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1.
西南峡谷型水库的季节性分层与水质的突发性恶化   总被引:40,自引:3,他引:37  
选择西南云贵高原乌江流域的百花湖水库进行了气象、水温度和水化学(DO、FeⅡ和MnⅡ)的连续监测(13个月).结果表明,由于气候等原因,百花湖水库的水体在夏季形成分层,但是没有典型分层湖泊的温跃层变化,这种水体温度结构可以在4-10月保持稳定;这种"不显著的"温度分层结构,有效限制了上下水团的混合,形成显著的水体溶解氧分层,氧化/还原界面可达到水深8m左右.20世纪90年代初以来,贵州多座水库频繁出现的季节性水质恶化现象,与水库水体混合期(多为夏末初秋),水体分层结构失稳有关.上下层水体的垂直交替,使下层水体中的还原性物质带入上层湖水,造成表层水体缺氧和表观浑浊,鱼类窒息死亡.在百花湖水库的研究表明,西南地区深水水库,可以在夏季出现一定的水体温度分层结构,并导致显著的水体水化学(如溶解氧)分层,进而影响水库水环境质量.  相似文献   

2.
热分层对水库水质的季节性影响——以西安黑河水库为例   总被引:3,自引:1,他引:2  
卢金锁  李志龙 《湖泊科学》2014,26(5):698-706
深水水库作为城市的重要供水水源,通常由于热量在垂向水体上的不均匀分配形成热分层.热分层会阻碍垂向上水体交换引发水质分层现象,在冬季水库发生“翻库”之后,水体混合导致水库的整体水质下降.结合热分层指数可以客观、直接地表达水库热分层的稳定程度.综合水库的气温、水体更新率和水质参数(溶解氧、pH、总磷、氨氮)的年度变化,对陕西黑河水库2008-2010年的热分层状况进行研究.研究表明:水库的热分层形成会直接恶化底部水质尤其会加速底部水体中溶解氧的消耗;热分层的年度变化主要受气温控制,但在特定时期较大的水体更新率可以在一定程度上弱化水体热分层,减缓底部水质恶化.该结果可使水库管理者在水库分层最稳定、水质恶化最严重时期以人工调节水体更新率的方式弱化热分层,为保证水质安全提供参考.  相似文献   

3.
Abstract

The aim of this study was to understand seasonal variations in the vertical structure of the water column, and to quantify the importance of the physical forces (solar radiation, wind and hydraulic retention time) that control mixing processes in a reservoir bordering the Pantanal floodplain. Samples were taken every three months in the reservoir centre, at four depths, for the measurement of nine physical and chemical water quality parameters. The reservoir presented a long stratification period with complete mixing in winter. The vertical structure showed that, during the stratification period, the upper layers of the reservoir are homogeneous and the physical and chemical composition only changes at greater depths. The wind acting over an extended period is the only factor that significantly influences the vertical structure in the reservoir, giving rise to mixing processes. Moreover, the position of the draw-off point in the upper layer of the reservoir, together with the reservoir depth, enhances vertical stability.  相似文献   

4.
大型深水水库溶解氧层化结构演化机制   总被引:2,自引:0,他引:2  
余晓  诸葛亦斯  刘晓波  杜强  谭宏 《湖泊科学》2020,32(5):1496-1507
深水水库溶解氧(DO)的演化成因目前尚不完全清楚,研究其演变机制对制定水库水质保护和管理策略十分重要.本文以我国京津冀地区重要的大型深水水源水库潘家口水库为例,系统分析了水库水温和DO浓度的时空分布特征、演化成因,以及水库的水质响应情况.结果表明:4月中旬-11月底该水库存在显著的季节性热分层,水库热分层为DO层化结构的形成提供了垂向分异性物理环境;与热分层类似,DO层化表现为3层结构,本文从上至下将其分别定义为混合层、氧跃层和氧亏层.垂向各层不同生化过程的作用为DO浓度空间差异性演变提供了驱动力,其中混合层受浮游藻类过量生长的影响,DO往往处于过饱和状态;氧跃层受大量生物的呼吸及有机物分解等耗氧的影响,DO浓度急剧下降,7-8月一般处于缺氧状态(DO2 mg/L);氧亏层受重污染沉积物耗氧的影响,DO浓度持续下降,热分层末期水库底部可能出现缺氧.热分层末期DO浓度降低的同时,沉积物中会发生Mn的还原、Mn-P解吸释放等现象,但沉积物中含量较高的Fe没有发生还原以及Fe-P的解吸释放现象.潘家口水库目前正在逼近缺氧、内源污染大量释放的临界点,其水环境治理应予以高度重视.  相似文献   

