Volatile emission on the moon; Possible sources and release mechanisms

Evidence for very recent emission of volatiles on the Moon is primarily of four types: (1) transient lunar optical events observed by Earth-based astronomers; (2) excursions on Apollo SIDE and mass spectrometer instruments; (3) localized Rn²²²/Po²¹⁰ enhancements on the lunar surface detected by Apollo 15 and 16 orbital alpha spectrometers; (4) presence in lunar fines of retrapped Ar⁴⁰ and other volatiles. Available evidence indicates that the release rate of volatile substances into the lunar atmosphere is not steady, but instead sporadic and episodic. Rn²²²/Po²¹⁰ anomalies are at locations that are among those from which transient events have most often been reported (edges of maria, certain specific craters), and are probably related to them. Volatiles emitted at maria rims may originate in the Moon's fluid core, reaching the surface through deep cylindrical fault systems that ring the maria borders. The sources of volatiles emitted at craters such as Aristarchus or Tsiolkovsky, which possess floors which are cracked or filled with dark lava and possess central peaks, are more likely to be local pockets of magma or trapped gas at shallower depths. The volatiles are produced directly by radioactive decay (He⁴, Ar⁴⁰, Rn) and by heating (other volatiles). The release by heating can occur either during melting or by ‘bakeout’ of unmelted materials. Release of gas into the lunar atmosphere is probably triggered by buildup of its own pressure. This may be assisted by tidal forces exerted on the Moon by the Earth. In addition to independent release, volatile emission is also expected to accompany other lunar activity, such as ash flows, if any lunar volcanism is presently active.

     

Model for radon diffusion through the lunar regolith

A model for radon diffusion through the lunar regolith is proposed in which the atom migrates by random walk. The regolith is represented by a system of randomly oriented baffles in which the mean distanced which the atom travels between two collisions takes on the role of a mean free path. The effective mean time between two collisions depends on two entities: the actual mean time-of-flight and the mean sticking time on grain surfaces for one collision. The latter depends strongly on the temperature and the heat of adsorption of radon on regolith materials. Bothd (mean free path) as well asQ (heat of adsorption) are either poorly known or unknown for the lunar regolith; hence these quantities are treated as free parameters. Because of the greatly different mean lifetimes against radioactive decay of²¹⁹Rn,²²⁰Rn, and²²²Rn, the regolith acts as a powerful filter for these species.²²²Rn escape is significant (32%) even ford = 1µ,Q = 7.0 kcal/mole and a regolith depth of 4 m. Calculations of radon escape from a 4 m thick regolith, usingd = 1, 10 and 80µ andQ = 4.0, 5.2 and 7.0 kcal/mole show that the²²²Rn/²²⁰Rn escape ratio can be as small as 7.7 and as large as, or larger than 47. The small value of 7.7 is of particular interest, because it is nearly equal to the escape ratio inferred by Turkevichet al. from their Surveyor 5 results.     

Cosmic ray exposure ages of features and events at the apollo landing sites

Cosmic ray exposure ages of lunar samples have been used to date surface features related to impact cratering and downslope movement of material. Only when multiple samples related to a feature have the same rare gas exposure age, or when a single sample has the same⁸¹Kr-Kr and track exposure age can a feature be considered reliably dated. Because any single lunar sample is likely to have had a complex exposure history, assignment of ages to features based upon only one determination by any method should be avoided. Based on the above criteria, there are only five well-dated lunar features: Cone Crater (Apollo 14) 26 m.y., North Ray Crater (Apollo 16) 50 m.y., South Ray Crater (Apollo 16) 2 m.y., the emplacement of the Station 6 boulders (Apollo 17) 22 m.y., and the emplacement of the Station 7 boulder (Apollo 17) 28 m.y. Other features are tentatively dated or have limits set on their ages: Bench Crater (Apollo 12) ?99 m.y., Baby Ray Crater (Apollo 16) ?2 m.y., Shorty Crater (Apollo 17) ≈ 30 m.y., Camelot Crater (Apollo 17) ?140 m.y., the emplacement of the Station 2 boulder 1 (Apollo 17) 45–55 m.y., and the slide which generated the light mantle (Apollo 17) ?50 m.y.     

