Assessment of nitrate contamination of Lidder catchment Kashmir, India

Nitrate contamination in the groundwater from various sources is one of the major problems of water resources in Liddercatchment, Kashmir. Systematic sampling was carried out during summer 2007, with a view to understand the source of nitrate ions in the groundwater of the Lidder catchment. Twelve sample sites were selected and samples were taken for a baseline study to understand the geochemistry of the groundwater and to assess the overall physico-chemical characteristics. Results showed that NO ₃ ^? concentration in ranged from 18.72?mg/L to 75.93?mg/L with an average of 47.03?mg/L. More than 80% (83.33%) of the samples collected from various sampling stations had nitrate concentrations exceeding the threshold value of 20?mg/L, and 58.33% of the samples collected had nitrate concentrations higher than 50?mg/L, the maximum acceptable nitrate concentration for drinking water. There is a wide spatial variation in the nitrate concentration in the groundwater. Monitoring the water quality of various sampling stations showed that the lowest concentrations of nitrate were found in the wet season (January, February, and December), while the highest concentrations were found in the dry season (August, September). Numerous human perturbations have been detected affecting the water quality of Lidder catchment. Disposal of sewage and animal wastes was found to contribute about 85% of total nitrate pollution in the study area. Based on the trend analysis (using previous data), future scenario of nitrate pollution has been predicted in the study area. The results of this study are useful to highlight one of the most important environmental problems, namely the degradation of the water quality, and may serve to alert and encourage local and national authorities to take substantial steps and actions to protect and manage water quality.     

Modeling groundwater quality in an agriculturally used water catchment

The sulfate pollution in an agriculturally used watershed has been investigated with respect to the transport in the saturated zone and the development of sulfate in the unsaturated zone. Besides of other sources such as acid wet and dry deposition or sulfate input by agricultural activities, most of the sulfate originates from oxidation of pyrite by either NO₃ or O₂. High sulfate concentrations coincided with high nitrate leaching caused by plowing of former grassland or by vegetable crop residues and with former wet lands that have become dry. By using soil water concentration data and maps showing the extension of former wetlands and grassland as well as agricultural land use, it was possible to delineate regions of high sulfate input. The transport of sulfate in the aquifer was analyzed with a modified version of the USGS MOC model, which takes into account the nonlinearity of the underlying equation describing unconfined groundwater flow. The calibration of the transport model showed good agreement between the estimated and modeled sulfate input rates. A prediction of future sulfate concentrations in the aquifer was feasible by using worst-case parameters.     

Soil and groundwater quality with reference to nitrate in a semiarid agricultural region

Nitrate is a common pollutant in surface water and groundwater of agricultural areas. It is essential to monitor this pollutant in groundwater, especially when it is used for drinking purposes without treatment. The present study was carried out in an intensively irrigated area which forms a part of Nalgonda district, Andhra Pradesh, India where groundwater meets all the water needs of the rural population living in this area. The objective was to assess the spatiotemporal variation in the concentration of nitrate in groundwater and soil. Based on the analysis of 496 groundwater samples collected from 45 wells over a period of 2 years from March 2008 to January 2010 by sampling every 2 months, it was observed that groundwater in 242 km² of the total 724 km² area had nitrate above the maximum permissible limit of 45 mg/l for drinking purposes. Nitrate concentration in groundwater showed a positive relation with potassium, chloride, and sulfate, indicating their source from fertilizers. Reasons for the high concentration of nitrate in domestic areas were the dumping of animal wastes and leakage from septic tanks. The pH of the soil samples showed that most of the area had basic soil. Apart from pH, organic carbon, available phosphorous, available potassium, ammoniacal nitrogen, and nitrate nitrogen were also analyzed in the 97 soil samples.     

