Geochemical constraints on blueschist- and amphibolite-facies rocks of the Central Cordillera of Colombia: the Andean Barragán region

Subduction zones are one of the most characteristic features of planet Earth. Convergent plate junctions exert enormous influence on the formation and recycling of continental crust, and they are also responsible for major mineral resources and earthquakes, which are of crucial importance for society. A subduction-related geologic unit containing high-pressure rocks occurs in the Barragán area (Valle del Cauca Department) on the western flank of the Central Cordillera of the Colombian Andes. Blueschists and amphibolites, serpentinized meta-ultramafic rocks, graphite-chlorite-muscovite-quartz schists, protocataclasites, and graphite-chlorite-andalusite-andesine-garnet-muscovite?± titanite schists are exposed in this region. In spite of the petrotectonic importance of blueschists, the high-pressure metamorphism of the Central Cordillera of Colombia has been rarely studied. New geochemical data indicate that protoliths of the blueschist- and amphibolite-facies rocks possessed normal mid-ocean ridge basalt bulk compositions. ⁴⁰Ar/³⁹Ar geochronology for a metapelite rock associated with the blueschists shows a plateau age of ～120 million years. We suggest that high-P/T conditions were present from ～150 to 125 Ma, depending on the model of generation and exhumation considered.     

Composition and genesis of endogenous borates from the Pitkáranta ore field,Karelia

The borate mineralization of the Pitkáranta skarn field of Karelia is localized in metasomatically altered Proterozoic dolomites. In the contact aureole of rapakivi granites, the zoning of magnesian skarns includes spinel-diopside or fassaite skarns with syngenetic magnetite and spinel-forsterite calciphyres surrounded by periclase marbles, which confirms their hypabyssal genesis. Stringer-stockwork bodies developing in the brecciation zone at the roof show a primitive zoning consisting of an inner diopside and an outer forsterite calciphyre zone grading into a dolomitic marble. All these zones inherited the Ca/Mg ratio of the primary carbonate rocks. Rhythmically banded textures observed in the skarns and calciphyres of the deposits studied suggest their formation under thermodynamically disequilibrium conditions typical of hypabyssal metasomatites. Magnesium and magnesium-iron borates in marbles and calciphyres and beryllium borates in greisens were formed during the postmagmatic stage. Data are reported on the chemical composition and genesis of suanite, kotoite, ludwigite, hulsite, pertsevite, fluoborite, szaibelyite, and humites from the Hopunvaara, Klara, Lupikko, and Herberz deposits. The deficit of boron in magnesian borates is related to their endogenous hydration. Data on hambergites and berborite are given according to E.I. Nefedov.     

Tropical Cyclone Impacts on Coastal Regions: the Case of the Yucatán and the Baja California Peninsulas,Mexico

Tropical cyclones (TCs) are large-scale natural disturbances that generate strong winds and heavy rainfall, impacting coastal and inland environments. TCs also influence biogeochemical and hydrological cycles controlling aquatic primary productivity in tropical and subtropical coastal ecosystems. We assessed TC landfall activity and identified sites along the Mexican east and west coasts with high frequency in the period 1970–2010 and evaluated TCs with significant precipitation. Changes in chlorophyll-a (Chl-a) concentrations before and after storm impacts were estimated using remotely sensed ocean color. There were 1,065 named TCs with a wide diversity in tracks. Three states with the highest number of landfalls were identified: Baja California Sur and Sinaloa on the west coast and Quintana Roo on the east coast. While a relative increase in Chl-a values following TC landfalls in the Baja California and Yucatán Peninsula regions appeared to be strongly linked to TC strength, the intensity of precipitation, the spatial scales of the two peninsulas, and the relative movement of TCs appeared to have contributed to Chl-a variability. Satellite estimates of Chl-a in the nearshore coastal waters following TC passage were likely enhanced by coastal morphology and water discharge along with constituents such as suspended particulate, colored dissolved organic matter and nutrients from rivers, tributaries, and groundwater.     

