岩石中元素背景值变化对地球化学成矿预测的影响

勘查地球化学是利用元素在各种介质中的含量变化来进行找矿勘查,因此,地球化学填图是勘查地球化学的最基础性的工作,正如地质图对于地质工作的重要性一样。在利用地球化学进行找矿预测过程中,元素在不同类型岩石中背景值的变化会对预测过程产生很大的影响,在利用中国西南地区76种元素编图的数据进行成矿预测过程中,将元素分成两类:一类是岩性变化对成矿预测影响较小的元素,这类元素的各类岩石最大背景值与预测区的异常下限比值小于1,且岩石中背景值的最大值与最小值比值也较小,一般小于4。这些元素包括Hg、Cd、Sb、Au、Sn、 Mo、Ag、U、Pb、Bi、W,它们都是地球化学方法应用最有效的矿种。另一类是岩性变化对成矿预测影响较大的元素, 这类元素有Pt、Co、Cr、Cu、Ni、V、Ti等,其岩石中的最大背景值与异常下限比值大于1,且岩石中的背景值最大值与最小值的比值大于8。以Sn和Cu两种元素为例,Sn属于岩性变化影响较小的元素,西南地区的Sn矿床与Sn地球化学异常之间的对应关系很好。而Cu属于岩性影响较大的元素,西南地区的Cu矿床分布与西南地区的巨大的 Cu地球化学异常对应关系较差。对于这组元素,应采用多重分形滤波技术,压制不同背景的干扰,从中提取出矿化信息。     

Garnet pyroxenite and eclogite in the Bohemian Massif: geochemical evidence for Variscan recycling of subducted lithosphere

High-temperature, high-pressure eclogite and garnet pyroxenite occur as lenses in garnet peridotite bodies of the Gföhl nappe in the Bohemian Massif. The high-pressure assemblages formed in the mantle and are important for allowing investigations of mantle compositions and processes. Eclogite is distinguished from garnet pyroxenite on the basis of elemental composition, with mg number <80, Na₂O > 0.75 wt.%, Cr₂O₃ < 0.15 wt.% and Ni < 400 ppm. Considerable scatter in two-element variation diagrams and the common modal layering of some eclogite bodies indicate the importance of crystal accumulation in eclogite and garnet pyroxenite petrogenesis. A wide range in isotopic composition of clinopyroxene separates [_Nd, +5.4 to –6.0; (⁸⁷Sr/⁸⁶Sr)_i, 0.70314–0.71445; ¹⁸O_SMOW, 3.8–5.8%o] requires that subducted oceanic crust is a component in some melts from which eclogite and garnet pyroxenite crystallized. Variscan Sm-Nd ages were obtained for garnet-clinopyroxene pairs from Dobeovice eclogite (338 Ma), Úhrov eclogite (344 Ma) and Nové Dvory garnet pyroxenite (343 Ma). Gföhl eclogite and garnet pyroxenite formed by high-pressure crystal accumulation (±trapped melt) from transient melts in the lithosphere, and the source of such melts was subducted, hydrothermally altered oceanic crust, including subducted sediments. Much of the chemical variation in the eclogites can be explained by simple fractional crystallization, whereas variation in the pyroxenites indicates fractional crystallization accompanied by some assimilation of the peridotite host.     

Permo-Carboniferous volcanism in late Variscan continental basins of the Bohemian Massif (Czech Republic): geochemical characteristic

