The early Paleozoic carbon cycle

A review of O, C, Sr and S isotope trends for the entire Phanerozoic shows that the present-day values of isotope signals are similar to those at the Proterozoic termination. The sharp rise in ⁸⁷Sr/⁸⁶Sr since 65 Ma has been attributed to an uplift and subsequent metamorphism and erosion associated with the Himalayas and Tibet. This orogenic evolution has been postulated to have influenced the global organic and inorganic carbon cycles and climate as well. A similar large-scale orogeny, the Pan-African event, also dominated the Neoproterozoic (Vendian) times, and the similarity of modern and Neoproterozoic isotope values for seawater may therefore have had a comparable tectonic cause. In this contribution, we present the results of a numerical model of the coupled C–alkalinity–S–Sr cycles suggesting that the early Paleozoic (from early Cambrian to late Devonian) evolution of Sr, O, C and S seawater isotope signals could have been the consequence of progressive oxidation of a large reduced carbon reservoir exhumed during the Pan-African orogeny. The δ¹⁸O measured in brachiopod shells is used as a forcing of the model, postulating that any change in the oxygen isotopic composition of seawater is the result of a disequilibrium in the organic carbon subcycle through the coupling of the oxygen isotopic and carbon cycles. The calculated δ¹³C, ⁸⁷Sr/⁸⁶Sr and δ³⁴S are in good agreement with the data, as is the reasonable calculated history for atmospheric pCO₂ and its relation to global climate.     

Relationship of Avalonian and Cadomian terranes to Grenville and Pan-African events

Suturing of the supercontinent Rodinia in the Grenville event (˜ 1000 Ma) was followed by rifting in the late Proterozoic (˜ 800-700 Ma), reorganization to Gondwana in the Pan-African (˜ 700-500 Ma) and further accretion to develop Pangea at the end of the Paleozoic. One of the Rodinian rifts followed part of the Grenville suture, it produced the margin of eastern North America and southern Baltica and the contrasting margin of west Gondwana in present South America. The Paleozoic accretionary wedge against the Grenville-age margin of North America and Baltica contains Avalonian/Cadomian terranes that exhibit Pan-African erogenic events ± sediments apparently developed while the terranes were in or near Gondwana. These terranes carry lower-Paleozoic fauna (Acado-Baltic) that are not indigenous to North America and Baltica.U---Pb zircon ages range from 1500-1000 Ma in Grenville terranes and from 800–500 Ma with minor inheritance in Avalonian terranes; they are generally much older in Cadomian terranes, implying very little resetting during Pan-African events. T_DM ages are generally 2000–1200 Ma in Grenville terranes, 1300–600 Ma in Avalonian terranes and 2000–1200 in Cadomian terranes. These summary data show that: (1) the Grenville orogenic event produced almost no juvenile crust; (2) the Avalonian terranes of North America contain crust that evolved primarily in the late Proterozoic, possibly as a mixture of juvenile Pan-African material and Grenville or slightly older material; (3) the Cadomian terranes of Europe consist of old (middle-Proterozoic to Archean) crust with minor juvenile Pan-African material. The Avalonian terranes apparently evolved near, and partly on, the Grenville-age crust now in South America during the intense orogeny associated with rotation of Gondwana away from North America. The Cadomian terranes of Europe, however, appear to be fragments of other parts of Gondwana, probably West Africa.     

Petrochemistry of sandstones from Neoproterozoic basins of the Bastar craton, Central Indian Shield: Implications for paleoweathering, provenance and tectonic history

