高分辨电感耦合等离子体质谱法测定透析用水中的12种元素

用高分辨率电感耦合等离子体质谱法（HR-ICP-MS）同时测定透析用水中的Na、Cd、Sn、Ba、Pb、Mg、Al、Ca、Cr、Cu、Zn、K等12种元素,对各元素的测定同位素及分辨率进行了优选,有效地消除了绝大多数多原子及双电荷离子干扰的影响.方法检出限在（0.002～1.5） μg/L之间,加标回收率为（90～102）％,相对标准偏差（0.53～5.83）％.     

Butyltin compounds in a sediment core from the old Tilbury basin, London, UK

Sections from a sediment core taken from the River Thames were analysed for butyltin species using gas chromatography with species-specific isotope dilution mass spectrometry. Results demonstrated that in most samples tributyltin concentrations of 20–60 ng/g accounted for <10% of the total butyltin species present, which is in agreement with data from other sediment samples which were historically contaminated with tributyltin. Vertical distribution of the organotin residues with depth throughout the core, with data on organochlorine compounds and heavy metals allowed for the construction of a consistent hypothesis on historical deposition of contaminated sediments. From this it was possible to infer that the concentrations of tributyltin in sediments deposited during the early 1960s were in the order of 400–600 μg/g by using degradation rate constants derived by other workers. Such values fall well within the range quoted for harbour sediments in the literature.     

Latitudinal distribution of the solar wind properties in the low- and high-pressure regimes: Wind observations

The solar wind properties depend on , the heliomagnetic latitude with respect to the heliospheric current sheet (HCS), more than on the heliographic latitude. We analyse the wind properties observed by Wind at 1 AU during about 2.5 solar rotations in 1995, a period close to the last minimum of solar activity. To determine , we use a model of the HCS which we fit to the magnetic sector boundary crossings observed by Wind. We find that the solar wind properties mainly depend on the modulus ||. But they also depend on a local parameter, the total pressure (magnetic pressure plus electron and proton thermal pressure). Furthermore, whatever the total pressure, we observe that the plasma properties also depend on the time: the latitudinal gradients of the wind speed and of the proton temperature are not the same before and after the closest HCS crossing. This is a consequence of the dynamical stream interactions. In the low pressure wind, at low ||, we find a clear maximum of the density, a clear minimum of the wind speed and of the proton temperature, a weak minimum of the average magnetic field strength, a weak maximum of the average thermal pressure, and a weak maximum of the average factor. This overdense sheet is embedded in a density halo. The latitudinal thickness is about 5° for the overdense sheet, and 20° for the density halo. The HCS is thus wrapped in an overdense sheet surrounded by a halo, even in the non-compressed solar wind. In the high-pressure wind, the plasma properties are less well ordered as functions of the latitude than in the low-pressure wind; the minimum of the average speed is seen before the HCS crossing. The latitudinal thickness of the high-pressure region is about 20°. Our observations are qualitatively consistent with the numerical model of Pizzo for the deformation of the heliospheric current sheet and plasma sheet.     

High-beta plasma blobs in the morningside plasma sheet

Equator-S frequently encountered, i.e. on 30%0of the orbits between 1 March and 17 April 1998, strong variations of the magnetic field strength of typically 5–15-min duration outside about 9R_E during the late-night/early-morning hours. Very high-plasma beta values were found, varying between 1 and 10 or more. Close conjunctions between Equator-S and Geotail revealed the spatial structure of these “plasma blobs” and their lifetime. They are typically 5–10° wide in longitude and have an antisymmetric plasma or magnetic pressure distribution with respect to the equator, while being altogether low-latitude phenomena (<15°). They drift slowly sunward, exchange plasma across the equator and have a lifetime of at least 15–30 min. While their spatial structure may be due to some sort of mirror instability, little is known about the origin of the high-beta plasma. It is speculated that the morningside boundary layer somewhat further tailward may be the source of this plasma. This would be consistent with the preference of the plasma blobs to occur during quiet conditions, although they are also found during substorm periods. The relation to auroral phenomena in the morningside oval is uncertain. The energy deposition may be mostly too weak to generate a visible signature. However, patchy aurora remains a candidate for more disturbed periods.     

