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1.
During an almost three months long expedition in the Arctic Ocean, the Beringia 2005, dissolved gaseous mercury (DGM) was measured continuously in the surface water. The DGM concentration was measured using an equilibrium system, i.e. the DGM in the water phase equilibrated with a stream of gas and the gas was thereafter analysed with respect to its mercury content. The DGM concentrations were calculated using the following equation, DGM = Hgeq / kH' where Hgeq is the equilibrated concentration of elemental mercury in the gas phase and kH' is the dimensionless Henry's law constant at desired temperature and salinity. During the expedition several features were observed. For example, enhanced DGM concentration was measured underneath the ice which may indicate that the sea ice acted as a barrier for evasion of mercury from the Arctic Ocean to the atmosphere. Furthermore, elevated DGM concentrations were observed in water that might have originated from river discharge. The gas-exchange of mercury between the ocean and the atmosphere was calculated in the open water and both deposition and evasion were observed. The measurements showed significantly enhanced DGM concentrations, compared to more southern latitudes.  相似文献   

2.
Mercury speciation and its distribution in surface and deep waters of the Mediterranean Sea were studied during two oceanographic cruises on board the Italian research vessel URANIA in summer 2003 and spring 2004 as part of the Med Oceaneor and MERCYMS projects. The study included deep water profiles of dissolved gaseous Hg (DGM), reactive Hg (RHg), total Hg (THg), monomethyl Hg (MeHg) and dimethyl Hg (DMeHg) in open ocean waters. Average concentrations of measured Hg species were characterized by seasonal and spatial variations. Overall average THg concentrations ranged between 0.41 and 2.65 pM (1.32 ± 0.48 pM) and were comparable to those obtained in previous studies of the Mediterranean Sea. A significant fraction of Hg was present as “reactive” Hg (average 0.33 ± 0.32 pM). Dissolved gaseous Hg (DGM), which consists mainly of Hg0, represents a considerable proportion of THg (average 20%, 0.23 ± 0.11 pM). The portion of DGM typically increased towards the bottom, especially in areas with strong tectonic activity (Alboran Sea, Strait of Sicily, Tyrrhenian Sea), indicating its geotectonic origin. No dimethyl Hg was found in surface waters down to the depth of 40 m. Below this depth, its average concentration was 2.67 ± 2.9 fM. Dissolved fractions of total Hg and MeHg were measured in filtered water samples and were 0.68 ± 0.43 pM and 0.29 ± 0.17 pM for THg and MeHg respectively. The fraction of Hg as MeHg was in average 43%, which is relatively high compared to other ocean environments. The concentrations reported in this study are among the lowest found in marine environments and the quality of analytical methods are of key importance. Speciation of Hg in sea water is of crucial importance as THg concentrations alone do not give adequate data for understanding Hg sources and cycling in marine environments. For example, photoinduced transformations are important for the presence of reactive and elemental mercury in the surface layers, biologically mediated reactions are important for the production/degradation of MeHg and DGM in the photic zones of the water column, and the data for DGM in deep sea indicate the natural sources of Hg in geotectonicaly active areas of the Mediterranean Sea.  相似文献   