Petrographic analysis and chemical analysis of major and trace elements including rare earth elements of the Neoproterozoic sandstones from the Chandarpur Group and the Tiratgarh Formation have been carried out to determine their provenance, tectonic setting and weathering conditions. All sandstone samples are highly enriched in quartz but very poor in feldspar and lithic fragments. Petrographically and geochemically these sandstones are classified as subarkose, sublitharenite and arenite. The Chemical Index of Alteration (CIA mean 68) and Th/U ratios (mean 4.2) for these sandstones suggest their moderate weathering nature. Generally, all sandstone samples are strongly depleted in major elements (except SiO₂), trace elements (except Zr) and REE in comparison with Post Archean Australian Shale (PAAS) and Upper Continental Crust (UCC). Their mineralogy and mean of elemental ratios suitable for determination of provenance and tectonic setting, e.g. Al₂O₃/SiO₂ (0.02), K₂O/Na₂O (10), Eu/Eu* (0.67), (La/Lu)n (10.4), La/Sc (3), Th/Sc (1.2), La/Co (0.22), Th/Co (0.08), and Cr/Th (7.2), support a felsic source and a passive margin tectonic setting for these sandstones. Also these key elemental ratios do not show much variation over a range of SiO₂. Thus we attest their significance in determining source rock characteristics of quartz rich sandstones. Chondrite‐normalized REE patterns with LREE enrichment and a strong negative Eu anomaly are also attributed to felsic source rock characteristics for these sandstones. The source rocks identified are granite and gneiss of the Bastar craton. Minor amounts may have been derived from older supracrustals of the Bastar craton. However, the major element data of the Paleoproterozoic Sakoli schists when compared with those of the Neoproterozoic sandstones indicate that the schists were derived from a mafic source and deposited in an active continental margin tectonic setting. There is, however, little difference in CIA values between the Paleoproterozoic Sakoli schists and Neoproterozoic sandstones, indicating prevailing of similar (moderate‐intense) weathering conditions throughout the Proterozoic in the Bastar craton. Our study also suggests a change in the provenance and tectonic setting of deposition of sediments from dominantly a mafic source and an active continental margin in the Paleoproterozoic to dominantly granite and gneiss (felsic source) and a passive continental margin in the Neoproterozoic in the Bastar craton.     

闽西晚白垩世红层的古环境探究

中国东南地区白垩纪红层通常被认为是陆相红色碎屑沉积物,是河流湖泊相沉积,但其古环境存在争论.本文以闽西晚白垩世红层为研究对象,利用环境磁学、粒度、地球化学、古土壤分析等方法,选取连城(LC)和冠豸山(GZS)两个剖面,分析探讨红层的古环境.结果显示:(1)闽西红层主要以细的粉砂颗粒为主,黏土和砂含量较少,表现为粉砂和砂互层,夹有薄层细粒砂砾层;样品磁化率偏低,主要载磁矿物为硬磁性矿物赤铁矿.(2)闽西红层有较高的风化程度,是暖湿气候下的中等风化程度;轻重稀土元素分异明显,Ce元素富集,Eu元素相对亏损,与上地壳(UCC)的分配模式相似,表明沉积物经历了充分混合,物质为混合沉积产物.(3)闽西红层虽然发育了一定的古土壤,但是成壤程度不强,没有明显的古土壤粘化层(Bt)和钙积层(Bk).由此推断,闽西红层沉积物在沉积前已在源区经过相当程度的风化过程,之后经过混合动力搬运沉积在盆地,沉积后风化成壤弱.可见,红层本身并不能直接反映沉积区环境,需结合古土壤发育特征判断沉积环境特征和变化.(4)闽西晚白垩世红层表现为相对干旱半干旱的古环境,红层中主要的着色矿物赤铁矿主要形成于源区,反映了地表透水性...     