Natural and anthropic perturbations to the chemical composition of the Colorado River (Tucumán,Argentina)

Economic and urban development in the province of Tucumán is closely associated with its hydrological network. In spite of the regulatory efforts to preserve the quality of the water resources, the lower basins of the majority of the rivers are contaminated with organic effluents derived from sugar-mill and citrus industry. In this paper, the conditions of the Colorado River basin are described. At its headwater, the lithology and geology determine the chemical composition. Calcite and gypsum dissolution and silicate influence water composition, which is slightly perturbed a few kilometers downstream by geothermal waters discharged by a tributary. Close to the discharge into the Salí River, the Colorado River receives a high organic matter load from the highly polluted Calimayo stream, which produces an increase in the organic matter and depletion of dissolved oxygen with redox conditions that promote the reduction of sulfate to sulfide.     

Geochemistry and zircon geochronology of the Archean granite suites of the Rio Maria granite-greenstone terrane,Carajás Province,Brazil

The Archean granites exposed in the Mesorchean Rio Maria granite-greenstone terrane (RMGGT), southeastern Amazonian craton can be divided into three groups on the basis of petrographic and geochemical data. (1) Potassic leucogranites (Xinguara and Mata Surrão granites), composed dominantly of biotite monzogranites that have high SiO₂, K₂O, and Rb contents and show fractionated REE patterns with moderate to pronounced negative Eu anomalies. These granites share many features with the low-Ca granite group of the Yilgarn craton and CA2-type of Archean calc-alkaline granites. These granites result from the partial melting of rocks similar to the older TTG of the RMGGT. (2) Leucogranodiorite-granite group (Guarantã suite, Grotão granodiorite, and similar rocks), which is composed of Ba- and Sr-rich rocks which display fractionated REE patterns without significant Eu anomalies and show geochemical affinity with the high-Ca granite group or Transitional TTG of the Yilgarn craton and the CA1-type of Archean calc-alkaline granites. These rocks appear to have been originated from mixing between a Ba- and Sr-enriched granite magma and trondhjemitic liquids or alternatively product of interaction between fluids enriched in K, Sr, and Ba, derived from a metasomatized mantle with older TTG rocks. (3) Amphibole-biotite monzogranites (Rancho de Deus granite) associated with sanukitoid suites. These granites were probably generated by fractional crystallization and differentiation of sanukitoid magmas enriched in Ba and Sr.The emplacement of the granites of the RMGGT occurred during the Mesoarchean (2.87–2.86 Ga). They are approximately coeval with the sanukitoid suites (∼2.87 Ga) and post-dated the main timing of TTG suites formation (2.98–2.92 Ga). The crust of Rio Maria was probably still quite warm at the time when the granite magmas were produced. In these conditions, the underplating in the lower crust of large volumes of sanukitoid magmas may have also contributed with heat inducing the partial melting of crustal protoliths and opening the possibility of complex interactions between different kinds of magmas.     

Nature and timing of magma interactions before,during, and after the caldera-forming eruption of Volcán Ceboruco,Mexico

