An experimental study in the structure of convective flows of magma melts in a complete system: Mantle chamber-intermediate chamber-volcano

A continuous interrelationship of melts in intermediate and mantle chambers is found by experiment. The interrelationship occurs due to the presence of two melt counter currents within the supply channel (conduit) of the intermediate chamber. In the upper part of the intermediate chamber horizontal rolling flows are found to go from the center to the periphery and backward horizontal flows over the entire bottom of the intermediate chamber travel from the periphery to the center (the conduit), then become an annular descending flow. Due to thermal interaction with the central ascending flow, the annular descending flow heats and becomes undersaturated relative to precipitated crystals, thus excluding encrustation of the conduit walls. The mechanism of continuous interaction between the melts in the mantle and intermediate chambers provides a quasisteady-state of the system irrespective of volcanic activity. It is thought that horizontal layering in large basic intrusives forms similarly to the described process of development and accumulation of cumulus at the bottom of the intermediate chamber.     

The Karymskii Volcanic Center: Volcanic rock geochemistry

This paper is concerned with the petrology and geochemistry of rocks found in the Karymskii Volcanic Center (KVC), which is the largest volcanic center in the Eastern volcanic belt of Kamchatka. The KVC has been built in a rhythmic manner since the Late Pliocene, forming successive differentiated rock complexes. The pattern of variation for major and minor elements in the KVC volcanic rocks can be explained by the fractionation of mineral phases from the parent melt. The process involved enrichment of the residual melts with alkalis and lithophile elements (Rb, Ba, Sr, Pb, Th, U, REE), as well as depletion in coherent elements (Ni, Cr, Sc, Ti). A geochemical study of the KVC volcanic rocks shows that these are typical island arc formations. The relationships between incompatible elements suggest a two-component magma generation system: a depleted mantle source (N-MORB) and suprasubduction fluids (an island arc component). The melt may have been contaminated by a metasomatically altered substratum in the top of the intermediate chamber with added crystalline cumulus phases (and melts) of the earlier magma generation phases in the KVC.     

The space-time relationships between volcanic associations of different alkalinities: The Belogolovskii massif in Kamchatka’s Sredinnyi Range. Part 1. The geology,mineralogy, and petrology of volcanic rocks

We proposed a geological and petrologic model for the generation of the Belogolovskii Late Pliocene to Early Pleistocene volcanic massif. We identified two petrochemical series of rocks with varying alkalinities, viz., normal and moderate. The evolution of volcanic products and the mineralogic composition of rocks of varying alkalinities provide evidence that the sources of parent magmas are spatially independent and reside at different depths. Crystallization differentiation is the leading process that is responsible for the generation of the initial melts that give rise to the range of rocks within a series. The evolution of the alkaline basaltic magma occurred stepwise, producing autonomous daughter melts with the following compositions: trachybasalt-trachyandesite-trachyte-trachyrhyolite and comendite. These melts were localized in inter-mediate magma chambers at different depths.     

Recurrent magma mingling in successive ignimbrites from Amealco caldera, central Mexico

The Amealco Tuff is a widespread (>2880 km²), trachyandesitic to rhyolitic pyroclastic deposit in the central Mexican Volcanic Belt that was erupted from the Amealco caldera at 4.7ǂ.1 Ma. It includes three major ignimbrites, each showing complex mingling of pumice fragments and matrix glass with andesitic to rhyolitic compositions. The different glasses are well mingled throughout each of the pyroclastic-flow deposits. Mingling of glasses may have occurred just before and during the explosive eruptions that produced the pyroclastic flows, as the distinct melts had insufficient time to homogenize. Mingling of glasses is evident in each of the three separate major ignimbrites of the Amealco Tuff; thus, the processes that caused it were repetitive. It is infered that the repetitive mingling of melts was due to repeated mafic magma inputs to an evolved magma chamber.     

