Early Archean spherule layers from the Barberton Greenstone Belt,South Africa: Mineralogy and geochemistry of the spherule beds in the CT3 drill core

Little is known about the Hadean and the Archean impact record on Earth. In the CT3 drill core from the Fig Tree Group of the northern Barberton Greenstone Belt, 17 spherule layer intersections occur, which, provide an outstanding new opportunity to gain insights into meteorite bombardment of the early Earth. CT3 spherules, as primary features, mostly exhibit textural patterns similar to those of the other Barberton spherule layers, but locally mineralogical and chemical compositional differences are observed, likely as a result of various degrees of alteration. The observed mineralogy of the spherule layers is of secondary origin and comprises K‐feldspar, phyllosilicates, carbonates, sulfides, and oxides, with the exception of secondary Ni‐Cr spinel that is of primary origin. Our petrographic investigations suggest alteration by K‐metasomatism, sericitization, silicification, and carbonatization. Siderophile element contents of bulk samples show significant enrichments in Ni (up to 2 wt%) and Ir (up to ~3 ppm), similar to previously studied Archean spherule layers. These values are indicative of the presence of a meteoritic component. On the other hand, lithophile and chalcophile element abundances indicate hydrothermal overprint on the CT3 samples; this may also have influenced the redistribution of the meteoritic component(s). Last, we group the CT3 spherule layers, which occur in three intervals (A, B, and C), according to their petrographic and geochemical features, which indicate evidence for at least three distinct impact events before tectonic overprint that affected the original deposits.     

Meteoritic highly siderophile element and Re‐Os isotope signatures of Archean spherule layers from the CT3 drill core,Barberton Greenstone Belt,South Africa

Archean spherule layers represent the only currently known remnants of the early impact record on Earth. Based on the lunar cratering record, the small number of spherule layers identified so far contrasts to the high impact flux that can be expected for the Earth at that time. The recent discovery of several Paleoarchean spherule layers in the BARB5 and CT3 drill cores from the Barberton area, South Africa, drastically increases the number of known Archean impact spherule layers and may provide a unique opportunity to improve our knowledge of the impact record on the early Earth. This study is focused on the spherule layers in the CT3 drill core from the northeastern Barberton Greenstone Belt. We present highly siderophile element (HSE: Re, Os, Ir, Pt, Ru, and Pd) concentrations and Re‐Os isotope signatures for spherule layer samples and their host rocks in order to unravel the potential presence of extraterrestrial fingerprints within them. Most spherule layer samples exhibit extreme enrichments in HSE concentrations of up to superchondritic abundances in conjunction with, in some cases, subchondritic present‐day ¹⁸⁷Os/¹⁸⁸Os isotope ratios. This indicates a significant meteoritic contribution to the spherule layers. In contrast to some of the data reported earlier for other Archean spherule layers from the Barberton area, the CT3 core is significantly overprinted by secondary events. However, HSE and Re‐Os isotope signatures presented in this study indicate chondritic admixtures of up to (and even above) 100% chondrite component in some of the analyzed spherule layers. There is no significant correlation between HSE abundances and respective spherule contents. Although strongly supporting the impact origin of these layers and the presence of significant meteoritic admixtures, peak HSE concentrations are difficult to explain without postdepositional enrichment processes.     

Structure and impact indicators of the Cretaceous sequence of the ICDP drill core Yaxcopoil‐1, Chicxulub impact crater,Mexico

