人工湿地对城市污染河水的净化效果及机理

针对采用人工湿地系统净化镇江市内污染较为严重的古运河河水中遇到的问题,采用复合垂直流人工湿地小试装置,研究人工湿地系统对污染河水的净化效果及净化机理.镇江古运河水质调查结果表明,河水中悬浮态污染物质含量较高,为劣V类水体;当水力负荷为750mm/d时,人工湿地系统对CODMn去除率约为50%-60%,TN去除率约为40%-50%,TP去除率约为30%-40%,能够将劣V类水处理为Ⅳ类水甚至Ⅲ类水,表明其对污染河水处理的有效性.研究人工湿地内部污染物浓度的沿程变化规律,可以发现河水中污染物质的去除主要发生在湿地下行池,尤其是表层30 cm处,而上行池未能发挥应有的作用,分析表明与可能与污染河水中的碳氮比有一定的关系.通过本次实验发现湿地表层对污染物的去除表现为滤料及植物根系的过滤、吸附、截留以及微生物的降解、植物吸收等综合作用.     

梅梁湖和五里湖水-沉积物界面的物质交换

从人工湿地水生植物根系实际生长深度、微生物及酶的空间分布以及不同深度人工湿地对污水的净化效果比较出发,研究了人工湿地污水处理系统的净化空间,以种植香蒲Typhaangustifolia和灯心草Juncuseffusus的人工湿地为例,水生植物根系主要分布在湿地基质上层25cm区域;微生物的数量随深度增加而递减,且35cm层的数量远远的低于上层;5－10cm层的磷酸酶、纤维素酶和蛋白酶活性亦大于20cm层;60cm深的人工湿地与20cm深的人工湿地对污水中污染物的净化效果基本一致。可以推断,人工湿地在净化污水的过程中,其上层存在一个较佳的净化空间。     

分级进水对阶梯垂直流人工湿地污水处理效果的影响

本文研究了分级进水对阶梯垂直流人工湿地处理生活污水效果的影响.在保持总水力负荷为100 mm/d的情况下,分别将总进水量的0%、10%、20%和30%用于湿地第2级阶梯的进水,分析了系统对化学需氧量(COD)和氮、磷的总去除率和沿程变化.结果表明,不同分级进水比例条件下人工湿地对COD和总磷(TP)的去除率差异不明显,COD和TP的最高去除率分别为87.80%和81.17%,COD的去除主要集中在第1级,其贡献率平均为82.18%,TP的去除主要集中在第3级,贡献率平均为54.37%.分级进水对总氮(TN)去除率影响显著(P0.05),当2级进水比例为20%时,TN去除率最高,为61.70%±4.48%,且3个梯级对TN的去除贡献率分别为36.52%、42.11%和21.37%.相同组合形式的垂直流人工湿地处理生活污水的工程应用中,可根据需求设置20%左右的2级进水比例,以提高人工湿地对污染物的去除效果.     

添加固体碳源对垂直流人工湿地污水处理效果的影响

以垂直流人工湿地小试系统为研究对象,探讨了不同位置(表层、上层、中层和下层)添加固体碳源对系统氮、磷及COD_Cr去除效果的影响.结果表明:湿地下层硝态氮去除率低于中层,最适宜碳源添加位置为垂直流人工湿地中、下层.添加碳源系统中,碳源添加位置为表层的系统COD_Cr去除率最高,各系统出水COD_Cr浓度均低于进水,不引起系统出水中COD_Cr浓度的增加.添加碳源显著提高脱氮除磷效果,碳源添加位置为下层的系统TN去除率最高,碳源添加位置为表层的系统氨氧化作用明显,出水铵态氮浓度最高,各系统对亚硝态氮和硝态氮去除率差异不明显,但对硝态氮都表现出良好的去除效果.碳源添加位置为下层的系统硝化作用最完全,TP去除能力也显著优于其他各系统.添加碳源至垂直流人工湿地下层可以达到同步脱氮除磷的效果.     

人工湿地植物的选择

本文阐述了植物在人工湿地中的作用和选择人工湿地植物的一些原则,并分析了人工湿地在我国的应用前景.植物在人工湿地中起着非常重要的作用,不但可以去除污染物质,维持湿地环境,而且具有生态美学和经济价值;选择了人工湿地植物应考虑植物的适应性、耐污能力、净化能力、根系、经济和观赏价值以及物种间的合理搭配.最后指出,人工湿地技术在我国有广阔的应用前景.     

