Study on System of Faults in the Gulf of Mexico and Adjacent Region based on Gravity Data

In the Gulf of Mexico and adjacent landmasses,faults are very complex,and their distribution is closely related to plate tectonics,ocean-land boundary,and former structure.The plane position of the faults can be identified by the maximum characteristic of the vertical derivative of the normalized vertical derivative of the total horizontal derivative(NVDR-THDR)of the Bouguer gravity anomaly.The apparent depth of the faults is inverted by the Bouguer gravity anomaly curvature property.Based on tectonic evolutionary processes and the plane distribution and apparent depth characteristics of the faults,a complete fault system for the Gulf of Mexico and adjacent areas has been established,including 102 faults.The apparent depths of 33 first-class faults are 16-20 km and for 69 second-class faults are 12-16 km.The F_1-2and F_1-3subduction fault zones are two caused by the subduction of the Cocos Plate into the old Yucatan and Chorti landmasses;F_1-11and F_1-12fault zones extend westward to the coast of Guatemala and do not extend into the continent;F_1-17and F_1-20faults,which control the boundary of the oceanic crust,do not extend southward into the continent.The fault system,which radiates in a"fan-shaped"structure as a whole,unfolds to the northeast.Faults of different nature and sizes are distributed in the Cocos Plate subduction zone,Continental,Gulf of Mexico,Yucatan old landmass and Caribbean Plate in NW,NNW,NS,NE and NEE directions.In the Gulf of Mexico region,the fault system is a comprehensive reflection of former tectonic movements,such as plate movement,drift of old landmasses and expansion of oceanic crusts.The first-class faults control the plate and ocean-continental boundaries.The second-class faults are subordinate to the first-class faults or related to the distribution of different sedimentary layers.     

Tectonic geomorphology of the easternmost extension of the Gulf of Corinth (Beotia, Central Greece)

The easternmost sector of the Gulf of Corinth, the Beotia area in Central Greece, is an area with active normal faults located between the two major rift structures of Central Greece, the Gulf of Corinth and the North Gulf of Evia. These active normal faults include WNW to E–W and NE to ENE-trending faults affect the landscape and generate basin and range topography within the Beotia. We study four normal fault zones and drainage basin geometry in the easternmost sector of the Gulf of Corinth to document the impact of active tectonics on the landscape evolution. Fault and drainage geometry are investigated based on detailed field mapping and high-resolution digital elevation models. Tectonic geomorphic analysis using several parameters of active tectonics provides information concerning the relative tectonic activity and fault growth. In order to detect areas of lateral stream migration that could indicate recent tectonic activity, the Transverse Topographic Symmetry Factor and the Asymmetry Factor are used to analyse drainage basin geometry in six large drainage basins and a drainage domain covering the study area. Our results show that vertical motions and tilting associated with normal faulting influence the drainage geometry and its development. Values of stream-gradient indices (S_L) are relatively high close to the fault traces of the studied fault zones suggesting high activity. Mountain-front sinuosity (S_mf) mean values along the fault zones ranges from 1.08 to 1.26. Valley floor width to valley height ratios (V_f) mean values along the studied fault zones range between 0.5 and 1.6. Drainage basin shape (B_S) mean values along the fault zones range from 1.08 to 3.54. All these geomorphic parameters and geomorphological data suggest that the analyzed normal faults are highly active. Lateral fault growth was likely produced by primarily eastward propagation, with the WNW to E–W trending faults being the relatively more active structures.     

Uranium, radon, helium and other trace elements and gases in well waters of parts of the St. Lawrence Lowlands, (Ottawa region) Canada

To test the usefulness of groundwater for U prospecting, 130 domestic wells were sampled from a 22,000 km² rectangular area extending south and west from Ottawa, Ontario. The waters were analyzed for twenty variables including ten gases and five trace elements.The dissolved gases give information on subsurface chemical and geological environments. Carbon dioxide highs occur at the contact of granites and limestones; He highs are along major faults; CH₄ and H₂S reveal strongly reducing environments, and O₂ in wells indicates shallow wells or active water turnover. Rn reveals U mineralization and granitic rocks.The South March U-Cu surface occurrence gives coincident U, Cu, Zn, Pb and Rn highs. A weak U-Rn-Cu high in the Richmond-North Gower area suggests more radioactive subcropping March formation there.A strong regional He anomaly coincident with the outcropping Rockcliffe Formation and controlled by the Hazeldean Fault is believed to be due to deep-seated He, but its coincidence with a weak regional Cu anomaly, a Rn anomaly in the Bells Corners area, its linear northeast trend, the presence of Helikian U-rich source rocks to the southwest, and northeast-dipping Paleozoic sandstones provide both indications of, and the right environment for epigenetic type U-Cu occurrences.     