The influence of rheologic crustal properties of the crust on the location of ore-forming hydrothermal magmatic systems

Based on a comprehensive study of hydrothermal magmatic systems at island arcs and a review of available mechanisms that cause elasto-plastic deformation in rocks, we considered the conditions for interaction between a convective magmatic cell and a convective hydrothermal cell in different rheologic zones of the crust. Three models have been developed to describe the generation of hydrothermal circulation systems: (1) the magma chamber is localized in a plastic zone, (2) partial and (3) complete penetration of the chamber into a brittle crust. It is shown that the last of these models is highly consistent with the structure of presentday high-temperature hydrothermal magmatic systems at depths greater than 1.0?C1.5 km and with the structure of Miocene to Pliocene ore-bearing volcano-plutonic complexes that are eroded to different depths in different geologic blocks within these complexes.     

The imprint of basalt on the geochemistry of silicic magmas

We propose that the fluid mechanics of magma chamber replenishment leads to a novel process whereby silicic magmas can acquire an important part of their chemical signatures. When flows of basaltic magma enter silicic magma chambers, they assume a ‘fingered' morphology that creates a large surface area of contact between the two magmas. This large surface area provides an opportunity for significant chemical exchange between the magmas by diffusion that is enhanced by continuous flow of silicic liquid traversing the basalt through thin veins. A quantitative analysis shows that a basaltic magma may thereby impart its trace-element and isotopic characteristics to a silicic magma. Depending on concentration differences and diffusion coefficients for the given components, this new mechanism may be as important as crystal fractionation and assimilation in producing the compositional diversity of silicic magmas. It may explain concentration gradients in silicic ash-flow tuffs and should be considered when interpreting the isotopic signatures of silicic rocks, even in the overt absence of mixing. For example, we show that, for several well studied, compositionally graded ash-flow tuffs, the concentrations and isotopic ratios of important geochemical tracers such as strontium could be largely due to this flow-enhanced diffusion process.     

Along-strike magma mixing beneath mid-ocean ridges: effects on isotopic ratios

The effects of mixing processes on the isotopic variability of mid-ocean ridge basalts are studied. The processes considered are porous flow dispersion and convective mixing in magma chambers. Porous flow dispersion is capable of mixing magmas over distances of only a few tens of meters. Convective mixing, on the other hand, is found to produce mixing over scales of kilometers to hundreds of kilometers. Calculations of convective mixing are carried out for continuous magma chambers, where mixing is limited by convective processes, and for discontinuous chambers, where mixing is limited by chamber size. Preliminary comparison of our calculations with observations along the mid-ocean ridges shows that the calculations are consistent with the existence of a correlation between bathymetry and isotopic ratio at long, but not at short, wavelengths. They are also capable of explaining a decrease in isotopic variability with increasing spreading rate.     

Evolution of double diffusion convection in a felsic magma chamber

The onset of double diffusion convection (DDC) is modeled in a two-dimensional case in respect to magma chambers. The viscosity model for the melt takes into account the effects of temperature and concentration of the dissolved component (H₂O). The upper boundary of the convecting magma chamber is assumed to be anhydrous and at constant temperature, whereas the lower boundary is treated as being hydrous permeable with a temperature greater than that within the upper boundary. The case of positive compositional and thermal buoyancy of melt is studied assuming a H₂O diffusion coefficient small in comparison with thermal diffusivity. The DDC has been modeled using a system of equations solved by the finite difference method on a square grid. The convective pattern evolution has been studied for fixed boundary conditions as well as for cooling and degassing. Due to the higher viscosity in the upper zone, the upper boundary layer is thicker than the lower one. The variation of water concentration in this zone of the convective cell can be significant. In nature, the high gradient of water concentration can be responsible for the observed variations of water content in minerals crystallized from a granite melt (e.g., biotite). Because of a high Lewis number (= 100), temperature variations in the magma chamber decay much faster than the water concentration. In this case the intensive convection can continue at a constant temperature due to the non-zero water content in the chamber. In principle, the effect can be applied to the formation of magmatic bodies. If the cooling and degassing system reaches a uniform temperature distribution prior to the crystallization temperature, water content throughout the body may still remain variable.     

