Composition and formation of laminated sediments in Diss Mere, Norfolk, England

The chemical and biological composition of laminated lake-sediments deposited between about 2,500 and 5,500 years B.P. in Diss Mere, Norfolk, England is described. The distribution of Ca, Fe, S, and Si in pale and dark laminae is established by energy-dispersive X-ray microanalysis. The pale laminae consist primarily of calcium carbonate and the dark layers contain mainly Fe, S, Si, and dark organic material. The diatom composition of 16 individual light and dark laminae shows no consistent differences between light and dark layers. There are, however, higher frequencies of chrysophycean cysts in seven of the eight dark layers, suggesting these layers were deposited in late summer or fall. Pollen analyses of the pale and dark layers show that pollen percentages of early-flowering trees and shrubs are highest in the dark laminae and that pollen values of late-flowering plants are highest in the pale layers. The biological data indicate that the pale layers were formed in the late spring and early summer, whereas the dark laminae were deposited in late summer, fall, winter, and the early spring. Seasonal supply of CaCO₃ was the major variable responsible for couplet formation.     

衡阳盆地始新世含鱼地层的成因分析

衡阳市郊五马归槽始新世鱼化石保存在黑色湖相纹层中。根据纹层序列的对比,发现该地的鱼化石均为同一层位;根据鱼化石在纹层序列中的具体位置及鱼化石的保存状况,笔者推测鱼群的死亡并非由于季节更替,而是由气候干旱引起的湖水盐度升高所控制;黑白纹层的变化是由大气降雨所致。     

The 1.5-ka varved record of Lake Montcortès (southern Pyrenees,NE Spain)

The karstic Lake Montcortès sedimentary sequence spanning the last 1548 yr constitutes the first continuous, high-resolution, multi-proxy varved record in northern Spain. Sediments consist of biogenic varves composed of calcite, organic matter and detrital laminae and turbidite layers. Calcite layer thickness and internal sub-layering indicate changes in water temperature and seasonality whereas the frequency of detrital layers reflects rainfall variability. Higher temperatures occurred in Lake Montcortès in AD 555–738, 825–875, 1010–1322 and 1874–present. Lower temperatures and prolonged winter conditions were recorded in AD 1446–1598, 1663–1711 and 1759–1819. Extreme and multiple precipitation events dominated in AD 571–593, 848–922, 987–1086, 1168–1196, 1217–1249, 1444–1457, 1728–1741 and 1840–1875, indicating complex hydrological variability in NE Spain since AD 463. The sedimentary record of Lake Montcortès reveals a short-term relation between rainfall variability and the detrital influx, pronounced during extended periods of reduced anthropogenic influences. In pre-industrial times, during warm climate episodes, population and land use increased in the area. After the onset of the industrialization, the relationship between climate and human activities decoupled and population dynamics and landscape modifications were therefore mostly determined by socio‐economic factors.     

Status of glacial Lake Columbia during the last floods from glacial Lake Missoula

The last floods from glacial Lake Missoula, Montana, probably ran into glacial Lake Columbia, in northeastern Washington. In or near Lake Columbia's Sanpoil arm, Lake Missoula floods dating from late in the Fraser glaciation produced normally graded silt beds that become thinner upsection and which alternate with intervals of progressively fewer varves. The highest three interflood intervals each contain only one or two varves, and about 200–400 successive varves conformably overlie the highest flood bed. This sequence suggests that jökulhlaup frequency progressively increased until Lake Missoula ended, and that Lake Columbia outlasted Lake Missoula. The upper Grand Coulee, Lake Columbia's late Fraser-age outlet, contains a section of 13 graded beds, most of them sandy and separated by varves, that may correlate with the highest Missoula-flood beds of the Sanpoil River valley. The upper Grand Coulee also contains probable correlatives of many of the approximately 200–400 succeeding varves, as do nearby parts of the Columbia River valley. This collective evidence casts doubt on a prevailing hypothesis according to which one or more late Fraser-age floods from Lake Missoula descended the Columbia River valley with little or no interference from Lake Columbia's Okanogan-lobe dam.     