5.
ABSTRACT

Water temperature dynamics in a reservoir are affected by its bathymetry, climatic conditions and hydrological processes. Miyun Reservoir in China is a large and deep reservoir that experienced a large water level decline in 1999–2004 due to low rainfall and relatively high water supply to Beijing. To study changes of stratification characteristics in Miyun Reservoir from 1998 to 2011, the one-dimensional year-round lake model MINLAKE2010 was modified by adding a new selective withdraw module and a reservoir hydrological model. Simulation results under three scenarios demonstrated that the new MINLAKE2012 model accurately predicted daily water levels and temperature dynamics during the water level fluctuation period. The water level decline led to 7.6 and 3.8°C increases in the maximum and mean bottom temperatures and about 29 days reduction in the stratification days. These simulation results provide an insight into the thermal evolution of Miyun Reservoir during the planned future water filling process.
Editor D. Koutsoyiannis Associate editor M. Acreman  相似文献   

6.
湖库热分层消亡引起的突发性水质恶化现象引起了广泛的关注,我国南方水库大多是暖单次混合型湖泊,每年混合一次,导致水库水质周期性下降,但目前对南方水库热分层消亡过程的高频监测研究较少。为探究我国南方水库热分层消亡期水体混合过程的时空变化规律及驱动因素,以广西南宁天雹水库为例,于冬季热分层消亡期(2019年11月—2020年2月)对水库多点位水体理化指标开展原位监测,并利用自建气象站获取气象水文数据。结果表明:(1)水库热分层消亡期间,过渡区水深较浅可在短期内达到完全混合状态且缺氧区同步消失;而湖泊区混合过程整体滞后于过渡区,混合层深度由6.85 m增加至13.65 m,缺氧区逐渐减小,缺氧指数(AI)由0.40减小至0.07,直至水体完全混合后缺氧区消失;水库过渡区较湖泊区提前约40 d达到完全混合状态。(2)气象因子是引起热分层结构变化的主要因素,气温(T)、辐射(R)与混合层深度(MLD)呈现显著负相关(RT=0.927、RR=0.925,P<0.01),风速(WS)与MLD呈现显著正相关(RWS=0.728,P&...  相似文献   

7.
This study focuses on a 10-m2 plot within a granitic hillslope in Cevennes mountainous area in France, in order to study infiltration and subsurface hydrological processes during heavy rainfalls and flash floods. The monitoring device included water content at several depths (0–70 cm for the shallow soil water; 0–10 m for the deep water) during both intense artificial and natural rainfall events, chemical and physical tracers, time-lapse electrical resistivity tomography. During the most intense events, the infiltrated water was estimated to be some hundreds of millimetres, which largely exceeds the topsoil capacity (≤40 cm deep in most of the cases). The weathered/fractured rock area below the soil clearly has an active role in the water storage and sub-surface flow dynamics. Vertical flow was dominant in the first 0–10 m, and lateral flow was effective at 8–10 m depth, at the top of the saturated area. The speed of the vertical flow was estimated between 1 and 10 m/hr, whereas it was estimated between 0.1 and 1 m/hr for the lateral flow. The interpretation of the experiments might lead to a local pattern of the 2D-hydrological processes and profile properties, which could be generic for most of the mountainous catchments under Mediterranean climate. It suggests that fast triggering of floods at the catchment scale cannot be explained by a mass transfer within the hillslope, but should be due to a pressure wave propagation through the bedrock fractures, which allows exfiltration of the water downstream the hillslope.  相似文献   

8.
ABSTRACT

Rainfall events largely control hydrological processes occurring on and in the ground, but the performance of climate models in reproducing rainfall events has not been investigated enough to guide selection among the models when making hydrological projections. We proposed to compare the durations, intensities, and pause periods, as well as depths of rainfall events when assessing the accuracy of general circulation models (GCMs) in reproducing the hydrological characteristics of observed rainfall. We also compared the sizes of design storm events and the frequency and severity of drought to demonstrate the consequences of GCM selection. The results show that rainfall and extreme hydrological event projections could significantly vary depending on climate model selection and weather stations, suggesting the need for a careful and comprehensive evaluation of GCM in the hydrological analysis of climate change. The proposed methods are expected to help to improve the accuracy of future hydrological projections for water resources planning.  相似文献   