Lunar color boundaries and their relationship to topographic features: A preliminary survey

By combining UV negatives with IR positives of the full Moon, it is possible to suppress albedo differences and to enhance color differences between various lunar regions. Areas within the lunar maria exhibit the greatest color variations, and many have sharp boundaries. In contrast, the terrae in general show only feeble color variations, although small terra regions situated near or surrounded by maria sometimes display enhanced redness. The mare color boundaries in some cases coincide with the edges of clear-cut lava flows, the bluer material overlying the redder. One wedge-shaped area of bluer material corresponds with a prominent sinuous rille, the rille source being situated precisely in the point of the wedge. This area has obliterated portions of two ray systems, showing that the bluer material was deposited later than both the surrounding redder material and the ray material. On the other hand, rays from the crater Olbers A cross both colored areas impartially. Other examples of ray obliteration by bluer deposits are found elsewhere. From Apollo and Surveyor analyses, it is found that there is an apparent correlation between degree of blueness and titanium content of the surface materials. The following conclusions may be drawn:

1. The various maria were deposited over considerable lengths of time; this does not support the fusion-through-impact hypothesis.
2. The bluer materials, which appear to be those of high Ti content, are the more recent.
3. The hypothesis that sinuous rilles are lava drainage channels is supported.
4. The terrae covered by this study are mostly monotonous, suggesting constant composition, but a few anomalously red isolated regions may be of substantially different composition.

     

Optical polarimetry of planet mercury

Polarimetric measurements were collected at different areas of the surface of Mercury, and for the whole disk in six wavelengths. The curves of polarization are compared with telescopic observations of the Moon and laboratory studies of minerals and returned lunar samples. The negative branch of polarization proves that Mercury's surface is almost everywhere covered by a regolith layer of fines of the lunar type, also made of dark and adsorbing material, and most probably of the same impact generated origin. The polarization maximum of Mercury is reproduced by lunar samples of fines of intermediate albedo corresponding to the lightest regolith found in the Apollo explored maria.The albedo of Mercury at phase angle 5° deduced from telescopic photometry is to be corrected by a factor of 1.20 and the best “polarimetric” values of albedos are 0.130 at λ = 0.585μm, 0.119 at λ = 0.520 μm, 0.093 at λ = 0.379μm and 0.087 at λ = 0.354μm. The contrast between light and dark-lined regions at the surface of Mercury is most probably much fainter than between the maria and continents on the Moon.The molecular atmosphere of Mercury, if any, has a surface pressure probably smaller than 2 × 10^?4 bars.     

Comparison of the analytical results from the surveyor,Apollo, and Luna missions

The principal chemical element composition and inferred mineralogy of the powdered lunar surface material at seven mare and one terra sites on the Moon are compared. The mare compositions are all similar to one another and comparable to those of terrestrial ocean ridge basalts except in having higher titanium and much lower sodium contents than the latter. These analyses suggest that most, if not all, lunar maria have this chemical composition and are derived from rocks with an average density of 3.19 g cm^–3. Mare Tranquillitatis differs from the other maria in having twice the titanium content of the others.The chemical composition of the single highland site studied (Surveyor 7) is distinctly different from that of any of the maria in having much lower amounts of titanium and iron and larger amounts of aluminium and calcium. Confirmation of these general characteristics of lunar highland material has come from recent observations by the Apollo 15 Orbiter. The inferred mineralogy is 45 mole percent high anorthite plagioclase and the parent rocks have an estimated density of 2.94 g cm^–3. The Surveyor 7 chemical composition is the principal contributor to present estimates of the overall chemical composition of the lunar surface.Presented at the NATO Advanced Study Institute on Lunar Studies, Patras, Greece, September 14–25, 1971. This paper is an expanded and updated version of a paper presented at the Apollo 12 Lunar Science Conference, Houston, Texas, January 11–14, 1971, and published in the Proceedings of this Conference (Turkevich, 1971).     

A primary analysis of microwave brightness temperature of lunar surface from Chang-E 1 multi-channel radiometer observation and inversion of regolith layer thickness

In China’s first lunar exploration project, Chang-E 1 (CE-1), a multi-channel microwave radiometer was aboard the satellite, with the purpose of measuring microwave brightness temperature (Tb) from lunar surface and surveying the global distribution of lunar regolith layer thickness. In this paper, the primary 621 tracks of swath data measured by CE-1 microwave radiometer from November 2007 to February 2008 are collected and analyzed. Using the nearest neighbor interpolation to collect the Tb data under the same Sun illumination, global distributions of microwave brightness temperature from lunar surface at lunar daytime and nighttime are constructed. Based on the three-layer media modeling (the top dust-soil, regolith and underlying rock media) for microwave thermal emission of lunar surface, the CE-1 measured Tb and its dependence upon latitude, frequency and FeO + TiO₂ content, etc. are discussed. The CE-1 Tb data at Apollo landing sites are especially chosen for validation and calibration on the basis of available ground measurements. Using the empirical dependence of physical temperature upon the latitude verified by the CE-1 multi-channel Tb data at Apollo landing sites, the global distribution of regolith layer thickness is further inverted from the CE-1 brightness temperature data at 3 GHz channel. Those inversions at Apollo landing sites and the characteristics of regolith layer thickness for lunar maria are well compared with the Apollo in situ measurements and the regolith thickness derived from the Earth-based radar data. Finally, the statistical distribution of regolith thickness is analyzed and discussed.     

