Origin of honeycombs and related weathering forms in Oligocene Macigno Sandstone,Tuscan coast near Livorno,Italy

Two types of cavernous‐weathering features are exposed in the Oligocene Macigno Sandstone along 5 km of the Tuscan coast south of Livorno, Italy. Honeycomb cells (type 1 features) are typical closely spaced, more or less circular pits of centimetre scale that have been eroded 2 to 6 cm below the general surface of bedding planes or joints. ‘Aberrant honeycomb’ cells (type 2 features) are highly elongate, polygonal, or irregular ?at depressions of decimetre scale surrounded by walls rarely higher than 2 cm, some of which pass into long, free‐standing walls or tendrils. Thus, not all type 2 ‘honeycomb’ cells are fully enclosed. We measured the geometry of 551 honeycomb cells and examined various rock properties (microscopic texture and fabric, mineralogy, porosity, permeability, and chemical composition) to isolate factors that control the size, shape, distribution, and pattern of the honeycombs. Our goal was to narrow potential origins of the features and to understand their formation. The ubiquitous occurrence of sea salt in the honeycombs and scanning electron microscope evidence of physical weathering of silicates, especially micas, favours an origin for the honeycombs chie?y by salt weathering. Honeycombs do not form in siltstone, iron‐oxide‐impregnated sandstone, calcite‐cemented concretions, or in case‐hardened joints. Thus, salt weathering of type 1 and 2 honeycombs is not effective in very low permeability rocks. We propose for type 1 honeycombs that seawater is drawn into micropores of the sandstone and evolves into self‐organized diffusion cells (Turing patterns). Selective evaporation at the stationary nodes of diffusion cells, which form at the same site over time, leads to the precipitation of salt, then grains spall off, and pits are formed. The deepest pits (>40 mm) formed where Turing patterns consistently formed at the same sites. Although the walls are more porous and weathered than the host sandstone, they become selectively case hardened by an unidenti?ed component of low abundance. Initial honeycomb cell shape and gravity locally in?uenced type 1 honeycomb shapes. We suggest that type 2 honeycombs develop where diffusion‐controlled Turing patterns lead to case‐hardening along linear trends; gravity and rock fabric are important locally in in?uencing the orientation of the walls. Only type 2 cells are forming today, suggesting recent environmental changes. Gravity is not a fundamental control on honeycomb shape; in places it is a contributing factor. Pre‐existing depressions (quarry tool marks) have strongly in?uenced honeycomb shape locally. Copyright © 2004 John Wiley & Sons, Ltd.     

Aeolian activity at a giant sandstone weathering pit in arid south‐central Utah

Aeolian abrasional, depositional and deflational features indicate exceptionally strong southwesterly winds in a giant sandstone weathering pit in Grand Staircase Escalante Monument, about 22 km southeast of Escalante, Utah. The 60 m wide, 5–20 m deep pit has developed near the summit of a broad, barren 160‐m‐high dome on the Lower Jurassic Navajo Sandstone. Unlike other giant weathering pits (10–30 m diameter) in the region, the bedrock floor of this pit is undulatory, and there is a cylindrical, 10‐m‐high rock pedestal in the centre of the pit. An active dune surrounds the central pedestal and at times has as much as 8 m of local relief. The dune shifts considerably over brief (<1 year) periods of time. Fine‐grained (<250 µm) dunal sand on the pit floor is periodically removed by deflation, leaving coarser sand (>250 µm) trapped in the pit. Dunal sand is typically derived from external sources (other than the pit walls and floor). Centimetre to metre‐scale abrasional features such as grooves, flutes and dedos occur on the bedrock walls and floor of the pit. These dedos and other streamlined aeolian sculpted host‐rock features occur in clusters and typically form in the lee of iron concretions. The dedos are similar to the controversial stalked blueberries on Mars. Above the western rim of the pit there is a 29‐m‐long, 5‐m‐wide aeolian groove with a fluted bedrock floor. A 1·2‐km‐long bedrock valley descends to the southwest from the pit and groove, amplifying southwesterly winds. Data from hand‐held anemometers suggest that southwesterly winds can be accelerated 200–300 per cent or more by local topography. Copyright © 2008 John Wiley and Sons, Ltd.     