Volcán Ceboruco, Mexico, erupted ~1,000 years ago, producing the Jala pumice and forming a ~4-km-wide caldera. During that eruption, 2.8 to 3.5 km³ of rhyodacite (~70 wt% SiO₂) magma and 0.2 to 0.5 km³ of mixed dacite (~67 wt% SiO₂) magma were tapped and deposited as the Jala pumice. Subsequently, the caldera was partially filled by extrusion of the Dos Equis dome, a low-silica (~64 wt% SiO₂) dacite dome with a volume of ~1.3 km³. Petrographic evidence indicates that the Jala dacite and Dos Equis dacite originated largely through the mixing of three end-member magmas: (1) rhyodacite magma, (2) dacite magma, and (3) mafic magma. Linear least-squares modeling and detailed modal analysis indicate that the Jala dacite is predominantly a bimodal mixture of rhyodacite and dacite with a small additional mafic component, whereas the Dos Equis dacite is composed of mostly dacite mixed with subordinate amounts of rhyodacite and mafic magma. According to Fe–Ti oxide geothermometry, before the caldera-forming eruption the rhyodacite last equilibrated at ~865 °C, whereas the dacite was originally at ~890 °C but was heated to ~960 °C by intrusion of mafic magma as hot as ~1,030 °C. Zoning profiles in plagioclase and/or magnetite phenocrysts indicate that mixing between mafic and dacite magma occurred ~34–47 days prior to eruption, whereas subsequent mixing between rhyodacite and dacite magmas occurred only 1–4 days prior to eruption. Following the caldera-forming eruption, continued inputs of mafic magma led to effusion of the Dos Equis dome dacite. In this case, timing between mixing and eruption is estimated at ~93–185 days based on the thickness of plagioclase overgrowth rims.Editorial responsibility: T.L. Grove     

Holocene and Pleistocene sea-level indicators at the coast of Jericoacoara,Ceará, NE Brazil

Beach-rock exposures provide a record of Holocene sea-level rise along the 560-km-long northeast-facing coast of Ceará, Brazil, that differs from the record available along the other 4300 km of Brazilian coastline further south. Whereas documentation is available from southern Brazil to show Holocene sea levels as much as 5 m above today's level, our observations along the northeastern coast indicate that sea level here was not above the present-day level during the Holocene. Near Jericoacoara, about 240 km northwest of Fortaleza, characterized by strong surf, Precambrian rocks crop out from under a temporary cover of sand in small protected locations with less surf. Here in this upper tidal zone beach rock is being formed, while it is being dismembered synchronously by erosion at lower tide levels. This shows a rising sea level. Along the entire coast of Ceará west of Ponta Grossa the absence of beach rock higher than spring tide level indicates that sea-level was not above its present-day level during the Holocene.Notches in bedrock situated between 2 m and 6 m above spring-tide high-water level that we formerly described as Holocene, are now believed to be Sangamonian.     

Approaches for tsunami risk assessment and application to the city of Cádiz, Spain

Tsunamis can represent a significant risk to the population and cause huge economic damage in many costal regions. In order to be able to identify risk hot spots and implement targeted risk reduction measures, decision makers need to have a clear picture of the risk situation in their countries or regions. This work reviews existing approaches for tsunami risk assessment and recommends a five-step process for assessing tsunami risk. As a case study, a qualitative risk assessment for a worst-case tsunami scenario was carried out to understand the tsunami risk to the population in Cádiz. Moreover, a sensitivity analysis of the tsunami hazard input parameters was performed as a strong influence of the variability of the input parameters on the resultant tsunami hazard and risk zonation maps was observed. The study shows that regardless of the assumptions made a non-negligible tsunami risk to Cádiz exists.     

Analysis of the geomagnetic anomaly within the Kolárovo basin using GMINV

GMINV is a computer program for inversion of potencial field data using damped approximate technique. In this paper we evaluate the results of geomagnetic field measuring in the area of Kolárovo basin magnetic anomaly, south-west Slovakia. In order to achieve more precise evaluation of the location and geometry of the perturbative body we use some preliminary knowledge concerning the geological structure of the locality, magnetic profile measuremenrs, etc.     