磷在"沉积物-自然生物膜-上覆水"三相体系中的迁移转化

地表水体中沉积物表面通常会附着一层自然生物膜,对上覆水-沉积物界面化学物质的迁移转化有着重要的影响.以往研究往往会忽略这一生物层面,因而,开展磷在"沉积物-自然生物膜-上覆水"三相界面之间的迁移转化研究具有重要的实际意义.以软性填料表面形成的自然生物膜模拟沉积物表层以及悬浮颗粒物表层的自然生物膜,开展磷在沉积物-自然生物膜-上覆水之间的迁移转化过程研究.结果表明:有无曝气情况下,自然生物膜界面的存在均能够显著降低上覆水中总磷、溶解态总磷、溶解态无机磷的含量,明显抑制沉积物中可交换态磷向上覆水释放.研究证明自然生物膜在水体磷的迁移转化中起着不可忽视的作用,在研究沉积物-上覆水界面之间磷的迁移转化行为时,要充分考虑自然生物膜界面的存在.     

基于植物昼夜释氧变化规律的复合垂直流人工湿地氮形态

为了研究植物根系释氧规律对人工湿地中硝化与反硝化作用的影响,采用传统连续运行方式及根据释氧规律调节的新型运行方式(白天连续进水、夜间停水),在复合垂直流人工湿地小试系统中进行实验,采用代表性的挺水植物香蒲作为湿地植物,水力负荷为0.71 m3/(m2.d).结果表明:系统内白天以好氧的硝化作用为主,夜间以厌氧、缺氧的反硝化作用为主,且在新型运行方式下,系统内白天亚硝酸盐氮累积量为传统运行方式的5倍,硝酸盐氮累积量为其2倍,夜间亚硝酸盐氮和硝酸盐氮减少量又分别比传统运行方式高64%和26%.这说明在新型运行方式下,人工湿地脱氮效果优于传统运行方式.     

垂直流人工湿地对尾水的净化效果及最佳水力负荷

以污水厂尾水为处理对象,研究垂直流人工湿地在4种水力负荷(125、250、375和500 mm/d)条件下的周年净化效果,结果表明:秋季时系统的总氮去除率最高,冬季则显著降低;温度为10℃、溶解氧浓度为1.1 mg/L是反硝化强度显著降低的关键拐点;总磷在冬季较其他季节净化效果高;125 mm/d水力负荷下CODCr去除率显著高于其他水力负荷,冬季CODCr去除率显著降低,而其他水力负荷及季节下的去除效果没有显著差异;当湿地以高去除率为目标时,最佳水力负荷为125 mm/d;当湿地以地表水水环境质量Ⅴ类标准为目标时,最佳水力负荷为375 mm/d;当湿地以污染物去除量为目标时,最佳水力负荷为500 mm/d.综合推荐375 mm/d为最佳水力负荷.     

旁路多级人工湿地对巢湖流域南淝河水的净化效果

为了削减南淝河输入巢湖的污染物,建成南淝河旁路多级人工湿地水质净化示范工程,包括预处理系统、垂直潜流湿地系统和水平潜流湿地系统3个工艺单元.2014年3月至2015年2月对人工湿地各净化单元出水进行周年监测,分析各净化单元对污染物的去除效果,并探讨季节变化对去除效果的影响.结果显示,旁路多级人工湿地体现较高的去除效果.对高锰酸盐指数(COD_(Mn))、总氮(TN)、铵态氮(NH_4~+-N)和总磷(TP)的总去除率分别为70.9%、43.7%、43.5%和76.6%.COD_(Mn)和TP的平均出水浓度均优于《地表水环境质量标准》(GB 3838-2002)中的Ⅳ类水标准,而NH_4~+-N的平均出水浓度优于《城镇污水处理厂污染物排放标准》(GB 18918-2002)一级A类标准.各净化单元对污染物的去除差异显著,COD_(Mn)的去除主要发生在预处理单元,其对COD_(Mn)削减的净化率为65.1%;TN、NH_4~+-N和TP的去除主要发生在垂直潜流湿地单元,其对TN、NH_4~+-N和TP削减的净化率分别为23.2%、27.1%和51.1%.不同季节,旁路多级人工湿地对污染物去除具有一定差异,对COD_(Mn)和TP的去除率均表现为夏季秋季春季冬季,对TN的去除率表现为秋季春季夏季冬季,对NH_4~+-N的去除率表现为秋季夏季春季冬季.最后,建议通过增加碳源和增大水力停留时间来进一步优化该工艺,以有效提高脱氮效果.     