Integrating structure-from-motion photogrammetry into rock weathering field methodologies

Despite recent rapid advances in the field of structure-from-motion (SfM) photogrammetry, the use of high-resolution data to investigate small-scale processes is a relatively underdeveloped field. In particular, rock weathering is rarely investigated using this suite of techniques. This research uses a combination of traditional non-destructive rock weathering measurement techniques (rock surface hardness) and SfM to map deterioration and loss of cohesion of the surface using three-dimensional data. The results are used to interpret weathering behaviour across two different lithologies present on the site, namely shale and limestone. This new approach is tested on seven sites in Longyearbyen, Svalbard, where active weathering of a rock surface was measured after 13 years of exposure to extreme temperature regimes and snow cover. The surface loss was quantified with SfM and combined with rock surface hardness measurement distributions extrapolated in geographic information system (GIS). The combined results are used here to quantify the difference in response of both lithologies to these extreme temperatures. This research demonstrates the potential for further integration of SfM in rock weathering research and other small-scale geomorphological investigations, in particular in difficult field conditions where portability of field equipment is paramount. © 2019 John Wiley & Sons, Ltd. © 2019 John Wiley & Sons, Ltd.     

Spatial characterization of salt accumulation in early stage limestone weathering using probe permeametry

This research characterizes the weathering of natural building stone using an unsteady‐state portable probe permeameter. Variations between the permeability properties of fresh rock and the same rocks after the early stages of a salt weathering simulation are used to examine the effects of salt accumulation on spatial variations in surface rock permeability properties in two limestones from Spain. The Fraga and Tudela limestones are from the Ebro basin and are of Miocene age. Both stone types figure largely in the architectural heritage of Spain and, in common with many other building limestones, they are prone to physical damage from salt crystallization in pore spaces. To examine feedbacks associated with salt accumulation during the early stages of this weathering process, samples of the two stone types were subjected to simulated salt weathering under laboratory conditions using magnesium sulphate and sodium chloride at concentrations of 5% and 15%. Permeability mapping and statistical analysis (aspatial statistics and spatial prediction) before and after salt accumulation are used to assess changes in the spatial variability of permeability and to correlate these changes with salt movement, porosity change, potential rock deterioration and textural characteristics. Statistical analyses of small‐scale permeability measurements are used to evaluate the drivers for decay and hence aid the prediction of the weathering behaviour of the two limestones. Copyright © 2010 John Wiley & Sons, Ltd.     

Biogenic origin of coastal honeycomb weathering

Honeycomb weathering occurs in two environments in Late Cretaceous and Eocene sandstone outcrops along the coastlines of south‐west Oregon and north‐west Washington, USA, and south‐west British Columbia, Canada. At these sites honeycomb weathering is found on subhorizontal rock surfaces in the intertidal zone, and on steep faces in the salt spray zone above the mean high tide level. In both environments, cavity development is initiated by salt weathering. In the intertidal zone, cavity shapes and sizes are primarily controlled by wetting/drying cycles, and the rate of development greatly diminishes when cavities reach a critical size where the amount of seawater left by receding tides is so great that evaporation no longer produces saturated solutions. Encrustations of algae or barnacles may also inhibit cavity enlargement. In the supratidal spray zone, honeycomb weathering results from a dynamic balance between the corrosive action of salt and the protective effects of endolithic microbes. Subtle environmental shifts may cause honeycomb cavity patterns to continue to develop, to become stable, or to coalesce to produce a barren surface. Cavity patterns produced by complex interactions between inorganic processes and biologic activity provide a geological model of ‘self‐organization’. Surface hardening is not a factor in honeycomb formation at these study sites. Salt weathering in coastal environments is an intermittently active process that requires particular wind and tidal conditions to provide a supply of salt water, and temperature and humidity conditions that cause evaporation. Under these conditions, salt residues may be detectable in honeycomb‐weathered rock, but absent at other times. Honeycomb weathering can form in only a few decades, but erosion rates are retarded in areas of the rock that contain cavity patterns relative to adjacent non‐honeycombed surfaces. Copyright © 2010 John Wiley & Sons, Ltd.     

