Experimental study on supercritical phenomena of WO<Subscript>3</Subscript> solubility in NaCl-H<Subscript>2</Subscript>O system

The solubility measurements of WO₃ in NaCl-H₂O system with 4.0% by weight salt were carried out to study the supercritical phenomena of solubility. These experiments were carried out using rapid-quench pressure vessels, with quantitative Na₂WO₄-2H₂O, HCl, NaCl and H₂O in Pt capsule to determine the solubility of WO₃ from supersaturated solution. The pressure was kept at 34 MPa, which was near the critical pressure 31.4 MPa and the temperatures varied from 250°C to 550°C. The experimental results indicate that the solubility of WO₃ has the features of supercritical phenomenon in critical region and is sensitive to the change of system temperature and solvent density. The temperature and pressure in this experiment are close to those of ore-forming fluids in many tungsten deposits, so the features of supercritical geofluids can be helpful to investigating the ore-forming mechanism of tungsten deposit.     

Soil H<Subscript>2</Subscript> and CO<Subscript>2</Subscript> Surveys at Several Active Faults in Japan

Soil H₂ and CO₂ surveys were carried out along seven active faults and around the aftershock region of the 2000 Tottori-ken Seibu earthquake in Japan. Diffuse CO₂ effluxes were also measured along one fault and around the 2000 aftershock region. The results show highly variable H₂ concentration in space and time and it seems that the maximum H₂ concentration at each active fault correlates with fault activity as exemplified by the time of the latest big earthquakes. Even though observed H₂ concentrations in four faults were markedly lower than those collected previously in the latter half of the 1970s, it is evident that the higher H₂ concentrations in this study are due to the addition of the fault gases. Comparing the chemical composition of trapped gases (H₂: 5–20% and CO₂/H₂: 0.5–12) in fractured rocks of drill cores bored at the Nojima fault, a soil gas sample with the highest H₂ concentration showed large amounts of the trapped fault gas, diluted with atmospheric component. The profile experiment across a fracture zone at the Yamasaki fault showed higher H₂ concentrations and lower CO₂/H₂ ratios as was observed in soil gas from the fracture zone. A few days after the 2000 Tottori-kei Seibu earthquake, no CO₂ effluxes related to the occurrence of earthquakes were observed at the aftershock region. However, only above the epicenter zone, relatively high H₂ concentrations in soil gases were observed.     

Physics and Seismic Modeling for Monitoring CO<Subscript>2</Subscript> Storage

We present a new petro-elastical and numerical-simulation methodology to compute synthetic seismograms for reservoirs subject to CO₂ sequestration. The petro-elastical equations model the seismic properties of reservoir rocks saturated with CO₂, methane, oil and brine. The gas properties are obtained from the van der Waals equation and we take into account the absorption of gas by oil and brine, as a function of the in situ pore pressure and temperature. The dry-rock bulk and shear moduli can be obtained either by calibration from real data or by using rock-physics models based on the Hertz-Mindlin and Hashin-Shtrikman theories. Mesoscopic attenuation due to fluids effects is quantified by using White's model of patchy saturation, and the wet-rock velocities are calculated with Gassmann equations by using an effective fluid modulus to describe the velocities predicted by White's model. The simulations are performed with a poro-viscoelastic modeling code based on Biot's theory, where viscoelasticity is described by generalizing the solid/fluid coupling modulus to a relaxation function. Using the pseudo-spectral method, which allows general material variability, a complete and accurate characterization of the reservoir can be obtained. A simulation, that considers the Utsira sand of the North Sea, illustrates the methodology.     

Experimental study on N<Subscript>2</Subscript>O and CH<Subscript>4</Subscript> fluxes from the dark coniferous forest zone soil of the Gongga Mountain,China