潜流湿地中微生物对三峡库区微污染水净化效果的影响

为了探讨潜流湿地对三峡库区微污染河水的净化效果,在野外构建芦竹、菖蒲、空心菜和无植物(空白)水平潜流人工湿地,研究人工湿地系统中微生物基本菌群和功能菌群数量分布,探讨污染物去除与微生物菌群种类和数量的相关性.结果表明:实验湿地系统运行情况良好,植物湿地系统对各污染物指标的去除效果优于空白湿地系统;芦竹、菖蒲、空心菜和空白湿地系统的微生物数量均随温度的降低而减少,其中,植物湿地系统的微生物数量高于空白系统;各湿地系统的微生物数量与水质指标去除率之间的相关性较强,在夏季,不同人工湿地系统的细菌总数与CODMn的去除率之间存在着显著的正相关,真菌、亚硝酸细菌总数与铵氮去除率之间均存在着显著的正相关,在冬季,不同人工湿地系统的反硝化细菌总数与总氮去除率之间存在着显著的正相关.     

人工湿地复合基质深度净水除磷实验

通过垂直上升流人工湿地模拟柱实验,研究了泥炭、蛭石、砾石以不同体积比(柱1比例1:1:3,柱2比例1:1:2, 柱3比例1:1:1,柱4全为砾石)组成的复合基质对人工湿地出水的深度除磷效果．结果表明,填充复合基质的柱1-3对总磷和正磷酸盐的处理效果较好,去除率分别达到了77％和90％以上,明显优于填充单一基质砾石的柱4(27％和 21％);蛭石、泥炭价格远高于砾石,从经济、有效的原则出发,用蛭石、泥炭、砾石以1:1:3的体积比例混合作为复合填料比较合理;该复合基质适合于水质深度净化,在进水总磷浓度不超过0．1 mg／L的情况下,除磷效果相当稳定,可以保证 0．02mg／L以下的出水浓度(地表Ⅲ类水质标准),并达到80％左右的去除率;遇到高浓度磷污染负荷冲击时,磷去除率会降低;该复合基质的除磷机制主要为吸附净化,单独使用易吸附饱和,而与人工湿地中与湿地植物的吸收净化衔接起来,就能形成稳定持久的除磷效果．     

Clogging process by suspended solids during groundwater artificial recharge: Evidence from lab simulations and numerical modelling

Permeability reduction of infiltration media due to suspended solid (SS) clogging is the bane of groundwater artificial recharge. To overcome the clogging problem and advance the understanding of the process‐based spatial‐temporal evolution of SS clogging, a 1D laboratory column simulation was carried out, followed by numerical modelling of the experimental data in this study. It was found that clogging caused a reduction in the hydraulic conductivity (K) in the upper layer at the beginning and extended deeper to approximately 50 cm, and no reduction in K was detected below 52 cm throughout the experimental period of 129 hr. The most clogged layer spanned from the surface to a depth of 11 cm, and the middle 11–52 cm was characterized by a slight decrease in K. The clogging rates of the different layers decreased with the depth, which was based on data analysis, with the largest value of 0.038 hr^?1 in the upper 1 cm. The overall K began to decrease from the surface layer and was increasingly affected by clogging with time. A mathematical model was established to simulate the SS clogging process evolution based on considerations of the attachments and detachments of particles. Then the model was applied to perform several scenario analyses after calibration and validation using the data obtained in the experiment. The simulation results indicated that the SS concentration was much more sensitive than the groundwater depth below the land surface, and 10 days of constant recharge is recommended as the disposal cycle of the clogged layer under the given conditions.     