Coeval biochemical and biophysical weathering processes on Quaternary sandstone terraces south of Rabat (Temara), northwest Morocco

Despite numerous investigations on substrate‐inhabiting microflora, especially lichens, very little is known about the colonization of coastal escarpments by lithobiontic micro‐organisms, inland of a retreating coastline in Africa. Reported herein are the results of a combined field observation and microscopy study focusing on the connection between microrelief of the substrate, colonies of lithobiontic micro‐organisms (in particular the lichen Xanthoria parietina) and microstructures of putative bacterial origin. The occurrence of weathering pits in which the early stages of the biotic development occurs, and the subsequent disintegration of the rock indicate that lichens, mosses and fungi act synergistically by alternating chemical and mechanical weathering. Penetration of grains by expansion and contraction of the hyphae depletes the rock matrix and contributes to the mechanical breakdown of the rock. Calcite rhombs on the weathered surfaces of the calcite‐cemented sandstones are severely etched with well‐developed rhomb‐shaped etch pits (‘spiky calcite’), holes, or has one or more of the faces removed, and their cores exposed and leached. Nanofilaments (c. 100–700 nm) and ‘nanomicrobial’ fruiting bodies (c. 250 nm) emanating from micropores appear to be common on affected crystalline structures. Weddellite present immediately below the thallus is a strong indicator of biomineralization. Quartz responds differently to chemical weathering by producing peeling structures and microbrecciation features. The dissolution of these crystals appears to be a surface reaction‐controlled process mediated by microbial microfilaments and nanofilaments. A model is proposed, firstly indicating early‐stage biochemical weathering, followed by biophysical weathering. Disintegration of the rock outcrops in due to a complex interplay of several events, probably beginning at the nanoscale with penetration of sites on crystal faces. Copyright © 2006 John Wiley & Sons, Ltd.     

Numerical modelling of combined erosion and weathering of slopes in weak rock

Due to various decay processes associated with weathering, the stability of artificial slopes in weak rocks may be affected well within their envisaged engineering lifetime. Conceptually, the decay following the initial stress release after excavation can be described as a process seeking equilibrium between weathering and erosion. The extent to which such an equilibrium is actually reached influences the outcome of the weathering‐erosion decay process as well as the effects that the decay has on the geotechnical properties of the exposed rock mass, and thus ultimately the stability of slopes affected by erosion and weathering. This paper combines two conceptual models for erosion and weathering, and derives a numerical model which predicts the resulting slope development. This can help to predict the development of a slope profile excavated in a weak rock in time, and can be extended with the addition of strength parameters to the weathering profile to enable prediction of slope stability as a function of time. Copyright © 2011 John Wiley & Sons, Ltd.     

A new technique for non‐destructive field measurement of rock‐surface strength: an application of the Equotip hardness tester to weathering studies

Tafone‐like depressions have developed on the Aoshima sandstone blocks used for a masonry bridge pier in the coastal spray zone. A thin layer of partial granular disintegration was found on the surface in depressions. To evaluate quantitatively the strength of the thin weathered layer, the hardness was measured at the surface of the sandstone blocks using both an Equotip hardness tester and an L‐type Schmidt hammer. Comparison of the two testing results indicates that the Equotip hardness value is more sensitive in evaluating the strength of a thin layer of weathered surface rock than the Schmidt hardness value. By applying two methods, i.e. both the repeated impact method and the single impact method, the Equotip tester can evaluate the strengths of fresh internal and weathered surficial portions of rocks having a thin weathering layer. Comparison of the two strengths enables evaluation of strength reduction due to weathering. Copyright © 2007 John Wiley & Sons, Ltd.     