Geometric analysis and scaling relations of deformation bands in porous sandstone

Displacement, length and linkage of deformation bands have been studied in Jurassic sandstones in southeastern Utah. Isolated deformation bands with lengths (L) that span more than three orders of magnitude show similar displacement (D) profiles with more or less centrally located maxima and gently increasing gradient toward the tips. Soft- and hard-linked examples exhibit steeper displacement gradients near overlap zones and immature hard links, similar to previously described fault populations. The deformation band population shows power-law length and displacement distributions, but with lower exponents than commonly observed for populations of larger faults or small faults with distinct slip surfaces. Similarly, the D_max-L relationship of the deformation bands shows a well-defined exponent of ca 0.5, whereas the general disagreement for other fault populations is whether the exponent is 1 or 1.5. We suggest that this important difference in scaling law between deformation bands and other faults has to do with the lack of well-developed slip surfaces in deformation bands. During growth, deformation bands link to form zones of densely spaced bands, and a slip surface is eventually formed (when 100 m < L < 1 km). The growth and scaling relationship for the resulting populations of faults (slip surfaces) is expected to be similar to ‘ordinary’ fault populations. A change in the D_max-L scaling relationship at the point when zones of deformation bands develop slip surfaces is expected to be a general feature in porous sandstones where faults with slip surfaces develop from deformation bands. Down-scaling of ordinary fault populations into the size domain of deformation bands in porous sandstones is therefore potentially dangerous.     

Wetting weakening of tertiary sandstones—microscopic mechanism

The micromechanism accounting for wetting weakening of tertiary sandstones was studied. It was found that intragranular fracture prevails for all dry sandstones. However, when the sandstone is wet, intergranular fracture occurs for Type B sandstones. Therefore, one sandstone from Type A sandstones, MS1, and another from Type B, TK, were selected to further investigate the nature of the matrix. It was found that (1) for both sandstones, the major mineral components of the matrix are illite and kaolinite except that the MS1 sandstone has more chlorite; (2) leaching of matrix induced an increase of porosity and consequently results in leaching softening; and (3) among the mineral composition, chlorite is easiest to be dissolved and leached out and induces a more significant increase of porosity, which, in turn, results in a more significant leaching softening.     

Geochemistry and Provenance of Maastrichtian Clastic Rocks in the Dikmendede Formation of Orhaniye in Kazan-Ankara-Turkey Region

An integrated petrographic and geochemical study of the sandstones of the Maastrichtian-aged in the Orhaniye (Kazan-Ankara-Turkey) was carried out to obtain more information on their provenance, sedimentological history and tectonic setting. Depending on their matrix and mineralogical content, the Maastrichtian sandstones are identified as lithic arenite/wacke. The Dikmendede sandstones derived from types of provenances, the recycled orogen and recycled transitional. The chemical characteristics of the Dikmendede sandstones, i.e., fairly uniform compositions, high Th/U ratios (>3.0), negative Eu anomalies (Eu/Eu* 0.72–0.99) and Th/Sc ratios (mostly less than 1.0), favor the OUC (old upper continental crust) provenance for the Dikmendede sandstones. The SiO2/Al2O3, Th/Sc (mostly <1.0) and La/Sc (<4.0) ratios are; however, slightly lower than typical OUC, and these ratios may suggest a minor contribution of young arc-derived material. The rare earth element (REE) pattern, and La/Sc versus Th/Co plot suggests that these sediments were mainly derived from felsic source rocks. The Dikmendede sandstones have high Cr (123–294 ppm) and Ni (52–212 ppm) concentrations, Cr/Ni ratio of 1.93, and a medium correlation coefficient between Cr and Ni and corresponding medium to high correlation of both (Cr and Ni, respectively) elements with Co. These relationships indicate a significant contribution of detritus from ophiolitic rocks. As rare earth element data are available for the Dikmendede sandstones, the Eu/Eu* is compared with LaN/YbN. Samples plot in the area of overlapping between continental collision, strike-slip and continental arc basins. The predominantly felsic composition of the Dikmendede sandstones is supported by the REE plots, which show enriched light REE, negative Eu anomaly and flat or uniform heavy REE. The Dikmendede sandstones have compositions similar to those of the average upper continental crust and post-Archean Australian shales. This feature indicates that the sediments were derived mainly from the upper continental crust. The Dikmendede sandstones have chemical index of alteration (CIA) values of 28–49, with an average of 40 indicating a low degree of chemical weathering in the source area. The compositional immaturity of the analyzed sandstone samples is typical of subduction-related environments, and their SiO2/Al2O3 and K2O/Na2O ratios and Co, Sc, Th and Zr contents reflect their oceanic and continental-arc settings. The Dikmendede sandstones were developed as flysch deposits derived from mixed provenance in a collision belt.     