Abstract As part of the ICDP Chicxulub Scientific Drilling Project, the Yaxcopoil‐1 (Yax‐1) bore hole was drilled 60 km south‐southwest of the center of the 180 km‐diameter Chicxulub impact structure down to a depth of 1511 m. A sequence of 615 m of deformed Cretaceous carbonates and sulfates was recovered below a 100 m‐thick unit of suevitic breccias and 795 m of post‐impact Tertiary rocks. The Cretaceous rocks are investigated with respect to deformation features and shock metamorphism to better constrain the deformational overprint and the kinematics of the cratering process. The sequence displays variable degrees of impact‐induced brittle damage and post‐impact brittle deformation. The degree of tilting and faulting of the Cretaceous sequence was analyzed using 360°‐core scans and dip‐meter log data. In accordance with lithological information, these data suggest that the sedimentary sequence represents a number of structural units that are tilted and moved with respect to each other. Three main units and nine sub‐units were discriminated. Brittle deformation is most intense at the top of the sequence and at 1300–1400 m. Within these zones, suevitic dikes, polymict clastic dikes, and impact melt rock dikes occur and may locally act as decoupling horizons. The degree of brittle deformation depends on lithology; massive dolomites are affected by penetrative faulting, while stratified calcarenites and bituminous limestones display localized faulting. The deformation pattern is consistent with a collapse scenario of the Chicxulub transient crater cavity. It is believed that the Cretaceous sequence was originally located outside the transient crater cavity and eventually moved downward and toward the center to its present position between the peak ring and the crater rim, thereby separating into blocks. Whether or not the stack of deformed Cretaceous blocks was already displaced during the excavation process remains an open question. The analysis of the deformation microstructure indicates that a shock metamorphic overprint is restricted to dike injections with an exception of the so called “paraconglomerate.” Abundant organic matter in the Yax‐1 core was present before the impact and was mobilized by impact‐induced heating and suggests that >12 km³ of organic material was excavated during the cratering process.     

Platinum group elements in impactites of the ICDP Chicxulub drill core Yaxcopoil‐1: Are there traces of the projectile?

Abstract— This study presents results of platinum group element (PGE) analyses of impactites from the Yaxcopoil‐1 (Yax‐1) and Yucatán 6 drill cores of the 180 km‐diameter Chicxulub crater. These are the main elements used for projectile identification. They were determined by nickel sulfide fire assay combined with inductively coupled plasma mass spectrometry. The concentration of PGE in the samples are low. The concentration patterns of the suevite samples resemble the pattern of the continental crust. We conclude that any meteoritic fraction in these samples is below 0.05%. A syn‐ and post‐impact modification of the PGE pattern from meteoritic toward a continental crust pattern is very unlikely. The globally distributed fallout at the Cretaceous‐Tertiary (K/T) boundary, however, has high PGE concentrations. Therefore, the lack of a significant meteoritic PGE signature in the crater is not an argument for a PGE‐poor impactor. Taking the results of three‐dimensional numerical simulations of the Chicxulub event into account, the following conclusions are drawn: 1) The main fraction of the impactor was ejected into and beyond the stratosphere, distributed globally, and deposited in the K/T boundary clay; and 2) the low amount of projectile contamination in the Yax‐1 lithologies may reflect an oblique impact. However, the role of volatiles in the mixing process between projectile and target is not well‐understood and may also have played a fundamental role.     

Geochemistry of drill core samples from Yaxcopoil‐1, Chicxulub impact crater,Mexico

Abstract— The chemical composition of suevites, displaced Cretaceous target rocks, and impact‐generated dikes within these rocks from the Yaxcopoil‐1 (Yax‐1) drill core, Chicxulub impact crater, Mexico, is reported and compared with the data from the Yucatán 6 (Y6) samples. Within the six suevite subunits of Yax‐1, four units with different chemical compositions can be distinguished: a) upper/lower sorted and upper suevite (depth of 795–846 m); b) middle suevite (depth of 846–861 m); c) brecciated impact melt rock (depth of 861–885 m); and d) lower suevite (depth of 885–895 m). The suevite sequence (a), (b), and (d) display an increase of the CaO content and a decrease of the silicate basement component from top to bottom. In contrast, the suevite of Y6 shows an inverse trend. The different distances of the Yax‐1 and Y6 drilling sites from the crater center (～60, and ～47 km, respectively) lead to different suevite sequences. Within the Cretaceous rocks of Yax‐1, a suevitic dike (depth of ～916 m) does not display chemical differences when compared with the suevite, while an impact melt rock dike (depth of ～1348 m) is significantly enriched in immobile elements. A clastic breccia dike (depth of ～1316 m) is dominated by material derived locally from the host rock, while the silicate‐rich component is similar to that found in the suevite. Significant enrichments of the K₂O content were observed in the Yax‐1 suevite and the impact‐generated dikes. All impactites of Yax‐1 and Y6 are mixtures of a crystalline basement and a carbonate component from the sedimentary cover. An anhydrite component in the impactites is missing (Yax‐1) or negligible (Y6).     