9.
Overlying bottom water samples were collected in the Vistula River plume, southern Baltic Sea, (Poland) and analysed for dissolved and labile particulate (1 M HCl extractable) Cu, Pb, Zn, Mn, Fe and Ni, hydrological parameters being measured simultaneously. Particulate organic matter (POM), chlorophyll a and dissolved oxygen are key factors governing the chemical behaviour of the measured metal fractions. For the dissolved Cu, Pb, Zn, Fe and Ni two maxima, in the shallow and in the deeper part of the river plume, were found. In the shallow zone desorption from seaward fluxing metal-rich riverine particles account for markedly increased metal concentrations, as confirmed also by high particulate metal contents. For Pb, atmospheric inputs were also considered to have contributed to the elevated concentrations of dissolved Pb adjacent to the river mouth. In the deep zone desorption from detrital and/or resuspended particles by aerobic decomposition of organic material may be the main mechanism responsible for enrichment of particle-reactive metals (Cu, Pb, Zn) in the overyling bottom waters. The increased concentrations of dissolved Fe may have been due to reductive dissolution of Fe oxyhydroxides within the deep sediments by which dissolved Ni was released to the water. The distribution of Mn was related to dissolved oxygen concentrations, indicating that Mn is released to the water column under oxygen reduced conditions. However, Mn transfer to the dissolved phase from anoxic sediments in deeper part of the Vistula plume was hardly evidenced suggesting that benthic flux of Mn occurs under more severe reductive regime than is consistent with mobilization of Fe. Behaviour of Mn in a shallower part has been presumably affected by release from porewaters and by oxidization into less soluble species resulting in seasonal removal of this metal (e.g. in April) from the dissolved phase. The particulate fractions represented from about 6% (Ni) and 33% (Mn, Zn, Cu) to 80% (Fe) and 89% (Pb) of the total (labile particulate plus dissolved) concentrations. The affinity of the metals for particulate matter decreased in the following order: Pb > Fe > Zn > or = > Cu > Mn > Ni. Significant relationships between particulate Pb-Zn-Cu reflected the affinity of these metals for organic matter, and the significant relationship between Ni-Fe reflected the adsorption of Ni onto Fe-Mn oxyhydroxides. A comparison of metal concentrations with data from other similar areas revealed that the river plume is somewhat contaminated with Cu, Pb and Zn which is in agreement with previous findings on anthropogenic origin of these metals in the Polish zone of southern Baltic Sea.  相似文献   

10.
11.
Water content and movement in soil profile and hydrogen isotope composition (δD) of soil water, rainwater, and groundwater were examined in a subalpine dark coniferous forest in the Wolong National Nature Reserve in Sichuan, China, following rainfall events in 2003–2004. Light rainfall increased water content in the litter and at soil depth of 0–80 cm, but the increased soil water was lost in several days. Heavy rainfall increased soil water content up to 85% at depths of 0–40 cm. Following the light rainfall in early spring, the δD of water from the litter, humus, illuvial, and material layers decreased first and then gradually reached the pre‐rainfall level. In summer, light rainfall reached the litter humus, and illuvial layer, but did not hit the material layer. Heavy rainfall affected δD of water in all layers. The δD of soil interflow slightly fluctuated with rainfall events. The δD of shallow groundwater did not differ significantly among all rainfall events. Light rainfall altered the shape of δD profile curve of water in the upper layer of soil, whereas heavy rainfall greatly affected the shape of δD profile curve of water in all soil layers. Following the heavy rainfall, preferential flow initially occurred through macropores, decayed plant roots, and rocks at different depths of soil profile. With continuing rainfall, the litter and surface soil were nearly saturated or fully saturated, and infiltration became homogeneous and plug‐like. Forest soil water, particularly in deeper soil profile, was slightly affected by rainfall and, thus, can be a source of water supply for regional needs, particularly during dry seasons. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

