed boundaries in permeable sedimentary rocks; highlighting the overwhelming importance of underlying geology.     

Land management impacts on runoff sources in small Amazon watersheds

Forest clearing and conversion to cattle pasture in the lowland Amazon region has been linked to soil compaction and increased soil water storage, which combine to diminish soil infiltration, enhance quick lateral flows and increase the stream flow response to precipitation. Quantifying the importance of quick surficial flow in response to this land use change requires identification of water sources within catchments that contribute to stream flow. Using an end member mixing analysis approach, potential contributing sources of stream flow were evaluated during an entire rainy season in a forest and a pasture watershed drained by ephemeral‐to‐intermittent streams in the south‐western Amazon. Water yield was 17% of precipitation in the pasture and 0·8% of precipitation in the forest. During the early rainy season, throughfall, groundwater, and soil water contributed 79%, 18%, and 3%, respectively, to total forest stream flow. Over the entire rainy season, throughfall, groundwater, and shallow soil water provided 57%, 24%, and 19%, respectively, of stream flow. In the pasture watershed, overland flow dominated stream flow both in the early (67%) and late (57%) rainy season, with a mean contribution of 60% overland flow, 35% groundwater, and 5% soil water. The uncertainty associated with those estimates was studied using a Monte Carlo approach. In addition to large changes in total surface flow, marked differences were found in the proportions of total stream flow in the second half of the rainy season between the forest and pasture watershed. These results suggest that (1) there is great potential for alteration of the hydrological budgets of larger watersheds as the proportion of deforested land in the Amazon increases, and (2) as more rainfall is diverted into fast flowpaths to streams in established pastures, the potential to deliver water with higher solute concentrations generated by erosion or by bypassing sites of solute removal increases. Copyright © 2007 John Wiley & Sons, Ltd.     

Isotope hydrology and water sources in a heavily urbanized stream

Complex networks of both natural and engineered flow paths control the hydrology of streams in major cities through spatio-temporal variations in connection and disconnection of diverse water sources. We used spatially extensive and temporally intensive sampling of water stable isotopes to disentangle the hydrological sources of the heavily urbanized Panke catchment (~220 km²) in the north of Berlin, Germany. The isotopic data enabled us to partition stream water sources across the catchment using a Bayesian mixing analysis. The upper part of the catchment streamflow is dominated by groundwater (~75%) from gravel aquifers. In dry summer periods, streamflow becomes intermittent in the upper catchment, possibly as a result of local groundwater abstractions. Storm drainage dominates the responses to precipitation events. Although such events can dramatically change the isotopic composition of the upper stream network, storm drainage only accounts for 10%–15% of annual streamflow. Moving downstream, subtle changes in sources and isotope signatures occur as catchment characteristics vary and the stream is affected by different tributaries. However, effluents from a wastewater treatment plant (WWTP), serving 700,000 people, dominate stream flow in the lower catchment (~90% of annual runoff) where urbanization effects are more dramatic. The associated increase in sealed surfaces downstream also reduces the relative contribution of groundwater to streamflow. The volume and isotopic composition of storm runoff is again dominated by urban drainage, though in the lower catchment, still only about 10% of annual runoff comes from storm drains. The study shows the potential of stable water isotopes as inexpensive tracers in urban catchments that can provide a more integrated understanding of the complex hydrology of major cities. This offers an important evidence base for guiding the plans to develop and re-develop urban catchments to protect, restore, and enhance their ecological and amenity value.     

Subsurface hydrology of tile-drained headwater catchments: Compatibility of concepts and hydrochemistry

Concepts and terms used in previous multidisciplinary studies of tile-drained aquitard-dominated catchments (TDADC) are inconsistent and confusing. We provide a well-defined, comprehensive conceptual model of the subsurface hydrology of TDADC by selecting seven mutually compatible and consistent concepts. These concepts are: (1) groundwater as the main source of baseflow in headwater streams, (2) dominance of ‘pre-event’ water in stormflow, (3) importance of both macropores and matrix, (4) changes in flowpaths with rate of stream discharge, (5) dominance of shallow, lateral subsurface flow, (6) interactive nature of subsurface water, (7) transpiration of groundwater. This conceptual model was successfully ‘field-tested’ by examining data collected in a TDADC in a rural area of southern Ontario, Canada. The data consist mainly of chemical and isotopes tracers in water samples (headwater streams, groundwater, precipitation, tile water, soil-surface water), supplemented by water levels and meteorological data.     