A low‐dimensional model of bedrock weathering and lateral flow coevolution in hillslopes: 2. Controls on weathering and permeability profiles,drainage hydraulics,and solute export pathways

The advance of a chemical weathering front into the bedrock of a hillslope is often limited by the rate weathering products that can be carried away, maintaining chemical disequilibrium. If the weathering front is within the saturated zone, groundwater flow downslope may affect the rate of transport and weathering—however, weathering also modifies the rock permeability and the subsurface potential gradient that drives lateral groundwater flow. This feedback may help explain why there tends to be neither “runaway weathering” to great depth nor exposed bedrock covering much of the earth and may provide a mechanism for weathering front advance to keep pace with incision of adjacent streams into bedrock. This is the second of a two‐part paper exploring the coevolution of bedrock weathering and lateral flow in hillslopes using a simple low‐dimensional model based on hydraulic groundwater theory. Here, we show how a simplified kinetic model of 1‐D rock weathering can be extended to consider lateral flow in a 2‐D hillslope. Exact and approximate analytical solutions for the location and thickness of weathering within the hillslope are obtained for a number of cases. A location for the weathering front can be found such that lateral flow is able to export weathering products at the rate required to keep pace with stream incision at steady state. Three pathways of solute export are identified: “diffusing up,” where solutes diffuse up and away from the weathering front into the laterally flowing aquifer; “draining down,” where solutes are advected primarily downward into the unweathered bedrock; and “draining along,” where solutes travel laterally within the weathering zone. For each pathway, a different subsurface topography and overall relief of unweathered bedrock within the hillslope is needed to remove solutes at steady state. The relief each pathway requires depends on the rate of stream incision raised to a different power, such that at a given incision rate, one pathway requires minimal relief and, therefore, likely determines the steady‐state hillslope profile.     

Weathering of coastal defensive structures in southwest England: a 500 year stone durability trial

Historic structures can be viewed as exposure trials of the stone of which they are constructed. As such, they represent a geomorphological weathering experiment. Several structures of Henrician (sixteenth century) and greater age on the coast of southwest England have been exposed to coastal salt weathering for 500–600 years. Long‐term weathering rates on five different rock groups are derived from careful study of weathering depths and forms. There is significant variation in weathering rate between five major rock groups. Rank ordering of weathering rate values reveals a durability order of these rock groups, which is confirmed by local juxtapositions. Controls on rock durability in the coastal weathering environment include both mechanical and mineralogical characteristics. Specific density, and combined quartz and muscovite content, are positively related to durability; high feldspar and chlorite content are associated with low durability. Copyright © 2000 John Wiley & Sons, Ltd.     

Colonization and weathering of engineering materials by marine microorganisms: an SEM study

Microorganisms are a ubiquitous feature of most hard substrata on Earth and their role in the geomorphological alteration of rock and stone is widely recognized. The role of microorganisms in the modification of engineering materials introduced into the intertidal zone through the construction of hard coastal defences is less well understood. Here we use scanning electron microscopy (SEM) to examine microbial colonization and micro‐scale geomorphological features on experimental blocks of limestone, granite and marine concrete after eight months' exposure in the intertidal zone in Cornwall, UK. Significant differences in the occurrence of microbial growth features, and micro‐scale weathering and erosion features were observed between material types (ANOVA p < 0·000). Exposed limestone blocks were characterized by euendolithic borehole erosion (99% occurrence) within the upper 34·0 ± 12·3 µm of the surface. Beneath the zone of boring, inorganic weathering (chemical dissolution and salt action) had occurred to a depth of 125·0 ± 39·0 µm. Boring at the surface of concrete was less common (27% occurrence), while bio‐chemical crusting was abundant (94% occurrence, mean thickness 45·1 ± 27·7 µm). Crusts consisted of biological cells, salts and other chemical precipitates. Evidence of cryptoendolithic growth was also observed in limestone and concrete, beneath the upper zone of weathering. On granite, biological activity was restricted to thin epilithic films (<10 µm thickness) with some limited evidence of mechanical breakdown. Results presented here demonstrate the influence of substratum lithology, hardness and texture on the nature of early micro‐scale colonization, and the susceptibility of different engineering materials to organic weathering and erosion processes in the intertidal zone. The implications of differences in initial biogeomorphic responses of materials for long‐term rock weathering, ecology and engineering durability are discussed. Copyright © 2010 John Wiley & Sons, Ltd.     