Shock metamorphism investigations of quartz grains in clasts from impact breccia of the Eyreville B drill core,Chesapeake Bay impact structure,USA

Abstract– The Chesapeake Bay impact structure, approximately 85 km in diameter, has been drilled in 2005–2006 at Eyreville (Virginia, USA), to a total depth of 1766 m. In the drill cores, the abundance of shock metamorphosed material is very variable with depth. Shocked mineral and lithic clasts, as well as melt particles, are most abundant in suevitic impact breccia section (1397–1451 m depth). Shocked quartz (i.e., quartz grains with planar fractures and/or planar deformation features) and melt particles, although rare, are also dispersed in the Exmore Formation unit (444–867 m depth). Other lithologies in the Eyreville drill cores show no clear evidence of shock metamorphism. Here, we report on the investigations of 40 samples from the impact breccia section. A total of more than 27,000 quartz grains were examined in about 200 clasts. The abundance of highly shocked clasts tends to decrease with increasing depth. Crystalline clasts derived from the crystalline basement are commonly only slightly shocked (contain generally <10 rel% of shocked quartz grains). The clasts of metamorphosed sediments show a low proportion of shocked quartz grains (mostly <10 rel%). Sedimentary clasts show a wide range of proportions of shocked quartz grains, with several of them being highly shocked clasts (most values between 0 and 40 rel%). Conglomerates show the highest proportion of shocked quartz grains of all types of clasts (up to 83 rel%). Polycrystalline quartz clasts are also commonly highly shocked (contain mostly between 10 and 40 rel% of shocked quartz grains). These hard nonporous clasts are possibly more liable to show evidence of shock. The investigations suggest that the intensity of shock metamorphism is the result of several parameters, such as original position in the target (both horizontal and vertical) and the properties of each lithology (e.g., grain size, porosity, and amount of matrix). According to the universal‐stage investigations, the dominant orientations of planar deformation features in quartz are , , and also .     

Physical properties of the Yaxcopoil‐1 deep drill core,Chicxulub impact structure,Mexico

Abstract– The Chicxulub structure in Mexico, one of the largest impact structures on Earth, was formed 65 Ma by a hypervelocity impact that led to the large mass extinction at the K‐Pg boundary. The Chicxulub impact structure is well preserved, but is buried beneath a sequence of carbonate sediments and, thus, requires drilling to obtain subsurface information. The Chicxulub Scientific Drilling Program was carried out at Hacienda Yaxcopoil in the framework of the International Continental Scientific Drilling Program in 2001–2002. The structure was cored from 404 m down to 1511 m, through three intervals: 794 m of postimpact Tertiary sediments, a 100 m thick impactite sequence, and 616 m of preimpact Cretaceous rocks thought to represent a suite of megablocks. Physical property investigations show that the various lithologies, including the impactite units and the K‐Pg boundary layer, can be characterized by their physical properties, which depend on either changes in fabric or on mineralogical variations. The magnetic properties show mostly dia‐ or paramagnetic behavior, with the exception of the impactite units that indicate the presence of ferromagnetic, probably hydrothermally deposited magnetite and pyrrhotite. The magnetic fraction contributes mainly to enhanced magnetization in the impactite lithologies and, in this way, to the observed magnetic anomalies. The shape and orientation of the magnetic grains are varied and reflect inhomogeneous fabric development and the influence of impact‐related redeposition and hydrothermal activity. The Chicxulub impact occurred at the time of the reverse polarity geomagnetic chron 29R, and this finding is consistent with the age of the K‐Pg boundary.     

