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1.
许多研究认为,只有北大西洋涛动(NAO)是一种具有物理意义的模态,而北极涛动(AO)则是EOF分解得到的一种统计假象模态。为了从一个新的角度进一步探讨二者的差别,我们运用附条件的最大协方差分析(CMCA)统计了前期北极边缘海冰密集度(MSCI)与来年冬季NAO之间的跨季节遥相关关系,其中的ENSO信号和线性趋势已经在分析之前被去除。统计显著性结果表明:冬季负位相的NAO信号可以追溯到6个月前自盛夏开始至早冬季节北极MSCI异常的逐步演变。然而根据先前的研究,北极海冰异常仅可以超前冬季AO 大概4个月表现出显著信号。这表明盛夏北极MSCI的持续异常对来年冬季NAO的影响比对AO更强,同时也从另一个角度证实了AO与NAO确实存在差异。进一步分析还表明,前期MSCI异常的逐步演变主要与海表面热通量及气温异常有关。此外,我们还重新审视了负位相的NAO对北半球冬季气候异常的影响以及可能的物理机制。 相似文献
2.
The rates of the reduction of Cr(VI) with S(IV) were measured in deaerated NaCl solution as a function of pH, temperature and ionic strength. The rates of the reaction were found to be first order with respect to Cr(VI) and second order with respect to S(IV), in agreement with previous results obtained at concentrations two order higher than the present study. The reaction also showed a first-order dependence of the rates on the concentration of the proton and a small influence of temperature with an apparent energy of activation ΔHapp of 22.8 ± 3.4 kJ/mol. The rates were independent of ionic strength from 0.01 to 1 M. The rate of Cr(VI) reduction is described by the general expression
−d[Cr(VI)]/dt=k[Cr(VI)][S(IV)]2