12.
Experiments were carried out on an intermittent estuary during its closed (summer) and open (winter) states to identify the physical processes responsible for vertical mixing across the halocline, and to quantify vertical fluxes of oxygen and salt between water layers. During the blocked phase a two-layer structure was observed, with a brackish surface layer overlying old seawater. Within a deep basin the wind-driven turbulent mixing was consistent with the measured surface-layer turbulent dissipation, but the dissipation in the bottom layer appeared to be driven by internal seiching. In the shallow regions of the estuary vertical fluxes of dissolved oxygen were indicative of oxygen demand by respiration and remineralization of organic material in bottom water and sediments. During the estuary's open phase a three-layer structure was observed, having a fresh, river-derived surface layer, a middle layer of new seawater, and a bottom layer of old seawater. In the shallower regions surface-layer turbulent diffusion was consistent with the strong, gusty winds experienced at the time. The dissolved oxygen of the incoming seawater decreased to very low values by the time it reached the upstream deep basin as a result of the low cross-pycnocline oxygen flux being unable to compensate for the oxygen utilization. At least 50 % of the cross-pycnocline salt fluxes in the shallow reaches of the open estuary are suggested to be driven by Holmboe instabilities. Responsible Editor: Hans Burchard  相似文献   

13.
The Arctic has experienced substantial warming during the past century with models projecting continued warming accompanied by increases in summer precipitation for most regions. A key impact of increasing air surface temperatures is the deepening of the active layer, which is expected to alter hydrological processes and pathways. The aim of this study was to determine how one of the warmest and wettest summers in the past decade at a High Arctic watershed impacted water infiltration and storage in deeply thawed soil and solute concentrations in stream runoff during the thaw period. In June and July 2012 at the Cape Bounty Watershed Observatory, we combined active layer measurements with major ion concentrations and stable isotopes in surface waters to characterize the movement of different runoff sources: snowmelt, rainfall, and soil water. Results indicate that deep ground thaw enhanced the storage of infiltrated water following rainfall. Soil water from infiltrated rainfall flowed through the thawed transient layer and upper permafrost, which likely solubilized ions previously stored at depth. Subsequent rainfall events acted as a hydrological flushing mechanism, mobilizing solutes from the subsurface to the surface. This solute flushing substantially increased ion concentrations in stream runoff throughout mid to late July. Results further suggest the importance of rainfall and soil water as sources of runoff in a High Arctic catchment during mid to late summer as infiltrated snowmelt is drained from soil following baseflow. Although there was some evaporation of surface water, our study indicates that flushing from solute stores in the transient layer was the primary driver of increased ion concentrations in stream runoff and not evaporative concentration of surface water. With warmer and wetter summers projected for the Arctic, ion concentrations in runoff (especially in the late thaw season), will likely increase due to the deep storage and subsurface flow of infiltrated water and subsequent flushing of previously frozen solutes to the surface.  相似文献   

14.
Catchment hydrological responses to precipitation inputs, particularly during exceptionally large storms, are complex and variable, and our understanding of the associated runoff generation processes during those events is limited. Hydrological monitoring of climatically and hydrologically distinct catchments can help to improve this understanding by shedding light on the interplay between antecedent soil moisture conditions, hydrological connectivity, and rainfall event characteristics. This knowledge is urgently needed considering that both the frequency and magnitude of extreme precipitation events are increasing worldwide as a consequence of climate change. In autumn 2018, we installed water level sensors to monitor stream water and near-stream groundwater levels at two Mediterranean forest headwater catchments with contrasting hydrological regimes: Font del Regàs (sub-humid climate, perennial flow regime) and Fuirosos (semi-arid climate, intermittent flow regime). Both catchments are located in northeastern Spain, where the extratropical cyclone Gloria hit in January 2020 and left in ca. 65 h outstanding accumulated rainfalls of 424 mm in Font del Regàs and 230 mm in Fuirosos. During rainfall events of low mean intensity, hydrological responses to precipitation inputs at the semi-arid Fuirosos were more delayed and more variable than at the sub-humid Font del Regàs. We explain these divergences by differences in antecedent soil moisture conditions and associated differences in catchment hydrological connectivity between the two catchments, which in this case are likely driven by differences in local climate rather than by differences in local topography. In contrast, during events of moderate and high mean rainfall intensities, including the storm Gloria, precipitation inputs and hydrological responses correlated similarly in the two catchments. We explain this convergence by rapid development of hydrological connectivity independently of antecedent soil moisture conditions. The data set presented here is unique and contributes to our mechanistic understanding on how streams respond to rainfall events and exceptionally large storms in catchments with contrasting flow regimes.  相似文献   