Geodetic data shed light on ongoing caldera subsidence at Askja, Iceland

Subsidence within the main caldera of Askja volcano in the North of Iceland has been in progress since 1983. Here, we present new ground- and satellite-based deformation data, which we interpret together with new and existing micro-gravity data, to help understand which processes may be responsible for the unrest. From 2003 to 2007, we observe a net micro-gravity decrease combined with subsidence and from 2007 to 2009 we observe a net micro-gravity increase while the subsidence continues. We infer subsidence is caused by a combination of a cooling and contracting magma chamber at a divergent plate boundary. Mass movements at active volcanoes can be caused by several processes, including water table/lake level movements, hydrothermal activity and magma movements. We suggest that, here, magma movement and/or a steam cap in the geothermal system of Askja at depth are responsible for the observed micro-gravity variations. In this respect, we rule out the possibility of a shallow intrusion as an explanation for the observed micro-gravity increase but suggest magma may have flowed into the residing shallow magma chamber at Askja despite continued subsidence. In particular, variable compressibility of magma residing in the magma chamber as well as compressibility of the surrounding rock may be the reason why this additional magma did not create any detectable surface deformation.     

Variation of volatile concentration in a magma system of Satsuma-Iwojima volcano deduced from melt inclusion analyses

Chemical analyses of 30 melt inclusions from Satsuma-Iwojima volcano, Japan, were carried out to investigate volatile evolution in a magma chamber beneath the volcano from about 6300 yr BP to the present. Large variations in volatile concentrations of melts were observed. (1) Water concentration of rhyolitic melts decreases with time; 3–4.6 wt.% at the time of latest caldera-forming eruption of Takeshima pyroclastic flow deposit (ca. 6300 yr BP), 3 wt.% for small pyroclastic flow (ca. 1300 yr BP) of Iwodake, post-caldera rhyolitic dome, and 0.7–1.4 wt.% for submarine lava eruption (Showa-Iwojima) in 1934. (2) Rhyolitic melts of the Takeshima and Iwodake eruptions contained CO₂ of less than 40 ppm, while the Showa-Iwojima melt has higher CO₂ concentration of up to 140 ppm. (3) Water and CO₂ concentrations of basaltic to andesitic melt of Inamuradake, a post-caldera basaltic scoria cone, are 1.2–2.8 wt.% and ≤290 ppm, respectively.Volatile evolution in the magma chamber is interpreted as follows: (1) the rhyolitic magma at the time of the latest caldera-forming eruption (ca. 6300 yr BP) was gas-saturated due to pressure variation in the magma chamber because the large variation in water concentration of the melt was attributed to exsolution of volatile in the magma prior to the eruption. Iwodake eruption (ca. 1300 yr BP) was caused by a remnant of the caldera-forming rhyolitic magma, suggested from the similarity of major element composition between these magmas. (2) Volatile composition of the Showa-Iwojima rhyolitic melt agrees with that of magmatic gases presently discharging from a summit of Iwodake, indicating the low pressure degassing condition. (3) The degassing of the magma chamber by magma convection in a conduit of Iwodake during non-eruptive but active degassing period for longer than 800 years decreased water concentration of the rhyolitic magma. (4) Geological and petrological observations indicate that a stratified magma chamber, which consists of a lower basaltic layer and an upper rhyolitic layer, might have existed during the post-caldera stage. Addition of CO₂ from the underlying basaltic magma to the upper gas-undersaturated (degassed) rhyolitic magma increased CO₂ concentration of the rhyolitic magma.     

Variations in column height and magma discharge during the May 18, 1980 eruption of Mount St. Helens