East Asian paleoclimate change in the Weihe Basin(central China)since the middle Eocene revealed by clay mineral analysis

Obtaining a continuous sedimentary record of Cenozoic East Asian paleoclimate change is key to understand the origin, evolution and driving mechanism of the East Asian monsoon and climate change. Based on the continuous Cenozoic fluvial and lacustrine sedimentary sequence in the Weihe Basin, central China, we carried out research on the content and crystal parameters of clay minerals. The paleoclimate change since the middle Eocene was reconstructed accordingly. The results show that smectite and illite are the dominant clay minerals in fluvial-lacustrine sediments of Weihe Basin. The crystallinity of illite,the chemical index of illite, the ratio of smectite to illite and chlorite decrease gradually, which indicates that chemical weathering in the Weihe River watershed stepwise weakened since the middle Eocene, under the background of a semi-arid and semi-humid climate. The formation of palygorskite may be affected by a weak diagenesis. In this case, the content of smectite and the illite crystallinity caused by the weathering in the corresponding period may be actually higher than that of the current,which indicates that the climate in the Weihe Basin region was relatively warm and humid from the middle Eocene to Pliocene.With the decrease of Cenozoic global temperature and the continuous accumulation of sediments, the intensity of chemical weathering in the Weihe Basin gradually weakened, and the East Asian monsoon climate gradually evolved until becoming dry in the Quaternary. Evidence from clay minerals also indicates that the aridification in the Weihe Basin from the late Eocene to the Oligocene may be a response to the global cooling event at the Eocene-Oligocene transition.     

Laboratory simulation of salt weathering under moderate ageing conditions: Implications for the deterioration of sandstone heritage in temperate climates

Salt weathering is a significant process affecting the deterioration and conservation of stone-built heritage in many locations and environments. While much research has focused on the impact of salt weathering under arid or coastal conditions with characteristic climatic conditions and salt types, many sites found to be experiencing salt-induced deterioration, such as sandstone rock-hewn cave temples in Gansu Province, China and sandstone buildings in the northern UK, experience high humidities, moderate temperature ranges, and different salt types. To evaluate the impact of salt weathering on sandstone-built heritage under such mild humid environmental conditions, a lab simulation experiment was designed. The experiment was carried out on three types of sandstone (used in the northern UK and Gansu Province, China) and utilized a realistic diurnal humidity and temperature cycle (85% RH/16°C + 60% RH/22°C), and three widespread damaging salts, that is, Na₂SO₄, MgSO₄, and the mixture of Na₂SO₄–MgSO₄. The nature and extent of deterioration was monitored by photography, weight loss, and the changes in petrophysical properties measured using hardness, ultrasonic pulse velocity (P-wave velocity), water absorption coefficient by capillarity, open porosity, and apparent density. All three sandstones were found to be susceptible to MgSO₄ and the mixture of Na₂SO₄–MgSO₄, but weakly affected by Na₂SO₄ under mild humid environmental conditions.     

Petrography and geochemistry of upper Triassic sandstones from the Tumengela Formation in the Woruo Mountain area,North Qiangtang Basin,Tibet: Implications for provenance,source area weathering,and tectonic setting

The petrography and major and trace element concentrations of the sandstones from the Tumengela Formation in the Woruo Mountain area, North Qiangtang Basin, are studied to determine their provenance, intensity of weathering and tectonic setting. The detrital compositions of the Tumengela sandstone samples are dominated by quartz (58.0–70.1 %, average 64.7 %) and lithic fragments (21.8–35.9 %, average 27.3 %), but low in feldspar content (4.9–12.9 %, average 8.0 %). The sandstones can be classified as litharenite and feldspathic litharenite according to their detrital compositions, which is consistent with the geochemical data. The detrital modal compositions reflect that these sandstones are probably derived from a recycled orogenic source. The index of chemical variability (ICV) and SiO₂/Al₂O₃ ratio values suggest that the compositional maturity and recycling were moderate. The weathering indices such as the chemical index of alteration (CIA), plagioclase index of alteration (PIA), chemical index of weathering (CIW), and Al₂O₃–(CaO* + Na₂O)–K₂O (A–CN–K) diagram indicate that the intensities of weathering in the source area were moderate. The Al₂O₃/TiO₂, Th/Co, La/Sc, La/Co, Th/Sc, Cr/Th ratio values and the discriminant function of the Tumengela sandstones indicate that the sediments were mainly derived from felsic source rocks, while also mixed with intermediate source rocks. The comparison of rare earth element patterns and its Eu anomalies to the probable source rocks infer that the sandstones were derived from the combination of granite, rhyolite, dacite, and gneisses. The proximal central uplift belt was probably the primary provenance area as evidenced by the petrographical and geochemical features of the Tumengela sandstones. The multidimensional tectonic discrimination diagram based on major elements show a collision setting (80 %) combined with a rift setting (20 %) for the Tumengela sandstones, which is consistent with the general geology of the study areas.     