Microfacies of detrital event layers deposited in Quaternary varved lake sediments of the Piànico-Sèllere Basin (northern Italy)

A Quaternary interglacial lake sediment record from the Piànico-Sèllere Basin (northern Italy) consists of biochemical calcite varves with intercalated detrital layers. At the end of the Piànico Interglacial, continuous varve formation was replaced by predominantly detrital sedimentation. However, 427 varve-years before this shift, an abrupt increase in the frequency and thickness of detrital layers occurred. Microfacies analyses reveal a total of 152 detrital layers, ranging from 0·2 to 20·15 mm in thickness, deposited during the last 896 years of the Piànico Interglacial. Three microfacies types are distinguished: (i) graded layers, (ii) non-graded silt layers, and (iii) matrix-supported layers. The position of detrital layers within an individual varve provides additional information on the season in which they have been deposited. Microfacies analyses in combination with varve counting further enabled precise varve-to-varve correlation of the detrital layers for two sediment sections cropping out ca 130 m apart. The detailed intra-basin correlation allows the source regions of detrital layers to be inferred. Moreover, micro-erosion at sub-millimetre scale has been established. Of the described facies types, only the accumulation of summer and spring graded and non-graded silt layers abruptly increased before the end of interglacial varve formation whereas non-graded winter silt and matrix-supported layers are randomly distributed over the entire study period. Heavy rainfalls are assumed to have triggered spring and summer graded layers, so that the occurrence of these layers is thought to be a proxy for extreme precipitation events in the past.     

Differential North Atlantic control of winter hydroclimate in late Holocene varved sediments of Lake Kortejärvi,eastern Finland

Sediment microfacies, geochemical μ‐XRF and X‐ray density analyses were conducted on varved sediments from Lake Kortejärvi (eastern Finland) covering the last 2700 years. The varves comprise couplets of detrital and organic sub‐layers throughout the complete time‐span. Based on their microfacies and stratigraphical position within a varve as well as comparisons with local discharge and meteorological data, thicker detrital layers are interpreted to reflect intensified snow‐melt floods following more humid winters. Detailed comparisons with monthly to annually resolved North Atlantic Oscillation (NAO) indices back to AD 1049 (901 a BP) suggest that multidecadal increases in snow‐melt layer thickness tend to be connected with a more positive phase of the NAO and, consequently, warmer winters. In contrast, distinct centennial intervals of thicker snow‐melt layers from −40 to 170, 280 to 460 and 1900 to 2300 a BP as well as around 2600 a BP do not consistently correspond to a particular NAO phase, but coincide with extended sea‐ice margins and a colder North Atlantic climate, causing intensified and southward shifted westerly cyclones. Our results point to a differential modification of North Atlantic winter hydroclimate working on varying time scales.     

Effects of detrital carbonate on stable oxygen and carbon isotope data from varved sediments of the interglacial Piànico palaeolake (Southern Alps,Italy)