Major and trace element compositions of melt particles and associated phases from the Yaxcopoil‐1 drill core,Chicxulub impact structure,Mexico

Abstract— Melt particles found at various depths in impactites from the Yaxcopoil‐1 borehole into the Chicxulub impact structure (Yucatán) have been analyzed for their major and trace element abundances. A total of 176 electron microprobe and 45 LA‐ICP‐MS analyses from eight different melt particles were investigated. The main purpose of this work was to constrain the compositions of precursor materials and secondary alteration characteristics of these melt particles. Individual melt particles are highly heterogeneous, which makes compositional categorization extremely difficult. Melt particles from the uppermost part of the impactite sequence are Ca‐ and Na‐depleted and show negative Ce anomalies, which is likely a result of seawater interaction. Various compositional groupings of melt particles are determined with ternary and binary element ratio plots involving major and trace elements. This helps distinguish the degree of alteration versus primary heterogeneity of melt phases. Comparison of the trace element ratios Sc/Zr, Y/Zr, Ba/Zr, Ba/Rb, and Sr/Rb with compositions of known target rocks provides some constraints on protolith compositions; however, the melt compositions analyzed exceed the known compositional diversity of possible target rocks. Normalized REE patterns are unique for each melt particle, likely reflecting precursor mineral or rock compositions. The various discrimination techniques indicate that the highly variable compositions are the products of melting of individual minerals or of mixtures of several minerals. Small, angular shards that are particularly abundant in units 2 and 3 represent rapidly quenched melts, whereas larger particles (>0.5 mm) that contain microlites and have fluidal, schlieric textures cooled over a protracted period. Angular, shard‐like particles with microlites in unit 5 likely crystallized below the glass transition temperature or underwent fragmentation during or after deposition.     

Extending the paleogeographic range and our understanding of the Neoarchean Monteville impact spherule layer (Transvaal Supergroup,South Africa)

The Monteville spherule layer (MSL) was deposited in the Griqualand West Basin (GWB) on the Kaapvaal Craton approximately 2.63 Ga. The spherules were generated by a large impact and reworked by impact‐generated waves and/or currents. The MSL has been intersected in three previously undescribed cores. Two of the cores, GKF‐1 and GKP‐1, were drilled ~30 km west of the southernmost outcrop of the MSL. The third core, BH‐47, was drilled ~250 km south and east of the GWB. The MSL contains medium to coarse sand‐size spherules like those described previously in all three cores but each one was emplaced in a different way. In GKF‐1, the MSL is 90 cm thick and contains large rip‐up clasts of basinal carbonate and early diagenetic pyrite. In GKP‐1, the MSL is only 1.5 cm thick and consists largely of fine carbonate sand, yet it contains pyrite intraclasts up to ~1 cm long. In BH‐47, the MSL consists of a lower coarse sandy zone ~37 cm thick rich in spherules, carbonate peloids/ooids, pyrite intraclasts, and quartzose sand and an upper, finer sandy zone ~46 cm thick; neither zone contains any large intraclasts. The new occurrences triple the known extent of the MSL from ~15,000 to ~46,000 km², support the oceanic impact model for the formation of the MSL, demonstrate that it is a persistent regional time‐stratigraphic marker, place new constraints on the Kaapvaal paleoshoreline at the time of impact, and support the existence of Vaalbara.     

Evidence for shock‐induced anhydrite recrystallization and decomposition at the UNAM‐7 drill core from the Chicxulub impact structure

Drill core UNAM‐7, obtained 126 km from the center of the Chicxulub impact structure, outside the crater rim, contains a sequence of 126.2 m suevitic, silicate melt‐rich breccia on top of a silicate melt‐poor breccia with anhydrite megablocks. Total reflection X‐ray fluorescence analysis of altered silicate melt particles of the suevitic breccia shows high concentrations of Br, Sr, Cl, and Cu, which may indicate hydrothermal reaction with sea water. Scanning electron microscopy and energy‐dispersive spectrometry reveal recrystallization of silicate components during annealing by superheated impact melt. At anhydrite clasts, recrystallization is represented by a sequence of comparatively large columnar, euhedral to subhedral anhydrite grains and smaller, polygonal to interlobate grains that progressively annealed deformation features. The presence of voids in anhydrite grains indicates SO_x gas release during anhydrite decomposition. The silicate melt‐poor breccia contains carbonate and sulfate particles cemented in a microcrystalline matrix. The matrix is dominated by anhydrite, dolomite, and calcite, with minor celestine and feldspars. Calcite‐dominated inclusions in silicate melt with flow textures between recrystallized anhydrite and silicate melt suggest a former liquid state of these components. Vesicular and spherulitic calcite particles may indicate quenching of carbonate melts in the atmosphere at high cooling rates, and partial decomposition during decompression at postshock conditions. Dolomite particles with a recrystallization sequence of interlobate, polygonal, subhedral to euhedral microstructures may have been formed at a low cooling rate. We conclude that UNAM‐7 provides evidence for solid‐state recrystallization or melting and dissociation of sulfates during the Chicxulub impact event. The lack of anhydrite in the K‐Pg ejecta deposits and rare presence of anhydrite in crater suevites may indicate that sulfates were completely dissociated at high temperature (T > 1465 °C)—whereas ejecta deposited near the outer crater rim experienced postshock conditions that were less effective at dissociation.     