羌北地块中-晚侏罗世雁石坪群古地磁新结果

本文报道青藏高原羌北地区中-晚侏罗世雁石坪群古地磁新结果.对采自青海省格尔木市唐古拉山乡雁石坪剖面(33.6°N, 92.1°E)11个灰岩采点(118块)和10个碎屑岩采点(99块)定向样品系统古地磁学研究表明,大部分样品的退磁曲线具有双分量特征.低温分量方向在地理坐标系下较为集中,应该为地层褶皱之后的黏滞剩磁.高温特征剩磁分量方向可分为两类:(1)索瓦组(J₃s)和布曲组(J₂b)灰岩,以磁铁矿为主要载磁矿物,高温特征剩磁分量(D_s=355.7°,I_s=42.1°,k=58.2,α₉₅=6°)可通过99%置信度的褶皱检验.(2)雪山组(J₂x)和雀莫错组(J₂q)碎屑岩,以赤铁矿、磁铁矿为主要载磁矿物,高温特征剩磁分量(D_s=3.3°,I_s=28.9°,k=30.7,α₉₅=8.9°)可通过95%置信度的倒转检验和99%置信度的褶皱检验.两组分量都应该是岩石形成时的原生剩磁信息.碎屑岩组的磁倾角比灰岩组偏低13°左右,其剩磁方向很可能存在着与压实作用相关的剩磁倾角变浅的状况.本文取灰岩组平均磁化方向作为雁石坪群的原生剩磁分量,获得羌北地区雁石坪群古磁极位置:80.0°N,295.2°E(dp/dm=7.4/4.5).古地磁结果表明,羌北-昌都地区晚石炭-晚二叠世期间位于南纬中低纬度地区,早三叠世以后开始大规模北向漂移,至中-晚侏罗世已到达24.3°N.其快速北向运动主要发生在早三叠至早侏罗世期间(3500 km左右),与现今位置相比中晚侏罗世之后的北向迁移总量为900 km左右.     

Chemical weathering since the Little Ice Age recorded in lake sediments: a high‐resolution proxy of past climate

Because of the different geochemical behaviour of rubidium and strontium in earth surface processes, variations of the Rb/Sr ratios in lake sediments were used as a geochemical proxy of chemical weathering and past climate in a single watershed. Low magnetic susceptibility, low CaCO₃, low Sr concentration and, hence, high Rb/Sr ratio in the lake sediments indicate weak chemical weathering under a cold but wet climate during the Little Ice Age (LIA) in the closed Daihai Lake watershed. The concordant change in both Sr and CaCO₃ concentrations with δ¹⁸O values in the Dunde ice core suggests that weak chemical weathering during the wet LIA was controlled by air temperature. After the LIA, however, precipitation played a dominant role in chemical weathering. Copyright © 2001 John Wiley & Sons, Ltd.     

Paleomagnetism of the western Cape Fold belt, South Africa, and its bearing on the Paleozoic apparent polar wander path for Gondwana