The Inata deposit,Belahouro District,northern Burkina Faso

The Inata gold deposit is hosted in the Bouroum greenstone belt of northern Burkina Faso and contains ca. 5 Moz of gold resource. The greenstone belt is divided into 4 distinct domains: The Pali West, Pali-Minfo and Fété Kolé domains comprised of variable proportions of mafic to intermediated volcanic, volcaniclastic and sedimentary rocks, and the Sona Basin comprised of feldspathic sandstones and turbidites. Potential Tarkwaian-like conglomerates are rarely observed on the eastern margin of the basin. The stratigraphy is crosscut by a series of intrusions between 2172 ± 15 Ma and 2122 ± 4 Ma. A complex deformation sequence is recorded in the rocks and has been interpreted in a five stage scheme: early syn-depositional basin margin faults reactivated through time and partitioning all subsequent regional deformation (De_B); N–S compression (D1_B > 2172 Ma); E-W compression (D2_B, < ca 2122 Ma); NW–SE compression (D3_B), and a late N–S compression (D4_B). D2_B-D4_B overprint all rocks, including those of the Sona Basin and Tarkwaian-like conglomerates. Peak metamorphism is mid- to upper-greenschist facies.Mineralisation at Inata is hosted in black shales and volcaniclastic rocks of the Pali-Minfo domain and comprises shear-zone hosted quartz-tourmaline-ankerite veins with associated sulphides dominated by pyrite and arsenopyrite. Three generations of pyrite (py1, py2, py3) and one generation of arsenopyrite (apy2) have been identified. Py1 is parallel to bedding and early D1_B foliation and not associated with gold. Py2 and apy2 are coeval, contain up to 1 ppm gold and are spatially associated with auriferous quartz veins. Py3 locally overprints previous assemblages and is also associated with Au. Fluid inclusions in quartz indicate H₂O to H₂O–CO₂–NaCl fluids in auriferous quartz veins.Microscopic to macroscopic observation of fabric-mineral-vein crosscutting relationships indicate that mineralisation is syn-D2_B, disrupted and remobilised during D3_B. All observations and data are consistent with Inata representing an orogenic style of gold mineralisation formed relatively late in the evolution of the host terrane.     

Geochemistry of the sandstones of Punagarh basin: Implications for two source terranes and Arabian - Nubian connection of Aravalli craton?

Sandstones of Punagarh basin of Trans Aravalli region, NW Indian shield were analyzed for their major and trace element contents in conjunction with petrographic modes. The Punagarh basin comprises four formations (Sojat, Bambolai, Khamal and Sowania), amongst which the Sojat Formation in uncoformable contact with overlying formations, is significantly older and enjoys separate status as rest of the formations constitute Punagarh Group. Petrographic attributes suggest that Sojat sandstones contain distinct modal abundances like high content of quartz and low content of feldspar, mica, matrix, rock fragments and cement. In general there is a decrease in the average modal abundance of quartz and mica with concomitant increase of feldspar, chert and rock fragments from base to top in Punagarh sandstones. Sojat sandstones are also geochemically distinct as they possess high SiO₂/Al₂O₃, Th/U and Cr/Th ratios coupled with lowest Na₂O/K₂O ratio and Zr content, least fractionated LREE, more fractionated HREE and largest Eu* anomaly compared to Punagarh sandstones. The weathering indices suggest intense chemical weathering for Sojat sandstones and low to moderate for Punagarh sandstones. Compositionally all the sandstones of the Punagarh basin come under the category of quartzarenite. Compared to PAAS and UCC, both suite of sandstones are generally depleted in REE, HFSE (with exception of Zr, Hf and Ta), and enriched in ferromagnesian trace elements particularly Cr and Co. The chemical data indicate that the sediments were derived from the source(s) of mixed felsic - mafic composition, with the former being dominant. The source rocks were granites, TTG, basalts, and rhyolites. The Sojat sandstones owe their source form Archean crust while Punagarh sandstones got detritus from Mesoproterozic crust. Immobile element ratios and REE abundances of Sojat sandstones closely match with Paleoproterozoic metagreywackes of Ghana of African craton while Punagarh sandstones show near geochemical characteristic with Gogunda, Kumbalgarh and Vindhyan quartzites of Aravalli craton. This geochemical similarity of Sojat sandstones provides credence to the hypothesis that Trans–Aravalli region of India had been an integral part of Arabian - Nubian shield. The chemical data advocate the deposition of these sandstones in a tectonic setting comparable to modern back arc setting.     

