Dating of thaw depths in permafrost terrain by the palaeomagnetic method: experimental acquisition of a freezing remanent magnetization

The acquisition of a freezing remanent magnetization (FRM) has been studied in controlled magnetic and thermal environments by successive freezing and thawing (−18 to +20°C) of samples of natural sediments from a frost polygon near Ny Ålesund, Spitsbergen. Successive freeze-thaw cycles cause a significant decrease in the intensity of the initially induced shock remanent magnetization (SRM), associated with directional trends towards the ambient magnetic field direction during the freezing phase. A slow increase in intensity commences after seven to 10 freeze-thaw cycles. The acquisition of a FRM in samples carrying an isothermal remanent magnetization shows a significantly smaller reduction in intensity and only minor directional variations. This result indicates that only a fraction of the magnetic grains in a natural sediment contributes to the natural remanent magnetization. Insignificant changes in lengths and directions of the principal susceptibility ellipsoid axes also indicate that magnetic fabric and remanent magnetization are carried by partly different populations of magnetic grains.
The acquisition of a FRM in nature has yet to be explored. If such a process is confirmed, however, it has the potential for obtaining age estimates of ancient thaw depths and for providing insights into material transport processes in frost polygons.     

Decay of a post-depositional remanent magnetization in wet sediments due to the effect of drying

Summary. The decay of the post-depositional remanent magnetization (post-DRM) during desiccation in magnetic field free space is measured as a function of the loss of water. The decay is ascribed to the drying effect and the time decay of viscous remanent magnetization (VRM). The VRM forms only 10 per cent of the total of loss of remanent magnetization. The decay due to the drying effects depends both on the loss of water and on either the evaporation rate or the period of storage. The percentage of loss of magnetization is independent of its intensity.
A critical drying stage appears (about 60 per cent in water content on a dry basis) which is characterized as a vanishing point of mobile particles or particle units. The mobile particles or units play an important role both in acquisition and demagnetization through physical rotational motion within wet sediments before the critical drying stage. More than 80 per cent of the total loss of the post-DRM is destroyed before the desiccation proceeds to the critical drying stage. The decay of post-DRh4 is concluded to be mainly due to the physically random rotation of the magnetic particles trapped in shallow energy wells which are overcome by the torques caused by the application of the alternating magnetic field less than 200 Oe.     

A magnetization process of sediments: laboratory experiments on post-depositional remanent magnetization

Summary. Palaeomagnetic studies require a theory of magnetization mechanism of sediments and a method of estimating magnetic field intensity from their remanences. This paper establishes a physical basis for the generation of the remanence in deep-sea and lake sediments experimentally.
Redeposition experiments have been carried out under centrifugal force in weak magnetic fields. The centrifuging method produces post-depositional remanent magnetization (post-DRM) in the compacted sediment, and its remanence and susceptibility are compatible with those of natural sediments and reconstituted materials of other redepositional experiments. Three properties of the post-DRM have been deduced from the experiments: (1) the efficiency of acquisition of post-DRM decreases with increase in density during the compaction process, (2) the total post-DRM is equal to the sum of the partial post-DRM (addition law), and (3) time is not a substantial factor for alignment of the magnetic particles. These results lead to the conclusions that the magnetic particles do not rotate steadily but in a series of steps, and that the density change is the crucial factor giving rise to the post-DRM.
A mathematical formula representing the remanence record in sediments is proposed on the basis of the experimental results and the model. The principal equation is expressed as an integral of the product of three parameters over time when sediments have been compacted; the field intensity variation, characteristic function of the sediment and the time derivative of the density change.     