In order to test two different proposals for the poorly defined African Paleozoic apparent polar wander path (APWP), a paleomagnetic study was carried out on Ordovician through Carboniferous clastic sediments from the Cape Fold belt, west of the 22nd meridian. One proposal involves a relatively simple APWP connecting the Ordovician Gondwana poles in North Africa with the Late Paleozoic poles to the east of South Africa in a more or less straight line crossing the present equator in the Devonian. The other proposal adds a loop to this path, connecting Ordovician poles in North Africa with poles to the southwest of South Africa and then returning to central Africa. This loop would occur mainly in Silurian time. New results reported herein yield paleopoles in northern and central Africa for Ordovician to lowermost Silurian and Lower to Middle Devonian formations. The best determined paleopole of our study is for the Early Ordovician Graafwater Formation and falls at 28°N, 14°E (k = 25, α₉₅ = 8.8°, N = 28 samples). The other paleopoles are not based on sufficient numbers of samples, but can help to constrain the apparent polar wander path for Gondwana. Our results give only paleopoles well to the north of South Africa and we observe no directions within the proposed loop. Hence, if the loop is real, it must have been of relatively short duration (60–70 Ma) and be essentially of Silurian/Early Devonian age, implying very high drift velocities for Gondwana (with respect to the pole) during that interval.     

A Rb/Sr record of catchment weathering response to Holocene climate change in Inner Mongolia

Variation in the rubidium to strontium (Rb/Sr) ratio of the loess–palaeosol sequences has been proposed to reflect the degree of pedogenesis and weathering in the northwestern region of China. To characterize the Rb/Sr ratio of the dissolved loads of a single catchment, we analysed a 12·08 m sediment core from Daihai Lake in Inner Mongolia, north China. Dating control was provided by ²¹⁰Pb, ¹³⁷Cs and AMS‐¹⁴C. Sequential extraction experiments were conducted to investigate the concentrations of Rb and Sr on various chemical fractions in the lake sediments. Down‐core variation in the Rb/Sr ratios provides a record of Holocene weathering history. From 9 to 3·5 ka bp , accelerated chemical weathering was experienced throughout the Daihai catchment under mainly warm and humid conditions, and this reached a maximum at c. 5 ka bp . However, weathering was reduced between c. 8·25 and 7·90 ka bp , which may reflect the global 8·2 ka cooling event. After c. 2·5 ka bp , increased Rb/Sr ratios with higher frequency of fluctuations indicate reduced weathering within the Daihai catchment. The highest Rb/Sr ratios in the Little Ice Age lake sediments indicate the weakest phase of Holocene chemical weathering, resulting from a marked reduction in Sr flux into the basin. The Rb/Sr record also shows an enhancement of chemical weathering under today's climate, but its intensity is less than that of the Medieval Warm Period. Increased Rb/Sr in lake sediment corresponding to reduced catchment weathering is in striking contrast to Rb/Sr decrease in the glacial loess layers in the loess–palaeosol sequence. Copyright © 2005 John Wiley & Sons, Ltd.     

Vestiges of an Iapetan rift basin in the New Jersey Highlands: implications for the Neoproterozoic Laurentian margin

Thin, discontinuous remnants of Neoproterozoic intracratonic rift-basin deposits of the Chestnut Hill Formation occur in the western New Jersey Highlands. These deposits form an important link between well-documented Iapetan rift-basins in both the northern and southern Appalachians. The close spatial relations of Chestnut Hill rocks to Paleozoic sedimentary rocks open the possibility that additional Iapetan rift-basins could be concealed beneath the rocks of the Valley and Ridge Province to the west indicating a much broader zone of rifting than has been previously proposed. The Chestnut Hill Formation is intermittently exposed along a 100 km-long band that extends northeast from Pennsylvania nearly to New York State. The lower part of the Chestnut Hill Formation is composed of interbedded lithic pebble- to boulder-conglomerate and feldspathic sandstone grading upward into interbedded phyllite, feldspathic and quartz sandstone, local paleosaprolite, quartz-pebble conglomerate, thin limestone lenses, volcanic, and volcaniclasic rocks, abundant bedded ironstone (hematite ore), and ultimately into diamictites that are interpreted as possible tilloids and containing rounded intra and extrabasinal clasts of the other lithologies. Extensive soft-sediment deformation, cross bedding, and clastic dikes are common in all but the lowest and upper facies. Banded hematite layers occur preferentially in fine-grained tuffs and tuffaceous sediments, but hematitization has affected most lithologies. Volcanic rocks consist of altered rhyolitic tuffs and lapilli tuffs that are interbedded with sediments. The Chestnut Hill Formation is interpreted to have been deposited in early alluvial, and later a complex of fluvial, lacustrine and deltaic environments. Provenance studies based upon petrographic and geochemical analysis of clastic rocks indicate that the sediments are predominantly immature and reflect derivation from local uplifted felsic basement sources in a rifted-margin tectonic setting. Low to moderate weathering of the source rocks is indicated by the geochemistry of most samples, as is the locally intense effect of hydrothermal alteration. Most occurrences of the Chestnut Hill Formation are associated with major faults that exhibit normal movement of apparent Neoproterozoic age. Rocks from the Morgan Hill fault near Easton, Pennsylvania display consistent normal shear sense and vary from low temperature S-C mylonites to breccia that contains deformed pieces of Chestnut Hill Formation.     