Peak eruption column heights for the B1, B2, B3 and B4 units of the May 18, 1980 fall deposit from Mount St. Helens have been determined from pumice and lithic clast sizes and models of tephra dispersal. Column heights determined from the fall deposit agree well with those determined by radar measurements. B1 and B2 units were derived from plinian activity between 0900 and about 1215 hrs. B3 was formed by fallout of tephra from plumes that rose off pyroclastic flows from about 1215 to 1630 hrs. A brief return to plinian activity between 1630 and 1715 hrs was marked by a maximum in column height (19 km) during deposition of B4.Variations in magma discharge during the eruption have been reconstructed from modelling of column height during plinian discharge and mass-balance calculations based on the volume of pyroclastic flows and coignimbrite ash. Peak magma discharge occurred during the period 1215–1630 hrs, when pyroclastic flows were generated by collapse of low fountains through the crater breach. Pyroclastic flow deposits and the widely dispersed co-ignimbrite ash account for 77% of the total erupted mass, with only 23% derived from plinian discharge.A shift in eruptive style at noon on May 18 may have been associated with increase in magma discharge and the eruption of silicic andesite mingled with the dominant mafic dacite. Increasing abundance of the silicic andesite during the period of highest magma discharge is consistent with the draw-up and tapping of deeper levels in the magma reservoir, as predicted by theoretical models of magma withdrawal. Return to plinian activity late in the afternoon, when magma discharge decreased, is consistent with theoretical predictions of eruption column behavior. The dominant generation of pyroclastic flows during the May 18 eruption can be attributed to the low bulk volatile content of the magma and the increasing magma discharge that resulted in the transition from a stable, convective eruption column to a collapsing one.     

La transition augite-diopside et les liquides silicatés intra-cristallins dans les pyroclastes de l’activité actuelle du Stromboli: témoignages de la réinjection et du mélange magmatiques

Refilling of undifferentiated magma at high temperature in the shallow chamber of Stromboli volcano induces both partial gas release of the crystallizing shoshonic liquid and a beginning of melting of salite-augite megacrysts in equilibrium with the liquid. In the new magma, crystallization of pyroxenes resumes with a chrome-diopside composition. The study of silicate melts inclusions in pyroxenes reveals the importance of refilling processes in the evolution products stored in the magma reservoir.     

Eruptive history of Mount Mazama and Crater Lake Caldera, Cascade Range, U.S.A.

New investigations of the geology of Crater Lake National Park necessitate a reinterpretation of the eruptive history of Mount Mazama and of the formation of Crater Lake caldera. Mount Mazama consisted of a glaciated complex of overlapping shields and stratovolcanoes, each of which was probably active for a comparatively short interval. All the Mazama magmas apparently evolved within thermally and compositionally zoned crustal magma reservoirs, which reached their maximum volume and degree of differentiation in the climactic magma chamber 7000 yr B.P.The history displayed in the caldera walls begins with construction of the andesitic Phantom Cone 400,000 yr B.P. Subsequently, at least 6 major centers erupted combinations of mafic andesite, andesite, or dacite before initiation of the Wisconsin Glaciation 75,000 yr B.P. Eruption of andesitic and dacitic lavas from 5 or more discrete centers, as well as an episode of dacitic pyroclastic activity, occurred until 50,000 yr B.P.; by that time, intermediate lava had been erupted at several short-lived vents. Concurrently, and probably during much of the Pleistocene, basaltic to mafic andesitic monogenetic vents built cinder cones and erupted local lava flows low on the flanks of Mount Mazama. Basaltic magma from one of these vents, Forgotten Crater, intercepted the margin of the zoned intermediate to silicic magmatic system and caused eruption of commingled andesitic and dacitic lava along a radial trend sometime between 22,000 and 30,000 yr B.P. Dacitic deposits between 22,000 and 50,000 yr old appear to record emplacement of domes high on the south slope. A line of silicic domes that may be between 22,000 and 30,000 yr old, northeast of and radial to the caldera, and a single dome on the north wall were probably fed by the same developing magma chamber as the dacitic lavas of the Forgotten Crater complex. The dacitic Palisade flow on the northeast wall is 25,000 yr old. These relatively silicic lavas commonly contain traces of hornblende and record early stages in the development of the climatic magma chamber.Some 15,000 to 40,000 yr were apparently needed for development of the climactic magma chamber, which had begun to leak rhyodacitic magma by 7015 ± 45 yr B.P. Four rhyodacitic lava flows and associated tephras were emplaced from an arcuate array of vents north of the summit of Mount Mazama, during a period of 200 yr before the climactic eruption. The climactic eruption began 6845 ± 50 yr B.P. with voluminous airfall deposition from a high column, perhaps because ejection of 4−12 km³ of magma to form the lava flows and tephras depressurized the top of the system to the point where vesiculation at depth could sustain a Plinian column. Ejecta of this phase issued from a single vent north of the main Mazama edifice but within the area in which the caldera later formed. The Wineglass Welded Tuff of Williams (1942) is the proximal featheredge of thicker ash-flow deposits downslope to the north, northeast, and east of Mount Mazama and was deposited during the single-vent phase, after collapse of the high column, by ash flows that followed topographic depressions. Approximately 30 km³ of rhyodacitic magma were expelled before collapse of the roof of the magma chamber and inception of caldera formation ended the single-vent phase. Ash flows of the ensuing ring-vent phase erupted from multiple vents as the caldera collapsed. These ash flows surmounted virtually all topographic barriers, caused significant erosion, and produced voluminous deposits zoned from rhyodacite to mafic andesite. The entire climactic eruption and caldera formation were over before the youngest rhyodacitic lava flow had cooled completely, because all the climactic deposits are cut by fumaroles that originated within the underlying lava, and part of the flow oozed down the caldera wall.A total of 51−59 km³ of magma was ejected in the precursory and climactic eruptions, and 40−52 km³ of Mount Mazama was lost by caldera formation. The spectacular compositional zonation shown by the climactic ejecta — rhyodacite followed by subordinate andesite and mafic andesite — reflects partial emptying of a zoned system, halted when the crystal-rich magma became too viscous for explosive fragmentation. This zonation was probably brought about by convective separation of low-density, evolved magma from underlying mafic magma. Confinement of postclimactic eruptive activity to the caldera attests to continuing existence of the Mazama magmatic system.     