Geochemical characteristics of sandstones from Cretaceous Garudamangalam area of Ariyalur,Tamilnadu, India: Implications of provenance and tectonic setting

The Trichinopoly Group (later redesignated as Garudamangalam) has unconformable relationship with underlying Uttatur Group and is divided into lower Kulakanattam Formation and upper Anaipadi Formation. These calcareous sandstones are analysed major, trace and rare earth elements (REEs) to find out CIA, CIW, provenance and tectonic setting. The silica content of fossiliferous calcareous sandstone show wide variation ranging from 12.93 to 42.56%. Alumina content ranged from 3.49 to 8.47%. Higher values of Fe₂O₃ (2.29–22.02%) and low MgO content (0.75–2.44%) are observed in the Garudamangalam Formation. CaO (23.53–45.90) is high in these sandstones due to the presence of calcite as cementing material. Major element geochemistry of clastic rocks (Al₂O₃ vs. Na₂O) plot and trace elemental ratio (Th/U) reveal the moderate to intense weathering of the source rocks. The Cr/Zr ratio of clastic rocks reveal with an average of 1.74 suggesting of felsic provenance. In clastic rocks, high ratios of \(\sum \)LREE/\(\sum \)HREE, La/Sc, Th/Sc, Th/Co, La/Co and low ratios of Cr/Zr, and positive Eu anomaly ranges from (Eu/Eu* = 1.87–5.30) reveal felsic nature of the source rocks.     

Geology and tectonics of the Boa Vista Basin (Paraíba, northeastern Brazil) and geochemistry of associated Cenozoic tholeiitic magmatism

The Boa Vista Basin (BVB) is located approximately 60 km southwest of Campina Grande, Paraíba, northeastern Brazil. It has a half-graben geometry controlled by dip-slip normal faults striking NE–SW. From the base to the top, the BVB is composed of (1) a lower volcanic unit of altered basalts and basaltic andesites overlying Precambrian basement rocks, (2) an intermediate unit of bentonitic shales that pass upward to medium- to coarse-grained sandstones and conglomerates and downward to sandstones and siltstones, and (3) an upper volcanic unit of massive to vesiculated basaltic flows grading to pillowed or autobrecciated basalts. These basalts show porphyritic (olivine and augite microphenocrysts), glomeroporphyritic, intersetal, pilotaxitic, and variolitic textures. They are medium-K, Fe-rich tholeiites with SiO₂ of 50.2–53.3 wt%, magnesium number of 50.54–60.21 wt%, total alkali of 2.15–3.92 wt%, and TiO₂ of 1.8–1.9 wt% and are related by low-pressure fractionation of olivine, plagioclase, magnetite, ilmenite, and apatite. They are LREE-enriched (La_N/Yb_N=8.54–44.14) with no significant europium anomaly. Trace element modeling suggests a garnet-bearing metasomatised lherzolite as their source. The geological context and geochemistry of the basalts suggest a close connection between reactivated deep-rooted Precambrian shear zones, which channeled mantle-derived Tertiary tholeiitic magmas, and continental rifting in northeastern Brazil.     

The structures of the Ardsheal Peninsula,Argyll, their age and regional significance

The lithologies and structures of the Dalradian rocks of the Ardsheal Peninsula, Argyllshire are described. The structures associated with the main synformal fold (part of the Appin Syncline) are shown to be F₁ in age. F₂ structures cross the Syncline and show progressive development towards the east. The Syncline is correlated and compared with other major F₁ folds in the region. This interpretation is contrasted with other interpretations of the Syncline as a third-phase structure which can be correlated with late-phase folds in the Dalradian.     