Permian felsic magmatism in the Neoproterozoic Nagar Parkar Igneous Complex of the Malani Igneous Suite: Evidence from zircon U–Pb age

We report Permian (ca. 272 Ma ±5.4 Ma) felsic dykes that intrude into the Neoproterozoic (ca. 750 Ma) magmatic suite of the Nagar Parkar Igneous Complex (NPIC), the western extension of the Malani Igneous Suite (MIS). The NPIC consists of Neoproterozoic basement amphibolites and granites (riebeckite–aegirine gray granites and the biotite–hornblende pink granites), all of which are intruded by several generations of mafic and felsic dykes. Granitic magmatism occurred in the Late Neoproterozoic (ca. 750 Ma) due to the subduction‐, followed by the rift‐related tectonic regime during the breakup of the Rodinia supercontinent. U–Th–Pb zircon and monazite CHIME age data of 700–800 Ma from the earlier generation porphyritic felsic dykes suggest the dyke intrusion was coeval or soon after the emplacement of the host granites. Our findings of Permian age orthophyric felsic dykes provide new insights for the prevalence of active tectonics in the MIS during late Paleozoic. Textural features and geochemistry also make the orthophyric dykes distinct from the early‐formed porphyritic dykes and the host granites. Our newly obtained age data combined with geochemistry, suggest the existence of magmatism along the western margin of India (peri‐Gondwana margin) during Permian. Like elsewhere in the region, the Permian magmatism in the NPIC could be associated with the rifting of the Cimmerian micro‐continents from the Gondwana.     

琼东南盆地基底特征及其构造演化

本文通过处理琼东南盆地现有的重磁数据资料,得到琼东南盆地重磁特征,并采用三维Parker法进行重磁基底深度的反演,获得琼东南盆地的重力基底深度变化在1～11 km之间,磁力基底深度变化在5～11 km之间,结合地震剖面的重磁震联合反演结果和钻井资料推断琼东南盆地的基底岩性主要以酸性花岗岩和中性安山岩为主,少量陆相中生界地层.琼东南盆地的基底演化表现为早期主要与古特提斯洋的演化相关,晚期则与太平洋板块的俯冲密切相关.     

Measurements and calculations of seasonal evaporation rate from bare sandstone surfaces: Implications for rock weathering