Chemical Speciation of Vanadium in Coal Bottom Ash

Chemical speciation of vanadium is important to understand the true nature of this element in the environment as well as its biochemical pathways. Sample pretreatment, preparation, and chemical speciation methods were applied for vanadium in coal bottom ash here. Two‐stage microwave acid digestion was used to preparation of samples. Determination of vanadium was performed using inductively coupled plasma‐optical emission spectrometry (ICP‐OES). Speciation of vanadium was carried out using a seven‐step sequential extraction procedure of the coal bottom ash each releasing species of vanadium: Water soluble, exchangeable, carbonate, reducible, oxidizable, sulfide, and residual fractions. Total vanadium concentration in the coal bottom ash is 701 mg kg^?1 d.w. The most abundant form of vanadium in coal bottom ash is residual fraction of vanadium (196 mg kg^?1 d.w.). Relative abundances of the remaining vanadium fractions in coal bottom ash are as follows: Reducible (176 mg kg^?1 d.w.) > sulfide (176 mg kg^?1 d.w.) > carbonate (85 mg kg^?1 d.w.) > oxidizable (50 mg kg^?1 d.w.) > water soluble (10.6 mg kg^?1 d.w.) > exchangeable (9.0 mg kg^?1 d.w.).     

A comparison of veloCity measurements from the CUTLASS Finland radar and the EISCAT UHF system

The CUTLASS Finland radar, which comprises an integral part of the SuperDARN system of HF coherent radars, provides near continuous observations of high-latitude plasma irregularities within a field-of-view which extends over some four million square kilometres. Within the Finland radar field-of-view lie both the EISCAT mainland and EISCAT Svalbard incoherent scatter radar facilities. Since the CUTLASS Finland radar commenced operation, in February 1995, the mainland EISCAT UHF radar has been run in common programme 1 and 2 modes for a total duration exceeding 1000 h. Simultaneous and spatially coincident returns from these two radars over this period provide the basis for a comparison of irregularity drift veloCity and F-region ion veloCity. Initial comparison is limited to velocities from four intervals of simultaneous radar returns; intervals are selected such that they exhibit a variety of veloCity signatures including that characteristic of the convection reversal and a rapidly fluctuating veloCity feature. Subsequent comparison is on a statistical basis. The velocities measured by the two systems demonstrate reasonable correspondence over the veloCity regime encountered during the simultaneous occurrence of coherent and incoherent scatter; differences between the EISCAT UHF measurements of F-region ion drift and the irregularity drift velocities from the Finland radar are explained in terms of a number of contributing factors including contamination of the latter by E-region echoes, a factor which is investigated further, and the potentially deleterious effect of discrepant volume and time sampling intervals.     

WIND observations of coherent electrostatic waves in the solar wind

The time domain sampler (TDS) experiment on WIND measures electric and magnetic wave forms with a sampling rate which reaches 120 000 points per second. We analyse here observations made in the solar wind near the Lagrange point L1. In the range of frequencies above the proton plasma frequency f_pi and smaller than or of the order of the electron plasma frequency f_pe, TDS observed three kinds of electrostatic (e.s.) waves: coherent wave packets of Langmuir waves with frequencies f ≃ f_pe, coherent wave packets with frequencies in the ion acoustic range f_pi ≥ f ≥ f_pe, and more or less isolated non-sinusoidal spikes lasting less than 1 ms. We confirm that the observed frequency of the low frequency (LF) ion acoustic wave packets is dominated by the Doppler effect: the wavelengths are short, 10 to 50 electron Debye lengths λ_D. The electric field in the isolated electrostatic structures (IES) and in the LF wave packets is more or less aligned with the solar wind magnetic field. Across the IES, which have a spatial width of the order of ≃25_D, there is a small but finite electric potential drop, implying an average electric field generally directed away from the Sun. The IES wave forms, which have not been previously reported in the solar wind, are similar, although with a smaller amplitude, to the weak double layers observed in the auroral regions, and to the electrostatic solitary waves observed in other regions in the magnetosphere. We have also studied the solar wind conditions which favour the occurrence of the three kinds of waves: all these e.s. waves are observed more or less continuously in the whole solar wind (except in the densest regions where a parasite prevents the TDS observations). The type (wave packet or IES) of the observed LF waves is mainly determined by the proton temperature and by the direction of the magnetic field, which themselves depend on the latitude of WIND with respect to the heliospheric current sheet.     