Seismic effects from major basin formations on the moon and mercury

Grooved and hilly terrains occur at the antipode of major basins on the Moon (Imbrium, Orientale) and Mercury (Caloris). Such terrains may represent extensive landslides and surface disruption produced by impact-generatedP-waves and antipodal convergence of surface waves. Order-of-magnitude calculations for an Imbrium-size impact (10³⁴ erg) on the Moon indicateP-wave-induced surface displacements of 10 m at the basin antipode that would arrive prior to secondary ejecta. Comparable surface waves would arrive subsequent to secondary ejecta impacts beyond 10³ km and would increase in magnitude as they converge at the antipode. Other seismically induced surface features include: subdued, furrowed crater walls produced by landslides and concomitant secondary impacts; emplacement and leveling of light plains units owing to seismically induced ‘fluidization’ of slide material; knobby, pitted terrain around old basins from enhancement of seismic waves in ancient ejecta blankets; and perhaps the production and enhancement of deep-seated fractures that led to the concentration of farside lunar maria in the Apollo-Ingenii region.     

Distribution of lunar impacts by objects in parabolic low inclination orbits

This paper presents a computer investigation extending to the case of parabolic orbits, an earlier investigation conducted by Barricelli and Metcalfe (1969) on lunar impacts by external low eccentricity satellites as a means to interpret the asymmetric distribution of lunar maria. Parabolic orbits can be approximated by two kinds of objects:

1. High eccentricity external satellites may, near periapsis, approach the Moon with orbital velocity and other characteristics closely resembling those of a parabolic orbit.
2. Asteroids and meteoroids approaching the Earth-Moon system with a low velocity may have moved in a nearly parabolic orbit when they reached the lunar distance from the Earth at the time when the impacts which carved the lunar maria took place.

The investigation gives, therefore, not only additional information relevant to the interpretation of the distribution of lunar maria by the satellite impacts hypothesis (in this case high eccentricity ones), but also information about the alternative hypothesis (Wood, 1973) that asteroid impacts rather than satellite impacts were involved.     

The velocity structure of the lunar crust

Seismic refraction data, obtained at the Apollo 14 and 16 sites, when combined with other lunar seismic data, allow a compressional wave velocity profile of the lunar near-surface and crust to be derived. The regolith, although variable in thickness over the lunar surface, possesses surprisingly similar seismic properties. Underlying the regolith at both the Apollo 14 Fra Mauro site and the Apollo 16 Descartes site is low-velocity brecciated material or impact derived debris. Key features of the lunar seismic velocity profile are: (i) velocity increases from 100–300 m s^–1 in the upper 100 m to 4 km s^–1 at 5 km depth, (ii) a more gradual increase from 4 km s^–1 to 6 km s^–1 at 25 km depth, (iii) a discontinuity at a depth of 25 km and (iv) a constant value of 7 km s^–1 at depths from 25 km to about 60 km. The exact details of the velocity variation in the upper 5 to 10 km of the Moon cannot yet be resolved but self-compression of rock powders cannot duplicate the observed magnitude of the velocity change and the steep velocity-depth gradient. Other textural or compositional changes must be important in the upper 5 km of the Moon. The only serious candidates for the lower lunar crust are anorthositic or gabbroic rocks.Paper dedicated to Professor Harold C. Urey on the occasion of his 80th birthday on 29 April, 1973.     

Lunar surface temperatures from apollo 12

The diurnal variation of temperatures in the lunar surface layer is calculated using the measured properties of the Apollo 12 samples. The results are compared with similar calculations made using data from the Apollo 11 samples and with previous infrared temperature measurements. Comparisons are also made with prior calculations which used assumed properties. These are based on an effective value of the thermal parameter [ = (kqc)^–1/2] of 1034 which is obtained from integrated average values of the specific heat and thermal conductivity of the Apollo 12 fines.     