Field evidence for the influence of weathering on rock erodibility and channel form in bedrock rivers

Erosion processes in bedrock‐floored rivers shape channel cross‐sectional geometry and the broader landscape. However, the influence of weathering on channel slope and geometry is not well understood. Weathering can produce variation in rock erodibility within channel cross‐sections. Recent numerical modeling results suggest that weathering may preferentially weaken rock on channel banks relative to the thalweg, strongly influencing channel form. Here, we present the first quantitative field study of differential weathering across channel cross‐sections. We hypothesize that average cross‐section erosion rate controls the magnitude of this contrast in weathering between the banks and the thalweg. Erosion rate, in turn, is moderated by the extent to which weathering processes increase bedrock erodibility. We test these hypotheses on tributaries to the Potomac River, Virginia, with inferred erosion rates from ~0.1 m/kyr to >0.8 m/kyr, with higher rates in knickpoints spawned by the migratory Great Falls knickzone. We selected nine channel cross‐sections on three tributaries spanning the full range of erosion rates, and at multiple flow heights we measured (1) rock compressive strength using a Schmidt hammer, (2) rock surface roughness using a contour gage combined with automated photograph analysis, and (3) crack density (crack length/area) at three cross‐sections on one channel. All cross‐sections showed significant (p < 0.01 for strength, p < 0.05 for roughness) increases in weathering by at least one metric with height above the thalweg. These results, assuming that the weathered state of rock is a proxy for erodibility, indicate that rock erodibility varies inversely with bedrock inundation frequency. Differences in weathering between the thalweg and the channel margins tend to decrease as inferred erosion rates increase, leading to variations in channel form related to the interplay of weathering and erosion rate. This observation is consistent with numerical modeling that predicts a strong influence of weathering‐related erodibility on channel morphology. Copyright © 2017 John Wiley & Sons, Ltd.     

Rates and patterns of bedrock denudation by coastal salt spray weathering: A seven-year record

Rapid surface lowering of bedrock is taking place in the supratidal zone by salt spray weathering. A seven-year run of data demonstrates a mean rate of lowering of 0·625 mm a^?1. Considerable variation exists in annual point lowering values within measurement sites, although between-site variation is not significant. Aggregate year to year variations in surface lowering are not significant. Spatial variation in individual point values may be compensated by temporal variation over an 11-year period. There is a marked summer maximum in surface lowering rate, and this is strongly correlated with monthly air temperature. Spatially and temporally episodic swelling of the rock surface is demonstrated. This does not correlate statistically with any available climatic variable and is deemed to be a real and largely stochastic phenomenon. It is interpreted as rock bursting at the granular scale due to haloclasty. The processes most likely to be responsible for the observed rapid denudation are crystallization and thermal expansion of halite, both of which are enhanced by high summer temperatures.     

Electrical imaging of lateritic weathering mantles over granitic and metamorphic basement of eastern Senegal, West Africa

The electrical properties of several tens of metres of lateritic weathering mantle were investigated by using electrical resistivity tomography (ERT) in two basement areas of eastern Senegal. The field survey was conducted along two profiles providing continuous coverage. Colour-modulated pseudosections of apparent resistivity vs. pseudo-depth were plotted for all survey lines, giving an approximate image of the subsurface structure. In the area underlain by granitic basement, the pseudosection suggests a very inhomogeneous weathered layer in which the apparent resistivity changes more rapidly than thickness. In the second area, underlain by schists, the lateral changes in electrical properties are less pronounced than those of the granitic area. Interpretation of 2D Wenner resistivity data yielded considerable detail about the regolith, even without pit information. In both areas, the near-surface topsoil comprising undersaturated lateritic material is highly resistive. The intermediate layer with low resistivities (e.g., 20–100 Ωm) contains clays including small quantities of water. The third, highly resistive layer reflects the granitic basement. Comparison of ERT survey results with pit information shows general agreement and suggests that ERT can be used as a fast and efficient exploration tool to map the thick lateritic weathering mantle in tropical basement areas with hard rock geology.     