Geochemical studies of the SUBO 18 (Enkingen) drill core and other impact breccias from the Ries crater,Germany

Suevite and melt breccia compositions in the boreholes Enkingen and Polsingen are compared with compositions of suevites from other Ries boreholes and surface locations and discussed in terms of implications for impact breccia genesis. No significant differences in average chemical compositions for the various drill cores or surface samples are noted. Compositions of suevite and melt breccia from southern and northeastern sectors of the Ries crater do not significantly differ. This is in stark contrast to the published variations between within‐crater and out‐of‐crater suevites from northern and southern sectors of the Bosumtwi impact structure, Ghana. Locally occurring alteration overprint on drill cores—especially strong on the carbonate‐impregnated suevite specimens of the Enkingen borehole—does affect the average compositions. Overall, the composition of the analyzed impact breccias from Ries are characterized by very little macroscopically or microscopically recognized sediment‐clast component; the clast populations of suevite and impact melt breccia are dominated consistently by granitic and intermediate granitoid components. The Polsingen breccia is significantly enriched in a dioritic clast component. Overall, chemical compositions are of intermediate composition as well, with dioritic‐granodioritic silica contents, and relatively small contributions from mafic target components. Selected suevite samples from the Enkingen core have elevated Ni, Co, Cr, and Ir contents compared with previously analyzed suevites from the Ries crater, which suggest a small meteoritic component. Platinum‐group element (PGE) concentrations for some of the enriched samples indicate somewhat elevated concentrations and near‐chondritic ratios of the most immobile PGE, consistent with an extraterrestrial contribution of 0.1–0.2% chondrite‐equivalent.     

Hyperspectral imaging of drill core from the Steen River impact structure,Canada: Implications for hydrothermal activity and formation of suevite‐like breccias

Hyperspectral imaging can be used to rapidly identify and map the spatial distributions of many minerals. Here, hyperspectral mapping in three wavelength regions (visible and near‐infrared, shortwave infrared, and thermal infrared) was applied to drill cores (ST001, ST002, and ST003) penetrating a continuous sequence of crater‐fill breccias from the Steen River impact structure in Alberta, Canada. The combined data sets reveal distinct mineralogical layering, with breccias derived predominantly from sedimentary rocks overlying those derived from granitic basement. This stratigraphy demonstrates that the breccias were not appreciably disturbed following deposition, which is inconsistent with formation models of similar breccias (suevites) by explosive impact melt–fluid interaction. At Steen River, volatiles from sedimentary target rocks were an inherent part of forming these enigmatic breccias. Approximately three quarters of terrestrial impact structures contain sedimentary target rocks; therefore, the role of volatiles in producing so‐called suevitic breccias may be more widespread than previously realized. The hyperspectral maps, specifically within the SWIR wavelength region, also delineate minerals associated with postimpact hydrothermal activity, including ammoniated clay and feldspar minerals not detectable using traditional techniques. These nitrogen‐bearing minerals may have originated from microbial processes, associated with oil‐ and gas‐producing units in the crater vicinity. Such minerals may have important implications for the production of habitable environments by impact‐induced hydrothermal activity on Earth and Mars.     