Contamination with detrital matter is a well‐known bias in δ¹⁸O records from lake carbonates but quantitative information of this effect is yet lacking. Therefore, we developed a new methodological approach combining isotope analyses with microfacies, X‐ray diffraction and micro‐X‐ray fluorescence data and applied this in a case study for the Piànico interglacial lake record in order to provide a quantitative estimate of the effect of detrital carbonate on stable δ¹⁸O and δ¹³C data. The Piànico record contains a long series of distinct and well‐preserved calcite varves and is correlated to Marine Isotope Stage 11. Intercalated in the varve sequence are detrital layers triggered by surface erosion events. These detrital layers are mainly composed of dolomite, thus reflecting the mineralogical signature of the catchment. Microfacies analyses of a 9350 varve year interval allows the identification of detrital layers down to sub‐millimetre scale and a precise selection of three different types of samples for isotope analyses: (1) pure endogenic calcite varves (five varves per sample) without detrital contamination; (2) individual detrital layers; and (3) ‘mixed’ samples including five calcite varves and up to four thin detrital layers. Detrital samples show the isotopic signature of the catchment dolomite and are up to 5.7‰ enriched in δ¹⁸O values with respect to endogenic calcite samples. In mixed samples, the degree of isotopic enrichment is directly related to the amount of detrital contamination; δ¹⁸O of bulk carbonates is significantly biased when the detrital component amounts to more than 5% of the sample. It is also shown that samples containing detrital material have an influence on the calculation of the covariance between δ¹³C and δ¹⁸O. Covariance is high (r = 0.76) when the correlation coefficient is calculated on the base of all samples, but absent (r = ?0.43) when samples containing detrital dolomite are excluded. It has been demonstrated that microfacies analysis is a quick tool to avoid or reduce detrital contamination in bulk carbonate samples during sample selection. Copyright © 2009 John Wiley & Sons, Ltd.     

Interpretation of Si concentrations in lake sediments: three case studies

 The biogenic Si concentration in a sediment can be determined as the non-detrital Si concentration by normalization of the total Si concentration with Al. This procedure is based upon the assumptions that (1) that Al exists predominantly in detrital, i.e. minerogenic, particles and (2) that biogenic Si (mainly diatom frustules) is the dominating non-detrital Si phase. This paper focuses on the reasons for the variations of the non-detrital Si concentration in these lake sediments. Data from three lakes are presented, representing three principally different cases regarding the Si concentration. The processes controlling the concentrations of detrital and non-detrital Si are discussed. Received: 10 June 2000 · Accepted: 25 November 2000     

Advances in understanding calcite varve formation: new insights from a dual lake monitoring approach in the southern Baltic lowlands

We revise the conceptual model of calcite varves and present, for the first time, a dual lake monitoring study in two alkaline lakes providing new insights into the seasonal sedimentation processes forming these varves. The study lakes, Tiefer See in NE Germany and Czechowskie in N Poland, have distinct morphology and bathymetry, and therefore, they are ideal to decipher local effects on seasonal deposition. The monitoring setup in both lakes is largely identical and includes instrumental observation of (i) meteorological parameters, (ii) chemical profiling of the lake water column including water sampling, and (iii) sediment trapping at both bi-weekly and monthly intervals. We then compare our monitoring data with varve micro-facies in the sediment record. One main finding is that calcite varves form complex laminae triplets rather than simple couplets as commonly thought. Sedimentation of varve sub-layers in both lakes is largely dependent on the lake mixing dynamics and results from the same seasonality, commencing with diatom blooms in spring turning into a pulse of calcite precipitation in summer and terminating with a re-suspension layer in autumn and winter, composed of calcite patches, plant fragments and benthic diatoms. Despite the common seasonal cycle, the share of each of these depositional phases in the total annual sediment yield is different between the lakes. In Lake Tiefer See calcite sedimentation has the highest yields, whereas in Lake Czechowskie, the so far underestimated re-suspension sub-layer dominates the sediment accumulation. Even in undisturbed varved sediments, re-suspended material becomes integrated in the sediment fabric and makes up an important share of calcite varves. Thus, while the biogeochemical lake cycle defines the varves’ autochthonous components and micro-facies, the physical setting plays an important role in determining the varve sub-layers’ proportion.     