Petrography and geochemistry of Eocene sandstones from eastern Pontides (NE TURKEY): Implications for source area weathering,provenance and tectonic setting

Subaerial weathering level, source area and tectonic environments were interpreted by using petrographic and geochemical characteristics of Eocene age sandstones found in the eastern Pontides. The thickness of Eocene age clastic rocks in the eastern Pontides ranges from 195 to 400 m. Mineralogical components of sandstones were mainly quartz, feldspar, rock fragments, and opaque and accessory minerals. Depending on their matrix and mineralogical content, Eocene age sandstones are identified as arkosic arenite-lithic arenite and feldspathic wacke-lithic wacke. CIA (Chemical Index of Alteration) values observed in the Eocene age sandstones (43–55) suggest that the source terrain of the sandstones was not affected by intense chemical weathering. Low CIW/CIA (Chemical Index of Weathering/Chemical Index of Alteration) values of the sandstones studied here suggest only slightly decomposed material and having undergone little transport until final deposition. Zr/Hf, Th/Sc, La/Sc and CIA ratios are low and demonstrate a mafic source; on the other hand, high LREE/HREE ratios and a slightly negative Eu anomaly indicate a subordinate fclsic source. Modal mineralogical and SiO₂/Al₂O₃ and K₂O/Na₂O and Th, Zr, Co, Sc of Eocene age sandstone contents indicate that they are probably magmatic arc originated and deposited in the back arc basin.     

Geochemistry of fine-grained sediments of the upper Cretaceous to Paleogene Gosau Group （Austria, Slovakia） Implications for paleoenvironmental and provenance studies

Bulk rock geochemistry of 169 fine-grained sediment samples of the upper Cretaceous to Paleogene Gosau Group（Northern Calcareous Alps,Austria and Slovakia） from borehole and outcrop localities was performed to separate non-marine and marine deposits.Geochemical characteristics of different Gosau depositional systems,basins and sediment provenance using major-,trace-,and rare earth elements were also investigated.Geochemical proxies such as boron concentrations were tested for seeking the possibilities of paleosalinity indicators.Due to the fact that several pelagic sections are represented by extremely low boron contents.B/Al^* ratios are recognized as more robust and differentiate reliably between marine（mean:160±34） and non-marine（mean:133±33） samples.Using statistical factor analysis,hemipelagic to pelagic samples from the Gieβhbl Syncline and Slovakian equivalents can be differentiated from marginal-marine to non-marine samples from the Grnbach and Glinzendorf Syncline related to terrigenous（SiCh.Al₂O₃,K₂O,Th,Rb,Zr and others） and pelagic indicative elements （CaO,Sr,TOT/C and B/Al^*）.A clear indication for ophiolitic provenance is traced by high amounts of chromium and nickel.Only non-marine successions of the Glinzendorf Syncline show higher Cr and Ni concentrations（up to 250 and 400 ppm,respectively） and enriched Cr/V and Y/Ni ratios trending to an ultramafic source.     

The application of lithogeochemistry in the search for unconformity-type uranium deposits, Northern Saskatchewan, Canada