Sedimentological and petrographic analysis of drill core FC77-1 from the flank of the central uplift,Flynn Creek impact structure,Tennessee

Drill core FC77-1 on the flank of the central uplift, Flynn Creek impact structure, Tennessee, contains 175 m of impact breccia lying upon uplifted Lower Paleozoic carbonate target stratigraphy. Sedimentological analysis of this 175-m interval carbonate breccia shows that there are three distinct sedimentological units. In stratigraphic order, unit 1 (175–109 m) is an overall coarsening-upward section, whereas the overlying unit 2 (109–32 m) is overall fining-upward. Unit 3 (32–0 m) is a coarsening-upward sequence that is truncated at the top by postimpact erosion. Units 1 and 3 are interpreted as debris or rock avalanches into finer sedimentary deposits within intracrater marine waters, thus producing progressively coarser, coarsening-upward sequences. Unit 2 is interpreted to have formed by debris or rock avalanches into standing marine waters, thus forming sequential fining-upward deposits. Line-logging of clasts ranging from 5 mm to 1.6 m, and thin-section analysis of selected drill core samples (including clasts < 5 mm), both show that the Flynn Creek impact breccia consists almost entirely of dolostone clasts (90%), with minor components of cryptocrystalline melt clasts, chert and shale fragments, and clastic grains. Cryptocrystalline melt clasts, which appear isotropic in thin section, are in fact made of exceedingly fine quartz crystals that exhibit micro-Fourier transform infrared (FTIR) and micro-Raman spectra consistent with crystalline quartz. These cryptocrystalline melt clasts are the first melt clasts of any kind to be reported from Flynn Creek impact structure.     

Terrestrial ages,pairing, and concentration mechanism of Antarctic chondrites from Frontier Mountain,Northern Victoria Land

Abstract— We report concentrations of cosmogenic ¹⁰Be, ²⁶Al, ³⁶Cl, and ⁴¹Ca in the metal phase of 26 ordinary chondrites from Frontier Mountain (FRO), Antarctica, as well as cosmogenic ¹⁴C in eight and noble gases in four bulk samples. Thirteen out of 14 selected H chondrites belong to two previously identified pairing groups, FRO 90001 and FRO 90174, with terrestrial ages of ?40 and ?100 kyr, respectively. The FRO 90174 shower is a heterogeneous H3–6 chondrite breccia that probably includes more than 300 individual fragments, explaining the high H/L chondrite ratio (3.8) at Frontier Mountain. The geographic distribution of 19 fragments of this shower constrains ice fluctuations over the past 50–100 kyr to less than ?40 m, supporting the stability of the meteorite trap over the last glacial cycle. The second H‐chondrite pairing group, FRO 90001, is much smaller and its geographic distribution is mainly controlled by wind‐transport. Most L‐chondrites are younger than 50 kyr, except for the FRO 93009/01172 pair, which has a terrestrial age of ?500 kyr. These two old L chondrites represent the only surviving members of a large shower with a similar preatmospheric radius (?80 cm) as the FRO 90174 shower. The find locations of these two paired L‐chondrite fragments on opposite sides of Frontier Mountain confirm the general glaciological model in which the two ice flows passing both ends of the mountain are derived from the same source area on the plateau. The 50 FRO meteorites analyzed so far represent 21 different falls. The terrestrial ages range from 6 kyr to 500 kyr, supporting the earlier proposed concentration mechanism.     

Petrography,geochemistry, and argon‐40/argon‐39 ages of impact‐melt rocks and breccias from the Ames impact structure,Oklahoma: The Nicor Chestnut 18‐4 drill core

Abstract— The 15 km diameter Ames structure in northwestern Oklahoma is located 2.75 km below surface in Cambro‐Ordovician Arbuckle dolomite, which is overlain by Middle Ordovician Oil Creek Formation shale. The feature is marked by two concentric ring structures, with the inner ring of about 5 km diameter probably representing the collapsed remnant of a structural uplift composed of brecciated Precambrian granite and Arbuckle dolomite. Wells from both the crater rim and the central uplift are oil‐ and gas‐producing, making Ames one of the economically important impact structures. Petrographic, geochemical, and age data were obtained on samples from the Nicor Chestnut 18‐4 drill core, off the northwest flank of the central uplift. These samples represent the largest and best examples of impact‐melt breccia obtained so far from the Ames structure. They contain carbonate rocks, which are derived from the target sequence. The chemical composition of the impact‐melt breccias is similar to that of target granite, with variable carbonate admixture. Some impact‐melt rocks are enriched in siderophile elements indicating the possible presence of a meteoritic component. Based on stratigraphic arguments, the age of the crater was estimated at 470 Ma. Previous ⁴⁰Ar‐³⁹Ar dating attempts of impact‐melt breccias from the Dorothy 1–19 core yielded plateau ages of about 285 Ma, which is in conflict with the stratigraphic age. The new ⁴⁰Ar‐³⁹Ar age data obtained on the melt breccias from the Nicor Chestnut core by ultraviolet (UV) laser spot analysis resulted in a range of ages with maxima around 300 Ma. These data could reflect processes related either the regional Nemaha Uplift or resetting due to hot brines active on a midcontinent‐wide scale, perhaps related to the Alleghenian and Ouachita orogenies. The age data indicate an extended burial phase associated with thermal overprint during Late Pennsylvanian‐Permian.     