Extensive Permo-Carboniferous volcanism has been documented from the Bohemian Massif. The late Carboniferous volcanic episode started at the Duckmantian–Bolsovian boundary and continued intermittently until Westphalian D to Stephanian B producing mainly felsic and more rarely mafic volcanics in the Central Bohemian and the Sudetic basins. During the early Permian volcanic episode, after the intra-Stephanian hiatus, additional large volumes of felsic and mafic volcanics were extruded in the Sudetic basins. The volcanics of both episodes range from entirely subalkaline (calc-alkaline to tholeiitic) of convergent plate margin-like type to transitional and alkaline of within-plate character. A possible common magma could not be identified among the Carboniferous and Permian primitive magmas, but a common geochemical signature (enrichment in Th, U, REE and depletion in Nb, Sr, P, Ti) in the volcanic series of both episodes was recognized. On the other hand, volcanics of both episodes differ in intensities of Nb, Sr and P depletion and also, in part, in their isotope signatures. High ⁸⁷Sr/⁸⁶Sr (0.707–0.710) and low ε_Nd (−6.0 to −6.1) are characteristic of the Carboniferous mafic volcanics, whereas low ⁸⁷Sr/⁸⁶Sr (0.705–0.708) and higher ε_Nd ranging from −2.7 to −3.4 are typical of the Permian volcanics. Felsic volcanics of both episodes vary substantially in ⁸⁷Sr/⁸⁶Sr (0.705–0.762) and ε_Nd (−0.9 to −5.1). Different depths of magma source or heterogeneity of the Carboniferous and Permian mantle can be inferred from variation in some characteristic elements of the geochemical signature for volcanics in some basins. The Sr–Nd isotopic data with negative ε_Nd values confirm a significant crustal component in the volcanic rocks that may have been inherited from the upper mantle source and/or from assimilation of older crust during magmatic underplating and ascending of primary basic magma. Two different types of primary magma development and formation of a bimodal volcanic series have been recognized: (i) creation of a unique magma by assimilation fractional crystallization processes within shallow-level reservoirs (type Intra-Sudetic Basin) and (ii) generation and mixing of independent mafic and felsic magmas, the latter by partial melting of upper crustal material in a high-level chamber (type Krkonoše Piedmont Basin). A similar origin for the Permo-Carboniferous volcanics of the Bohemian Massif is obvious, however, their geochemical peculiarities in individual basins indicate evolution in separate crustal magma chambers.     

Multipurpose geochemical maps produced by integration of geochemical exploration data sets in The Paraná Shield, Brazil

Old geochemical datasets from the Paraná Shield of southern Brazil have been integrated into a new geochemical database and the results are presented as a series of multipurpose geochemical maps. Although the 24 datasets retrieved were analysed by three different laboratories, the maps produced correlate surprisingly well with bedrock geological features.The retrieval of old geochemical exploration data sets for the purpose of generating maps showing element depletions and enrichments is a powerful tool with a wide range of applications: trace elements such as Zn, Cu and Mo can significantly affect crop productivity; areas with high abundances of harmful elements such as As and F can be delineated in order to identify public health hazards; heavy metals such as Cd, Pb and Hg can be measured in order to better constrain knowledge of chemical background levels for environmental monitoring. The integration and manipulation of different data sets can however be complicated by the heterogeneity in sampling and analytical procedures.     

Improved reliability in the interpretation of geochemical measurements by the quantification of uncertainty from sampling

All geochemical measurements require the taking of field samples, but the uncertainty that this process causes is often ignored when assessing the reliability of the interpretation, of the geochemistry or the health implications. Recently devised methods for the estimation, optimisation and reduction of this uncertainty have been evaluated by their application to the investigation of contaminated land. Uncertainty of measurement caused by primary sampling has been estimated for a range of six different contaminated land site investigations, using an increasingly recognized procedure. These site investigations were selected to reflect a wide range of different sizes, contaminants （organic and metals）, previous land uses （e.g. tin mining, railway sidings and gas works）, intended future use （housing to nature reserves） and routinely applied sampling methods. The results showed that the uncertainty on measurements was substantial, ranging from 25% to 186% of the concentration values at the different sites. Sampling was identified as the dominant source of the uncertainty （〉70% of measurement uncertainty） in most cases. The fitness-for-purpose of the measurements was judged using the optimized contaminated land investigation （OCLI） method. This identifies the optimal level of uncertainty that reduces to overall financial loss caused by the measurement procedures and the misclassification of the contamination, caused by the uncertainty. Generally the uncertainty of the actual measurements made in these different site investigations was found to be sub-optimal, and too large by a factor of approximately two. The uncertainty is usually limited by the sampling, but this can be reduced by increasing the sample mass by a factor of 4 （predicted by sampling theory）. It is concluded that knowing the value of the uncertainty enables the interpretation to be made more reliable, and that sampling is the main factor limiting most investigations. This new approach quantifies this problem for the first time, and allows sampling procedures to be critically evaluated, and modified, to improve the reliability of the geochemical assessment.     