15.
We investigated the importance of meteorological and lake physical conditions for temporal, horizontal and vertical differences in the concentration of dissolved oxygen (DO) and water temperature, and the derived daily estimates of gross primary production (GPP), ecosystem respiration (R) and net ecosystem production (NEP). Our study was conducted in a subtropical and polymictic lake in Southern Brazil, during a spring–summer transition. Metabolic rates were determined from two sites using the open water oxygen technique. At the central deep site, oxygen sondes were deployed at three depths to assess patterns in vertical variability. During 10 days, an additional DO and temperature sonde was placed near the shoreline allowing us to compare metabolic differences in the surface layers between the central pelagic and littoral site. While GPP was similar, R was significantly higher at the shallower littoral site, causing NEP to be lower, although NEP was still positive. The littoral site had less diel changes in DO and higher daily variability in all metabolic rates. Variability in GPP and R at the littoral site was related to temperature, wind speed and rainfall suggesting that short-term variability in metabolic rates in shallow areas are sensitive to resuspension of sediments caused by a less stable water column. A clear vertical gradient was furthermore found for the metabolic rates at the central deep part of the lake, related to the light extinction, with highest GPP around 0.3 m and decreasing with depth, while respiration showed the inverse pattern. Below subsurface, respiration prevailed at 5.0 m depth and was uncoupled to primary production. Under conditions with high light and temperature, and low wind speeds, the mixing depth became shallower, in turn increasing the water column stability at the deep pelagic site, which resulted in higher mean light available and higher GPP in the water column. Our results confirm that deployment of sensors in different sites and depths allows for spatially, as well as temporally more representative estimates of lake metabolism.  相似文献   

16.
To evaluate the influence of hydrological processes on dissolved organic carbon (DOC) dynamics in a forested headwater catchment, DOC concentration was observed along the flow path from rainfall to stream water via throughfall, soil water, groundwater, and spring water for 4 years, and DOC flux through the catchment was calculated. The spatial and temporal variations in DOC concentration and flux were compared with physical hydrological observations and the mean residence time of water. In the upslope soil layer, DOC concentrations were not significantly correlated with water fluxes, suggesting that DOC concentrations were not strictly controlled by water fluxes. In the upslope perennial groundwater, DOC concentration was affected by the change in the amount of microbial degradation of DOC produced by changes in the mean residence time of water. In stream water, the temporal variation in DOC concentration was usually affected by changes in DOC concentration of the inflow component via vertical infiltration from above the perennial groundwater. During dry periods, however, the component from inflow via vertical infiltration was negligible and DOC in the upslope perennial groundwater became the major component of stream water DOC. The temporal variation in stream water DOC concentration during baseflow was affected by rainfall patterns over several preceding months. Therefore, records of rainfall over several preceding months are one of the most important factors for predicting changes in DOC concentration on a catchment scale. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   

17.
姜欣  朱林  许士国  谢在刚 《湖泊科学》2019,31(2):375-385
铁和锰是氧化还原敏感的元素,水源水库热分层引起的底层水体缺氧造成了沉积物中铁和锰的释放,对城市供水造成了极大的影响.以往鲜有悬浮物行为对铁和锰在水库水-沉积物界面迁移影响的研究,于2014年2月-2015年2月对碧流河水库深水区的水、悬浮物以及沉积物铁和锰的垂向分布特征进行综合调查分析,并进一步分析铁和锰的季节性变化规律及悬浮物行为对其的影响.Spearman相关分析结果表明铁浓度与总悬浮固体、总氮和总磷的相关性较大;锰浓度与总悬浮固体、溶解氧、pH和总氮的相关性较大.进一步讨论分析表明碧流河水库的热分层、底层缺氧以及沉积物再悬浮是影响铁和锰浓度的重要因素,水库铁和锰的季节变化规律存在差异.分层期溶解态的锰在底层累积,平均浓度达到0.18 mg/L,而沉积物中溶解态的铁释放很少.混合期水库的中上层锰浓度升高,达到了0.07 mg/L.沉积物的再悬浮是水库底层水体中铁的主要来源,底层颗粒态铁的平均浓度约为0.3 mg/L.絮凝的颗粒物以及其吸附的锰在水库长期悬浮,难以沉积到水库底部,使得悬浮物中Mn的含量显著高于表层沉积物,约为沉积物的7倍.建议应在碧流河水库采用分层取水、水库曝气以及联合供水等措施,以减少铁和锰的浓度升高对供水产生的影响,保障大连市城市供水安全.  相似文献   