Distribution of nitrate in groundwater affected by the presence of an aquitard at an agricultural area in Chiba, Japan

Geological and geographical parameters including land use, stratigraphic structure, groundwater quality, and N- and O-isotopic compositions of nitrate in groundwater were investigated to elucidate the mechanism of groundwater pollution by NO₃ ^? in the agricultural area of Katori, Chiba, Japan. An aquitard distributed in the western part of the study area has produced two unconfined aquifers. The average concentrations of NO₃ ^? and dissolved oxygen (DO) were high in the aquifer above the aquitard (7.5 and 7.6 mg/L, respectively) and in the aquifer of the eastern part of the study area that was not influenced by the aquitard (11.9 and 7.8 mg/L, respectively); however, the levels in the aquifer under the aquitard were relatively low (2.2 and 3.7 mg/L, respectively). The δ¹⁵N and δ¹⁸O values of NO₃ ^? generally increased exponentially in the groundwater that flowed into the aquifer under the aquitard as the concentration of NO₃ ^? decreased, although this decrease in NO₃ ^? also occasionally occurred without isotopic changes. These results indicated that the aquitard prevented the penetration of NO₃ ^?, DO, and gaseous O₂. Under the aquitard, denitrification and dilution with unpolluted water that entered from natural forested areas reduced the NO₃ ^? concentrations in the groundwater. The major sources of NO₃ ^? in groundwater in the study area were estimated to be NH₄-chemical fertilizer, livestock waste, and manure.     

Assessment of suspended particulate pollution in the Bhadra River catchment,Southern India: an environmental magnetic approach

Open-cast mining generates sediment in river systems at globally significant scales. One of the challenges in attributing measured sediment loads to upstream mining activities is establishing the source of sediments that are a mixture of natural and mining-based materials. The environmental magnetic data (mass-specific magnetic susceptibility, anhysteretic remanent magnetisation, isothermal remanent magnetisation and inter-parametric ratios) on 57 samples of suspended sediment from the Bhadra River in the Sahyadri (the Western Ghat) of India have been used in this study. Samples were collected upstream, adjacent to and downstream of Kudremukh, a mountainous and high rainfall site where the largest mechanised open-cast mine in south Asia was located. Graphical and multivariate analyses and modelling of the data show that on average ~29% of the river suspended load downstream of the mine is derived from mining and allied activities at Kudremukh although the mine occupies less than 5% of the catchment. The contribution of primary ore is the maximum (18%), followed by transitional hard weathered ore (7%) and weathered ore (4%). The model has done a fairly good job of unmixing; the sum of errors is <1 for 40 samples, 1–4,254 for five samples and >71,000 for four samples. Modelling of samples with small mass seems to produce large errors. This investigation demonstrates the utility of environmental magnetic data, which can be obtained in a simple and rapid manner, and the unmixing of such data in identifying the contribution of mining activities to the total suspended sediment load.     

Flow and patterns of nitrate pollution in groundwater: a case study of an agricultural area in Tsukuba City, Japan

A numerical simulation was applied to first characterize the groundwater flow and patterns of nitrate pollution of a small-agricultural catchment in Tsukuba City, Japan, for a 10-year period. There was a good performance of the flow simulation. In contrast, although the transport model calculated the evolution of the plume, it only provided estimates of solute concentrations. Groundwater contamination increased exponentially during the first 594 days of the simulation, reaching then a near-equilibrium state. Fertilizer applications are responsible for most of the leaching of NO₃⁻ to groundwater, therefore, shifting of crops and the associated agricultural practices may translate into decreases of contamination levels. A series of hypothetical scenarios demonstrated that replacing grasslands by other crops may reduce the contamination levels up to 12%. As the chosen field is a representative of many other agricultural areas in Japan, the approach and results should also be applicable to similar cases around the country.     

Modeling effects of nitrate from non-point sources on groundwater quality in an agricultural watershed in Prince Edward Island, Canada

Intensification of potato farming has contaminated groundwater with nitrate in many cases in Prince Edward Island, Canada, which raises concerns for drinking water quality and associated ecosystem protection. Numerical models were developed to simulate nitrate-N transport in groundwater and enhance understanding of the impacts of farming on water quality in the Wilmot River watershed. Nitrate is assumed non-reactive based on δ¹⁵N and δ¹⁸O in nitrate and geochemical information. The source functions were reconstructed from tile drain measurements, N budget and historical land-use information. The transport model was calibrated to long-term nitrate-N observations in the Wilmot River and verified against nitrate-N measurements in two rivers from watersheds with similar physical conditions. Simulations show groundwater flow is stratified and vertical flux decreases exponentially with depth. While it would take several years to reduce the nitrate-N in the shallow portion of the aquifer, it would take several decades or even longer to restore water quality in the deeper portions of the aquifer. Elevated nitrate-N concentrations in base flow are positively correlated with potato cropping intensity and significant reductions in nitrate-N loading are required if the nitrate level of surface water is to recover to the standard in the Canadian Water Quality Guidelines.     