青藏高原北部可可西里库赛湖年纹层微区分析及形成机理

湖泊年纹层是进行高分辨率古气候环境研究的重要载体之一,其形成机理的研究能够为高分辨率古气候环境信息的提取提供重要的依据。本文以青藏高原北部可可西里库赛湖沉积的年纹层为研究对象,通过纹层薄片显微镜观察,以及纹层的扫描电镜、X衍射和同步辐射X射线荧光等微区分析,对库赛湖沉积年纹层的形态、沉积和成分特征进行了研究,以探讨库赛湖年纹层形成过程和机理。结果表明:年纹层层偶由深浅相间的微层组成,深色层主要由灰褐色—黑褐色的粗颗粒物质组成,磨圆中等、分选性差,矿物以石英、长石、白云母、黏土矿物等为主,其中石英含量占73%左右,且具有明显的风力搬运特征;浅色层呈灰白色,矿物颗粒较细,除石英、长石、白云母、黏土外,还有自生的文石,同时浅色层中含有大量的枝角类碎片和半月形介形类生物壳体。研究认为,库赛湖冬季温度低、风力强劲,风的机械搬运作用使大量的陆源物质在冰面堆积,等到春季湖泊开封,冰面上粗颗粒物质沉积到湖底形成库赛湖年纹层的深色层(粗颗粒层);夏季温度升高,冰雪融化,降水增加,河流搬运的陆源粗颗粒物质由于重力作用先在湖泊边缘沉积,而黏土矿物等细颗粒物质则在湖泊中心沉积,同时夏季湖水温度升高,蒸发作用加强,生物活动增强,湖泊自身的生物、化学作用加强,从而形成以细碎屑矿物、生物残体、自生碳酸盐沉积为主的浅色层(细颗粒层)。因此,库赛湖的年纹层层偶是由冬季冰面风成物质形成的粗颗粒深色层(冰融化后,风成物质沉降至湖底堆积)和夏季沉积的细颗粒浅色层两者交替而形成的。     

A local clay-varve chronology and proglacial sedimentary environment in glacial Lake Peipsi, eastern Estonia

Ten cores consisting of varved clay from the northern part of Lake Peipsi in eastern Estonia have been correlated using varve thickness variations and specific marker varves into a 375-year floating varve chronology. Continuous sedimentation during gradual ice recession is concluded from a clear transition from proximal to distal varves. Cyclic variations in varve thickness are caused mainly by thickness changes of clayey winter layers. This is interpreted to indicate increased influx of finer material due to faster melting of the glacier. The cyclic pattern of thickness change is explained by alternating periods of increased and decreased melting of the ice. Simultaneous accumulation of varved clay in glacial Lake Peipsi and in the Luga and Neva basins of Russia is concluded from the good visual correlation between the mean varve thickness diagrams for the three chronologies. Because the varve chronologies from northwestern Russia have been tentatively correlated to the Swedish varve chronology, the timing of the clay accumulation in glacial Lake Peipsi is placed between c . 13 500 and 13 100 varve years BP.     

Glaciomarine varves in late-Pleistocene clays near Göteborg, southwestern Sweden

Cyclic variations in the grain size, colour, carbonate content and organic content are interpreted as the result of proximal glaciomarine varve deposition along a fjord-like valley in southwestern Sweden. The sedimentological factors which allow varve development in this generally inhibiting environment arc considered by analogy with modern examples. Density stratification which is best developed during the spring and summer period of high discharge is suggested to have an essential influence on the cyclic character. Since sedimentation is interpreted to have occurred primarily from meltwater overflow the degree of mixing and salinity-induced coagulation largely governs fine-sediment sorting. Although these varves are not as well defined or as easily correlated as classical varves, they are considered useful in many comparable applications.     

巴西典型祖母绿矿床介绍

巴西的祖母绿矿床主要属于所谓的片岩型祖母绿矿床。它们产于富含暗色岩和伟晶岩的古老地盾区内。与矿化有关的伟晶岩往往脉幅小，分异不完全。最有利于矿化的围岩是富镁的滑石片岩，含滑石片岩，含滑石大理岩和黑云母片岩等。     