3.
In situ experiments using isotopically labeled mercury species (199Hg(II) and Me201Hg) are used to investigate mercury transformation mechanisms, such as methylation, demethylation and reduction, in coastal and marine surface waters of the Mediterranean Sea. The aim of this work is to assess the relative contribution of photochemical versus biological processes to Hg transformation mechanisms. For this purpose, potential transformation rates measured under diurnal and dark incubation conditions are compared with major biogeochemical parameters (i.e. hydrological and biological data) in order to obtain the relative contribution of various biotic and abiotic mechanisms in both surface (high light) and bottom (low light) waters of the euphotic zone. The results demonstrate that coastal and marine euphotic zones are significant reactors for all Hg transformations investigated (i.e. methylation, demethylation, reduction). A major outcome demonstrates that Hg methylation is taking place in oxic surface seawater (0.3–6.3% day− 1) and is mainly influenced by pelagic microorganism abundance and activities (phyto- and bacterioplankton). This evidences a new potential MeHg source in the marine water column, especially in oligotrophic deep-sea basins in which biogeochemistry is mostly governed by heterotrophic activity. For coastal and marine surface waters, although MeHg is mainly photochemically degraded (6.4–24.5% day− 1), demethylation yields observed under dark condition may be attributed to microbial or chemical pathways (2.8–10.9% day− 1). Photoreduction and photochemical reactions are the major mechanisms involved in DGM production for surface waters (3.2–16.9% day− 1) but bacterial or phytoplanktonic reduction of Hg(II) cannot be excluded deeper in the euphotic zone (2.2–12.3% day− 1). At the bottom of the euphotic zone, photochemical processes are thus avoided due to the attenuation of UV-visible sunlight radiation allowing biotic processes to be the most significant. These results suggest a new potential route for Hg species cycling in surface seawater and especially at the maximum biomass depth located at the bottom of the euphotic zone (i.e. maximum chlorophyll fluorescence). In this environment, DGM production and demethylation mechanisms are thus probably reduced whereas Hg methylation is enhanced by autotrophic and heterotrophic processes. Experimental results on mercury species uptake during these investigations further evidenced the strong affinity of MeHg for biogenic particles (i.e. microorganisms) that correspond to the first trophic level of the pelagic food web.  相似文献   

4.
Dissolved gaseous mercury (DGM) was measured continuously using two newly developed techniques and a manual technique. The continuous techniques were based on the equilibrium between the aqueous and gaseous phase (DGM = Hgextr / H', Hgextr is the measured mercury concentration in the gas phase, H' is the Henry's Law coefficient at the desired temperature). In order to calculate the annual mercury evasion from the Mediterranean Sea, diurnal and seasonal measurements of DGM, total gaseous mercury in air (TGM), water temperature and wind speed were performed. During August 2003, March–April 2004 and October–November 2004 measurements of these parameters were conducted on board the RV Urania. The continuous measurements of DGM showed a diurnal variation in concentration, at both coastal and off shore sites, with higher concentrations during daytime than nighttime. The concentration difference could be as large as 130 fM between day and night. The degree of saturation was calculated directly from the measurements, S = Hgextr / TGM and was found to vary between the different seasons. The highest average degree of saturation (850%) and the largest variation in saturation (600–1150%) was observed during the summer. The spring showed the lowest variation (260–360%) and the lowest average degree of saturation (320%). The autumn also showed a large variation in saturation (500–1070%) but a lower average (740%) compared to the summer cruise. This might be explained by the temperature difference between the different seasons, since that parameter varied the most. The flux from the sea surface was calculated using the gas exchange model developed by Nightingale et al. [Nightingale, P.D., Malin, G., Law, C.S., Watson, A.J., Liss, P.S., Liddicoat, M.I., Boutin, J., Upstill-Goddard, R. C., 2000. In situ evaluation of air–sea gas exchange parameterization using novel conservative and volatile tracers. Global Biogeochemical Cycles, 14(1):373–387]. The evasion varied between the different seasons with the highest evasion during the autumn, 24.6 pmol m− 2 h− 1. The summer value was estimated to 22.3 pmol m− 2 h− 1 and the spring to 7.6 pmol m− 2 h− 1. Using this data the yearly evasion from the Mediterranean Sea surface was estimated to 77 tons.  相似文献   