Laboratory studies of depositional DRM

Summary. Acquisition of magnetic remanence in slurries of fme grained organic muds settling in long tubes is investigated using a cryogenic magnetometer. The average settling behaviour of remanence carrying grains relative to the whole sediment gives information about the relative magnetic grain size spectrum, whereas the response of settled deposits to vibration gives an indication of the degree of alignment of particles and their average shape.
Two classes of behaviour are apparent in both the time and field dependence of detrital remanent magnetization (DRM) acquisition. Dilute slurries settling in the Earth's field (analogous to detrital sedimentation) acquire a remanence which reaches a maximum after about 2 day, whereas for concentrated slurries (analogous to slumped or bioturbated sediments) this takes only a matter of minutes. The field dependence of DRM in dilute slurries is in plausible quantitative agreement with Stacey's extension of the classical Langevin expression for the susceptibility of a paramagnetic gas, whereas concentrated slurries show a quasi-linear dependence of DRM on the applied field. Inclination errors are generally absent, but do appear in fields less than about 0.5 Oe, and when the magnetic fraction settles out preferentially. A weak negative dependence of DRM on temperature is found, but the results are too crude to provide a further test of Stacey's theory.
Remanence acquisition in slurries settled in zero field indicates that short term post-depositional magnetization processes are relatively unimportant in slurries that have ceased to compact rapidly. A large increase in remanence from naturally occurring sediments to slowly redeposited long cores, to rapidly settled slurries is best explained as a feature of compaction.     

Are hydrodynamic shape effects important when modelling the formation of depositional remanent magnetization?

Recent conceptual models have attributed the weak depositional remanent magnetizations observed in natural sediments to flocculation processes in the water column. Magnetic particles included into flocs have not only to rotate themselves into alignment with the geomagnetic field but also the larger particles to which they are attached, making remanence acquisition an inefficient process. Alignment is hindered further when the magnetization vectors of the particles in any given floc partially cancel, reducing the overall magnetic torque. Existing numerical simulations of flocculation effects on depositional remanence formation have been limited to spherical bodies with translational and rotational motion acting independently of each other. In the case of non-spherical flocs, the translational and rotational motion are coupled and such bodies will describe a complex trajectory through the water column. Calculations will be presented that show the torque exerted on a non-spherical floc by the surrounding water can be orders of magnitude greater than the magnetic torque. Non-spherical flocs will, therefore, align less efficiently with the geomagnetic field and hydrodynamic effects may play an important role in controlling the magnitude of sedimentary remanence.     

Gyroremanent magnetization and the magnetic properties of greigite-bearing clays in southern Sweden

The acquisition of a gyroremanent magnetization (GRM) by single-domain (SD) greigite particles during alternating-field (AF) demagnetization is demonstrated. Previous palaeomagnetic studies failed to identify the presence of authigenic greigite in the glacio-marine clays studied. These clays formed the subject of an earlier debate about the validity of a Late Weichselian geomagnetic excursion (the Gothenburg Flip) in southern Sweden. The greigite carries a stable chemical remanent magnetization (CRM), which coexists with a detrital remanent magnetization (DRM) carried by magnetite. AF demagnetization could not isolate the primary remanence in the sediments where magnetite and greigite coexist, due to the overlapping coercivity spectra of the two minerals and the inability to determine the time lag between sediment deposition and CRM formation. Thermal demagnetization removed the CRM at temperatures below 400 C, but this method was hindered by the unconsolidated nature of the sediments and the formation of secondary magnetic minerals at higher temperatures. The results suggest that the low-coercivity DRM carried by magnetite was mistaken for a 'viscous' component in the earlier studies. Hence the former debate about the record of the Gothenburg Flip may have been based on erroneous palaeomagnetic interpretations or non-reproducible results. AF demagnetization procedures applied to samples suspected of bearing SD magnetic particles (such as greigite) should be carefully selected to recognize and account for GRM acquisition.     

The palaeomagnetism and magnetic fabric of sediments from Peak Cavern, Derbyshire

Summary. This paper describes the magnetic remanence and susceptibility anisotropy of 42 samples of laminated clay from Peak Cavern. The sediments are shown to have acquired a stable remanent magnetization due to the depositional alignment of magnetite grains. The magnetic fabric data confirm the existence of alteration within a reddened surface layer. A record of geomagnetic secular variation in the underlying clay is compared to a dated lake sediment magnetostratigraphy to suggest that deposition occurred around 7000 yr bp . A method for estimating water current directions based on the remanence and magnetic fabric data is critically assessed before deducing the sense of palaeoflow in the cave.     

Surface tension phenomena in the magnetization of sediments

Summary. This paper examines the role of surface tension effects in the post-depositional magnetization of a sediment. After deposition, magnetic grains experience both frictional and magnetic forces but during dessication surface tension forces also become important. It is shown from order of magnitude calculations that surface tension forces will predominate for grains smaller than about 1.3 mm and therefore remanence changes may occur in fine grained sediments upon drying. A simple model predicts that in a moist sediment containing bladed magnetic particles the effect of vertical fluctuations in the level of saturation will be to shallow the remanent inclination.
Remanence changes due to surface tension are demonstrated in a controlled experiment with synthetic sediment. Implications for sediment palaeomagnetism are discussed and alternative drying procedures for sediments are suggested.     