Variscan stress regime rotation: Insights from the analysis of kink folds in the northern margin of the Bohemian Massif,South Poland

We aimed to determine variations in stress regimes during the youngest Variscan deformations in the northern part of the Bohemian Massif. For this purpose, we calculated the orientation of the principal stress and strain axes for kink folds observed in the metamorphic envelope of the Karkonosze Granite, using two methods: 1) the traditional method, incorporating structural diagrams (for conjugate kink folds only), and 2) butterfly diagram analysis. The use of both methods enabled us to determine the stress regime, based not only on conjugate but also on monoclinal kink bands. The obtained results prove that butterfly diagram analysis, when applied to monoclinal kink folds, yields reliable results, especially when calibrated using the internal friction angle (Ф) calculated for the conjugate structures.We identified two generations of kink folds: 1) an older one, developed under sublatitudinal shortening and most probably related to the Early Carboniferous terminal stages of the northwest-directed thrusting of the metamorphic units, and 2) a younger one; produced by north-south Variscan Carboniferous compression, and the emplacement and subsequent doming of the Karkonosze Granite. This is the first study on brittle-ductile structures observed commonly in the metamorphic units of the Bohemian Massif, showing their relation to the granitoid intrusion and complementing the tectonic models that usually omit kink folds.     

浅析黔西北地区铅锌矿成矿元素地球化学特征

文章对黔西北地区典型铅锌矿床矿石、围岩中常量元素及微量元素的地质地球化学特征及同位素地球化学特征进行研究,总结了各元素的迁移、富集规律,对今后在该地区寻找和开采铅锌矿具有重要的地质意义。     

Mineralization of pegmatites in parts of the Oban Massif, Southeastern Nigeria： A preliminary analysis

The Oban Basement Massif of southeastern Nigeria is composed of metamorphosed rocks including phyllites, schists, gneisses and amphibolites cut by pegmatitic dykes of varying length and thickness, which intruded the metamorphic rocks. Preliminary geochemical study and analysis of these pegmatites from western Oban Massif at Uyanga, Akwa Ibami, Iwuru I, Iwuru Ⅱ and Igbofia showed that the pegmatites are highly albitized. This is incon-sistent with earlier postulations that the pegmatites in this part of Nige...     

Tectonic evolution of a continental magmatic arc from transpression in the upper crust to exhumation of mid-crustal orogenic root recorded by episodically emplaced plutons: the Central Bohemian Plutonic Complex (Bohemian Massif)

The Central Bohemian Plutonic Complex (CBPC) consists of episodically emplaced plutons, the internal fabrics of which recorded tectonic evolution of a continental magmatic arc. The ~354–350 Ma calc-alkaline plutons were emplaced by multiple processes into the upper-crustal Teplá-Barrandian Unit, and their magmatic fabrics recorded increments of regional transpression. Multiple fabrics of the younger, ~346 Ma Blatná pluton recorded both regional transpression and the onset of exhumation of mid-crustal orogenic root (Moldanubian Unit). Continuous exhumation-related deformation during pluton cooling resulted in the development of a wide zone of sub-solidus deformation along the SE margin of the CBPC. Finally, syn-exhumation tabular durbachitic pluton of ultrapotassic composition was emplaced atop the intrusive sequence at ~343–340 Ma, and the ultrapotassic Tábor pluton intruded after exhumation of the orogenic root (~337 Ma). We suggest that the emplacement of plutons during regional transpression in the upper crust produced thermally softened domain which then accommodated the exhumation of the mid-crustal orogenic root, and that the complex nature of the Teplá-Barrandian/Moldanubian boundary is a result of regional transpression in the upper crust, the enhancement of regional deformation in overlapping structural aureoles, the subsequent exhumation of the orogenic root domain, and post-emplacement brittle faulting.     