Determination of runoff components using path analysis and isotopic measurements in a glacier‐covered alpine catchment (upper Hailuogou Valley) in southwest China

Monitoring of stable water isotopes (δ¹⁸O and δ²H) at the watershed scales can improve our understanding of complex hydrology and hydroclimatology of the watershed, especially in remote regions. Previous studies that used tracers for hydrograph separation are largely based on end‐member mixing approach (EMMA), but one drawback of this approach is that at least two independent tracers are required for multi‐component separation. Here we introduce a new approach—path analysis, in combination with isotopic measurements to investigate the runoff generation in a glacier‐covered alpine catchment (upper Hailuogou Valley) in southwest China. This newly developed method can not only provide a multi‐component hydrograph separation with the aid of only one tracer but also determine the direct and indirect influence of sources on streamflow. Path analysis show that the majority of streamflow is dominated by ice/snow meltwater that represents about 63–78% of the total discharge, whereas precipitation and groundwater contribute approximately 19–39% and 2–4% of the streamflow discharge, respectively. These results are in good agreement with those derived from EMMA (using ¹⁸O and Cl^? as tracers), corroborating that our proposed approach is successful in hydrograph separation of the catchment. This approach may provide new opportunities for the hydrograph separation of catchment with sparse data and be of interest to catchment hydrologists who seek to understand the behaviour of hydrologic systems. Copyright © 2015 John Wiley & Sons, Ltd.     

An efficient methodology for estimating irrigation return flow coefficients of irrigated crops at watershed and seasonal scale

Irrigation return flow coefficients, i.e. the ratio between the quantity of water returned from the cultivated area to the groundwater system and the amount of abstraction, vary by more than 50% for rice cultivation using standing water irrigation to 0% in the case of drip irrigation technique. This component of the groundwater budget plays an important role, particularly in intensively irrigated areas. Thus, to avoid any inaccurate aquifer budgeting, modelling and consequently any erroneous watershed management, this component needs to be accurately assessed for a particular time‐step (e.g. weekly, seasonally) onto the studied area. The present paper proposes a cost‐effective and useful methodology for assessing irrigation return flow coefficients (C_f = irrigation return flow/pumping flow) based on (i) basic crops field survey and meteorological data and (ii) the use of a simple hydraulic model that combines both water balance technique and unsaturated/saturated flow theory. An attempt to estimate the uncertainty of irrigation return flow coefficient estimates based on the uncertainty introduced by the pumping and the natural spatial variability of the soil characteristics is also proposed. Results have been compared to real field conditions and allow us to (i) estimate the uncertainty and (ii) validate and demonstrate the robustness of the applied methodology. The proposed methodology allows relatively good estimates of the irrigation return flow coefficients at watershed and seasonal scale. The irrigation return flow coefficients are calculated as: 51 ± 8% in rainy season (Kharif) and 48 ± 4% in summer (Rabi) for rice; 26 ± 11% in rainy season and 24 ± 4% in summer for vegetables; 13 ± 8% in rainy season and 11 ± 3% in summer for flowers. These results were found to be consistent with the existing literature. Copyright © 2007 John Wiley & Sons, Ltd.     

Improved understanding of spring and stream water responses in headwaters of the Indian Lesser Himalaya using stable isotopes,conductivity and temperature as tracers

Stable isotope data are presented for precipitation, spring and stream water in a headwater catchments in the Indian Lesser Himalaya. Isotopic contents of phreatic groundwater followed the local meteoric water line and showed minimal alteration by evaporation, suggesting fast recharge. Mean isotopic values for springs and the stream were close to the weighted annual mean for precipitation, indicating recharge was in synchrony with seasonal rainfall distribution. Precipitation exhibited isotopic declines of ?0.6‰ and ?0.2‰ δ¹⁸O per 100 m rise in elevation in July and August (monsoon), respectively. The time lag of one month between rainfall and spring discharge, combined with the isotopic lapse rate indicated a recharge elevation of 70–165 m above the spring outflow point, implying the water originated within the catchment. Time series of electrical conductivity and temperature of spring, seepage and stream waters confirmed the rapid recharge and limited storage capacity of the shallow aquifers.     