Incipient weathering rind development on introduced machine‐polished granite discs in an Arctic alpine environment,northern Scandinavia

Weathering rinds, zones of alteration on the exterior surfaces of rock outcrops and coarse unconsolidated surficial debris are widely used by geomorphologists and Quaternary geologists as indicators of the relative age of landforms and landscapes. Additionally they provide unique insights into the earliest stages of rock and mineral weathering, yet the origin of these alteration zones is relatively poorly understood. This lack of understanding applies especially to the initial stages of rind formation. The study reported in this paper has two principal objectives. The first is to use lightly polished granite discs inserted in soil profiles under several different plant communities in an Arctic alpine environment for a period of four or five years to investigate the nature of incipient weathering rind development. The second is to investigate the factors responsible for spatial variability in the nature and rates of rind formation. Incipient weathering rind development on the outer edges of the granite discs is observable and measurable over a period of time as short as four years in the mild Arctic alpine environment of Swedish Lapland. The earliest stages of rind development involve the development of a porous structure consisting of a combination of pits and fractures which have been solutionally enlarged and modified. Solution appears to be preferentially concentrated on the surfaces of feldspars and, to a lesser extent, quartz. In addition, iron oxides are present along grain boundaries and in grain interiors and are interpreted to have been derived from the oxidation of ferromagnesian minerals. Spatial variability in weathering rind development appears to be particularly driven by differences in moisture but is not related to soil pH. Copyright © 2005 John Wiley & Sons, Ltd.     

Exploring geochemical controls on weathering and erosion of convex hillslopes: beyond the empirical regolith production function

Landscape curvature evolves in response to physical, chemical, and biological influences that cannot yet be quantified in models. Nonetheless, the simplest models predict the existence of equilibrium hillslope profiles. Here, we develop a model describing steady‐state regolith production caused by mineral dissolution on hillslopes which have attained an equilibrium parabolic profile. When the hillslope lowers at a constant rate, the rate of chemical weathering is highest at the ridgetop where curvature is highest and the ridge develops the thickest regolith. This result derives from inclusion of all the terms in the mathematical definition of curvature. Including these terms shows that the curvature of a parabolic hillslope profile varies with distance from the ridge. The hillslope model (meter‐scale) is similar to models of weathering rind formation (centimeter‐scale) where curvature‐driven solute transport causes development of the thickest rinds at highly curved clast corners. At the clast scale, models fit observations. Here, we similarly explore model predictions of the effect of curvature at the hillslope scale. The hillslope model shows that when erosion rates are small and vertical porefluid infiltration is moderate, the hill weathers at both ridge and valley in the erosive transport‐limited regime. For this regime, the reacting mineral is weathered away before it reaches the land surface: in other words, the model predicts completely developed element‐depth profiles at both ridge and valley. In contrast, when the erosion rate increases or porefluid velocity decreases, denudation occurs in the weathering‐limited regime. In this regime, the reacting mineral does not weather away before it reaches the land surface and simulations predict incompletely developed profiles at both ridge and valley. These predictions are broadly consistent with observations of completely developed element‐depth profiles along hillslopes denuding under erosive transport‐limitation but incompletely developed profiles along hillslopes denuding under weathering limitation in some field settings. Copyright © 2013 John Wiley & Sons, Ltd.     

Evidence for freeze–thaw events and their implications for rock weathering in northern Canada

Discussions regarding weathering in cold environments generally centre on mechanical processes and on the freeze–thaw mechanism in particular. Despite the almost ubiquitous assumption of freeze–thaw weathering, unequivocal proof of interstitial rock water actually freezing and thawing is singularly lacking. Equally, many studies have used the crossing of 0 °C, or values close to that, as the basis for determining the number of ‘freeze–thaw events’. In order to assess the weathering regime at a site in northern Canada, temperatures were collected at the surface, 1 cm and 3 cm depth for sets of paving bricks, with exposures both vertical and at 45°, orientated to the four cardinal directions. Temperature data were collected at 1 min intervals for 1 year. These data provide unequivocal proof for the occurrence of the freezing and thawing of water on and within the rock (freeze–thaw events). The freeze event is evidenced by the exotherm associated with the release of latent heat as the water actually freezes. This is thought to be the ?rst record of such events from a ?eld situation. More signi?cantly, it was found that the temperature at which freezing occurred varied signi?cantly through the year and that on occasion the 1 cm depth froze prior to the rock surface. The change in freeze temperature is thought to be due to the chemical weathering of the material (coupled with on‐going salt inputs via the melting of snowfall), which, it is shown, could occur throughout the winter despite air temperatures down to ?30 °C. This ?nding regarding chemical weathering is also considered to be highly signi?cant. A number of thermal stress events were also recorded, suggesting that rock weathering in cold regions is a synergistic combination of various chemical and mechanical weathering mechanisms. Copyright © 2003 John Wiley & Sons, Ltd.     