The rock magnetism of the Mississippian Madison Limestone north-central Wyoming

Summary. A history of remanence acquisition in the Madison Limestone in north-central Wyoming suggests that many processes affected the primary magnetization, including (1) dolomitization, (2) solution of evaporites during uplift in the Late Mississippian and (3) partial remagnetization in the Late Cretaceous or Cenozoic. The stability and intensity of the magnetization was greatest in the dolomitic limestones, while the dolomites and the less intense fossiliferous limestones contained magnetization of intermediate directional stability. The coarse- and fine-grained limestones gave erratic directions. The preservation of the Mississippian magnetization in the dolomitic limestone from the lower portion of the Madison testifies to the delicate mechanism of the dolomitization process, and suggests that the dolomitization may even have aided in the preservation of the magnetization. The presence of solution features corresponds closely to the presence of unstable directional behaviour. It appears that the formation of these features by solution of the evaporite beds led to the destruction of the primary remanence in the upper portion of the Madison.
Thermomagnetic curves indicate the presence in the lower portion of the Madison of almost pure magnetite. Although thermomagnetic curves from the upper portion are irreversible, alternating field and thermal demagnetization experiments show intensity changes similar to those from the lower portion, suggesting a similar magnetic mineral. Isothermal remanent magnetization acquisition curves also suggest the presence of a large amount of hematite or goethite in over half the samples which apparently did not contribute significantly to the natural remanent magnetization.     

Fidelity and time resolution of the magnetostratigraphic record in Siwalik sediments: high-resolution study of a complete polarity transition and evidence for cryptochrons in a Miocene fluviatile section

The Surai Khola section in southwest Nepal, a 5000 m continuously exposed record of fluvial sedimentation since Middle Miocene, was revisited for high-resolution magnetostratigraphy in sequences with expected cryptochrons and reversals of the geomagnetic field. Polarity intervals with durations of a few tens of thousands of years are recorded as zones of stable palaeomagnetic directions. Polarity transitions are recorded as zones with complex demagnetization behaviour of specimens in the sedimentary column. Almost antiparallel palaeoremanence directions, residing in different haematite phases in the same specimens, could generally not be separated properly by thermal demagnetization. Differing demagnetization paths for neighbouring specimens during a reversal suggest that measured transitional directions are not true geomagnetic field directions, but rather are generated by the superposition of variable amounts of at least two almost antiparallel components of magnetization. Accompanying studies of recent river sand deposits demonstrate that these sediments acquire a true depositional remanent magnetization (DRM) with considerable inclination errors and scattered directions for individual specimens.     

The detection of single-domain greigite (Fe3S4) using rotational remanent magnetization (RRM) and the effective gyro field (Bg): mineral magnetic and palaeomagnetic applications

The intensity of rotational remanent magnetization (RRM) acquired by single-domain greigite at a rotation frequency of 5 rps was combined with measurements of anhysteretic remanent magnetization (ARM) to calculate the effective biasing field ( Bg ) that produced the RRM. Samples of single-domain greigite had Bg values between -137 and -84 μT, and a MDF_RRM of c. 80 mT. By contrast, a suite of natural and synthetic ferrimagnetic iron oxide samples, including single-domain magnetite and y Fe₃O₄ tape particles, acquired Bg values between -3 and -14 μT, and MDF_RRM ranged between 43 and 68 mT (when RRM was acquired). Multidomain magnetite did not acquire a RRM. Bg values at 5 rps were calculated from previously published data for magnetite particles of different grain sizes, which revealed a minimum Bg value of -24 μT and a MDF_RRM of 57 mT for the finest fraction (0.2-0.8 μm in diameter). In a geological example, measurements of Bg and MDF_RRM were used to detect the presence of greigite in a 4 m long Late Weichselian sediment core. Variations in inclination, declination and the intensity of the natural remanent magnetization (NRM) correlate with changes in magnetic mineralogy.     