5.
Dissolved gaseous mercury (DGM) was measured continuously using two newly developed techniques and a manual technique. The continuous techniques were based on the equilibrium between the aqueous and gaseous phase (DGM = Hgextr / H', Hgextr is the measured mercury concentration in the gas phase, H' is the Henry's Law coefficient at the desired temperature). In order to calculate the annual mercury evasion from the Mediterranean Sea, diurnal and seasonal measurements of DGM, total gaseous mercury in air (TGM), water temperature and wind speed were performed. During August 2003, March–April 2004 and October–November 2004 measurements of these parameters were conducted on board the RV Urania. The continuous measurements of DGM showed a diurnal variation in concentration, at both coastal and off shore sites, with higher concentrations during daytime than nighttime. The concentration difference could be as large as 130 fM between day and night. The degree of saturation was calculated directly from the measurements, S = Hgextr / TGM and was found to vary between the different seasons. The highest average degree of saturation (850%) and the largest variation in saturation (600–1150%) was observed during the summer. The spring showed the lowest variation (260–360%) and the lowest average degree of saturation (320%). The autumn also showed a large variation in saturation (500–1070%) but a lower average (740%) compared to the summer cruise. This might be explained by the temperature difference between the different seasons, since that parameter varied the most. The flux from the sea surface was calculated using the gas exchange model developed by Nightingale et al. [Nightingale, P.D., Malin, G., Law, C.S., Watson, A.J., Liss, P.S., Liddicoat, M.I., Boutin, J., Upstill-Goddard, R. C., 2000. In situ evaluation of air–sea gas exchange parameterization using novel conservative and volatile tracers. Global Biogeochemical Cycles, 14(1):373–387]. The evasion varied between the different seasons with the highest evasion during the autumn, 24.6 pmol m− 2 h− 1. The summer value was estimated to 22.3 pmol m− 2 h− 1 and the spring to 7.6 pmol m− 2 h− 1. Using this data the yearly evasion from the Mediterranean Sea surface was estimated to 77 tons.  相似文献   

6.
Determination of the actual mercury concentration in Mediterranean basin seawater was achieved by means of an instrument based on fluorescence spectrometry developed for this purpose, during a field study aboard the oceanographic ship “L.F. Marsili”, between August 1980 and May 1982.Dissolved ·total’ and ·reactive’ mercury and mercury associated with particulate matter were determined on surface and subsurface waters in the Tyrrhenian Sea from La Spezia to Sicily.Concentrations in the range 1.4–19.7 ng l−1 for ·total dissolved mercury’, 0.5–5.9 ng l−1 for ·reactive dissolved mercury’ and 0.3–8.0 ng l−1 for mercury associated with the particulate matter, were measured on surface and subsurface waters in the Tyrrhenian Sea from La Spezia to Sicily.Even if the mean value of the total mercury concentration (dissolved + particulate) was found to be about twice as high as those observed for the oceans, the difference does not seem to be as high as predicted by the model proposed by Buffoni and co-workers to explain the large difference of mercury levels between tunas caught, respectively, in the Mediterranean and in the Oceans.  相似文献   

7.
《Marine Geology》1999,153(1-4):137-146
Cyclical fluctuations in planktic foraminiferal assemblages have been recognized in the pre-evaporitic Messinian in a marginal basin of the western Mediterranean. The fluctuations coincide with a dominantly precession-controlled sedimentary cyclicity (sapropels). During sapropel deposition, high planktic foraminiferal diversities are indicative of relatively stable marine conditions, while during homogeneous marl deposition low diversities seem to indicate the presence of unfavourable, more saline surface water conditions. The dominance of a precession-related signal indicates that regional climate oscillations rather than (obliquity-related) glacio-eustatically controlled influxes of Atlantic and/or Mediterranean waters are responsible for the faunal fluctuations and sedimentary cyclicity. Our scenario links the persistence of normal marine conditions during sapropel formation with increased rainfall and run-off along the western Mediterranean at times that perihelion occurred in Northern Hemisphere summer. Less favourable, highly saline surface water conditions prevailed during periods of drier climate induced by opposite precessional extremes. The cyclical oceanographic fluctuations could also have governed periodic reef growth along the margins.  相似文献   

8.
Correlations between daily fish settlement and environmental and physical parameters were examined during two consecutive years in two labrid species (Symphodus roissali and Symphodus ocellatus) in the NW Mediterranean Sea. Both these species have a short planktonic larval duration (12±0.3 and 9±0.4 days, respectively) and limited offshore larval dispersal. Time-series analysis was used to compare the daily settlement patterns with various environmental variables, and non-linear generalized additive models (GAM) were used to examine the relationship between environmental conditions averaged over larval period and daily settlement patterns. Settlement was not uniform and took place as pulses of different length. Although the analyses detected a few significant correlations between day-to-day patterns in environmental variables and settlement (e.g. solar radiation, atmospheric pressure, daytime or nocturnal wind components), these were not consistent among years. In S. ocellatus, however, wind components (daytime or nighttime) explained part of the variance in settlement intensity. The correlations (GAM outputs) observed between settlement patterns and environmental variables (averaged during the whole planktonic period) suggest that calm weather during the planktonic period usually increases settlement success.  相似文献   