油页岩灰渣提取白炭黑的方法

以油页岩灰渣制备的水玻璃为原料,结合传统沉淀法和热风干燥工艺成功地制备了白炭黑。实验过程中研究了各种因素对白炭黑性质的影响,并确定了白炭黑的最佳制备工艺：水玻璃中w（SiO₂）为8.1%、c（H₂SO₄）为1.5 mol/L,陈化时间为8 h,反应温度为70～80 ℃,pH值为8.0。透射电镜分析结果表明：采用热风干燥技术制备的白炭黑平均粒径约为50 nm,而且团聚体较少,性能优于烘箱干燥制备的白炭黑。     

Multiproxy evidence of an early Holocene (8.2 kyr) climate oscillation in central Nova Scotia,Canada

An early Holocene lake sediment record from central Nova Scotia contains a minerogenic oscillation that is closely correlative with the 8.2 kyr event (ca. 8200 cal. yr BP), an event that has not been reported elsewhere in Atlantic Canada. A variety of biological and sedimentological indicators have been examined to characterise autochthonous and allochthonous changes that occurred during this time. The minerogenic upper oscillation (UO, ca. 8400 cal. yr BP) is marked by an increase in the chrysophyte:diatom ratio. Following the oscillation, the diatom community reflects a shift to more productive, less acidic conditions. The pollen record shows no major response to this short‐lived event. Lithostratigraphic analyses indicates that the UO is characterised by an increase in clastic content, magnetic susceptibility and mean sediment grain size, all indicators of changing environmental conditions, most likely the result of regional cooling. The Taylor Lake record adds to a growing body of evidence for a widespread, hemispheric climate oscillation at 8.2 kyr. Copyright © 2002 John Wiley & Sons, Ltd.     

Mechanism of Varve Formation and Paleoenvironmental Research at Lake Bolterskardet, Svalbard, the Arctic

On the basis of observation of thin sections and 137Cs data, laminations in sediment are interpreted to be varves in Bolterskardet Lake (78°06' N, 16°01' E), Svalbard, the Arctic. Varves appear under a petrologic microscope as couplets of dark-silt and light-clay layers. The mechanism of varve formation is surmized as follows: each silt layer is the production of sediment inflow interpreted as mainly derived from snowmelt during summer; each clay layer was deposited in a stillwater environment during an ice-cover period. A light -clay layer provides an important index bed to identify the annual interface. The high accumulation rates, long period of ice cover, and topographically closed basin are probably all critical factors in forming and preserving varves. Varve thickness is known to be controlled mainly by summer temperature. The variation of varve thickness in Lake Bolterskardet can then be used to reconstruct summer temperature. The varve series show that there has been distinct decade-scale variability of summer temperature over the past 150 years. Warm periods occurred in the 1860s, around 1900, the 1930s, 1950s, and 1970s, and in the last 20 years. The varved sediments of Lake Bolterskarde preserve an ideal record for high-resolution paleoclimatic and paleoenvironmental research in this data-sparse area.     

Diurnal laminations in the varved sediment of Lake Lovojärvi, south Finland

A man-induced extensive silty layer in the sediment of Lake Lovojärvi, dating back to the year 1960, contained 18 laminations due to rhythmical variations in the size classes of the mineral particles. A good agreement was found between the thicknesses of the successive laminae, and one period in a sequence of arbitrary 'wind sums' calculated from the meteorological statistics of the spring 1960 for periods of winds exceeding 3 m/s. Most of these wind pulses were diurnal; the longest one lasted for five days. The deposition of the layer in early spring was further confirmed through diatom analysis, which revealed within the laminated sequence a diatom succession typical of Lake Lovojärvi immediately after the melting of ice in spring     

Magnetic mineral variations of South Caspian Sea sediments at laminae scale

The 998-cm long sediment core was collected from the South basin of the Caspian Sea. Sediments from the lower, Late Pleistocene part of the core (998-90 cm) are marked by laminations, which rapidly disappear under oxidising conditions. TEM/EDS analyses of magnetic extracts, done at laminae scale, show the presence of iron monosulphide (greigite Fe₃S₄) in grey and black laminae. There are also small amounts of magnetite. Magnetic hysteresis parameters Mrs/Ms and Bcr/Bc, presented on a Day plot, cluster near SD/PSD boundary, with smaller particles for black laminae. This tendency is due to a higher content of greigite, relative to coarser grained detrital magnetite in black laminae, and to a lower relative content of greigite in grey laminae. Analyses of Ca/Mg carbonates, grain size of the bulk sediment, feldspars/quartz ratios and water content show that these parameters do not vary at laminae scale. These results suggest that the laminae are of early diagenetic rather than detrital origin, reflecting rhythmic, subtle variations in the geochemical environment during laminae formation.     