Greigite (Fe3S4) as an indicator of drought – The 1912–1994 sediment magnetic record from White Rock Lake, Dallas, Texas, USA

Combined magnetic and geochemical studies were conducted on sediments from White Rock Lake, a reservoir in suburban Dallas (USA), to investigate how land use has affected sediment and water quality since the reservoir was filled in 1912. The chronology of a 167-cm-long core is constrained by the recognition of the pre-reservoir surface and by 137Cs results. In the reservoir sediments, magnetic susceptibility (MS) and isothermal remanent magnetization (IRM) are largely carried by detrital titanomagnetite that originally formed in igneous rocks. Titanomagnetite and associated hematite are the dominant iron oxides in a sample from the surficial deposit in the watershed but are absent in the underlying Austin Chalk. Therefore, these minerals were transported by wind into the watershed. After about 1960, systematic decreases in Ti, Fe, and Al suggest diminished input of detrital Fe-Ti oxides from the surficial deposits. MS and IRM remain constant over this interval, however, implying compensation by an increase in strongly magnetic material derived from human activity. Anthropogenic magnetite in rust and ferrite spherules (from fly ash?) are more common in sediment deposited after about 1970 than before and may account for the constant magnetization despite the implied decrease in detrital Fe-Ti oxides. An unexpected finding is the presence of authigenic greigite (Fe3S4), the abundance of which is at least partly controlled by climate. Greigite is common in sediments that predate about 1975, with zones of concentration indicated by relatively high IRM/MS. High greigite contents in sediment deposited during the early to mid-1950s and during the mid-1930s correspond to several-year periods of below-average precipitation and drought from historical records. Relatively long water-residence times in the reservoir during these periods may have led to elevated levels of sulfate available for bacterial sulfate reduction. The sulfate was probably derived via the oxidation of pyrite that is common in the underlying Austin Chalk. These results provide a basis for the paleoenvironmental interpretation of greigite occurrence in older lake sediments. The results also indicate that greigite formed rapidly and imply that it can be preserved in the amounts produced over a short time span (in this lake, only a few years). This finding thus suggests that, in some lacustrine settings, greigite is capable of recording paleomagnetic secular variation.     

Reappraisal of surface wave magnitudes in the Eastern Mediterranean region and the Middle East

We report on a detailed palaeomagnetic study of the Miocene Farellones volcanic formation in the Chilean Andes near Santiago (two sections, 37 sites, about 400 orientated cores). Petrological observations show evidence of low-grade metamorphism increasing downwards through the volcanic sequence. Optical observations of opaque minerals and magnetic experiments suggest that in many cases maghemitization is associated with hydrothermal alteration. However, thermal demagnetization data indicate that the low-grade metamorphism did not significantly modify the direction of the primary remanent magnetization recorded at the time of emplacement of the volcanic lava flows. Four intervals of polarity with two intermediate palaeodirections were observed in the ~650-m-thick composite section. According to the dispersion of flow average directions, palaeosecular variation was slightly larger than that observed in general during the Upper Cenozoic. The site mean directions obtained in this study differ significantly from the expected Miocene direction. Clockwise rotations of up to 20° of small blocks are probably associated with the deformation of the Andean Cordillera since middle Miocene times. Geomagnetic palaeointensity data were obtained, using the Thellier method, on 24 samples from eight distinct lava flows. The flow mean VDM varies from 1.4 to 4.0 × 10²² A m⁻². Altogether, our data seem to suggest the existence of a relatively low geomagnetic field undergoing large fluctuations. Although a linear relationship was observed between the natural remanent magnetization and the thermal remanent magnetization acquired during the Thellier–Thellier experiments, undetected chemical alteration of the magnetic minerals during hydrothermalism may also explain the unusually low palaeointensity obtained.     

Effect of compaction on the acquisition of a detrital remanent magnetization in fine-grained sediments

Summary. Measurements of the detrital remanent magnetization (DRM) of redeposited deep-sea sediment of the silty clay grade are described. Variations in the magnitude of an observed remanence inclination error are related to conditions of sediment accumulation, contrasted here as grain-by-grain settling from a dilute dispersion or by settling from a concentrated slurry. For these artificial redepositions post-depositional compaction is shown to be a major factor in shallowing the observed inclination from the ambient field inclination. The term compactive DRM is tentatively assigned to describe such behaviour.     