9.
Water temperature, salinity, nutrient concentrations and the composition of the plankton community were recorded at three stations in inner Tokyo Bay over a period of 328 days (from June 8, 1995 to April 30, 1996) with a nominal sampling frequency of once per day. Inspection of the results revealed that the data could be divided into two blocs as an aid to analysis: the period from June to October was characterized by the development of stratification of temperature and salinity (stratification period), and November to March was characterized by uniform temperature and salinity in the water column due to vertical mixing (mixing period). Oxygen-depleted water forms in the bottom layer during the stratification period, but vertical mixing of the water column, due to changing wind and rainfall conditions caused by passing weather fronts, results in the breakdown of the oxygen-depleted water mass. Nutrient loads are high in the surface water due to the freshwater supply, but occasional pulses of primary production cause a depletion of phosphate in the surface water, suggesting that the phosphorus becomes a limiting nutrient for phytoplankton growth in this period. Several short-term peaks of plankton abundance (blooms) occurred as responses to temporal changes in water quality from June to November, with consequent species succession. Significant fluctuations in the densities of the diatom Skeletonema costatum and several species of ciliates corresponded to the daily changes in the physical and chemical characteristics of the coastal environment. During the mixing period, when water temperature and solar radiation decreased, there were no short-term variations in water quality and although nutrient concentrations gradually increased from November to February, primary production remained low. This study shows that the short-term dynamics of the phytoplankton community are closely coupled to fluctuations in environmental forcing, and that the degree of coupling is stronger during periods when solar radiation is greater. The results provide a novel typological understanding of seasonal plankton dynamics in a shallow, eutrophicated marine embayment, and suggest how such systems may be treated in simulation modeling.  相似文献   

10.
In Tokyo Bay the concentrations of dissolved gaseous mercury (DGM) in the surface seawater and total gaseous mercury (TGM) over the sea were measured during December 2003, October 2004 and January 2005. Based on these data, the evasional fluxes of mercury from the sea surface were estimated using a gas exchange model. In addition, an automatic wet and dry deposition sampler was used to measure the wet and dry depositional fluxes of mercury from December 2003 to November 2004 at three locations in and near Tokyo Bay. The results indicate that the average DGM and TGM levels of seven locations are 52 ± 26 ng m−3 and 1.9 ± 0.6 ng m−3, respectively, which shows that the surface seawater in Tokyo Bay is supersaturated with gaseous mercury, leading to an average mercury evasional flux of 140 ± 120 ng m−2d−1. On the other hand, the annual average wet and dry depositional fluxes of mercury at three locations were 19 ± 3 μg m−2yr−1 and 20 ± 9 μg m−2yr−1, respectively. These depositional fluxes correspond to the daily average total depositional flux of 110 ± 20 ng m−2d−1. Thus, it is suggested that in Tokyo Bay, the evasional fluxes of mercury are comparable to the depositional fluxes.  相似文献   

11.
针对海水养殖中水质、气象参数的自动监测和预警需求, 采用YSI 600R 多参数水质仪和TRM-ZS2 型自动气象站作为养殖现场水质和气象参数在线监测仪, 结合GPRS 无线传输技术和信息处理技术, 设计开发了海水养殖多环境因子在线监测系统。该系统可在线、连续地对水温、酸碱度、溶解氧含量、盐度4 个水质参数以及风速、气压、太阳辐射、雨量4 个气象参数进行测量, 并提供了养殖自动预警功能。系统能实时对海水养殖风险的潜在因子进行监测, 可解决采用人工方式无法满足大规模、集约化海水养殖环境因子监测需要的问题。  相似文献   

12.
Total and reactive mercury concentrations have been measured on samples of surface water taken along the shores of the Bay of Biscay and in the Gironde Estuary. In the low turbid areas of the Bay of Biscay the average concentration of total mercury of unfiltered samples is 3.5 ± 0.7 (n = 15) and the reactive mercury 2.1 ± 0.7 (n = 12) pmol l−1; the high levels, up to 27.6 (total mercury) and 4.6 (reactive mercury) pmol l−1 are from the most turbid samples taken from the Marennes-Oléron basin. In the Gironde Estuary, the distribution of total dissolved mercury rises to a peak of concentration (38 pmol l−1) within the high turbidity zone where the salinity is lower than 10‰. The possible origin of this pattern of distribution is discussed.  相似文献   