Using of neural networks for the prediction of nitrate groundwater contamination in rural and agricultural areas

As a neural network provides a non-linear function mapping of a set of input variables into the corresponding network output, without the requirement of having to specify the actual mathematical form of the relation between the input and output variables, it has the versatility for modeling a wide range of complex non-linear phenomena. In this study, groundwater contamination by nitrate, the ANNs are applied as a new type of model to estimate the nitrate contamination of the Gaza Strip aquifer. A set of six explanatory variables for 139 sampled wells was used and that have a significant influence were identified by using ANN model. The Multilayer Perceptrons (MLP), Radial Basis Function (RBF), Generalized Regression Neural Network (GRNN), and Linear Networks were used. The best network found to simulate Nitrate was MLP with six input nodes and four hidden nodes. The input variables are: nitrogen load, housing density in 500-m radius area surrounding wells, well depth, screen length, well discharge, and infiltration rate. The best network found had good performance (regression ratio 0.2158, correlation 0.9773, and error 8.4322). Bivariate statistical test also were used and resulting in considerable unexplained variation in nitrate concentration. Based on ANN model, groundwater contamination by nitrate depends not on any single factor but on the combination of them.     

Fluoride incidence in groundwater in an area of Peninsular India

Groundwater samples were collected from Anantapur District, Andhra Pradesh, India. The district is mainly underlain by Peninsular Gneisses of Archaean age. The samples were analysed for fluoride (F^–) along with other chemical parameters. The results suggest that the main sources of F^– in groundwater in the district are the country rocks, in which fluorine is strongly absorbed in soils consisting of clay minerals. A strong positive correlation between F^– and lithogenic sodium reflects weathering activity. This is responsible for the leaching of F^–, which is also caused by the semi-arid climate and intensive irrigation in the area. An alkaline environment of circulating water in the investigated area mainly facilitates leaching of F^– from the soils, contributing to high F^–-containing groundwater. A longer residence time of water in the aquifer zone, caused by a high rate of evapotranspiration and a weathered zone of low hydraulic conductivity, which promotes the dissolution of fluorine-bearing minerals, is another factor that further increases the F^– content in groundwater. Suggestions are made to improve groundwater quality and, thus, the health status of the population.     

Integration of monthly water balance modeling and nutrient load estimation in an agricultural catchment

Non-point sources pollution has become a serious environmental problem in the aquatic systems throughout the world. The Xitiaoxi catchment is located in the southwest of Taihu Basin, contributing large amounts of runoff and associated nutrients to Taihu Lake. Thus, identifying critical non-point sources pollution in this catchment is urgent and essential to control water pollution, improve the water quality, and reduce the pollutants drained into water bodies. The present study integrated a monthly water balance model with the export coefficient model for total nitrogen and total phosphorus loads estimation in the Xitiaoxi catchment in southeastern China. The simulated monthly runoff are in good agreement with the observed streamflow at both Hengtangcun and Fanjiancun stations with Nash?CSutcliffe coefficients higher than 0.80. The predictions showed reasonable ranges from 1687 to 2046?t/y (2002?C2005) for total nitrogen loads, and from 106 to 157?t/y for total phosphorus loads (1999?C2007), respectively, which are consistent with the observed values at Hengtangcun. Overall, the monthly export coefficient model coupling monthly water balance simulation to export coefficient model presented both the seasonal dynamics and magnitude for streamflow and nutrients loads, which generally match well with the observations. These findings demonstrate that the proposed model can provide encouraging results and can be used as an efficient tool to identify the pollution sources for planning and management of large-scale agricultural catchment.     