Evaporation from porous rock plays an important role in weathering processes. In the case of salt weathering, the evaporation rate controls supersaturation of salt solutions within pores and the amount of precipitated aggressive salts, therefore weathering occurs mostly in places with intense evaporation. Evaporation also strongly affects frost, hydric and biogenic weathering, as these are influenced by water content and its temporal changes. Despite its importance, evaporation from porous rocks has seen little scientific focus. We present a study on evaporation from bare sandstone, one of the most common rocks affected by weathering. A new method that measures the evaporation rate from the surfaces of sandstone samples under field microclimate was developed and tested. Also, a simple calculation of 1D evaporation rate from bare sandstone surfaces based on Fick's law of diffusion is presented. The measurement was performed using sandstone cores (with a set depth of the vaporization plane) in a humid continental climate and measured on a roughly monthly interval for about 1 year. For the calculations, a laboratory-measured water-vapour diffusion coefficient of the sandstone, in-situ seasonally measured vaporization plane depth, and values of air humidity and temperature were used. The sensitivity analyses showed that the most important factor controlling the evaporation rate was the vaporization plane depth, while seasonal and spatial changes of air humidity and temperature were of lesser importance. The calculated evaporation rate reasonably follows measured values. For its simplicity and the small number of parameters required, the proposed method has the potential to improve knowledge of weathering and living conditions of endolithic and epilithic organisms. Further research should focus on factors affecting the evaporation rate (wind, hygroscopicity, hydrophobicity, etc.) to improve the accuracy of the calculations, as well as to test the applicability of the method for other lithologies and climates. © 2020 John Wiley & Sons, Ltd.     

Contrasting weathering and climate regimes in forested and cleared sandstone temples of the Angkor region

Comparative assessment of stone weathering intensities and bioclimatic conditions was conducted at four temples located in cleared and forested sites of the Angkor Park, based on similar protocols. Four thousand sculpted lotus petals carved in the same grey sandstone were categorized by using two customized scales of weathering intensity, and climate monitoring was conducted from December 2008 to November 2009. Whereas 70% of the sandstone lotus petals are almost completely destroyed by mechanical weathering in cleared areas, 74% of petals located in forested environments appear to be totally free of mechanical weathering and are only affected by superficial biochemical weathering. Ambient conditions are also contrasting, with the magnitude of the diurnal surface temperature and relative humidity ranges being three times higher at cleared sites than in wooded areas. As wetting–drying cycles are the driving force of sandstone decay at Angkor, causal links are suggested between weathering and climate regimes. In wooded areas, the microclimate is buffered by the forest and the associated lithobionts, which maintain constant humidity levels, reduce thermal stresses at the stone surface and induce a slow biochemical weathering regime. In cleared areas, direct exposure to sunshine and monsoon rains induces pronounced wetting–drying cycles conducive to swelling–shrinking movements and other potential processes, provoking the rapid mechanical decay of the sandstone. Even if local damage can be caused by tree roots, the forest cover and the associated lithobionts obviously play an overall protective role. Additionally, microtopographical factors related to architectural designs and post‐building events probably explain intra‐site and between site minor differences in the amount of sandstone decay, by influencing key factors such as the water residence time at the stone surface. Last, the contrasting weathering regimes in forested and cleared sites are but a trend, for besides overwhelming mechanical weathering, chemical weathering is also operative at cleared sites, as indicated by salt efflorescences and ferric oxidation. Copyright © 2012 John Wiley & Sons, Ltd.     

Petrology and geochemistry of clastic sedimentary rocks as evidences for provenance of the Late Palaeozoic Madzaringwe Formation,Tshipise-Pafuri Basin,South Africa

Petrography and geochemistry(major, trace and rare earth elements) of clastic rocks from the Late Palaeozoic Madzaringwe Formation, in the Tshipise-Pafuri Basin, Northern South Africa, have been investigated to understand their provenance. Sandstone petrography and detrital modes indicates that the Late Palaeozoic succession was derived from craton interior and recycled orogen provenance. Sandstones in the Madzaringwe Formation are sub-arkosic to sub-litharenite. The sediments may represent a recycled to craton interior provenance. The geochemical data of major elements show that sandstone and shales have the same source. The study of paleoweathering conditions based on modal composition, chemical index of alteration(CIA) and A-CN-K(Al2O3-Ca O+Na2O-K2O) relationships indicate that probably chemical weathering in the source area and recycling processes have been more important in shale and sandstone rocks. The relatively high CIA values(70–90%) indicates moderate to high weathering conditions of the samples and the paleoclimate of the source area was warm. K2O/Na2 O versus Si O2 and Na2O-Ca O-K2 O tectonic setting discrimination plots, suggest a passive continental margin. In the study of trace elements, triangular Th-Sc-Zr/10 and La-Th-Sc plots both suggest a passive margin setting of the basin. Petrographic and geochemical results of the samples suggest uplifted basement source areas dominated by sedimentary rocks and/or granite-gneiss rocks. The source rocks might have been the recycled pre-Soutpansberg Karoo Supergroup rocks and the metasedimentary rocks of the Soutpansberg Group. Other source rocks may have been the pre-Beit-Bridge basement rocks(granites and gneisses).     