Temporal variations in magma composition at Merapi Volcano (Central Java, Indonesia): magmatic cycles during the past 2000 years of explosive activity

Merapi Volcano (Central Java, Indonesia) has been frequently active during Middle to Late Holocene time producing basalts and basaltic andesites of medium-K composition in earlier stages of activity and high-K magmas from 1900 ¹⁴C yr BP to the present. Radiocarbon dating of pyroclastic deposits indicates an almost continuous activity with periods of high eruption rates alternating with shorter time spans of distinctly reduced eruptive frequency since the first appearance of high-K volcanic rocks. Geochemical data of 28 well-dated, prehistoric pyroclastic flows of the Merapi high-K series indicate systematic cyclic variations. These medium-term compositional variations result from a complex interplay of several magmatic processes, which ultimately control the periodicity and frequency of eruptions at Merapi. Low eruption rates and the absence of new influxes of primitive magma from depth allow the generation of basaltic andesite magma (56–57 wt% SiO₂) in a small-volume magma reservoir through fractional crystallisation from parental mafic magma (52–53 wt% SiO₂) in periods of low eruptive frequency. Magmas of intermediate composition erupted during these stages provide evidence for periodic withdrawal of magma from a steadily fractionating magma chamber. Subsequent periods are characterised by high eruption rates that coincide with shifts of whole-rock compositions from basaltic andesite to basalt. This compositional variation is interpreted to originate from influxes of primitive magma into a continuously active magma chamber, triggering the eruption of evolved magma after periods of low eruptive frequency. Batches of primitive magma eventually mix with residual magma in the magmatic reservoir to decrease whole-rock SiO₂ contents. Supply of primitive magma at Merapi appears to be sufficiently frequent that andesites or more differentiated rock types were not generated during the past 2000 years of activity. Cyclic variations also occurred during the recent eruptive period since AD 1883. The most recent eruptive episode of Merapi is characterised by essentially uniform magma compositions that may imply the existence of a continuously active magma reservoir, maintained in a quasi-steady state by magma recharge. The whole-rock compositions at the upper limit of the total SiO₂ range of the Merapi suite could also indicate the beginning of another period of high eruption rates and shifts towards more mafic compositions.     