The static closed chamber technique is used in the study on the CH₄ and N₂O fluxes from the soils of primeval Abies fabri forest, the succession Abies fabri forest and the clear-cut areas of mid-aged Abies fabri forest in the Gongga Mountain from May 1998 to September 1999. The results indicate the following: (i) The forest soil serves as the source of atmospheric N₂O at the three measurement sites, while the fluxes of CH₄ are all negative, and soil is the sink of atmospheric CH₄. The comparative relations of N₂O emissions between the three sites are expressed as primeval Abies fabri forest < clear-cut areas < succession Abies fabri forest, and those of CH₄ consumption fluxes are primeval Abies fabri forest < succession Abies fabri forest < clear-cut areas, (ii) Significant seasonal variations of N₂O emission at various sites were observed, and two emission peaks of N₂O occurr during summer (July—August) and spring (February—March), whereas N₂O emission is relatively low in winter and spring (mid March—April). Seasonal variations of CH₄ consumption at each measurement site fluctuate drastically with unclear regularities. Generally, CH₄ consumption fluxes of succession Abies fabri forest and clear-cut areas are higher from mid May to late July but lower in the rest of sampling time, while the CH₄ flux keeps a relatively high value even up to September in primeval Abies fabri forest. In contrast to primeval Abies fabri forest, the CH₄ absorbabilities of succession Abies fabri forest and clear-cut areas of mid-aged Abies fabri forest are weaker. Particularly, the absorbability of the clear-cut areas is even weaker as compared with the other two sites, for the deforestation reduces the soil absorbability of atmospheric CH₄. (iii) Evident diurnal variation regularity exists in the N₂O emissions of primeval Abies fabri forest, and there is a statistic positive correlation between the fluxes of N₂O and air temperature (R=0.95, n=11, α· 0.01), and also the soil temperature of 5-cm layer (R=0.81, n=11, α> 0.01), whereas the CH₄ diurnal variation regularities are unclear and have no significant correlation with the soil temperature of 5-cm layer and air temperature.     

Soil organic carbon storage and soil CO<Subscript>2</Subscript> flux in the alpine meadow ecosystem

High-resolution sampling, measurements of organic carbon contents and ¹⁴C signatures of selected four soil profiles in the Haibei Station situated on the northeast Tibetan Plateau, and application of ¹⁴C tracing technology were conducted in an attempt to investigate the turnover times of soil organic carbon and the soil-CO₂ flux in the alpine meadow ecosystem. The results show that the organic carbon stored in the soils varies from 22.12×10⁴ kg C hm⁻² to 30.75×10⁴ kg C hm⁻² in the alpine meadow ecosystems, with an average of 26.86×10⁴ kg C hm⁻². Turnover times of organic carbon pools increase with depth from 45 a to 73 a in the surface soil horizon to hundreds of years or millennia or even longer at the deep soil horizons in the alpine meadow ecosystems. The soil-CO₂ flux ranges from 103.24 g C m⁻² a⁻¹ to 254.93 gC m⁻² a⁻¹, with an average of 191.23 g C m⁻² a⁻¹. The CO₂ efflux produced from microbial decomposition of organic matter varies from 73.3 g C m⁻² a⁻¹ to 181 g C m⁻² a⁻¹. More than 30% of total soil organic carbon resides in the active carbon pool and 72.8%281.23% of total CO₂ emitted from organic matter decomposition results from the topsoil horizon (from 0 cm to 10 cm) for the Kobresia meadow. Responding to global warming, the storage, volume of flow and fate of the soil organic carbon in the alpine meadow ecosystem of the Tibetan Plateau will be changed, which needs further research. Supported by the National Natural Science Foundation of China (Grant Nos. 40231015, 40471120 and 40473002) and the Guangdong Provincial Natural Science Foundation of China (Grant No. 06300102)     

Study on the processing method of nighttime CO<Subscript>2</Subscript> eddy covariance flux data in ChinaFLUX

At present, using Eddy Covariance (EC) method to estimate the “true value” of carbon sequestration in terrestrial ecosystem arrests more attention. However, one issue is how to solve the uncertainty of observations (especially the nighttime CO₂ flux data) appearing in post-processing CO₂ flux data. The ratio of effective and reliable nighttime EC CO₂ flux data to all nighttime data is relatively low (commonly, less than 50%) for all the long-term and continuous observation stations in the world. Thus, the processing method of nighttime CO₂ flux data and its effect analysis on estimating CO₂ flux annual sums are very important. In this paper, the authors analyze and discuss the reasons for underestimating nighttime CO₂ flux using EC method, and introduce the general theory and method for processing nighttime CO₂ flux data. By analyzing the relationship between nighttime CO₂ flux and air fraction velocity u*, we present an alternate method, Average Values Test (AVT), to determine the thresholds of fraction velocity (u*_c) for screening the effective nighttime CO₂ flux data. Meanwhile, taking the data observed in Yucheng and Changbai Mountains stations for an example, we analyze and discuss the effects of different methods or parameters on nighttime CO₂ flux estimations. Finally, based on the data of part ChinaFLUX stations and related literatures, empirical models of nighttime respiration at different sites in ChinaFLUX are summarized.     