13.
青岛地区太阳紫外线辐射研究   总被引:12,自引:0,他引:12  
通过对青岛地区2004年全年紫外线观测数据的分析,在预设局地纬度、海拔高度、大气中臭氧量及其分布、空气质量状况、地表反照率等因素基本不变的情况下,总结了青岛地区紫外辐射随与太阳天顶角相关的不同季节和时段、天气状况(云况)的统计性变化规律,以服务于该地区人们日常生活中对紫外线的防护,尤其是为调光生态膜的研制及改善提供参考。  相似文献   

14.
辽东湾冰季太阳辐射分析   总被引:11,自引:1,他引:11  
利用渤海辽东湾JZ20-2石油平台上的气象和海冰观测数据,研究了冰季大气层和云层对太阳辐射的影响,结果表明,辽东湾冰季大气光学可取为0.83,碧空、少云、多云阴天、雾天和雨雪等不同天气条件下的云量系数可分别取为0、3、6、8、9和10。分析了冰水混合情况下海面对太阳辐射的反射情况;讨论了太阳辐射对冰面长波辐射和对流传热的影响。利用冰面太阳辐射的实测值和计算结果,对整个冰季内太阳辐射的规律进行了分析  相似文献   

15.
《Marine Geology》1999,153(1-4):57-75
Reconstructions with comprehensive estimates of confidence intervals are presented of changes in the W–E stable oxygen isotope gradient in Mediterranean surface waters between the Holocene Climate Optimum and the Present, and between the Last Glacial Maximum and the Present. Rigorous statistical assessment is made of the significances of the mean geographic trends observed in these reconstructions. Firstly, it is concluded that any reconstruction should strictly be based on values obtained by analyses of one single foraminiferal species throughout the basin, as different species are found to respond with isotopic variations of different amplitudes to climatic/hydrographic change. This difference is tentatively related to differences between the habitats and seasons of growth of the various species. Secondly, a significant increase of roughly a factor 3 is found in the Mediterranean W–E oxygen isotope gradient during the Last Glacial Maximum, relative to the Present. This difference is almost entirely due to increased glacial values in the Levantine Sea, which are considered to be a result of a combination of increased evaporation rates and/or somewhat cooler than anticipated surface water conditions. Thirdly, an eastward increase of roughly half the present-day magnitude is found for the W–E oxygen isotope gradient during the Holocene Climate Optimum. Values in the Levantine Sea appear to have undergone up to 0.3‰ more depletion than those elsewhere in the eastern Mediterranean. However, no significant trends are found between the eastern and western parts of the Levantine Sea, nor between values near the Nile delta and those from elsewhere in the Levantine Sea. The Holocene Climate Optimum's eastward increase in the Mediterranean oxygen isotope gradient, although weaker than the Present, suggests that the Mediterranean continued to function as a concentration basin, albeit in a less vigorous way than today. Finally, simple mixing arguments are used to argue that inferred oxygen isotope ratios of surface waters may not be used as an indication of conservative property (e.g. salinity) distribution on geological timescales, but instead show amplitudes of response to climatic/hydrographic changes that likely are >2 times larger than the corresponding amplitudes of response for truly conservative properties.  相似文献   

16.
渤海海面太阳辐照强度的观测分析与计算方法研究   总被引:8,自引:2,他引:8  
对渤海海面(1998-09-24~10-07和1999-04-28~05-11)实测太阳辐射日总量同云量的关系和春、秋季的对比关系及其与插值计算出的晴日太阳辐射日总量的关系进行了分析,并同烟台(福山)测站的结果进行了对比分析.通过分析发现,渤海海面太阳辐射日总量春季远大于秋季,其无云条件下的太阳辐射日总量与插值计算出的晴日太阳辐射日总量的差异秋季大于春季.分析表明,海陆温差引起的海面大气垂直输送与水汽物的产生是造成这种差异的主要原因.采用经验公式对渤海海面太阳辐射日总量进行计算,计算结果与实测结果具有较好的一致性.结果表明所用经验公式及推算出的参数适合于春、秋季渤海海面太阳辐照度的计算.  相似文献   