The intensity of plinian eruptions

Peak intensities (magma discharge rate) of 45 Pleistocene and Holocene plinian eruptions have been inferred from lithic dispersal patterns by using a theoretical model of pyroclast fallout from eruption columns. Values range over three orders of magnitude from 1.6 × 10⁶ to 1.1 × 10⁹ kg/s. Magnitudes (total erupted mass) also vary over about three orders of magnitude from 2.0 × 10¹¹ to 6.8 × 10¹⁴ kg and include several large ignimbrite-forming events with associated caldera formation. Intensity is found to be positively correlated with the magnitude when total erupted mass (tephra fall, surges and pyroclastic flows) is considered. Initial plinian fall phases with intensities in excess of 2.0 × 10⁸ kg/s typically herald the onset of major pyroclastic flow generation and subsequent caldera collapse. During eruptions of large magnitude, the transition to pyroclastic flows is likely to be the result of high intensity, whereas the generation of pyroclastic flows in small magnitude eruptions may occur more often by reduction of magmatic volatile content or some transient change in magma properties. The correlation between plinian fall intensity and total magnitude suggests that the rate of magma discharge is related to the size of the chamber being tapped. A simple model is presented to account for the variation in intensity by progressive enlargement of conduits and vents and excess pressure at the chamber roof caused by buoyant forces acting on the chamber as it resides in the crust. Both processes are fundamentally linked to the absolute size of the pre-eruption reservoir. The data suggest that sustained eruption column heights (i.e. magma discharge rates) are indicators of eventual eruption magnitude, and perhaps eruptive style, and thus are key parameters to monitor in order to assess the temporal evolution of plinian eruptions.     

Origin of silicic volcanic rocks in Central Costa Rica: a study of a chemically variable ash-flow sheet in the Tiribí Tuff

Chemical heterogeneities of pumice clasts in an ash-flow sheet can be used to determine processes that occur in the magma chamber because they represent samples of magma that were erupted at the same time. The dominant ash-flow sheet in the Tiribí Tuff contains pumice clasts that range in composition from 55.1 to 69.2 wt% SiO₂. It covers about 820 km² and has a volume of about 25 km³ dense-rock equivalent (DRE). Based on pumice clast compositions, the sheet can be divided into three distinct chemical groupings: a low-silica group (55.1-65.6 wt% SiO₂), a silicic group (66.2-69.2 wt% SiO₂), and a mingled group (58.6-67.7 wt% SiO₂; all compositions calculated 100% anhydrous). Major and trace element modeling indicates that the low-silica magma represents a mantle melt that has undergone fractional crystallization, creating a continuous range of silica content from 55.1-65.6 wt% SiO₂. Eu/Eu*, MREE, and HREE differences between the two groups are not consistent with crystal fractionation of the low-silica magma to produce the silicic magma. The low-silica group and the silicic group represent two distinct magmas, which did not evolve in the same magma chamber. We suggest that the silicic melts resulted from partial melting of relatively hot, evolved calc-alkaline rocks that were previously emplaced and ponded at the base of an over-thickened basaltic crust. The mingled group represents mingling of the two magmas shortly before eruption. Electronic supplementary material to this paper can be obtained by using the Springer LINK server located at http://dx.doi.org/10.1007/s00445-001-0188-8.     

A resurgent cauldron in the early Paleozoic of Wales, U.K.

The paper presents a controversial interpretation of a mid-Ordovician volcano-sedimentary complex. It deals with the cyclic interdependence of intrusive, volcanic, and sedimentary processes, due to the development of a nearshore resurgent cauldron in the Caledonian fold belt of North Wales. Deformed volcanotectonic features include a resurgent dome and apical graben, surrounded by a moat and peripheral crescentic ring-fault, constituting a caldera 20 km in diameter. The resurgent Snowdon caldera developed through three cycles of ash-flow volcanism resulting from the continuous supply of magma into a shallow magma chamber emplaced beneath the floor of a marine basin. Each ash-flow cycle was preceded by the emergence, above sea level, of a geotumour that subsequently collapsed following eruption and evacuation of the magma chamber. Localized unconformities at the base of individual ash-flow cycles are compared with caldera margin and associated collapse features. Deeper-seated effects of caldera collapse are expressed as gaps in the Ordovician sequence due to normal faulting along the structural boundary of the caldera. Major ash-flow fissure vents were located at points of maximum unloading of the magma chamber by distention faults in its roof. Explosive mechanisms were triggered by rapid pressure release due to tectonic erosion.The presence of a resurgent cauldron implies that the Ordovician succession of North Wales is more complete than recorded in the literature, and that Caledonian structures were largely predetermined by Caradocian volcano-tectonics.     