Functioning of intertidal flats inferred from temporal and spatial dynamics of O<Subscript>2</Subscript>, H<Subscript>2</Subscript>S and pH in their surface sediment

In this article, we describe the dynamics of pH, O₂ and H₂S in the top 5–10 cm of an intertidal flat consisting of permeable sand. These dynamics were measured at the low water line and higher up the flat and during several seasons. Together with pore water nutrient data, the dynamics confirm that two types of transport act as driving forces for the cycling of elements (Billerbeck et al. 2006b): Fast surface dynamics of pore water chemistry occur only during inundation. Thus, they must be driven by hydraulics (tidal and wave action) and are highly dependent on weather conditions. This was demonstrated clearly by quick variation in oxygen penetration depth: Seeps are active at low tide only, indicating that the pore water flow in them is driven by a pressure head developing at low tide. The seeps are fed by slow transport of pore water over long distances in the deeper sediment. In the seeps, high concentrations of degradation products such as nutrients and sulphide were found, showing them to be the outlets of deep-seated degradation processes. The degradation products appear toxic for bioturbating/bioirrigating organisms, as a consequence of which, these were absent in the wider seep areas. These two mechanisms driving advection determine oxygen dynamics in these flats, whereas bioirrigation plays a minor role. The deep circulation causes a characteristic distribution of strongly reduced pore water near the low water line and rather more oxidised sediments in the centre of the flats. The two combined transport phenomena determine the fluxes of solutes and gases from the sediment to the surface water and in this way create specific niches for various types of microorganisms.     

Geochemical evidence of the renewal of volcanic activity inferred from CO<Subscript>2</Subscript> soil and SO<Subscript>2</Subscript> plume fluxes: the 2007 Stromboli eruption (Italy)

On 27 February 2007, a new eruption occurred on Stromboli which lasted until 2 April. It was characterized by effusive activity on the Sciara del Fuoco and by a paroxysmal event (15 March). This crisis represented an opportunity for us to refine the model that had been developed previously (2002–2003 eruption) and to improve our understanding of the relationship between the magmatic dynamics of the volcano and the geochemical variations in the fluids. In particular, the evaluation of the dynamic equilibrium between the volatiles (CO₂ and SO₂) released from the magma and the corresponding fluids discharged from the summit area allowed us to evaluate the level of criticality of the volcanic activity. One of the major accomplishments of this study is a 4-year database of summit soil CO₂ flux on the basis of which we define the thresholds (low–medium–high) for this parameter that are empirically based on the natural volcanological evolution of Stromboli. The SO₂ fluxes of the degassing plume and the CO₂ fluxes emitted from the soil at Pizzo Sopra la Fossa are also presented. It is noteworthy that geochemical signals of volcanic unrest have been clearly identified before, during and after the effusive activity. These signals were found almost simultaneously in the degassing plume (SO₂ flux) and in soil degassing (CO₂ flux) at the summit, although the two degassing processes are shown to be clearly different. The interpretation of the results will be useful for future volcanic surveillance at Stromboli.     

Relationship between the daytime critical frequencies of the <Emphasis Type="Italic">F</Emphasis><Subscript>2</Subscript> layer and thermospheric characteristics

The relationship between the critical frequency of the F ₂ layer and the atmospheric characteristics has been obtained in a general form. It has been shown that this relation makes it possible to sufficiently accurately describe the daytime values of foF2 while comparing them with the observed monthly median values. Such comparisons were performed, first, for the data of measurements in Irkutsk using the DPS-4 digital ionosonde in 2003–2006 and, second, based on the annual variations in the noon foF2 values at 24 stations of the Northern Hemisphere in 1984. The calculations were performed using the MSIS-86 thermospheric model [Hedin, 1987].     

Links between global CO<Subscript>2</Subscript> variability and climate anomalies of biomes

The global rate of fossil fuel combustion continues to rise, but the amount of CO₂ accumulating in the atmosphere has not increased accordingly. The causes for this discrepancy are widely debated. Particularly, the location and drivers for the interannual variability of atmospheric CO₂ are highly uncertain. Here we examine links between global atmospheric CO₂ growth rate (CGR) and the climate anomalies of biomes based on (1986–1995) global climate data of ten years and accompanying satellite data sets. Our results show that four biomes, the tropical rainforest, tropical savanna, C₄ grassland and boreal forest, and their responses to climate anomalies, are the major climate-sensitive CO₂ sinks/sources that control the CGR. The nature and magnitude by which these biomes respond to climate anomalies are generally not the same. However, one common influence did emerge from our analysis; the extremely high CGR observed for the one extreme El Niño year was caused by the response of the tropical biomes (rainforest, savanna and C₄ grassland) to temperature.     