Lithogeochemical-mineralogical haloes around unconformity-type uranium deposits in northern Saskatchewan can expand the size of drill targets up to fifteen times. The deposits are located at or near the unconformity between Aphebian metamorphosed basement rocks in close proximity to Archean granitoids and overlying unmetamorphosed sandstones of the Helikian Athabasca Group. Deposits studied include Key Lake (Deilmann), Midwest Lake and Eagle Point.Unconformity-type deposits are associated with broad alteration haloes in the overlying sandstones and more restricted haloes in the basement rocks. The haloes in the sandstone are localized around steeply dipping fault structures and are characterized by zones of intense leaching of specular hematite and detrital heavy mineral layers and by changes in chemistry related to clay mineral alteration and tourmalinization.Clay mineral alteration haloes are common in the sandstone and basement host rocks. Interstitial clays consist mainly of kaolinite and illite with lesser amounts of chlorite. The ratio K₂O/AI₂O₃ proved useful in delineating illite-kaolinite patterns in the sandstone and in the uppermost portions of the paleoweathering profile in basement rocks. The Midwest deposit is characterized by a broad bell-shaped zone (500 m across strike) of high K₂O/AI₂O₃ ratios (>0.18) in which illite is the dominant clay mineral. The sandstone above the Deilmann deposit, on the other hand, is characterized by silicification and kaolinitization with low K₂O/AI₂O₃ ratios (<0.04). This kaolinite cap overprints a preexisting illite zone.Anomalously high boron values are characteristic of the three deposits considered in this study. Boron anomalies are similar in extent to the anomalous clay mineral alteration haloes. Altered sandstones commonly contain aggregates of radiating magnesium-rich dravite needles within the clay matrix. The interpretation of boron patterns is problema tical however, mainly because of the detrital tourmaline component in sandstones and metamorphic tourmalines present in the Aphebian metasediments.Trace elements such as U, Ni, As and Co are generally of limited use in expanding targets in sandstone because their haloes are restricted to a few tens of metres horizon-anomalies along the steeply dipping zones of mineralization related to fault structures. Uranium (>3 ppm) does form an anomaly more than 200 metres laterally across the Midwest deposit. At the Deilmano deposit anomalous uranium dispersion is restricted to within a few metres of high grade ore.In the basement rocks, the various layers of the paleoweathering profile are geochemically overprinted up to 250 m from mineralization. Bleaching related to illitization and chloritization is associated with enrichment in K₂O, MgO, B, S, U, As, Ni and P₂O₃. The ratio Fe₂O₃/MgO is useful in delineating chloritization in the upper portion of the paleo weathering profile.Deposits with large root extensions in the Aphebian metasediments such as Eagle Point, have intense dravite-chlorite-illite alteration zones which are restricted to within a few metres of mineralization across strike. ‘Quartzite” units are alteration related. The complexity of the basement lithology inhibits the use of individual elements as alteration guides other than in the intensely altered zone. The application of multivariant techniques, element ratios and clay mineralogical work prove useful in identifying the mineralogical changes at Eagle Point.     

Petrography and geochemistry of the Upper Cretaceous Nubia sandstones,Eastern Desert,Egypt: implications for provenance,paleoweathering, and tectonic setting

The provenance of the Upper Cretaceous Nubia sandstones from four vertical sections along Qena-Safaga and Qena-Quseir roads in central Eastern Desert of Egypt was investigated based on their modal composition and geochemical data. The Nubia sandstone samples are abundant in quartz content with low feldspar and lithic fragments. Their average modal composition (Q_94.2F_1.3R_4.5) classifies them as quartz arenites with subordinate quartz wackes which is consistent with geochemistry data. The average CIA, CIW, PIA, and Th/U ratio values revealed that the intensity of weathering in the studied areas was similar, varying from moderate to intensive weathering, and may reflect low-relief and warm humid climatic conditions in the source area. The ICV (<?1) and SiO₂/Al₂O₃ ratio (>?5) indicate that the Nubia sandstones are texturally and mineralogically mature. The petrographical and geochemical analyses suggest that the Nubia sandstones were mainly derived from felsic (granitic) and/or recycled sand sources. The major element-based multidimensional tectonic discrimination diagrams suggested the Nubia sandstones were deposited in a passive continental margin of a syn-rift basin. This result agreed with the general geology of central Eastern Desert of Egypt during the Upper Cretaceous.     

Geochemical modelling of sandstone diagenesis and its consequences on the evolution of porosity

Geochemical modelling of fluid-rock interaction is one theoretical approach that can be used for understanding diagenetic processes and their effects on reservoir quality. Results of successive modelling of dissolution and heating, using two specific path calculation codes DISSOL and THERMAL, from 25 to 160°C, are presented. If one considers one volume of reacting solution, the diagenetic effects are very important for fluid chemistry, while mass transfers have little effect on porosity. Only cumulative effects due to the circulation of fluids in reservoirs may explain the extent of diagenetic processes on minerals. Comparison between the computed data (this study) and available data from the North Sea, from Gulf Coast sandstones, from Pattani Basin (Gulf of Thailand), from San Joaquin Basin (California, U.S.A.) and from a Triassic sandstone reservoir in the Rhine Graben (Cronenbourg, France) show interesting similarities in the chemical evolution of the fluid. The modelling has interesting implications for the relations between ph-pCO₂ conditions and the diagenetic stability of calcic plagioclase.     