Ascent and eruption of a lunar high-titanium magma as inferred from the petrology of the 74001/2 drill core

Abstract— An analysis of the orange glasses and crystallized beads from the 68 cm deep 74001/2 core has been conducted to understand the processes occurring during ascent and eruption of the Apollo 17 orange glass magma. Equilibrium between melt and metal blebs (Fe₈₅Ni₁₄Co₁) within the core, along with Cr contents in olivine phenocrysts, suggest there was an oxidation of C and a reduction of the melt at an O fugacity of IW-1.3 and 1320 °C to form CO gas at 200 bars or ～4 km depth. This was followed by development of more oxidized conditions during ascent. Also during ascent, there was formation of euhedral, homogeneous Fo₈₁ olivine crystals and spinel crystals with higher Al and Mg contents than the smaller spinels in the crystallized beads. Both the metal blebs and Al-rich spinels were trapped inside the Fo₈₁ olivine phenocrysts as they grew prior to eruption. The composition of the orange glasses are homogeneous throughout the core, except for a few distinct glasses at the top that appear to have been mixed in by micrometeorite reworking. A few glassy melt inclusions of orange glass composition trapped in the Fo₈₁ phenocrysts contain 600 ± 100 ppm S and ～50 ppm Cl compared to the 200 ppm S and 50 ppm Cl in the orange glass melt when quenched. These inclusions therefore document the addition of 400 ppm S to the CO-rich volcanic gas during the eruption. The size and distribution of different volcanic beads in the Apollo 17 deposit indicate a mode of eruption in which the orange glasses and partially crystallized beads formed further away from the volcanic vent where cooling rates were faster. Progressively larger and more numerous crystals in the black beads reflect slower cooling rates at higher optical densities in the volcanic plume. The development of a brown texture in the orange glasses at the bottom of the core, where the black beads dominate, is interpreted to result from devitrification by subsolidus heating either as the orange glasses fell back through the hot plume or after deposition on the surface. The change from domination by orange glasses to black beads in the core probably reflects a decrease in gas content over time, which consequently would increase the plume optical density and favor slower cooling rates.     

Composition of impact melt particles and the effects of post‐impact alteration in suevitic rocks at the Yaxcopoil‐1 drill core,Chicxulub crater,Mexico

Abstract Petrographical and chemical analysis of melt particles and alteration minerals of the about 100 m‐thick suevitic sequence at the Chicxulub Yax‐1 drill core was performed. The aim of this study is to determine the composition of the impact melt, the variation between different types of melt particles, and the effects of post‐impact hydrothermal alteration. We demonstrate that the compositional variation between melt particles of the suevitic rocks is the result of both incomplete homogenization of the target lithologies during impact and subsequent post‐impact hydrothermal alteration. Most melt particles are andesitic in composition. Clinopyroxene‐rich melt particles possess lower SiO₂ and higher CaO contents. These are interpreted by mixing of melts from the silicate basement with overlying carbonate rocks. Multi‐stage post‐impact hydrothermal alteration involved significant mass transfer of most major elements and caused further compositional heterogeneity between melt particles. Following backwash of seawater into the crater, palagonitization of glassy melt particles likely caused depletion of SiO₂, Al₂O₃, CaO, Na₂O, and enrichment of K₂O and FeO_tot during an early alteration stage. Since glass is very susceptible to fluid‐rock interaction, the state of primary crystallization of the melt particles had a significant influence on the intensity of the post‐impact hydrothermal mass transfer and was more pronounced in glassy melt particles than in well‐crystallized particles. In contrast to other occurrences of Chicxulub impactites, the Yax‐1 suevitic rocks show strong potassium metasomatism with hydrothermal K‐feldspar formation and whole rock K₂0 enrichment, especially in the lower unit of the suevitic sequence. A late stage of hydrothermal alteration is characterized by precipitation of silica, analcime, and Na‐bearing Mg‐rich smectite, among other minerals. This indicates a general evolution from a silica‐undersaturated fluid at relatively high potassium activities at an early stage toward a silica‐oversaturated fluid at relatively high sodium activities at later stages in the course of fluid rock interaction.     