Territory and territorial transformation: the rural properties of the Dávalos-Bracamontes family in the Compostela region (Seventeenth Century)

This investigation seeks to analyse the territorial transformations, land uses, and land tenures in the region of Compostela, Nueva Galicia during the seventeenth century, using land grants for sites of cattle and sheep husbandry and farmland granted as the rural properties to the Dávalos-Bracamontes family, who in 1690 obtained the title of the Counts of Miravalle. The novohispanas haciendas served as territorial control mechanisms of the use and incorporation of new forms of exploitation of the area’s natural resources. The methodology is based on the analysis of the archival data, historical cartography, supplemented by information collected in fieldwork and use of historical modality of geographic information systems. The haciendas of La Lagunilla, Miravalle and San José were located and together represented 33,736.60 ha of land for livestock and agriculture. The territorial extension was possible due to the disappearance of villages, parse indigenous populations in the surroundings and commitments made by the Spanish Crown to the Dávalos-Bracamontes family.

     

Ore Control Factors of the High-grade BIF of the Carajás Iron Province in Brazil

Please refer to the attachment(s) for more details.     

Provenance of the Upper Triassic siliciclastics of the Mecsek Mountains and Villány Hills (Pannonian Basin,Hungary): constraints to the Early Mesozoic paleogeography of the Tisza Megaunit

International Journal of Earth Sciences - The Tisza Megaunit in the Southern Pannonian Basin formed part of the southern margin of the European Plate in the Early Mesozoic era. Its exact...     

Sequence stratigraphy of Holocene incised-valley fills and coastal evolution in the Gulf of Cádiz (southern Spain)

This first sedimentary interpretation of two incised-valley fills in the Gulf of Cádiz (southern Spain), which accumulated during the last fourth-order eustatic cycle in response to fluvial incision, changes of sea level, and correlative deposition, relates the filling of the estuarine basins and their barriers with four regional progradation phases, H₁ to H₄. The cases studied are the wave-dominated Guadalete, and the mixed, tide and wave-dominated Odiel-Tinto estuaries. The sequence boundary is a type-1 surface produced during the lowstand of the Last Glacial period ca. 18 000 ¹⁴C yr BP. No fluvial lowstand deposits were found in the area. Due to rapid transgression the valley fills consist of transgressive and highstand sediments. The maximum landward advance of the estuarine barriers occurred ca. 6500–6000 ¹⁴C yr BP during the maximum of the Flandrian transgression, but there is no evidence of sea level rising appreciably above the present. A large part of the estuaries was filled during H₁ (ca. 6500–4400 ¹⁴C yr BP) but ravinement by shifting tidal inlets destroyed most of the coeval barriers. During the H₂ phase (ca. 4200–2550 ¹⁴C yr BP) sedimentation was favoured by arid conditions and concentrated in the axial estuarine zones and the barriers. Between H₂ and H₃ prevailing winds changed from W to WSW, increasing spit growth to the east and south-east. Progradation of bay-head deltas and flood-plains during H₃ (ca. 2300–800 ¹⁴C yr BP) and H₄ (500 yr ago to the present) further reduced the accommodation space in the largely-filled valleys, and sediment by-passed the estuaries and accumulated in the estuarine barriers as fast-growing spits. Arid conditions and increasing human activity have caused rapid coastal modifications.     

Interpretation of gravity profiles across the northern Oaxaca terrane,its boundaries and the Tehuacán Valley,southern Mexico

A gravity study was conducted across the northern Oaxaca terrane and its bounding faults: the Caltepec and Oaxaca Faults to the west and east, respectively. These faults juxtapose the Oaxaca terrane against the Mixteca and Juarez terranes, respectively. The Oaxaca Fault also forms the eastern boundary of the Cenozoic Tehuacán depression. On the west, at depth, the Tehuacán valley is limited by the normal buried Tehuacán Fault. This gravity study reveals that the Oaxaca Fault system gives rise to a series of east tilted basamental blocks (Oaxaca Complex). The tectonic depression is filled with Phanerozoic rocks and has a deeper depocenter to the west. The gravity data also indicate that on the west, the Oaxaca Complex, the Caltepec and Santa Lucia faults continue northwestwards beneath Phanerozoic rocks. A major E–W to NE–SW discontinuity is inferred to exist between profiles 1 and 2.     