Carbon assimilation characteristics of plants in oasis-desert ecotone and their response to CO<Subscript>2</Subscript> enrichment

Six species of more than 20-year-old desert woody plants in the oasis-desert ecotone were selected for study. The results showed that: (1) in different growing seasons δ¹³C values of assimilating organ varied between -14%. and -16%. for Haloxylon ammodendron (HA),-14%. - -15%. for Calligonum mongolicum (CM) and -25%. - -28%. for Caragana korshinskii (CK), Nitraria sphaerocarpa (NS) and Hedysarum scoparium (HS). (2) The net photosynthetic rate (Pn) of HA and CM was significantly higher than those of the other species. With the decrease in Pn for the six species, their intercellular CO₂ concentration increased, but stomatal limitation value decreased under the intensive light. At the same time, the photochemical efficiency of PS II dropped to different degrees. (3) The CO₂ enrichment experiment demonstrated that, Pn of HA and CM increased to different extent under 450 μmol/mol, but their Pn reduced or approximated to the current condition under 650 μmol/mol. Under 450 μmol/mol the efficiency for solar energy utilization of CK and HS significantly reduced and under 650 μmol/mol their respiration rate exceeded photosynthesis rate. It can be concluded that HA and CM have some function of pathway for C₄ but the other three species have the function for C₃. The decline in their Pn is mainly caused by non-stomatal factors. HA, CM, CK and HS exhibited photoinhibition, which disappeared in a short time. This is a kind of positive readjustment to adapting to the desert environment. HA and CM can adapt to the high CO₂ environment, but CK and HS cannot. With the rise in atmospheric CO₂ concentration and climate warming, the latter two species in the oasis-desert ecotone may be gradually degraded or even disappear.     

Characteristics of <Emphasis Type="Italic">p</Emphasis>CO<Subscript>2</Subscript> in surface water of the Bering Abyssal Plain and their effects on carbon cycle in the

Characteristics of the pCO₂ distribution in surface water of the Bering Abyssal Plain and their relationships with the ambient hydrological conditions were discussed using variations of the partial pressure of CO₂ in surface water of the Bering Abyssal Plain and the Chukchi Sea. Data in this study are from a field investigation during the First Chinese National Arctic Research Expedition in 1999. Compared to the high productivity in the Bering Continental Shelf, much lower levels of chlorophyll a were observed in the Bering Abyssal Plain. The effect of hydrological factors on the pCO₂ distribution in surface seawater of the Plain in summer has become a major driving force and dominated over biological factors. The Plain also presents a High Nutrient Low Chlorophyll (HNLC). In addition, the pCO₂ distribution in the Bering Abyssal Plain has also been found to be influenced from the Bering Slope Current which would transform to the Anadyr Current when it inflows northwestward over the Plain. The Anadyr Current would bring a high nutrient water to the western Arctic Ocean where local nutrients are almost depleted in the surface water during the summer time. Resupplying nutrients would stimulate the growth of phytoplankton and enhance capacity of absorbing atmospheric CO₂ in the surface water. Otherwise, in the Bering Sea the dissolved inorganic carbon brought from freshwater are not deposited down to the deep sea water but most of them would be transported into the western Arctic Ocean by the Alaska Coastal Current to form a carbon sink there. Therefore, the two carbon sinks in the western Arctic Ocean, one carried by the Anadyr Current and another by the Alaska Costal Current, will implicate the western Arctic Ocean in global change.     

Thermal simulation experiments of saturated hydrocarbons with calcium sulfate and element sulfur: Implications on origin of H<Subscript>2</Subscript>S

Temperature-programmed simulation experiments of saturated hydrocarbons with calcium sulfate and element sulfur were compared in this study. Based on the variation analysis of the yields and evolvement features of gaseous hydrocarbon (C1-C5) and inorganic gaseous CO2, H2 and H2S, the reaction mechanisms were analyzed and discussed. In the calcium sulfate-saturated hydrocarbon system, H2S was produced by a small quantity, which indicates this reaction belongs to the low-degreed thermal sulfate reduction (TSR...     