Formation of a salt plume in the Coastal Plain aquifer of Israel: the Be''er Toviyya region

The formation and development of a salt plume (salinity up to 800 mg Cl 1⁻¹) in the inner part of the Coastal Plain aquifer of Israel is analyzed. Massive groundwater exploitation during the 1950s caused a large drop in the water level and formation of a hydrologic depression in the Be'er Toviyya-Kefar Warburg area. The depression reached a maximal depth during the late 1960s; thereafter a reduction in the rate of pumpage led to restoration of water levels and shallowing of the depression, until its complete disappearance towards the end of the 1980s. A spot of high salinity first appeared in 1956, following a deep drawdown in the water levels. This saline plume has been continuously expanding with increasing salinity concentrations (200–800 mg Cl 1⁻¹) in its center. The average rate of radial expansion was about 50 m year⁻¹. The expansion and salinization did not cease as the depression disappeared. Rather, equalization of water levels in wells situated within the plume area with those of situated along its margins resulted in the salinization of the latter within a period of 1 year.

Mass balances for water and chloride contents were made for the period 1967–1990. Taking into consideration the storage change, pumpage, natural replenishment and artificial recharge, the lateral inflow to the depression is estimated as 60 × 10⁶ m³. Upon addition of the chloride balance, and taking into consideration the chloride concentrations of the surrounding fresh water and the apparent possible end-member of the saline source (based on geochemical considerations), the saline inflow is estimated as (40–60) × 10⁶ m³. These estimates indicate that a large amount of saline water penetrated into the aquifer, of about half of the natural replenishment of the study area, with an estimated salinity of 1900–2700 mg Cl 1⁻¹.

It is suggested that the salt plume was formed as a result of a drop in water level combined with a flow of underlying saline water bodies from deeper strata. The chemical composition of the groundwater points to the existence of two saline water bodies of Ca-chloride composition and a marine Br/Cl ratio: (1) saline water with low Na/Cl (0.6), So₄/Cl, and B/Cl ratio; (2) saline water with higher Na/Cl (> 0.6), So₄/Cl, and B/Cl ratios. These chemical compositions resemble Ca-chloride saline waters found in other locations in the Coastal Plain aquifer and in underlying formations. The saline water bodies may occur in either pockets at the bottom of the aquifer or lumachelle and sandstone layers of high hydraulic conductivity in underlying sediments.     

Effects of aspect on weathering: anomalous behaviour of sandstone gravestones in southeast England

Rocks in the humid temperate zone tend to weather more severely on faces exposed to the prevailing winds than on their more sheltered leeward faces. In southeast England, however, gravestones composed of a non‐local, quartz‐rich sandstone exhibit a reverse weathering pattern. The east‐facing, lee sides exhibit a much greater depth and areal extent of weathering than the west sides which face the westerly wind and rain. Possible reasons for the asymmetric pattern of weathering are discussed. Copyright © 2000 John Wiley & Sons, Ltd.     

Origin of the red earth and gravel deposits in Nankou piedmont,northwestern Beijing,China

Analytic results of the mechanical and chemical composition, clay minerals, sedimentary structures and microtextures of the red earth and gravel deposits in Nankou piedmont, northwestern Beijing, China, suggest that the deposits have nothing to do with glaciation but are palaeodebris‐flow deposits. During the period of their deposition, the climate was humid and hot with plentiful rainfall, and oxidation, physical and chemical weathering were rather intense. Copyright © 2000 John Wiley & Sons, Ltd.