Tektites - volcanic ejecta from the moon?

The problem of the origin of the enigmatic tektites is still unsolved. The two leading hypotheses - viz., ejecta from terrestrial impacts, and ejecta from lunar volcanoes or lunar impacts, each encounters serious difficulties. The former has ballistic and water content difficulties, while the latter has some compositional difficulties, especially in the trace elements, as determined from the returned samples. It is possible that the latter problem may be met through lunar volcanic ejecta from sites suggesting more differentiation than the majority of the Moon. That such features may exist is suggested from the identity of some granitic material in the returned rocks and soil samples implying fairly sizable source regions on the Moon. The rare terrestrial strewn tektite fields require restrictive ballistic trajectories from the Moon. Calculations reveal that ellipses of varying, decreasing sizes which depend on velocity of vertical ejection from which ejecta will intersect the earth at low-entrance angles occur on the nearside of the Moon. Reasonable velocities were chosen (2.55 to 3.0 km s^?1) and these ellipses circumscribe areas with longitudes between 30 and 50° east and latitudes between 7° north and south of the Moon's equator. These areas were searched for evidence of volcanism. As tektites have compositions ranging from acidic (major tektites) to basic (micro-tektites) contents of silica (SiO₂) both acidic and basic volcanic features were sought. Since tektites range in age from about 30 million to 700000 yr old, they imply recent volcanism. Lunar Transient Phenomena (LTP) and data from various Apollo missions indicate that mild internal activity may still be occurring on the Moon. LTP sites are logical sources to investigate, of which four occur within the above delimited regions. These and their surroundings were examined and a number of possible explosive volcanism sites were found. These sites are identified and discussed after a review of the manifestations found from the various kinds of terrestrial volcanism for which lunar counterparts were sought.     

Lunar paleotides and the origin of the Earth-Moon system

A new method for determining the early history of the Earth-Moon system is described. Called the study of lunar paleotides, it describes a method for explaining features of the remnant lunar gravity field, and the generation of the lunar mascons. A method for the determination of Earth-Moon distances compared with the radiometric ages of the maria is developed. It is shown that the Moon underwent strong anomalous gravitational tidal forces, for a durationt<10⁶yr, prior to the formation of the mascon surfaces. As these tidal forces had not been present at the time of the formation of the Moon, this shows that the Moon could not have been formed in orbit about the Earth.There are tides in the affairs of men which, taken at the flood, lead on to fortune... William Shakespeare 1564–1616     

Ubvri photometry of some lunar topographies

Examples of pure lunar mountains, dark and light maria, and cratered terrae have been observed with the UBVRI stellar photometry system. Johnson's (1965) absolute calibration was used to compute brightnesses. These brightnesses were reduced using Hapke's photometric model to a standard geometry (angle of incidence 60°, emergence 40°, phase 90°), and relative albedos were then computed.The mountains, as distinct from the other regions, appear to require a wavelength dependent phase function. The albedos for the four topographic types are approximately linear functions of wavelength. The terrae are redder than the maria. Very low contrast between the topographies is predicted for full-moon at wavelengths shorter than 0.30. On the basis of laboratory studies, the lunar particles are comparable to basalt grains having sizes less than 50m. Larger particle sizes are associated with the dark maria and smaller ones with the cratered highlands.     

Electrical conductivity of lunar surface rocks and chondritic meteorites

The electrical conductivities of several samples from returned Apollo 11 and 12 lunar rocks and from chondritic meteorites were measured from 300 to 1100K. Collectively the lunar samples represent all three of the major NASA classifications of lunar surface rocks. Of general interest is the observation that the conductivities of the lunar samples are much larger than the values which have previously been used in theoretical discussions of lunar phenomena. It is also found that the conductivity at 300K, (300), is extremely sensitive to the thermal history of the sample for both lunar and meteoritic material. Magnetic measurements are presented to help characterize the changes which occur upon heating.Principal Investigator - Apollo Lunar Science Program, Geophysics Research Laboratory, University of Tokyo, Japan.     

Lunar physical librations and laser ranging

The analysis of lunar laser ranging data requires very accurate calculations of the lunar physical librations. Libration terms are given which arise from the additive and planetary terms in the lunar theory. The large size of the recently discovered terms due to third degree gravitational harmonics will allow some of these harmonics to be measured, in addition to and, by laser ranging to the Moon. Combining the laser ranging determinations of = 630.6 ± 0.5 × 10^–6 and = 226.4 ± 3.0 × 10^–6 with lunar orbiter measurements ofC ₂₀ andC ₂₂ givesC/MR ²=0.395 _-0.010 ^+0.006 . Numerical integration promises to be an effective method of calculating librations. Comparison of numerical integrations with analytic series indicates that the calculation of the series due to third and fourth degree harmonics is not yet as accurate as the more extensively developed second degree terms.Communication presented at the Conference on Lunar Dynamics and Observational Coordinate Systems, held January 15–17, 1973, at the Lunar Science Institute, Houston, Tex., U.S.A.     