Spheroidal weathering of granite porphyry with well‐developed columnar joints by oxidation,iron precipitation,and rindlet exfoliation

Spheroidal weathering, one of the important rock weathering styles, has been attributed to chemical weathering by the water from joint surfaces, and mechanical aspects of the weathering have not been well addressed. We made an investigation on spheroidal weathering of Miocene granite porphyry with well‐developed columnar joints and found that this spheroidal weathering proceeds through chemical processes and accompanying mechanical processes. The investigation of the textures, physical properties, mineralogy, and chemistry of the porphyry revealed the presence of a brown band on the surface margins of corestones, representing the oxidation of pyrite and chlorite, and the precipitation of iron hydroxides, and the consequent generation of micro‐cracks within the band. During weathering, oxidation progresses inwards from joints that surround the rindlets, including both high‐angle columnar and low‐angle planar joints, and causes rounding of the unweathered interior portion of the rock. Microscopic observations of the brown band embedded with fluorescent resin show that pores are first filled with iron hydroxides, and that micro‐cracks then form parallel to the oxidation front in the outer portion of the brown band. Iron hydroxide precipitation increases the P‐wave velocity in the brown band, while micro‐crack formation decreases the tensile strength of the rock. Where the brown band has thickened to ~6 cm, the micro‐cracks are connected to one another to create continuous cracks, which separate the rindlets from the corestone. Micro‐crack formation parallel to the corestone surface may be attributed to compressive stresses generated by small amounts of volumetric expansion due to the precipitation of iron hydroxides in the brown band. Earth surface is under oxidizing environments so that precipitation of iron hydroxides commonly occurs; the spheroidal weathering in this paper is a typical example of the combination of chemical and mechanical processes under such environments. Copyright © 2016 John Wiley & Sons, Ltd.     

Climate driven coevolution of weathering profiles and hillslope topography generates dramatic differences in critical zone architecture

Considerable debate revolves around the relative importance of rock type, tectonics, and climate in creating the architecture of the critical zone. We demonstrate the importance of climate and in particular the rate of water recharge to the subsurface, using numerical models that incorporate hydrologic flowpaths, chemical weathering, and geomorphic rules for soil production and transport. We track alterations in both solid phase (plagioclase to clay) and water chemistry along hydrologic flowpaths that include lateral flow beneath the water table. To isolate the role of recharge, we simulate dry and wet cases and prescribe identical landscape evolution rules. The weathering patterns that develop differ dramatically beneath the resulting parabolic interfluves. In the dry case, incomplete weathering is shallow and surface parallel, whereas in the wet case, intense weathering occurs to depths approximating the base of the bounding channels, well below the water table. Exploration of intermediate cases reveals that the weathering state of the subsurface is strongly governed by the ratio of the rate of advance of the weathering front itself controlled by the water input rate, and the rate of erosion of the landscape. The system transitions between these end‐member behaviours rather abruptly at a weathering front speed ‐ erosion rate ratio of approximately 1. Although there are undoubtedly direct roles for tectonics and rock type in critical zone architecture, and yet more likely feedbacks between these and climate, we show here that differences in hillslope‐scale weathering patterns can be strongly controlled by climate.     

A preliminary scanning electron microscope study of honeycomb weathering of sandstone in a coastal environment

Honeycomb weathering has been observed in a Carboniferous sandstone at a coastal location near Ballycastle on the north coast of Northern Ireland. Specimens of this sandstone have been analysed by X-ray diffraction, scanning electron microscopy, and energy dispersive spectrometry. Results reveal that calcium sulphate (gypsum) is the only salt present and is found only at and immediately below the rock surface. SEM observations suggest that crystallization of salts in pores could easily dislodge quartz grains to promote granular disintegration, whilst etching of quartz grain surfaces attests to chemical weathering activity within the rock However, the reason for the development of the honeycomb pattern is not known.