17.
18.
Downward particle fluxes and hydrodynamics in the northwestern Mediterranean basin were measured by a sediment trap and a current meter deployed at 2350 m depth, 250 m above bottom, from November 2003 to April 2005. During the winter of 2003–2004 there were high river discharges, two strong E–SE storms and several moderate storms and short periods of moderate dense shelf-water cascading during which dense shelf water did not reach the deep basin. Downward particle fluxes at the basin site were low during most of this winter but increased above one order of magnitude as a consequence of the strong storm and moderate cascading event that occurred in late February 2004. During the winter of 2004–2005, neither important river floods nor strong storms occurred but there were very intense and persistent dense shelf-water cascading events from February to April 2005. Dense shelf water, mixed with offshore convection water, reached the basin site in early March 2005, increasing downward particle fluxes by more than two orders of magnitude for more than 1 month. These observations indicate that events of significant sediment transport to the northwestern Mediterranean basin can be caused by severe winter E–SE storms associated with moderate cascading events or by exceptionally intense and persistent dense shelf-water cascading episodes alone. On the other hand, river floods, severe storms during water column stratification conditions (without cascading) and moderate storms concurrent with moderate dense shelf-water cascading did not generate sediment transport events able to reach the basin.  相似文献   

19.
《Marine Geology》1999,153(1-4):77-89
The sediments of the eastern Mediterranean basin contain Corg-enriched layers (sapropels) interbedded with the Corg-poor sediments which form by far the greater part of the record. While it is generally appreciated that different surface ocean productivity and bottom water conditions are necessary for the formation and preservation of these two sediment types, less attention has been paid to diagenetic effects which are an expected consequence of transitions between dramatically different bottom water oxygenation levels. A geochemical interpretation has emerged of post-depositional oxidation of the most recent sapropel (S1), initially based on the relationship of the Mn, Fe, Corg and S concentration/depth profiles observed around S1, and the characteristic shapes of these elemental profiles known from other situations. This indicates that post-depositional oxidation has removed approximately half of the visual evidence of the sapropel (∼6 cm from a total of ∼12 cm in the deep basin). The oxidation interpretation from redox-sensitive element redistribution profiles has subsequently been consolidated with evidence from pore water (O2, NO3, Mn2+ and Fe2+) studies, from characteristic solid phase Ba profiles which yield palaeoproductivity records, and from oxidation-sensitive indicator trace elements (I and Se). So far, these geochemical observations have been concentrated in the deeper central parts of the basin, where sediment accumulation rates are lower than on the basin margins, and radiocarbon dating indicates that S1 formation occurred between 5.3 and 9.0 ky (uncorrected conventional radiocarbon time). It remains to be demonstrated whether or not these times are applicable to the entire E. Mediterranean basin. The implications of these findings to guide sampling in future work on the S1 productivity episode and on older sapropels for palaeoenvironmental investigations are discussed.  相似文献   

20.
基于滨海核电站海上γ辐射剂量率的智能化自动监测系统是一种无人值守的辐射监测装备,可全天候、长时间、在线组网、连续自动测量水面和空气中的γ剂量率、获取水中γ能谱数据并进行核素识别和计算活度浓度,并实时地将监测数据通过无线通信链路和北斗短报文两种形式上传至地面数据服务中心。在非事故情况下,该系统是对核电厂监督性监测系统的重要补充和完善;在发生重大核安全事故或放射性物质泄漏的情况下,能够有效解决传统的派船巡测时方法不标准、数据不及时不连续、人员受照风险大、船只易受污染和行动代价高等问题;在恶劣的极端气象条件下,无人值守的自动监测系统能够为核电站提供实时有效的水体和空气中的γ剂量率、气象、海水温度等监测数据,有效地提升了核电站在极端气象条件下的监测能力,对滨海核电站整体的安全性和可靠性具有一定积极意义。  相似文献   

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