Ion upflow and downflow at the topside ionosphere observed by the EISCAT VHF radar

We have determined the MLT distribution and KpK_P dependence of the ion upflow and downflow of the thermal bulk oxygen ion population based on a data analysis using the EISCAT VHF radar CP-7 data obtained at Tromsø during the period between 1990 and 1996: (1) both ion upflow and downflow events can be observed at any local time (MLT), irrespective of dayside and nightside, and under any magnetic disturbance level, irrespective of quiet and disturbed levels; (2) these upflow and downflow events are more frequently observed in the nightside than in the dayside; (3) the upflow events are more frequently observed than the downflow events at any local time except midnight and at any K_P level and the difference of the occurrence frequencies between the upflow and downflow events is smaller around midnight; and (4) the occurrence frequencies of both the ion upflow and downflow events appear to increase with increasing KP level, while the occurrence frequency of the downflow appears to stop increasing at some KP level     

On the dispersion of two coexisting nongyrotropic ion species

Space observations in the solar wind and simulations of high Mach number bow-shocks have detected particle populations with two coexisting nongyrotropic ion species. We investigate the influence of these two sources of free energy on the stability of parallel (with respect to the ambient magnetic field) and perpendicular propagation. For parallel modes, we derive their dispersion equation in a magnetoplasma with protons and alpha particles that may exhibit stationary nongyrotropy (SNG) and discuss the characteristics of its solutions. Kinetic simulations study the behaviour of perpendicular electrostatic (Bernstein-like) waves in a plasma whose ion populations (positrons and fictitious singly-charged particles with twice the electron mass, for the sake of simulation feasability) can be time-varying nongyrotropic (TNG). The results show that the coexistence of two gyrophase bunched species does not significantly enhance the parallel SNG instability already found for media with only one nongyrotropic species, whereas it strongly intensifies the growth of Bernstein-like modes in TNG plasmas.     

Analysis of thick, non-planar boundaries using the discontinuity analyser

The advent of missions comprised of phased arrays of spacecraft, with separation distances ranging down to at least mesoscales, provides the scientific community with an opportunity to accurately analyse the spatial and temporal dependencies of structures in space plasmas. Exploitation of the multi-point data sets, giving vastly more information than in previous missions, thereby allows unique study of their small-scale physics. It remains an outstanding problem, however, to understand in what way comparative information across spacecraft is best built into any analysis of the combined data. Different investigations appear to demand different methods of data co-ordination. Of the various multi-spacecraft data analysis techniques developed to affect this exploitation, the discontinuity analyser has been designed to investigate the macroscopic properties (topology and motion) of boundaries, revealed by multi-spacecraft magnetometer data, where the possibility of at least mesoscale structure is considered. It has been found that the analysis of planar structures is more straightforward than the analysis of non-planar boundaries, where the effects of topology and motion become interwoven in the data, and we argue here that it becomes necessary to customise the analysis for non-planar events to the type of structure at hand. One issue central to the discontinuity analyser, for instance, is the calculation of normal vectors to the structure. In the case of planar and ‘thin’ non-planar structures, the method of normal determination is well-defined, although subject to uncertainties arising from unwanted signatures. In the case of ‘thick’, non-planar structures, however, the method of determination becomes particularly sensitive to the type of physical sampling that is present. It is the purpose of this article to firstly review the discontinuity analyser technique and secondly, to discuss the analysis of the normals to thick non-planar structures detected in magnetometer data.     

Parametric decay of beam-driven Langmuir wave and enhanced ion-acoustic fluctuations in the ionosphere: a weak turbulence approach

We present a model that describes the decay of beam generated Langmuir waves into ion-acoustic waves in the topside ionosphere. This calculation is done within the frame of the weak turbulence approximation. We study the spectral signature of such a process as seen by a VHF incoherent scatter radar. An incoherent scatter (IS) spectrum is characterized by two maxima at k_radar and −k_radar, the right and left ion lines respectively. It is shown that, for reasonable beam parameters, the parametric decay of beam-generated Langmuir waves can enhance either the right, the left or both ion lines simultaneously. The shape of the spectrum can change drastically on time scale of about 0.1 to 1 s. The role of the beam parameter as well as the ionospheric parameters is also investigated. For a given beam number density, the beam energy or the background density are important to trigger either the left or the right ion line. A large energy spread of the beam or low electron collision frequencies can explain the simultaneous observations of the left and the right ion line. The importance of the electron collision frequency can explain the altitude distribution of the coherent echoes observed by incoherent scatter radars.     