Magnetic properties of hydrothermally synthesized greigite (Fe3 S4 )—II. High- and low-temperature characteristics

The magnetic behaviour of hydrothermally synthesized greigite was analysed in the temperature range from 4 K to 700 °C. Below room temperature, hysteresis parameters were determined as a function of temperature, with emphasis on the temperature range below 50 K. Saturation magnetization and initial susceptibility were studied above room temperature, along with X-ray diffraction analysis of material heated to various temperatures. The magnetic behaviour of synthetic greigite on heating is determined by chemical alteration rather than by magnetic unblocking. Heating in air yields more discriminative behaviour than heating in argon. When heated in air, the amount of oxygen available for reaction with greigite determines the products and magnetic behaviour. In systems open to contact with air, haematite is the final reaction product. When the contact with air is restricted, magnetite is the final reaction product. When air is excluded, pyrrhotite and magnetite are the final reaction products; the amount of magnetite formed is determined by the purity of the starting greigite and the degree of its surficial oxidation. The saturation magnetization of synthetic greigite is virtually independent of temperature from room temperature down to 4 K. The saturation remanent magnetization increases slowly by 20–30 per cent on cooling from room temperature to 4 K. A broad maximum is observed at ~10 K which may be diagnostic of greigite. The coercive and remanent coercive force both increase smoothly with decreasing temperature to 4 K. The coercive force increases from ~50 mT at room temperature to approximately 100–120 mT at 4 K, and the remanent coercive force increases from approximately 50–80 mT at room temperature to approximately 110–180 mT at 4 K.     

巴丹吉林沙漠高大沙山湿沙层水分特征

湿沙层水分及其运移过程是沙漠地区水循环的重要环节。巴丹吉林沙漠高大沙山湿沙层规模巨大,本文对巴丹吉林沙漠高大沙山湿沙层水分特征进行了初步分析。结果表明：湿沙层水分具有区域相似性特征,含水量多小于3%;吸附水和沙粒空隙间的水汽是湿沙层水分两种主要的类型,沙粒粒级级配影响吸附水水量变化,两种水分在沙山垂直剖面上的运移过程及相互转化可能维持了湿沙层水分的相对平衡状态;沙丘表层形成的“逆温层”以及由此引起的沿沙丘表层向沙丘内部的热量传递,形成与湿沙层水分蒸发相反的空气运动方向,使得湿沙层水分在夏季晴朗的白天受到保护;夏季受温度梯度影响,湿沙层中的水汽和膜状水向沙山底部缓慢运移;冬季受温度梯度和水势的双重影响,沙山底部潜水面附近的水汽和膜状水向上缓慢运移,补给湿沙层;湿沙层水分来源包括大气降水、大气水汽、凝结水及地下水等。     

Further reliability tests for determination of palaeointensities of the Earth's magnetic field

Summary. In palaeomagnetic studies of volcanic rocks it is often considered that, if the direction of NRM does not change much and the intensity de-creases gradually and smoothly during ac cleaning, then the remanent magnetization is stable and chiefly composed of TRM. This argument is extended as a consistency check to detect unwanted effects during laboratory heating. A simple procedure which employs orientated samples and a short heating (15 min) for TRM acquisition in the laboratory has been used for determining the ancient geomagnetic field intensity using seven volcanic rocks of Late Cenozoic age from central Mexico. The main reliability tests are based on the stability of direction, the close correspondence of the entire coercitivity spectra of both NRM and TRM to ac demagnetization, the low scatter of TRM directions, close correspondence of the TRM directions and the direction of the laboratory magnetic field, proportionality of TRM intensities to applied field, susceptibility comparison before and after heating, and the within-unit consistency of palaeointensity determinations.     