An estimation of the height system bias parameter <Emphasis Type="Italic">N</Emphasis><Subscript>0</Subscript> using least squares collocation from observed gravity and GPS-levelling data

This paper deals with the analysis of gravity anomaly and precise levelling in conjunction with GPS-Levelling data for the computation of a gravimetric geoid and an estimate of the height system bias parameter N_o for the vertical datum in Pakistan by means of least squares collocation technique. The long term objective is to obtain a regional geoid (or quasi-geoid) modeling using a combination of local data with a high degree and order Earth gravity model (EGM) and to determine a bias (if there is one) with respect to a global mean sea surface. An application of collocation with the optimal covariance parameters has facilitated to achieve gravimetric height anomalies in a global geocentric datum. Residual terrain modeling (RTM) technique has been used in combination with the EGM96 for the reduction and smoothing of the gravity data. A value for the bias parameter N_o has been estimated with reference to the local GPS-Levelling datum that appears to be 0.705 m with 0.07 m mean square error. The gravimetric height anomalies were compared with height anomalies obtained from GPS-Levelling stations using least square collocation with and without bias adjustment. The bias adjustment minimizes the difference between the gravimetric height anomalies with respect to residual GPS-Levelling data and the standard deviation of the differences drops from 35 cm to 2.6 cm. The results of this study suggest that N_o adjustment may be a good alternative for the fitting of the final gravimetric geoid as is generally done when using FFT methods.     

The trend,seasonal cycle,and sources of tropospheric NO<Subscript>2</Subscript> over China during 1997–2006 based on satellite measurement

The characteristics of spatial and temporal distribution of tropospheric NO2 column density concentration over China are presented, on the basis of measurements from the satellite instruments GOME and SCIAMACHY. From these observations, monthly averaged tropospheric NO2 variations are determined for the period of 1997 to 2006. The trend and seasonal cycle are also investigated. The possible source of tropospheric NO2 over megacity area is discussed in this paper. The results show a large growth of tropospheric NO2 over eastern China, especially above the industrial areas with a fast economical growth, such as, Yangtze Rive Delta region and Pearl River Delta region because of the prominent anthropogenic activity. There is a rapid increase of tropospheric NO2 over megacities in China. For instance, Shanghai had a linear significant increase in NO2 columns of ～20% per year (reference year 1997) in the period of 1997-2006, which is the rapidest increase among all the selected cities. The seasonal pattern of the NO2 concentration shows a difference between the east and west in China. In the eastern part of China, an expected winter maximum in seasonal cycle is found because of the prominent anthropogenic activity and meteorological conditions. In the western part this cycle shows a NO2 maximum in summer time, which is attributed to natural emissions, especially soil emissions and lightning. A quickly increasing vehicle population may contribute to the increase of tropospheric NO2 over megacities in China for the remarkable correlation for vehicle population with tropospheric NO2.     

Trend analysis using nonhomogeneous stochastic diffusion processes. Emission of CO<Subscript>2</Subscript>; Kyoto protocol in Spain

In this study, we propose a methodology to analyse the gradual secular trends present in the time evolution of certain endogenous variables, which are of particular interest in environmental research. This methodology is based on modelling such variables by nonhomogeneous stochastic diffusion processes, the trend functions of which may be made to depend on other, exogenous, variables, which are controllable and which affect and model, in turn, the possible irregularities of such trends. The methodology is applied to analyse the evolution of the emission of CO₂ in Spain, and it is shown that the evolution of the Spanish GDP affects the trend component. These circumstances are considered in the context of Spain’s non-compliance with the Kyoto protocol on controlling the emission of greenhouse gases.     