18.
Australian arid zone ephemeral rivers are typically unregulated and maintain a high level of biodiversity and ecological health. Understanding the ecosystem functions of these rivers requires an understanding of their hydrology. These rivers are typified by highly variable hydrological regimes and a paucity, often a complete absence, of hydrological data to describe these flow regimes. A daily time‐step, grid‐based, conceptual rainfall–runoff model was developed for the previously uninstrumented Neales River in the arid zone of northern South Australia. Hourly, logged stage data provided a record of stream‐flow events in the river system. In conjunction with opportunistic gaugings of stream‐flow events, these data were used in the calibration of the model. The poorly constrained spatial variability of rainfall distribution and catchment characteristics (e.g. storage depths) limited the accuracy of the model in replicating the absolute magnitudes and volumes of stream‐flow events. In particular, small but ecologically important flow events were poorly modelled. Model performance was improved by the application of catchment‐wide processes replicating quick runoff from high intensity rainfall and improving the area inundated versus discharge relationship in the channel sections of the model. Representing areas of high and low soil moisture storage depths in the hillslope areas of the catchment also improved the model performance. The need for some explicit representation of the spatial variability of catchment characteristics (e.g. channel/floodplain, low storage hillslope and high storage hillslope) to effectively model the range of stream‐flow events makes the development of relatively complex rainfall–runoff models necessary for multisite ecological studies in large, ungauged arid zone catchments. Grid‐based conceptual models provide a good balance between providing the capacity to easily define land types with differing rainfall–runoff responses, flexibility in defining data output points and a parsimonious water‐balance–routing model. Copyright © 2004 John Wiley & Sons, Ltd.  相似文献   

19.
The hydrology and water balance of megadunes and lakes have been investigated in the Badain Jaran Desert of China. Field observations and analyses of sand layer water content, field capacity, secondary salt content, and grain size reveal 3 types of important natural phenomenon: (a) vegetation bands on the leeward slope of the megadunes reflect the hydrological regime within the sandy vadose zone; (b) seepage, wet sand deposits, and secondary salt deposits indicate the pattern of water movement within the sandy vadose zone; (c) zones of groundwater seeps and descending springs around the lakes reflect the influence of the local topography on the hydrological regime of the megadunes. The seepage exposed on the sloping surface of the megadunes and gravity water contained within the sand layer confirm the occurrence of preferential flow within the vadose zone of the megadunes. Alternating layers of coarse and fine sand create the conditions for the formation of preferential flows. The preferential flows promote movement of water within the sand layer water that leads to deep penetration of water within the megadunes and ultimately to the recharging of groundwater and lake water. Our results indicate that a positive water balance promotes recharge of the megadunes, which depends on the high permeability of the megadune material, the shallow depth of the surface sand layer affected by evaporation, the occurrence of rainfall events exceeding 15 mm, and the sparse vegetation cover. Water balance estimates indicate that the annual water storage of the megadunes is about 7.5 mm, accounting for only 8% of annual precipitation; however, the shallow groundwater per unit area under the megadunes receives only 3.6% of annual precipitation, but it is still able to maintain a dynamic balance of the lake water. From a water budget perspective, the annual water storage in the megadunes is sufficient to serve as a recharge source for lake water, thereby enabling the long‐term persistence of the lakes. Overall, our findings demonstrate that precipitation is a significant component of the hydrological cycle in arid deserts.  相似文献   

20.
This study presents the distribution of dissolved inorganic carbon (DIC) along the Strait of Gibraltar, its tidal-induced variability, as well as the inorganic carbon exchange between the Atlantic Ocean and Mediterranean Sea. During November 2003, water column samples were collected at nine stations to measure total alkalinity (TA), pH, and dissolved oxygen (DO) for the spatial characterization of the carbonate system. At the same time, anchored samplings were carried out, above the Camarinal Sill and in the Eastern Section of the Strait, in order to assess the tidal mixing effects for oxygen and DIC distribution on the water column. Three distinct water masses can be discerned in this area: the Surface Atlantic Water (SAW), the Mediterranean Water (MW), and the less abundant North Atlantic Central Water (NACW). The observations show an increase in the DIC and a decrease in oxygen concentration with depth, related to the different physico-chemical features of each water mass. The results show the high time-dependence of the vertical distribution of DIC with the interface oscillation, affected by the intense mixing processes taking place in the Strait. Intense mixing episodes over the Camarinal Sill are responsible for an increase in the DIC concentrations in the upper layer of the Eastern Section of the Strait. Higher DIC concentrations in the Mediterranean than in the Atlantic waters are responsible for a net DIC transport of 1.47×1012 mol C yr−1 to the Atlantic Ocean. Nevertheless, the net exchange is highly sensitive to the interface definition, as well as to the estimate of water volume transport used.  相似文献   

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