Investigation of the relationship between optical auroral forms and HF radar E region backscatter

The SuperDARN HF radars have been employed in the past to investigate the spectral characteristics of coherent backscatter from L-shell aligned features in the auroral E region. The present study employs all-sky camera observations of the aurora from Husafell, Iceland, and the two SuperDARN radars located on Iceland, Þykkvibær and Stokkseyri, to determine the optical signature of such backscatter features. It is shown that, especially during quiet geomagnetic conditions, the backscatter region is closely associated with east-west aligned diffuse auroral features, and that the two move in tandem with each other. This association between optical and radar aurora has repercussions for the instability mechanisms responsible for generating the E region irregularities from which radars scatter. This is discussed and compared with previous studies investigating the relationship between optical and VHF radar aurora. In addition, although it is known that E region backscatter is commonly observed by SuperDARN radars, the present study demonstrates for the first time that multiple radars can observe the same feature to extend over at least 3 h of magnetic local time, allowing precipitation features to be mapped over large portions of the auroral zone.     

Transport of thermal plasma above the auroral ionosphere in the presence of electrostatic ion-cyclotron turbulence

The electron component of intensive electric currents flowing along the geomagnetic field lines excites turbulence in the thermal magnetospheric plasma. The protons are then scattered by the excited electromagnetic waves, and as a result the plasma is stable. As the electron and ion temperatures of the background plasma are approximately equal each other, here electrostatic ion-cyclotron (EIC) turbulence is considered. In the nonisothermal plasma the ion-acoustic turbulence may occur additionally. The anomalous resistivity of the plasma causes large-scale differences of the electrostatic potential along the magnetic field lines. The presence of these differences provides heating and acceleration of the thermal and energetic auroral plasma. The investigation of the energy and momentum balance of the plasma and waves in the turbulent region is performed numerically, taking the magnetospheric convection and thermal conductivity of the plasma into account. As shown for the quasi-steady state, EIC turbulence may provide differences of the electric potential of δ V ≈ 1–10 kV at altitudes of 500 < h < 10 000 km above the Earth’s surface. In the turbulent region, the temperatures of the electrons and protons increase only a few times in comparison with the background values.     

Effect of the IMF B y component on the ionospheric flow overhead at EISCAT: observations and theory

We have analysed a database of 300 h of tristatic ionospheric velocity measurements obtained overhead at Tromsø (66.3° magnetic latitude) by the EISCAT UHF radar system, for the presence of flow effects associated with the y-component of the IMF. Since it is already known that the flow depends upon IMF B_z, a least-squares multivariate analysis has been used to determine the flow dependence on both IMF B_y and B_z simultaneously. It is found that significant flow variations with IMF B_y occur, predominantly in the midnight sector (2100/0300 MLT), but also pre-dusk (1600/1700 MLT), which are directed eastward for IMF B_y positive and westward for IMF B_y negative. The flows are of magnitude 20/30 m s^–1 nT^–1 in the midnight sector, and smaller, 10/20 m s^–1 nT^–1, pre-dusk, and are thus associated with significant changes of flow of order a few hundred m s^–1 over the usual range of IMF B_y of about ±5 nT. At other local times the IMF B_y-related perturbation flows are much smaller, less than 5 m s^–1 nT^–1, and consistent with zero within the uncertainty estimates. We have investigated whether these IMF B_y-dependent flows can be accounted for quantitatively by a theoretical model in which the equatorial flow in the inner magnetosphere is independent of IMF B_y, but where distortions of the magnetospheric magnetic field associated with a penetrating component of the IMF B_y field changes the mapping of the field to the ionosphere, and hence the ionospheric flow. We find that the principal flow perturbation produced by this effect is an east-west flow whose sense is determined by the north-south component of the unperturbed flow. Perturbations in the north-south flow are typically smaller by more than an order of magnitude, and generally negligible in terms of observations. Using equatorial flows which are determined from EISCAT data for zero IMF B_y, to which the corotation flow has been added, the theory predicts the presence of zonal perturbation flows which are generally directed eastward in the Northern Hemisphere for IMF B_y positive and westward for IMF B_y negative at all local times. However, although the day and night effects are therefore similar in principle, the model perturbation flows are much larger on the nightside than on the dayside, as observed, due to the day-night asymmetry in the unperturbed magnetospheric magnetic field. Overall, the model results are found to account well for the observed IMF B_y-related flow perturbations in the midnight sector, in terms of the sense and direction of the flow, the local time of their occurrence, as well as the magnitude of the flows (provided the magnetic model employed is not too distorted from dipolar form). At other local times the model predicts much smaller IMF B_y-related flow perturbations, and thus does not account for the effects observed in the pre-dusk sector.     