On the Age of the Dongtang Formation in the Hengyang Basin of Hunan and the Cretaceous and Tertiary Boundary

Since the coexistence of the Cretaceous and Palaeocene was ascertained in the Hengyang Basin of Hunan in the middle of the 1960's, the Cretaceous and Tertiary boundary has been discussed in several papers, but it still remains controversal. The points at issue are the connotation, stratigraphical position and lateral correlation of the Dongtang (or Chejiang) Formation.     

Mafic forearc cumulates and associated rocks in the central high-pressure belt of the Acatlán Complex of southern México: geochemical constraints

The high-pressure (HP) Piaxtla Suite at Tehuitzingo contains peridotites, gabbros, and serpentinized peridotites, as well as granitoids and metasedimentary rocks. The HP mafic rocks are characterized by low SiO₂ (38–52 wt.%) and high Mg# (～48–70), Ni (100–470 ppm), and Cr (180–1750 ppm), typical of cumulate compositions. Trace elements and rare earth element (REE) primitive mantle-normalized patterns display generally flat profiles, indicative of derivation from a primitive mantle with two distinct patterns: (1) gabbroic patterns are characterized by a positive Eu anomaly, low REE abundances, and slightly depleted high REE (HREE) relative to low REE (LREE), typical of cumulus olivine, pyroxene, and plagioclase; and (2) mafic-intermediate gabbroic patterns exhibit very flat profiles characteristic of olivine and clinopyroxene as cumulus minerals. Their Nb/Y and Zr/TiO₂ ratios suggest a subalkaline character, whereas low Ti/V ratios indicate that the Tehuitzingo cumulates are island arc tholeiitic basalts that resemble modern, immature oceanic, forearc magmas. These cumulates have high values of ? _Nd(t) = 5.3–8.5 and ¹⁴⁷Sm/¹⁴⁴Nd = 0.18–0.23, which renders calculations of model ages meaningless. Our data are consistent with the Tehuitzingo arc rocks being part of a tectonically extruded Devonian–early Carboniferous arc developed along the west margin of Gondwana.     

Geochronology and geochemistry of eclogites from the Mariánské Lázně Complex,Czech Republic: Implications for Variscan orogenesis

The Mariánské Lázn complex (MLC) is located in the Bohemian Massif along the north-western margin of the Teplá-Barrandian microplate and consists of metagabbro, amphibolite and eclogite, with subordinate amounts of serpentinite, felsic gneiss and calcsilicate rocks. The MLC is interpreted as a metaophiolite complex that marks the suture zone between the Saxothuringian rocks to the north-west and the Teplá-Barrandian microplate to the south-east. Sm-Nd geochronology of garnet-omphacite pairs from two eclogite samples yields ages of 377±7, and 367±4 Ma. Samples of eclogite and amphibolite do not define a whole rock Sm-Nd isochron, even though there is a large range in Sm/Nd ratio, implying that the suite of samples may not be cogenetic. Eclogites do not have correlated _Nd values and initial ⁸⁷Sr/⁸⁶Sr ratios. Five of the eight eclogite samples have high _Nd values (+10.2 to +7.1) consistent with derivation from a MORB-like source, but variable ⁸⁷Sr/⁸⁶Sr ratios (0.7033 to 0.7059) which probably reflect hydrothermal seawater alteration. Three other eclogite samples have lower _Nd values (+ 5.4 to –0.8) and widely variable ⁸⁷Sr/⁸⁶Sr ratios (0.7033 to 0.7096). Such low _Nd values are inconsistent with derivation from a MORB, source and may reflect a subduction or oceanic island basalt component in their source. The MLC is an important petrotectonic element in the Bohemian Massif, providing evidence for Cambro-Ordovician formation of oceanic crust and interaction with seawater, Late Devonian (Frasnian-Famennian) high- and medium-pressure metamorphism related to closure of a Saxothuringian ocean basin, Early Carboniferous (Viséan) thrusting of the Teplá terrane over Saxothuringian rocks and Late Viséan extension.     