Density variation amongst mid-ocean ridge basalts: Implications for magma mixing and the scarcity of primitive lavas

Densities calculated from glass compositions of observed mid-ocean ridge basalts show that the more primitive melts are likely to be buoyant in more evolved melts. Consideration of this and other physical properties indicates that convective mixing between most basaltic magmas occurs under intermittently turbulent to turbulent conditions (transitional Reynolds Numbers) accounting for the widespread occurrence of hybrid lavas. Hypothetical picritic melts inferred to be parental to mid-ocean ridge basalts are by contrast denser than most basalts erupted on the sea floor. The most primitive basalts observed to erupt occupy a density minimum when compared to more primitive and more fractionated melts. The density minimum occurs approximately at those compositions where plagioclase and/or pyroxene join olivine as major fractionating phases. Picritic basalts are rarely erupted, because they stratify at the base of magma reservoirs.     

Cumulate nodules as evidence for convective fractionation in a phonolite magma chamber

The physical mechanism by which chemical zonation develops in magma chambers has been controversial partly because unambiguous geological constraints have been lacking. The 11,000 years B.P. eruption of Laacher See Volcano produced a zoned tephra deposit and also ejected crystal-rich nodules which provide a snapshot of the materials crystallising at the magma chamber margins. New data on petrography and chemical compositions of nodules, their cumulate minerals and interstitial glasses are used to deduce the chemical evolution of the phonolite melt due to fractional crystallisation of the mineral assemblages. These data, together with those on the vertical zonation of the melt in the bulk of the chamber, are shown to be consistent with a model of stratification of the chamber by convective fractionation, in which a thin boundary layer of residual melt from fractional crystallisation ascends at the chamber side and accumulates at the roof. Crystallisation could have provided buoyancy to drive convection by enriching incompatible volatile components (mainly water) in the residual melt. Available fluid dynamic studies of single- and double-diffusive boundary layers are used to assess convection in the Laacher See chamber. The boundary layer is likely to have been: (1) laminar, which implies that the density gradient in the chamber steepened upwards; (2) in the counterflow regime, in which compositional and thermal layers flow in opposite directions; and (3) thin ( 10 cm), estimated from theory for a flat wall, suggesting that wall morphology could be important in determining boundary layer characteristics. Estimates of mass transfer rates due to this mechanism suggest that the chamber could have become stratified in a time of the order of 10³ years.     

Olivine basalts at the Karymskii Volcanic Center: Mineralogy, petrogenesis, and magma sources

The olivine basalts of the Karymskii Volcanic Center (KVC) can be traced during the history of the area from the Lower Pleistocene until recently (the 1996 events); they are typical low-and moderate-potassium tholeiite basalts of the geochemical island-arc type. We have investigated the compositions of phenocryst minerals represented by plagioclase, olivine, clinopyroxene, as well as solid-phase inclusions of spinel in olivine, and more rarely in anorthite. The evolutionary trends of the rock-forming minerals provide evidence of the comagmaticity of these basalts, and thus of a long-lived intermediate magma chamber in the interior of the structure. The activity of this chamber is related to periodic transport of high temperature basalt melts to the surface. The geochemistry of the basalts is controlled by their origin at the same depleted magma source close to N-MORB, by successive crystallization of the primary melt, and by restricted mixing with magma components that are crystallizing at different depths. It is hypothesized that the solid-phase inclusions of high alumina spinel (hercynite?) found in olivine (and anorthite) of the basalts in the KVC north sector are of relict origin.