Petrography and geochemistry of clastic sedimentary rocks as evidences for provenance of the Lower Cambrian Lalun Formation, Posht-e-badam block, Central Iran

Petrography and geochemistry (major, trace and rare earth elements) of clastic rocks from the Lower Cambrian Lalun Formation, in the Posht-e-badam block, Central Iran, have been investigated to understand their provenance. Petrographical analysis suggests that the Lalun conglomerates are dominantly with chert clasts derived from a proximal source, probably chert bearing Precambrian Formations. Similarly, purple sandstones are classified as litharenite (chertarenite) and white sandstones as quartzarenite types. The detrital modes of purple and white sandstones indicate that they were derived from recycled orogen (uplifted shoulders of rift) and stable cratonic source. Most major and trace element contents of purple sandstones are generally similar to upper continental crust (UCC) values. However, white sandstones are depleted in major and trace elements (except SiO₂, Zr and Co) relative to UCC, which is mainly due to the presence of quartz and absence of other Al-bearing minerals. Shale samples have considerably lower content in most of the major and trace elements concentration than purple sandstones, which is possibly due to intense weathering and recycling. Modal composition (e.g., quartz, feldspar, lithic fragments) and geochemical indices (Th/Sc, La/Sc, Co/Th, Cr/Th, Cr/V and V/Ni ratios) of sandstones, and shales (La/Sc and La/Cr ratios) indicate that they were derived from felsic source rocks and deposited in a passive continental margin. The chondrite-normalized rare earth element (REE) patterns of the studied samples are characterized by LREE enrichment, negative Eu anomaly and flat HREE similar to an old upper continental crust composed chiefly of felsic components in the source area. The study of paleoweathering conditions based on modal composition, chemical index of alteration (CIA), plagioclase index of alteration (PIA) and A–CN–K (Al₂O₃ − CaO + Na₂O − K₂O) relationships indicate that probably chemical weathering in the source area and recycling processes have been more important in shale and white sandstones relative to purple sandstones. The results of this study suggest that the main source for the Lalun Formation was likely located in uplifted shoulders of a rifted basin (probably a pull-apart basin) in its post-rift stage (Pan-African basement of the Posht-e-badam block).     

Detrital Zircon Records of the Banxi Group in the Western Jiangnan Orogen: Implications for Crustal Evolution of the South China Craton

The Neoproterozoic evolution of the Jiangnan Orogen is important for understanding the tectonic history of South China. As a volcanic-sedimentary sequence developed in the Nanhua rift, the Banxi Group preserves the records of important magmatic and tectonic events linked to the assembly and breakup of the Rodinia supercontinent. In this study, we report the results from whole-rock major-and trace-element concentrations, with zircon LA-(MC)-ICP-MS U-Pb ages, trace elements and Lu-Hf isotopic comp...     

A theoretical investigation of the relative stabilities of Fe-free clinozoisite and orthozoisite

 The relative stabilities of orthozoisite, Ca₂Al₃[O|OH|Si₂O₇|SiO₄], space group Pnma, and the monoclinic polymorph, clinozoisite, space group P2₁/m, have been investigated using calculations based on density functional theory. It is found that orthozoisite is more stable than clinozoisite by about 1 kJ mol⁻¹ at zero pressure in the athermal limit. The bulk moduli of the two polymorphs have been calculated to be B_ortho=117.5(1.7) GPa and B_clino=136(4) GPa. Received: 20 March 2000 / Accepted: 26 February 2001     

The biogeochemical expression of deeply buried uranium mineralization in Saskatchewan, Canada

Ten kilometres from the eastern edge of the Athabasca Sandstone, near McClean Lake, uranium mineralization (locally up to 27% U₃O₈) lies 150 m beneath the surface at the unconformity between the Athabasca and crystalline basement.A biogeochemical survey of the area sampled A_H and B_F soil horizons, peat moss, and plant organs from the dominant species, viz. black spruce (Picea mariana), jack pine (Pinus banksiana), labrador tea (Ledum groenlandicum), and leather leaf (Chamaedaphne calyculata). Uranium concentrations in the ash of various media are surprisingly high: spruce twigs up to 154 ppm U; labrador tea and leather leaf stems around 100 ppm U. Conversely, labrador tea roots yield < 5 ppm U and spruce trunk wood usually < 1 ppm U. Soils give values of 1–3 ppm U. Contoured U values reveal that highest concentrations occur in plants growing above, but laterally displaced from the mineralization. Track-Etch data show a similar pattern. Upward migration of ions along steeply inclined fractures is invoked to explain the phenomenon. Other elements are present in varying concentrations, depending upon the plant species and the plant organ. High concentrations of several elements are recorded, most notably Cd and Ag in the conifers.