Geological and SHRIMP II U-Pb constraints on the age and origin of the Breves Cu-Au-(W-Bi-Sn) deposit,Carajás,Brazil

The Breves deposit in the Carajás Copper-Gold Belt, Brazil, a member of the Cu-Au-(W-Bi-Sn) group of deposits, contains about 50 Mt of 1.22% Cu, 0.75 g/t Au, 2.4 g/t Ag, 1,200 g/t W, 70 g/t Sn, 175 g/t Mo and 75 g/t Bi. It is hosted by sandstones and siltstones of the Águas Claras Formation (minimum age of 2,681±5 Ma) in the roof zone of a complex, highly altered granite intrusion. The mineralisation is disseminated in a greisenized zone, resulting from alteration of probable monzogranites and syenogranites. The ore-bearing greisen contains abundant xenomorphic quartz in association with Fe-chlorite and muscovite. The gangue assemblage also includes fluorite, tourmaline, and minor amounts of monazite, xenotime, chlorapatite, thorite, zircon, calcite, siderite and bastnäesite. Copper mineralisation is dominated by chalcopyrite associated with pyrite, arsenopyrite, pyrrhotite and molybdenite. Gold particles, in equilibrium with native bismuth, are common as inclusions in chalcopyrite. The greisen contains sub-economic concentrations of tungsten and niobium that are related to the presence of ferberite, qitianlingite and Nb-rutile. SHRIMP II zircon dating of the host granites gives ²⁰⁷Pb/²⁰⁶Pb ages of 1,878±8 and 1,880±9 Ma for two phases, and a combined age of 1,879±6 Ma. SHRIMP II dating of monazite and xenotime grains in late- to post-mineralisation veins gives a combined ²⁰⁷Pb/²⁰⁶Pb age of 1,872±7 Ma, indistinguishable from the ages of the granites. This provides a genetic connection between the Breves deposit and the ca. 1.88 Ga A-type granite magmatism that typifies the Carajás Belt as part of a much larger, intracratonic magmatic province that extends over much of the Amazonian Craton. The recognition of this association has exploration implications, not only for the geophysical signature of the granite roof zones, but also for likely geochemical dispersion around the deposits of this type.Editorial handling: G. Beaudoin     

On Metallogenic Conditions and Regularities of the Lower and Middle Reaches of the Changjiang River

The paper deals with the metallogenic conditions and regularities of the region ol the lower-middle reachesof the Changjiang River in China. The complicated structural network with the Changjiang (Yangtse) deepfracture as its trunk is the leading rock-and ore-controlling structure of the metallogenic belt. Thehigh-potassium granodiorites of the first magmatic sequence of the Mesozoic Yangtse syntexis type and thesodium-rich diorites of the second sequence are genetically related to the copper ore series and the iron ore se-ries respectively. and occur respectively in the block-faulted and-folded uplift area and the down-faulted vol-canic basin as well as the transitional zone between the two. The ore-hosting horizons show specific associa-tions of rocks and often contain ore beds basically of stratabound nature.     

Chronostratigraphy and Stratigraphic Classification of the Cretaceous of the Songliao Basin

Isotopic ages of synsedimentary clay minerals were directly determined with the ultrasonicscattering-settlement separation-K-Ar dilution technique. The apparent age of black mudstoneis 123 Ma for the Quantou Formation, 111.9-89.0 Ma for the Qingshankou Formation and77.6-76.8 Ma for the upper part of the Nenjiang Formation. The Rb-Sr isochrone age of themuddy limestone-mudstone sequence of the lower part of the Nenjiang Formation is 81 Ma andthat of the muddy evaporite of the middle part of the Quantou Formation is 122.2 Ma. On thebasis of the above isotopic ages, the authors propose a modified scheme of stratigraphic classifi-cation of the Cretaceous of the Songliao basin.