人工湿地植物根区微生物与净化效果的季节变化

人工湿地污水处理系统具有净化效果显著、建设和运行费用低廉、管理简便等优点.近年来越来越受到人们的重视.人工湿地生态系统受环境影响较大,研究人工湿地在不同季节的净化功能对于充分发挥其作用具有重要意义.对不同季节的芦苇(Phragmite saus-tralis)、茭白(Zizania caduciflora)和香蒲(Typha latifolia)等湿地系统植物根区、无植物对照基质微生物分布状况以及净化效果进行了研究,结果显示:(1)种植不同植物的湿地系统根区微生物数量不同,其湿地净化效果也不同;(2)季节变化显示湿地系统秋季的细菌总数量比夏季高;但对照系统夏季的真菌和放线菌数量明显高于秋季;(3)湿地系统总磷(TP)的去除率夏季高于秋季;(4)相关性分析发现湿地植物根区的细菌总数与BOD5的去除率之间存在显著相关性;而根区微生物数量与TP、CODCr和凯氏氮(KN)的去除率之间不存在显著相关性,具体机理还需进一步研究.     

表面流湿地沉积物再悬浮及其对湿地净化效果的影响

选取典型表面流人工湿地——盐龙湖人工湿地为研究对象,通过对沉积物理化性质分析,湿地系统水动力模拟,风场与悬浮物(SS)再悬浮浓度关系的拟合及全年再悬浮对湿地净化效果的影响估算,探索表面流湿地沉积物在动力条件下的再悬浮特征及此过程中营养物质的再悬浮量.结果显示:0.3～0.5 m水深沉积物的理论起动流速在18.54～22.62cm/s之间,模拟得到湿地运行过程中水体流速最大值为1.62 cm/s,会远小于理论起动流速值,因此湿地内部流动产生的底部扰动难以形成湿地底泥的大规模再悬浮现象.但湿地内部仍存在一定的底泥再悬浮效应,风场扰动是主要影响因素,风场作用受植物影响显著,萌发期(3-4月)和收割期(11月-次年2月)再悬浮贡献量大于生长期(5-8月)与成熟期(9-10月),并且当风速4 m/s时再悬浮浓度明显增加.再悬浮浓度与运行水深也有关,0.3 m水深SS再悬浮浓度分别高出0.4 m和0.5 m水深12.48%和18.67%;高锰酸盐指数(CODMn)分别高出12.61%和19.52%;总氮(TN)分别高出248.12%和341.94%;总磷(TP)分别高出35.53%和43.48%.全年SS、CODMn、TN和TP再悬浮量分别达到2.8、0.47、0.15和0.011 kg/m2.     

利用生物膜强化表流湿地处理农村生活污水的试验

针对农村生活污水难以集中处理的问题,提出了采用生物膜强化表流湿地工艺就地进行农村生活污水处理的方法,并对其进行试验研究.结果表明:在表流湿地表面设置生物膜载体后,系统的水质净化能力提高,处理负荷较高的条件下(COD_Cr:657.27 mg/L、TN:26.27 mg/L、TP:8.66 mg/L和SS:276 mg/L),处理效果显著提高.在效果明显的试验组中,生物膜设置后系统对TN、TP、COD_Cr的去除率分别提高了21.64%、16.24%、19.12%.另外,通过对系统中微生物的检测发现,生物膜载体的引入对湿地系统本身影响不大,系统水质净化能力的提高主要源于载体上微生物的增加.该方法在未增加系统占地面积的情况下提高了水质净化能力,为解决农村生活污水处理难的问题提供了新的思路.     

Potential use of mangroves as constructed wetland for municipal sewage treatment in Futian, Shenzhen, China

A pilot-scale mangrove wetland was constructed in Futian, Shenzhen for municipal sewage treatment. Three identical belts (length: 33m, width: 3m, depth: 0.5m) were filled with stone (bottom), gravel and mangrove sand (surface). Seedlings of two native mangrove species (Kandelia candel, Aegiceras corniculatum) and one exotic species (Sonneratia caseolaris) were transplanted to the belts with one species for each belt. The hydraulic loading was 5m(3)d(-1) and hydraulic retention time 3d. High levels of removal of COD, BOD(5), TN, TP and NH(3)-N were obtained. The treatment efficiency of S. caseolaris and A. corniculatum was higher than that of K. candel. Faster plant growth was obtained for S. caseolaris. The substrate in the S. caseolaris belt also showed higher enzyme activities including dehydrogenase, cellulase, phosphatase, urease and beta-glucosidase. The removal rates of organic matter and nutrients were positively correlated with plant growth. The results indicated that mangroves could be used in a constructed wetland for municipal sewage treatment, providing post-treatment to remove coliforms was also included.     