Post-sunset cooling behavior of the lunar surface

Differential infrared flux scans at 22m have been made across the nighttime lunar surface over a range of phases before and after new Moon. The differential chopping technique effectively cancels atmospheric emission in the beam path but records the flux difference between adjacent resolution elements on the lunar disk. The scans show that the brightness temperature gradient across the highlands after sunset is much greater than that across the western maria. The large gradients consistently disappear approximately 3.5 days after sunset. The post-sunset enhancement could be due to surface roughness in the highlands or to a significant surface rock population with a mean size of approximately 0.5 m. The effect can be seen in the 10m measurements of other investigators, but its global nature was not detected in their limited data sets.     

Energetic lunar nighttime ion events

The Rice University Suprathermal Ion Detector Experiment regularly observes ion events normally ranging from 250 eV q^?1 to 1000 eV q^?1 all through the lunar night. These ion events occur most often 2 to 3 days prior to the sunrise terminator. There is also a secondary activity peak 3 to 4 days after local sunset on the Moon. The events are normally of 4 hr or less in duration and the integral flux is 10⁶ ions cm^?2 s^?1 ster^?1. This article discusses the character of these events and presents the preliminary findings of a detailed study begun on this subject.     

Paleocratering of the Moon: Review of post-Apollo data

As a result of the dating of lunar samples, we are in a position to utilize the lunar surface as a recorder of environmental conditions in the Earth-Moon neighborhood in the past. Plots of crater density vs rock age at different lunar landing sites can be used to date unexplored lunar provinces. These plots also demonstrate evolution in the population of planetesimals that struck the Moon. Prior to 4.1 aeons ago, the cratering rate on the Moon was at least 10³ times the present rate, and the rate declined with a half-life less than 8×10⁷ yr. During the interval from 4.1 to 3.2 aeons ago, the number of planetesimals showed an exponential decay with a half-life about 3×10⁸ yr, corresponding to sweep-up of particles from solar orbits somewhat similar to those of Apollo asteroids. A more nearly constant cratering rate applied in the last three aeons. These data indicate that the Moon displays at least the final stages of an ancient accretion process; they also set certain conditions on possible capture processes relating to the Moon's origin. Pre-Apollo expectations that the Moon would provide a Rosetta Stone for interpreting solar system history and planet formation thus appear justified.Paper given at Philadelphia meeting of American Association for Advancement of Science, December, 1971.     

Orbital mapping of the lunar magnetic field

Magnetometer data obtained during the first four lunations after the deployment of the Apollo 15 subsatellite have been used to construct contour maps of the lunar magnetic field referred to 100 km altitude. These contour maps cover a relatively small band on the lunar surface. Within the region covered there is a marked near side-far side asymmetry. The near-side field is generally weaker and less structured than the far-side field. The strongest intrinsic lunar magnetic field detected is between the craters Van de Graaff and Aitken, centered at 20°S and 172°E. The variation in field strength with altitude for this feature suggests that its scale size is on the order of 80 km. A magnetization contrast between this region and its surroundings of the order of 6 × 10^–5 emu-cm^–3 is obtained assuming a 10-km thick slab. Preliminary Apollo 16 magnetometer data at extremely low altitude (0 to 10 km) show a very structured magnetic field with field strengths up to 56. Large compressions in the magnetic field magnitude, just above the lunar limb regions, are occasionally detected when the Moon is in the solar wind. The occurrence of limb compressions is strongly dependent on the selenographic coordinates of the lunar region on the solar wind terminator beneath the orbit of the sub-satellite. The discovery of remanent magnetization of varying strength over much of the lunar surface and its correlation with limb compression source regions supports the hypothesis that limb compressions are due to the deflection of the solar wind by regions of strong magnetization at the lunar limbs. If this hypothesis is correct, then the map of lunar regions associated with compressions indicates that the northerly equatorial region on the far side is less strongly magnetized than the southerly equatorial region on the far side.Paper dedicated to Professor Harold C. Urey on the occasion of his 80th birthday on 29 April, 1973.