A study on hydrochemical elucidation of coastal groundwater in and around Kalpakkam region, Southern India

The chemical composition of 29 bore well water samples throughout the Kalpakkam region, South India, was determined to identify the major hydrogeochemical processes and the suitability of groundwater for domestic and irrigation purposes. The hydrochemical data were analyzed with reference to World Health Organization (WHO) standards and their hydrochemical facies were determined. The Piper plot shows that most of the groundwater samples fall in the field of mixed calcium–sodium–bicarbonate type followed by sodium–chloride, calcium–bicarbonate and mixed calcium–magnesium–chloride water types. The concentration of total dissolved solids exceeds the desirable limit in about 14% of samples; alkalinity values exceed the desirable limit in about 34% of the samples. The concentration of sulphate is well within the desirable limit at all the locations. The dominance of various heavy metals in the groundwater followed the sequence: Zn > Fe > Mn > Cu > Ni > Pb > Cr > Cd. Among the metal ions, the concentration of chromium and cadmium are within the permissible limit. Data are plotted on the US Salinity Laboratory diagram, which illustrates that most of the samples fall in the field of high salinity and low sodium hazard, which can be used to irrigate salt tolerant and semi-tolerant crops under favorable drainage conditions. Based on the analytical results, chemical indices like sodium adsorption ratio and residual sodium carbonate were calculated which show that most of the samples are good for irrigation.     

Estimating surface runoff and groundwater recharge in an urban catchment using a water balance approach

Hydrogeology Journal - Land-use changes often have significant impact on the water cycle, including changing groundwater/surface-water interactions, modifying groundwater recharge zones, and...     

Geochemical characterization of groundwater from an arid region in India

A study on the geochemical processes in arid region of western India (Kachchh district) was carried out using major, minor, trace metal data and isotopic composition (δ²H, δ¹⁸O) of groundwaters. Results indicate that the distribution of chemical species in groundwater of this district is controlled by leaching of marine sediments, dissolution of salts in root zone and incongruent dissolution of carbonate minerals. Common inorganic contaminants such as fluoride, nitrate and phosphate are within drinking water permissible limits. However, most of the samples analyzed contain total dissolved salts more than desirable limits and fall in doubtful to unsuitable category with regard to irrigational purpose. Trace metal data indicates no contamination from toxic elements such as arsenic and lead. An increased salt content is observed in groundwater at shallower depths indicating mixing with surface water sources. The chemical characteristics of the groundwater have found to be strongly dependent on the local lithological composition. Environmental isotopic data indicates that the groundwater is of meteoric origin and has undergone limited modification before its recharge. The processes responsible for observed brackishness are identified using chemical and isotope indicators, which are in agreement with subsurface lithology and hydrochemistry. These data though represent hydrochemical scenario of 2001 can still be used for understanding the long-term fluctuations in water chemistry and would be quite useful for the planners in validating groundwater quality models.     

Evaluation of groundwater vulnerability in the lower Varuna catchment area,Uttar Pradesh,India using AVI concept

Groundwater vulnerability assessments calculate the sensitivity of quality of groundwater to an imposed contaminant load which is essential element of the aquifer management plans. Seventy five groundwater samples have been analyzed for different chemical parameters to understand the groundwater quality of the lower Varuna river basin, Uttar Pradesh, India. The intrinsic groundwater vulnerability map of the lower Varuna catchment area in the north of the city of Varanasi (India) shows a high dependency on the depth to groundwater. The topmost layer of alluvial silty clay, protects the groundwater against contamination in this urban area, but the retention time in the unsaturated zone can be estimated to several months only. The input dataset is very sparse i.e. groundwater levels were measured twice (pre- and post-monsoon 2009) and the geological map shows only alluvium as the outcrop. Several boreholes in this area show, that the alluvium has a thickness of about 4 m and below that are fine grained sands. The surface information does not allow the development of a risk map since land use changes very fast and contamination areas can not be identified accurately. The vulnerability maps developed in this study have become important tools for environmental planning and predictive management of the groundwater resources in the fast urbanizing region in the Varanasi area.     

Identification and evolution of hydrogeochemical processes in the groundwater environment in an area of the Palar and Cheyyar River Basins,Southern India