On the spectrum of mid-latitude sporadic-E irregularities

We discuss the creation of mid-latitude sporadic-E plasma irregularities (with length-scales smaller than sporadic layer thickness) by the neutral atmosphere turbulence. Using fluid equations, the relation between plasma density fluctuations and the velocity field of neutrals is derived. After a brief discussion of the relevant neutral turbulence, the analytical expression for the power spectrum of plasma irregularities is obtained. This expression allows a power-law type of experimental irregularity spectra (the spectral index depends on sporadic-E characteristics) and possible departures in detail of the irregularity spectra from the power-law form to be explained. In addition, it allows us to make estimates of length-scales at which such departures must occur.     

Low frequency waves in plasmas with spatially varying electron temperature

Low frequency electrostatic waves are studied in magnetized plasmas with an electron temperature which varies with position in a direction perpendicular to the magnetic field. For wave frequencies below the ion cyclotron frequency, the waves need not follow any definite dispersion relation. Instead a band of phase velocities is allowed, with a range of variation depending on the maximum and minimum values of the electron temperature. Simple model equations are obtained for the general case which can be solved to give the spatial variation of a harmonically time varying potential. A simple analytical model for the phenomenon is presented and the results are supported by numerical simulations carried out in a 2.5-dimensional particle-in-cell numerical simulation. We find that when the electron temperature is striated along B₀ and low frequency waves (_ci) are excited in this environment, then the intensity of these low frequency waves will be striated in a manner following the electron temperature striations. High frequency ion acoustic waves (_ci) will on the other hand have a spatially more uniform intensity distribution.     

Simultaneous measurements from the Millstone Hill radar and the Active satellite during the SAID/SAR arc event of the March 1990 CEDAR storm

During a nearby passage of the Active satellite above the Millstone Hill radar on 21 March 1990 at local sunset, the satellite and the radar performed simultaneous measurements of upper ionospheric parameters in nearly the same spatial volume. For this purpose the radar carried out a special azimuth-elevation scan to track the satellite. Direct comparisons of radar data and in situ satellite measurements have been carried out quite rarely. In this case, the coincidence of co-ordinated measurements and active ionospheric-magnetospheric processes during an extended storm recovery phase presents a unique occasion resulting in a very valuable data set. The measurements show generally good agreement both during quiet prestorm and storm conditions and the combination of radar and satellite observations gives a more comprehensive picture of the physical processes involved. We find a close relationship between the rapid westward ion drift peak at subauroral latitudes (SAID event) and the occurrence of a stable auroral red (SAR) arc observed after sunset by an all-sky imager and reported in an earlier study of this event. The SAID electric field is caused by the penetration of energetic ions with energies between about 1 keV and 100 keV into the outer plasmasphere to a latitude equatorward of the extent of the plasmasheet electrons. Charge separation results in the observed polarisation field and the SAID. Unusually high molecular ion densities measured by the satellite at altitudes of 700–870 km at subauroral and auroral latitudes point on strong upward-directed ion acceleration processes and an intense neutral gas upwelling. These structures are collocated with a narrow trough in electron density and an electron temperature peak as observed simultaneously by the radar and the satellite probes.     

Nongyrotropic particle distributions in space plasmas

In nonstationary, strong inhomogeneous or open plasmas particle orbits are rather complicated. If the nonstationary time scale is smaller than the gyration period, if the inhomogeneity scale is smaller than the gyration radius, i.e. at magnetic plasma boundaries, or if the plasma has sources and sinks in phase space, then nongyrotropic distribution functions occur. The stability of such plasma configurations is studied in the framework of linear dispersion theory. In an open plasma nongyrotropy drives unstable waves parallel and perpendicular to the background magnetic field, whereas in the gyrotropic limit the plasma is stable. In nonstationary plasmas nongyrotropy drives perpendicular unstable waves only. Temporal modulation couples a seed mode with its side lobes and thus it renders unstable wave growth more difficult. As an example of an inhomogeneous plasma a magnetic halfspace is discussed. In a layer with thickness of the thermal proton gyroradius a nongyrotropic distribution is formed which may excite unstable parallel and perpendicular propagating waves.