Physical properties of rocks from the upper part of the Yaxcopoil‐1 drill hole,Chicxulub crater

Abstract— Physical properties were determined in a first step on post‐impact tertiary limestones from the depth interval of 404–666 m of the Yaxcopoil‐1 (Yax‐1) scientific well, drilled in the Chicxulub impact crater (Mexico). Thermal conductivity, thermal diffusivity, density, and porosity were measured on 120 dry and water‐saturated rocks with a core sampling interval of 2–2.5 m. Nondestructive, non‐contact optical scanning technology was used for thermal property measurements including thermal anisotropy and inhomogeneity. Supplementary petrophysical properties (acoustic velocities, formation resisitivity factor, internal surface, and hydraulic permeability) were determined on a selected subgroup of representative samples to derive correlations with the densely measured parameters, establishing estimated depth logs to provide calibration values for the interpretation of geophysical data. Significant short‐ and long‐scale variations of porosity (1–37%) turned out to be the dominant factor influencing thermal, acoustic, and hydraulic properties of this post impact limestone formation. Correspondingly, large variations of thermal conductivity, thermal diffusivity, acoustic velocities, and hydraulic permeability were found. These variations of physical properties allow us to subdivide the formation into several zones. A combination of experimental data on thermal conductivity for dry and water‐saturated rocks and a theoretical model of effective thermal conductivity for heterogeneous media have been used to calculate thermal conductivity of mineral skeleton and pore aspect ratio for every core under study. The results on thermal parameters are the necessary basis for the determination of heat flow density, demonstrating the necessity of dense sampling in the case of inhomogeneous rock formations.     

Geology and geochemistry of shallow drill cores from the Bosumtwi impact structure,Ghana

Abstract— The 1.07 Ma well‐preserved Bosumtwi impact structure in Ghana (10.5 km in diameter) formed in 2 Ga‐old metamorphosed and crystalline rocks of the Birimian system. The interior of the structure is largely filled by the 8 km diameter Lake Bosumtwi, and the crater rim and region in the environs of the crater is covered by tropical rainforest, making geological studies rather difficult and restricted to road cuts and streams. In early 1999, we undertook a shallow drilling program to the north of the crater rim to determine the extent of the ejecta blanket around the crater and to obtain subsurface core samples for mineralogical, petrological, and geochemical studies of ejecta of the Bosumtwi impact structure. A variety of impactite lithologies are present, consisting of impact glassrich suevite and several types of breccia: lithic breccia of single rock type, often grading into unbrecciated rock, with the rocks being shattered more or less in situ without much relative displacement (autochthonous?), and lithic polymict breccia that apparently do not contain any glassy material (allochtonous?). The suevite cores show that melt inclusions are present throughout the whole length of the cores in the form of vesicular glasses with no significant change of abundance with depth. Twenty samples from the 7 drill cores and 4 samples from recent road cuts in the structure were studied for their geochemical characteristics to accumulate a database for impact lithologies and their erosion products present at the Bosumtwi crater. Major and trace element analyses yielded compositions similar to those of the target rocks in the area (graywacke‐phyllite, shale, and granite). Graywacke‐phyllite and granite dikes seem to be important contributors to the compositions of the suevite and the road cut samples (fragmentary matrix), with a minor contribution of Pepiakese granite. The results also provide information about the thickness of the fallout suevite in the northern part of the Bosumtwi structure, which was determined to be ≤15 m and to occupy an area of ?1.5 km². Present suevite distribution is likely to be caused by differential erosion and does not reflect the initial areal extent of the continuous Bosumtwi ejecta deposits. Our studies allow a comparison with the extent of the suevite at the Ries, another well‐preserved impact structure.