The Palar and Cheyyar River Basins in Tamil Nadu state of Southern India are characterised by different geological formations, and groundwater is the major source for domestic, agricultural and other water-related activities. Hydrogeochemical studies were carried out in this area with the objective of identifying the geochemical processes and their relation to groundwater quality. Groundwater samples were collected once a month from 43 groundwater wells in this area from January 1998 to July 1999. Sampling procedures and chemical analysis were carried out as per the standard methods. Chemical data are used for mathematical calculations and graphical plots to understand the chemical process and its relation to the groundwater quality. The chemical composition of groundwater in the central part of the study area mainly depends on the recharge from lakes and the river, which is explained by a mixing mechanism. In addition, weathering of silicate minerals controls the concentration of major ions such as sodium, calcium, magnesium and potassium in the groundwater of this area. Further, the activity ratios indicate that the groundwater is in equilibrium with kaolinite, smectite and montmorrillonite. The reverse ion exchange process controls the concentration of calcium, magnesium and sodium in hard rock formations, and dissolution of carbonate minerals and accessory minerals is the source of Ca and Mg, in addition to cation exchange in the sedimentary formations. In general, the chemical composition of the groundwater in this area is influenced by rock–water interaction, dissolution and deposition of carbonate and silicate minerals, ion exchange, and surface water interactions.     

Deep groundwater circulation in Hercynian basement

Observations in deep drillholes reveal slow but extensive movement of crustal fluids. Geothermal observables and their interpretation by modelling heat- and mass-transfer yield flow-rates and penetration depths of deep groundwater circulation. As examples, two sites in Hercynian terranes are examined: 1) northern Switzerland and 2) KTB (Kontinentales Tiefbohrprogramm) in Germany. Flow rates are of the order of liters per square meter per year for both sites; depth of penetration is different (5 km and 0.5 km, respectively). Received: 3 September 1996 / Accepted: 17 December 1996     

Evaluation of groundwater monitoring network of Kodaganar River basin from Southern India using entropy

A discrete entropy-based approach is used to assess the groundwater monitoring network that exists in Kodaganar River basin of Southern India. Since any monitoring system is essentially an information collection system, its technical design and evaluation require a quantifiable measure of information and this measure can be derived using entropy. The use of information-based measures of groundwater table shows that the existing monitoring network contains a sufficient number of wells but is not well designed for the measurement of groundwater level. Entropy-based results show that 15 wells are vital to measure regional groundwater level, not 28 wells which are being monitored effectively in this basin.     

Groundwater nitrate contamination and risk assessment in an agricultural area,South Korea

The nitrate of groundwater in the Gimpo agricultural area, South Korea, was characterized by means of nitrate concentration, nitrogen-isotope analysis, and the risk assessment of nitrogen. The groundwaters belonging to Ca–(Cl + NO₃) and Na–(Cl + NO₃) types displayed a higher average NO₃ ⁻ concentration (79.4 mg/L), exceeding the Korean drinking water standard (<44.3 mg/L NO₃ ⁻). The relationship between δ¹⁸O–NO₃ ⁻ values and δ¹⁵N–NO₃ ⁻ values revealed that nearly all groundwater samples with δ¹⁵N–NO₃ ⁻ of +7.57 to +13.5‰ were affected by nitrate from manure/sewage as well as microbial nitrification and negligible denitrification. The risk assessment of nitrate for groundwater in the study area was carried out using the risk-based corrective action model since it was recognized that there is a necessity of a quantitative assessment of health hazard, as well as a simple estimation of nitrate concentration. All the groundwaters of higher nitrate concentration than the Korean drinking water standard (<44.3 mg/L NO₃ ⁻) belonged to the domain of the hazard index <1, indicating no health hazard by nitrate in groundwater in the study area. Further, the human exposure to the nitrate-contaminated soil was below the critical limit of non-carcinogenic risk.     

The use of nitrate, bacteria and fluorescent tracers to characterize groundwater recharge and contamination in a karst catchment, Chongqing, China

The Qingmuguan subterranean river system is located in the suburb of Chongqing, China, and it is the drinking water source that local people downstream rely on. The study aims to provide a scientific basis for groundwater protection in that area, using a hydrogeological framework, tracer tests, hydrological online monitoring, and hydrochemical and microbiological investigation, including heterotrophic plate count (HPC) and the analysis of denitrifying bacteria (DNB) and nitrobacteria (NB). The tracer tests proved simple and direct connections between two important sinkholes and the main springs, and also proved that the underground flows here are fast and turbulent. DNB and NB analyses revealed that the main recharge to the underground river in the dry season is the soil-leached water passing through the fissures of the epikarst, while in the rainy season, it is the surface water flow through sinkholes. The hydrochemical and microbiological data confirmed the notable impact of agriculture and sewage on the spring water quality. In the future, groundwater protection here should focus on targeted vulnerability mapping that yields different protection strategies for different seasons.