Effects on catchment water balance from the management of Pinus plantations on the coastal lowlands of south‐east Queensland,Australia

A paired catchment study was conducted over a 10‐year period on the hydrology of an exotic Pinus plantation in the coastal lowlands of south‐east Queensland, Australia. Each catchment was instrumented with a stream monitoring station, tipping bucket rain gauge, and a network of piezometers to monitor the shallow perched water table. After a 6‐year calibration period a harvest treatment was imposed on one catchment (Review): clearfelling approximately 90% of the catchment area, which contained a mature (44‐year‐old) Pinus elliottii plantation. This subsequently was re‐established with a second rotation plantation of a hybrid of P.elliottii × P.caribaea var. hondurensis. The control catchment (Crayfish) contained a P. elliottii plantation similar to that clearfelled at Review. The post‐harvest period was monitored for a further 4 years. Evapotranspiration was found to be the major output flux, with stream flow only a minor component of the study catchments' water budget. Areas with gleyed podzolic soils were found to remain waterlogged for periods up to 7 months following the seasonally high summer rainfall period, with other soils having water logging periods of only a few months. Little change was observed in waterlogging characteristics following harvesting, in contrast to stream flow which increased for 3 years but with evidence of a decline after 5 years. The perched‐watertable piezometric surface indicated that its lateral drainage differs from that of surface flows; the perched‐watertable drainage fluxes from the study catchments seem minor and off‐site movement of solutes (e.g. nutrients and contaminants) via them would be limited. It was identified that the interaction between the perched and deep aquifers was poorly understood, as well as the relative importance of the soil moisture storage of the aquitard clay layer between them. It was concluded that there is a need to undertake more detailed analysis using modelling, and to obtain additional field data on soil‐layer properties and piezometric levels of the deep aquifer. Copyright © 2002 John Wiley & Sons, Ltd.     

Field data and flow system response in clay (vertisol) shale terrain,north central Texas,USA

The water budget in clay shale terrain is controlled by a complex interaction between the vertisol soil layer, the underlying fractured rock, land use, topography, and seasonal trends in rainfall and evapotranspiration. Rainfall, runoff, lateral flow, soil moisture, and groundwater levels were monitored over an annual recharge cycle. Four phases of soil–aquifer response were noted over the study period: (1) dry‐season cracking of soils; (2) runoff initiation, lateral flow and aquifer recharge; (3) crack closure and down‐slope movement of subsurface water, with surface seepage; (4) a drying phase. Surface flow predominated within the watershed (25% of rainfall), but lateral flow through the soil zone continued for most of the year and contributed 11% of stream flow through surface seepage. Actual flow through the fractured shale makes up a small fraction of the water budget but does appear to influence surface seepage by its effect on valley‐bottom storage. When the valley soil storage is full, lateral flow exits onto the valley‐bottom surface as seasonal seeps. Well response varied with depth and hillslope position. FLOWTUBE model results and regional recharge estimates are consistent with an aquifer recharge of 1·6% of annual precipitation calculated from well heights and specific yield of the shale aquifer. Copyright © 2005 John Wiley & Sons, Ltd.     

The application of electrical conductivity as a tracer for hydrograph separation in urban catchments

Two‐component hydrograph separation was performed on 19 low‐to‐moderate intensity rainfall events in a 4·1‐km² urban watershed to infer the relative and absolute contribution of surface runoff (e.g. new water) to stormflow generation between 2001 and 2003. The electrical conductivity (EC) of water was used as a continuous and inexpensive tracer, with order of magnitude differences in precipitation (12–46 µS/cm) and pre‐event streamwater EC values (520–1297 µS/cm). While new water accounted for most of the increased discharge during storms (61–117%), the contribution of new water to total discharge during events was typically lower (18–78%) and negatively correlated with antecedent stream discharge (r² = 0·55, p < 0·01). The amount of new water was positively correlated with total rainfall (r² = 0·77), but hydrograph separation results suggest that less than half (9–46%) of the total rainfall on impervious surfaces is rapidly routed to the stream channel as new water. Comparison of hydrograph separation results using non‐conservative tracers (EC and Si) and a conservative isotopic tracer (δD) for two events showed similar results and highlighted the potential application of EC as an inexpensive, high frequency tracer for hydrograph separation studies in urban catchments. The use of a simple tracer‐based approach may help hydrologists and watershed managers to better understand impervious surface runoff, stormflow generation and non‐point‐source pollutant loading to urban streams. Copyright © 2007 John Wiley & Sons, Ltd.