基于采样点的化探异常成矿元素研究--以广东大宝山铜多金属矿田为例

化探异常成矿元素的确定是异常评价的主要问题之一。在总结前人研究工作的基础上提出了一种基于采样点的成矿元素确定方法,将异常矿化度、异常衬度值与浓集系数联系起来,提出浓集系数越低的元素,成为成矿元素要求其异常矿化度越高,异常衬度值越低;一定范围内采样点上第一成矿元素的组合反映了矿种类型。将该方法成功应用于广东大宝山铜铅锌钨钼多金属矿田构造岩石测量成矿元素的分析中,对于详细分析化探异常主要成矿元素及其分布、分带特征具有重要的实用价值,适用于浓集系数不同的元素成矿能力的比较研究。     

鄂尔多斯盆地北缘地球化学大数据样本优选分析

众所周知,地球化学数据携带有众多地质噪音,这些噪音严重影响地球化学数据信息的客观性与可靠性;对于地球化学大数据融合分析而言,确定样品的有效性及变量优选是滤除地质噪音、建立最优样本集合的必要性工作,因而在地球化学大数据处理分析前需首先进行大样本优选,从而更加客观、真实的揭示地球化学大数据信息及相关地质意义。本文以鄂尔多斯盆地北缘1∶20万地球化学土壤测量数据为例,考虑元素之间的地球化学亲和力与组合匹配关系,建立非线性大样本优选模型。具体做法是基于优选后的样品矩阵,将39个元素变量分解成若干独立因子向量,将最优独立因子向量作为元素组合,其向量各分量作为元素变量的权重,依权重大小进行变量优选;优选后的样本集合可以作为该区地球化学数据分析与信息识别的有效地学信息集合,运用这种集合可以有效开展鄂尔多斯盆地外围铀地球化学分析,并为盆地铀资源预测奠定基础。     

R型聚类分析在区域化探元素分组中的作用探讨

在处理化探数据方面,R型聚类分析是应用较为广泛的一种数理统计方法。随着研究的深入发现,R型聚类分析的结果并非总是对元素分组起到积极有效的作用。这里对大石寨地区的二叠纪地层、白垩纪地层、黑云母花岗岩以及研究区全区进行39种元素R型聚类分析,得到地层、岩体以及全区的元素组合,但是分组的结果表明,通过R型聚类分析得到的各元素组合均不能明确反映地层、岩体以及全区的地质特征,因此对于R型聚类分析的使用需谨慎。     

川滇黔桂76种元素地球化学图编制中分析方法与分析质量研究(一) 不同实验室产生地球化学图的相似性——以Ag、Cs、Ga、Ge为例

编制中国76种元素地球化学图将使我们首次了解元素周期表上除氢、氧及惰性气体之外所有元素在中国大陆表层的分布,川滇黔桂76种元素地球化学图的编制是这一研究项目的试点。本文以不同实验室取得的Ag、Cs、Ga、Ge分析数据为例,探索、衡量不同实验室地球化学图相似性的方法,以优选实验室进行川滇黔桂4省区约4000件组合样76种元素的大规模分析工作。     

同步辐射X射线荧光微探针测定岩石中的元素分布

同步辐射X射线(白光)荧光微探针在大气环境下,光斑尺寸为(50×50)μm~2,位移为1mm/步,计数时间30s,扫描测量了含石榴石紫苏花岗岩中多元素(K、Ca、Ti、Cr、Mn、Fe、Cu、Zn、Rb和Sr)的分布并绘制成图。检测限达x×10ppm,绝对量为10~(-10)—10~(-11)g范围。     

区域气候模式在中国西北地区气温和降水长时间序列模拟的误差分析

气温和降水微小的变化都可能引起中国西北地区脆弱生态环境空间格局剧烈变化.由于西北地区气象站点分布稀疏,站点观测结果难于完全代表西北地区复杂地貌的气象要素空间分布格局.区域气候模式模拟可以弥补现有观测资料的不足,但模式模拟存在的误差,往往制约着西北区域气候变化评估工作.本文在CN05格点数据和站点数据基础上,从空间格局、极值模拟等方面对高分辨率WRF模式数据气温和降水模拟精度进行评估,假定偏差恒定基础上,使用分类回归树模型建立偏差预测模型.结果表明:CN05数据和WRF模式多年年平均气温和多年平均年降水数据空间格局基本一致,但WRF模式结果空间格局更加细致.WRF模式结果在山区和湖泊地区降水偏高估,气温和降水距平在新疆地区相对于其他地区变化较为一致;95%分位数的降水在甘肃和新疆地区模拟结果好于宁夏、青海和陕西;5%和95%分位数气温,WRF模式大部分站点表现为暖偏差,而CN05数据表现为冷偏差;不同的地貌单元区域气温和降水的偏差时间序列存在一定的相关性.在西北五省区气温和降水的分类树模型中,由于高程和地形复杂度对偏差预测模型影响较大,无法在整个西北地区建立统一的误差预测模型.     