Ciliate communities in a constructed mangrove wetland for wastewater treatment

In wetlands constructed for treating municipal and industrial wastewater, including mangroves, the effect of wastewater discharged on the substrate has often been neglected. Ciliates, an important group of protozoa, are sensitive to pollutants and any changes in ciliate diversity and community structure reflects the habitat quality. The ciliate communities at six sections along a constructed mangrove belt (33 m in length) planted with Aegicerascorniculatum were investigated in Shenzhen, South China. In all samples collected in both rainy and dry seasons, 183 ciliate species were observed. Most species (56%) were free-swimming forms, while only 10.8% were sessile ciliates. The abundance and species number of ciliates were both found to decrease from the anterior (the wastewater inlet) to the posterior (the outlet) parts of the wetland belt, indicating that organic matter and bacteria in wastewater, which served as food for most ciliates, were gradually removed by the constructed wetland. The r/K (number of r- and K-selected species) ratios at the six sections were relatively small, between 0.2 and 0.4, whereas the C/P (abundance of colpodids and polyhymenophorans) quotient at some sections was higher than 1. These results indicate that although most of the environments along the constructed wetland belt were not stressful for ciliate communities, there were habitats that favored colpodids in high abundances.     

人工湖滨湿地磷素汇-源功能转换及理论解释

采用水动力弥散和吸附理论建立了表流湿地水-土界面磷通量模型,定义了湿地汇-源转换的临界水体磷浓度值.模型揭示,湿地对磷的截留是水动力弥散和吸附共同作用的结果.在湿地建成运行初期,吸附作用明显,临界浓度值较低,湿地较好地发挥截磷功能.随着湿地的运行,土壤吸附趋于饱和,吸附作用减弱,水动力弥散变为主导因素,临界浓度值增大,使湿地除磷功能减弱,在一定条件下,反而可能释放磷.本文建立的磷通量模型具有明确的物理基础,能解释湿地对磷去除功能退化的机理和汇-源转换条件.应用模型对抚仙湖马料河湿地的观测数据作了初步解释,该湿地运行两年后,临界磷浓度值为0.58 mg/L,湿地除磷功能明显衰退.     

Variations in Phosphorus Speciation in Pilot Scale Subsurface Flow Wetlands Constructed with Blast Furnace Slag and Gravel

Variations in phosphorus (P) speciation were compared for two types of pilot scale wetlands: a blast furnace slag‐based constructed wetland (SCW), and a gravel‐based constructed wetland (GCW). Synthetic secondary effluent was used as the influent of the wetlands, which contained 1.1 mg/L P with more than 95% present as soluble reactive P (SRP). However, dissolved organic phosphorus (DOP) and particulate phosphorus (PP) emerged in the water along both wetlands. The levels of these three P species varied between the two wetlands. The GCW was more efficient than SCW at removing SRP, but showed a different trend. SRP decreased continually in the SCW, while it increased at the end of the GCW due to biological release. DOP was constant in SCW and GCW, and the mean value was 0.023 and 0.020 mg/L, respectively. The mean values of PP in the GCW ranged between 0.093 and 0.216 mg/L; much higher than the 0.05 ± 0.01 mg/L measured in the SCW. Sequential extractions showed that iron bound PP (Fe‐PP), aluminum bound PP (Al‐PP), organic PP (Org‐PP) and occluded PP (Oc‐PP) were the major components of PP at most locations of the GCW. Fe‐PP decreased from 0.53 to 0.14 mg/L in the upper layer, with DO steady at about 0.15 mg/L at the bottom. Oc‐PP increased at each layer. Al‐PP and Org‐PP were steady in the first 140 cm of the GCW, but decreased sharply at the end. Considering the variation of SRP, DOP and PP fractionations, it can be seen that PP exchanged intensively with SRP in the GCW, and might act as an intermediate in the P removal process. Part of the SRP was first transformed into PP, and then absorbed by substrates or deposited in the wetlands. P removal was mainly via Ca precipitation in the SCW, but involved multiple mechanisms in the GCW, such as precipitation, adsorption and biological interactions. The multiple P removal mechanisms might be the reason for the low proportion of SRP, and the better P removal efficiency observed in the GCW.