High-altitude varve records of abrupt environmental changes and mining activity over the last 4000 years in the Western French Alps (Lake Bramant,Grandes Rousses Massif)

Two twin short gravity cores and a long piston core recovered from the deepest part of proglacial Lake Bramant (Grandes Rousses Massif, French Alps), under and overlying a large slump identified by high-resolution seismic profile, allow the investigation of Holocene natural hazards and interactions between human activity and climatic changes at high-altitude. Annual sedimentation throughout the cores (glacial varves) is identified on photographs, ITRAX (high-resolution continuous microfluorescence-X) and CAT-Scan (computerized axial tomography) analyses and is supported by (1) the number of dark and light laminations between dates obtained by radionuclide measurements (¹³⁷Cs, ²⁴¹Am), (2) the correlation of a slump triggered by the nearby AD 1881 Allemond earthquake (MSK intensity VII) and of a turbidite triggered by the AD 1822 Chautagne regional earthquake (MSK intensity VIII), (3) the number of laminations between two accelerator mass spectrometry (AMS) ¹⁴C dates, and (4) archaeological data. In Lake Bramant, dark layers are coarser, contain less detrital elements, but more neoformed elements and organic matter content. These darker laminations result from calm background sedimentation, whereas the lighter layers are finer and rich in detrital elements and reflect the summer snowmelt. Traces of mining activity during the Roman civilization apogee (AD 115–330) and during the Early Bronze Age (3770–3870 cal BP) are recorded by lead and copper content in the sediments and probably result from regional and local mining activity in the NW Alps. Warmer climate during the Bronze Age in this part of the Alps is suggested by (1) two organic deposits (4160–3600 cal BP and 3300–2850 cal BP) likely reflecting a lower lake level and smaller glaciers and (2) evidence of a different vegetation cover around 2500 m a.s.l. The onset of clastic proglacial sedimentation between 3600–3300 cal BP and since 2850 cal BP is synchronous with periods of glacier advances documented in the Alps and high-lake levels in west-central Europe. This major change in proglacial sedimentation highlights the development of a larger St. Sorlin glacier in the catchment area of Lake Bramant.     

Yixunite and Damiaoite—A Twin of New Native Alloys of Indium and Platinum from the Yanshan Mountains

Yixunite and damiaoite Were found in a cobalt- and copper-bearing platinum ore vein of a contact metasomatic deposit. The chief ore minerals are bornite, chalcopyrite, magnetite and carrollite. The platinum minerals include moncheite, sperrylite, daomanite, cobalt malanite and cooperite. Yixunite and damiaoite occur as immiscible globules, 1.0 to 2.0 mm in diameter. Yixunite is always in the central part of a globule. It is opaque with metallic lustre, bright white colour and black streak. HM = 5.8; VHN50 = 634 kg/mm2 (573-681 kg/ mm2); insoluble in HCl, HNO3, HF or H3PO4; no cleavage; no magnetism. Density is hard to measure because of small grain size. Calculated density = 18.21 g/cm3. Reflective colour is bright white with a yellowish tint. Isotropic. The mean analytical results (ranges) (%) are: Pt 82.8 (81.8-83.6), In 16.4(15.6-17.1) and total 99.2. The empirical formula (based on 4 atoms) is Pt2.993 In1.007 . The five strongest lines of X-ray diffraction (hkl, d,I) are 111, 2.30 (100); 200, 1.99 (