中国早期人类分布的环境制约因素探讨

在环境因素起制约作用的背景下,随着中国古人类演化与生存能力的进步,其数量和空间分布在不同时间段呈现出不同的特征。为了更好地了解中国早期人类的时空分布特征,本研究以中国境内已发表的2110处旧石器遗址的坐标和年代信息为基础,采用统计学和空间分析的方法,对遗址的时间分布进行以蒙特卡洛模拟为基础的时间不定性模拟,对遗址的空间分布进行核密度估计和聚类分析;同时,利用环境空间数据集中的海拔、水源、气温和降水信息,对不同时期内各个遗址所在地的环境条件进行统计分析。研究结果表明,在旧石器时代,随着时间的发展,中国境内的遗址数量不断增多,分布范围也逐渐从中部、南部和东部地区向条件较恶劣的北部和西部扩张。其中,600 ka和57 ka为这一变化的两个关键时间点,600 ka之前遗址数量较少,分布也较为局限;在600 ka至57 ka之间,遗址数量缓慢增加,分布范围也在季风区内逐渐扩大;57 ka之后,遗址数量迅速增长,分布遍布中国境内的大部分地区。本文所梳理的中国境内旧石器遗址整体时空分布特征,为进一步解读中国早期人类的环境适应能力,特别是古人类的体质演化和技术进步的环境驱动机制提供参考。

     

东太平洋海盆CC区沉积物因子分析揭示的沉积环境地球化学演化信息

对中国大洋矿产资源开发研究协会DY851和DY853航次获得的东太平洋晚新生代沉积物(包括61个表层沉积物样品和16个沉积物柱状岩芯)进行了系统的地球化学和数理统计分析，揭示了东太平洋海盆CC区晚新生代沉积环境地球化学演化的一些特征。认为洋底扩张、沉积区离东太平洋洋脊的距离、海底的地热强度及地热活动频率影响了研究区CCD的深度和CCD波动的频率及幅度，从而在一定程度上制约了研究区的沉积环境。     

层状土场中冲刷作用下部分埋置单桩动力响应分析

桩周土场受冲刷作用的变化是部分埋置单桩结构失效的主要原因之一。工程中土场多呈层状,此类场地中桩基的力学特性研究日益受到关注。为精确揭示冲刷作用对层状土场中部分埋置单桩动力响应的影响,基于改进Vlasov地基模型,利用Hamilton原理建立层状土场中横向受荷单桩的动力学模型。利用有限差分法求解受冲刷作用单桩的固有频率,实现对冲刷作用下土−结构相互作用系统的准确建模,进而用Green函数法求得单桩受迫振动的解析解。通过数值计算和参数分析,研究了层状土场的物理特性对受冲刷作用部分埋置单桩动力响应的影响。结果表明：基于改进Vlaosv地基模型建立的层状土场中部分埋置单桩动力学模型可精确预测冲刷作用对桩基动力学特性的影响。随冲刷程度加剧,层状土场中单桩的第一阶固有频率显著降低,改进Vlasov地基模型中各层土体的地基反力系数均减小,剪切系数则增大。当冲刷至非埋置段桩长 （ 为桩长）时,部分埋置单桩在动荷载作用下出现横向失稳现象。随底层土体厚度增加,各冲刷等级下单桩的第一阶固有频率均增大。如果第1层土的弹性模量增大了约0.43倍、1.14倍、1.86倍,则冲刷等级为0时单桩第一阶固有频率分别增大了约8.9%、19.5%、27.1%。