3D <Emphasis Type="Italic">v</Emphasis><Subscript>P</Subscript> and <Emphasis Type="Italic">v</Emphasis><Subscript>S</Subscript> models of southeastern margin of the Tibetan plateau from joint inversion of body-wave arrival times and surface-wave dispersion data

A new 3D velocity model of the crust and upper mantle in the southeastern (SE) margin of the Tibetan plateau was obtained by joint inversion of body- and surface-wave data. For the body-wave data, we used 7190 events recorded by 102 stations in the SE margin of the Tibetan plateau. The surface-wave data consist of Rayleigh wave phase velocity dispersion curves obtained from ambient noise cross-correlation analysis recorded by a dense array in the SE margin of the Tibetan plateau. The joint inversion clearly improves the v _S model because it is constrained by both data types. The results show that at around 10 km depth there are two low-velocity anomalies embedded within three high-velocity bodies along the Longmenshan fault system. These high-velocity bodies correspond well with the Precambrian massifs, and the two located to the northeast of 2013 M _S 7.0 Lushan earthquake are associated with high fault slip areas during the 2008 Wenchuan earthquake. The aftershock gap between 2013 Lushan earthquake and 2008 Wenchuan earthquake is associated with low-velocity anomalies, which also acts as a barrier zone for ruptures of two earthquakes. Generally large earthquakes (M ≥ 5) in the region occurring from 2008 to 2015 are located around the high-velocity zones, indicating that they may act as asperities for these large earthquakes. Joint inversion results also clearly show that there exist low-velocity or weak zones in the mid-lower crust, which are not evenly distributed beneath the SE margin of Tibetan plateau.     

Anomalous variations in the structure of the ionospheric <Emphasis Type="Italic">F</Emphasis><Subscript>2</Subscript> region at geomagnetic midlatitudes of the Southern and Northern hemispheres in going from summer to winter conditions at high solar activity

The structure and dynamics of the ionosphere and plasmasphere at high solar activity under quiet geomagnetic conditions of June 2–3, 1979, and January 5–6, 1980, over Millstone Hill station and Argentine Islands ionosonde, the locations of which are approximately magnetically conjugate, have been theoretically calculated. The plasma drift velocity, determined by comparing the calculated and measured heights of the F ₂ layer maximum (hmF2), and the correction of [N₂] and [O₂], found in the NRLMSISE-00 model, make it possible to coordinate the electron densities (NmF2) calculated at the hmF2 height and the measured anomalous variations in NmF2 over the Argentine Islands ionosonde as well as the calculated and measured NmF2 and electron temperature at the hmF2 height over Millstone Hill station. It has been shown that, if the interference of the diffusion velocities of O⁺(⁴S) and H⁺ ions is taken into account, the additional heating of plasmaspheric electrons leads to an increase in the flux of O⁺(⁴S) ions from the topside ionosphere to lower F ₂ layer altitudes, as a result of which an anomalous nighttime increase in NmF2 6, observed on January 6, 1980, over Millstone Hill station, is mainly produced. The second component of the formation of anomalous night-time NmF2 is the plasma drift along the magnetic field caused by the neutral wind, which shifts O⁺(⁴S) ions to higher altitudes where the recombination rate of O⁺(⁴S) with N₂ and O₂ is lower and slows down a decrease in NmF2 in the course of time. It has been shown that the influence of electronically excited O⁺ ions and vibrationally excited N₂ and O₂ molecules on electron density (N _e ) considerably differs under winter and summer conditions. This difference forms significant part of the winter anomaly in N _e at heights of the F ₂ region and topside ionosphere over Millstone Hill station.     

Anomalous variations in the ionospheric <Emphasis Type="Italic">F</Emphasis><Subscript>2</Subscript>-layer structure at geomagnetic midlatitudes of the Southern and Northern hemispheres at the transition from summer to winter conditions under low solar activity

The structure and dynamics of the ionosphere and plasmasphere at low solar activity under quiet geomagnetic conditions on January 15–17, 1985, and July 10–13, 1986, over Millstone Hill station and Argentine Islands ionosonde, the locations of which are approximately magnetically conjugate, have been theoretically calculated. The detected correction of the model input parameters makes it possible to coordinate the measured and calculated anomalous variations in the electron density NmF2 at the height hmF2 of the ionospheric F2 layer over Argentine Islands ionosonde as well as the calculated and measured values of NmF2 and electron temperature at the hmF2 height over Millstone Hill station. It has been shown that vibrationally excited N₂ and O₂ molecules almost do not influence the formation of the winter anomaly under the conditions of low solar activity. A difference between the influence of electronically excited O⁺ on N _e ions under winter and summer conditions forms not more than 11% of the N _e winter anomaly event in the F ₂ layer and topside ionosphere. The model without electronically excited O⁺ ions reduces the duration of the N _e winter anomaly event. It has been shown that the seasonal variations in the composition of the neutral atmosphere form mainly the NmF2 winter anomaly event over the Millstone Hill radar at low solar activity.