A mineral magnetic and scaled-chrysophyte paleolimnological study of two northeastern Pennsylvania lakes: records of fly ash deposition, land-use change, and paleorainfall variation

A combined mineral magnetic and scaled chrysophyte study of lake sediments from Lake Lacawac and Lake Giles in northeastern Pennsylvania was conducted to determine the effects of land-use and sediment source changes on the variation of pH, conductivity, and alkalinity inferred from biotic changes. Ten 30–40 cm long gravity cores were collected from Lake Lacawac and three from Lake Giles. Isothermal remanent magnetizations (IRMs) were given to the lake sediments in a 1.3 T magnetic field to measure magnetic mineral concentration variations. IRM acquisition experiments were conducted to identify magnetic mineralogy. The bedrock, soils and a peat bog on the shores of Lake Lacawac were also sampled for magnetic analysis to determine possible lake sediment sources. The top 10 cm of sediment collected from Lakes Lacawac and Giles was two to four times more magnetic than deeper sediment. ²¹⁰Pb dating suggests that this intensity increase commenced circa 1900. SEM images of magnetic extracts from the highly magnetic sediments indicates the presence of magnetic fly ash microspheres from fossil fuel burning electric power generation plants. The similarity in magnetic coercivity in the top 8 cm lake sediments and in the peat bog supports an atmospheric source for some of the magnetic minerals in the youngest lake sediments. The highly magnetic sediments also contain an antiferromagnetic mineral in two cores closest to Lake Lacawacs southeastern shore. This magnetic mineral is only present deep in the soil profile and would suggest erosion and significant land-use changes in the Lacawac watershed as another cause for the high magnetic intensities (concentrations) in the top 10 cm of the lake sediments. The most significant changes in the scaled chrysophyte flora occurred immediately above the 10 cm level and were used to infer a doubling of the specific conductivity between circa 1910 and 1929. These variations also support land-use changes in the Lacawac catchment at this time. A similar shift in the scaled chrysophte flora was not observed in the top of Lake Giles, however, distinct changes were found in the deeper sections of the core coupled with a smaller peak in magnetic concentration. Fourier analysis of the ²¹⁰Pb-dated lake sediment magnetics indicates the presence of a 50 year period, low amplitude variation in the Lake Lacawac, Lake Giles, and Lake Waynewood (Lott et al., 1994) magnetic concentration records. After removal of the land-use/fly ash magnetic concentration peak by Gaussian filtering, the 50 year variation correlates strongly from lake to lake even though the lakes are in different watersheds separated by up to 30 km. When this magnetic variation is compared with Gaussian-filtered rainfall variations observed in New York City and Philadelphia over the past 120–250 years there is a strong correlation suggesting that magnetic concentration variations can record regional rainfall variations with an approximately 50 year period. This result indicates that magnetics could be used to document regional variations in climatic change.     

A brief introduction to recent applications of several sediment-analysis techniques in palaeolimnological studies-dry bulk density and water content, mineral magnetism, carbonate content, and content of total organic carbon, nitrogen content and c

ChalacteriStics of lacustrine sediments are often capable of ~ring the hydrological regales of the lakeand its environment and human achvihes in itS catclunent during the sedimentahon of these sedimentS.Therefore, by identifying these characteristics of sedimentS, it is likely to postUlate the physicalconditions in and around the lake during geological periods. Such reconstrUction of palaeoenvironmentshas become an increasingly important branch of ear sciences as there has been an expanded n…     

Efficiency of heavy liquid separation to concentrate magnetic particles

Low-temperature rock magnetic measurements have distinct diagnostic value. However, in most bulk marine sediments the concentration of ferrimagnetic and antiferromagnetic minerals is extremely low, so even sensitive instrumentation often responds to the paramagnetic contribution of the silicate matrix in the residual field of the magnetometer. Analysis of magnetic extracts is usually performed to solve the problems raised by low magnetic concentrations. Additionally magnetic extracts can be used for several other analyses, for example electron microscopy or X-ray diffraction. The magnetic extraction technique is generally sufficient for sediments dominated by magnetite. In this study however, we show that high-coercivity components are rather underrepresented in magnetic extracts of sediments with a more complex magnetic mineralogy. We test heavy liquid separation, using hydrophilic sodium polytungstenate solution Na₆[H₂W₁₂O₄₀], to demonstrate the efficiencies of both concentration techniques. Low-temperature cycling of zero-field-cooled, field-cooled and saturation isothermal remanent magnetization acquired at room temperature was performed on dry bulk sediments, magnetic extracts, and heavy liquid separates of clay-rich pelagic sediments originating from the Equatorial Atlantic. The results of the thermomagnetic measurements clarify that magnetic extraction favours components with high spontaneous magnetization, such as magnetite and titanomagnetite. The heavy liquid separation is unbiased with respect to high- and low-coercive minerals, thus it represents the entire magnetic assemblage.