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色谱/光谱联机检测化石燃料中的芳香化合物80年代发展起来的毛细管柱气相色谱/傅里叶变换红外光谱(CGC/FTIR)是分离和鉴定组成复杂、结构相似的芳香烃混合物的有效工具,其特点是能在高效分离基础上提供未知物的整体结构信息,尤其是对各种官能团和异构体有... 相似文献
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超临界CO2对煤化学结构的改造对煤层CO2封存能力极为关键。论文开展了模拟埋深1500m (62.5℃、15 MPa)条件下4组不同变质程度煤的ScCO2-H2O体系与煤岩地球化学反应实验。通过傅里叶变换红外光谱和X射线粉末衍射实验获得了反应前后煤化学结构演化特征,探讨了煤化学结构演化的机理。结果表明:ScCO2作用后,煤中脂肪烃链长度普遍增加,仅肥煤的芳香烃丰度增大,肥煤、瘦煤和贫煤含氧基团丰度的增大主要由氢键基团含量的增加贡献,无烟煤含氧基团丰度则主要受低分子化合物溶出的影响。ScCO2引起的溶胀作用造成肥煤和瘦煤芳香层面之间交联键断裂,芳香微晶内部结构疏松,而芳香层面内CAr-CAr交联的形成提高了肥煤和瘦煤芳香性和芳香环缩合度;贫煤和无烟煤中非稠合多苯结构脱落使芳香微晶内部更紧凑,脂肪烃链长度的增加则降低了贫煤和无烟煤芳香性和芳香环缩合度。 相似文献
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在多煤层发育地区,各煤层组之间发育低渗透岩层,使得上下煤组之间形成独立的多层叠置含煤层气系统。根据相对独立含气系统理论对西山煤田南部赤峪地区的多煤层进行了含气系统的划分,并对储层压力、临界解吸压力等参数进行了分析,在此基础上采用COMET3数值模拟软件进行了单层排采、合层排采和递进排采分析。模拟结果显示:单层排采产量低,经济可采时间短,且成本较高;合层排采比单层排采产量高,经济可采时间长,但各含气系统之间由于相互干扰,贡献不一,使资源浪费;递进排采产气量和稳产时间均优于前两者。可根据产气压力来确定多层叠置含煤层气系统排采次序,首先排采产气压力最高的含气系统,当压力降至压力低的系统时再合排。 相似文献
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生油岩中有机质加速溶剂萃取和索氏萃取方法对比 总被引:2,自引:1,他引:2
文章报道通过与传统的索氏萃取方法的对比,对于加速溶剂萃取(ASE 200)技术用于烃源岩可溶有机质萃取的实验方法研究结果。利用东北地区的1个泥岩样品,探讨了分散度、温度、压力对加速溶剂萃取技术的影响,确定最优化的萃取条件参数:分散度为8∶3、温度110℃、萃取压力10.3 MPa。进行方法的重现性实验,萃取结果具有很好的精密度,相对标准偏差(RSD,n=10)为2.6%。回收率达到了90%以上。采用吐哈盆地的东深1井的1个油页岩样品,从抽提的有机质、饱和烃和芳香烃组分的量上对加速溶剂萃取与传统索氏萃取进行了方法比较。采用6个样品进一步对饱和烃和芳香烃中的生物标志物进行了对比,加速溶剂萃取的烷烃、萜类、甾烷、芳烃等系列化合物的相对丰度、色谱-质谱特征、有机地化参数指标结果均与经典的索氏萃取的结果相一致。实验结果表明,加速溶剂萃取技术可有效地应用于烃源岩的有机地球化学分析测试及样品前处理。 相似文献
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为克服煤层气有利区评价中参数难以取全、取准的问题,综合利用测井信息与测试数据,建立了一个由2个二级评价参数(资源条件和开发条件)、8个三级评价参数和2个四级评价参数构成的多层次模糊评价模型。通过该模型,利用测井信息拟合预测各项评价参数,对山西寿阳地区3号、9号和15号煤层气单采与合采下有利区进行了评价。研究发现单层开发时,3号煤层整体较有利,9号煤层较为不利,15号煤层适中;合层开发时,(3+15)号煤层合采最为有利,而(3+9)号煤层合采最为不利。不论单采还是合采,该区煤层气勘探开发有利区集中在北部,这与目前该区近1年的试采现状吻合。 相似文献
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芳烃化合物是烃源岩和原油中非常重要的有机族组分,与饱和烃一样含有丰富的地球化学信息。应用GC-MS能检测到的芳烃化合物可分为常规多环芳烃、含NSO杂环芳烃、芳香甾萜烷及脱羟基维生素E。它们的一些参数可作为母质来源、热成熟度、沉积环境和油气运移判识的有效指标,是饱和烃地球化学研究的重要补充和佐证,对油气勘探与开发有重要的实际意义,但生物降解、混源油等因素会影响这些参数的正确性。应用全二维气相色谱-飞行时间质谱仪(GC×GC-TOF)对生物降解油芳烃中的鼓包化合物UCM(unresolve dcomple xmixtures)进行探索性研究取得了一定的效果,这也将是今后芳烃研究的重要方向。 相似文献
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Allocation of commingled pipeline oils to field production 总被引:3,自引:0,他引:3
This paper presents a case study of using oil fingerprinting technology to correctly back allocate commingled pipeline crude to production from six contributing fields in an offshore southeast Asia basin. A large number of oil and pipeline samples were collected over time and analyzed by gas chromatography for their oil fingerprints. In this case, production from each field pipeline could easily be distinguished by their whole-oil fingerprints that changed little with time. However, oils collected from the commingled pipelines showed significant chromatographic variation with time, indicating production contribution from the different fields to the pipelines varied with time. Quantitative results were attained using a proprietary computer program which mathematically calculates relative contributions (±3%) of oil mixes based on a best-fit least-squares regression of selected chromatographic peak ratios. This allocation method assisted operations to more accurately determine production for each field or a group of fields in the basin. The technique, which provides a new approach to supplement and cross-check production metering necessary for defining tax liability, has helped save significant tax dollars for field operation units. 相似文献
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通过对淮南顾桥井田5口地面煤层气试验井的开发地质条件及开发现状进行分析,并对影响煤层气单井产量的关键因素进行了讨论。结果表明,顾桥井田煤层气井产量主要受地质条件和压裂改造、排采控制等工程条件影响。渗透率低、微孔发育、煤岩体力学性能以及地应力大小和地应力方向等是影响整个井田煤层气产量的主要地质因素;压裂规模和压裂液返排率低等储层改造参数对顾桥井田煤层气井产能也能产生重要影响;层间距大且合层开发层间干扰、煤层非均质性严重造成排采参数波动是影响试验井煤层气产量的主要排采控制因素。 相似文献
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Based on the established mathematic model and graphic interpretation, a new method, which is used to calculate the contribution of single-zone production in a commingled producing well by the ultraviolet spectrum technique, has been established. The standard plate was drawn using the extinction coefficient E of sample oils formulated artificially as y-axis and the wavelength as x-axis. The curve resulting from the UV analysis of sample oils in the commingled well was inserted into the standard plate and compared. The proportion of each single zone in the commingled producing well was identical with the proportion of the curve which is closest to the curve of sample oils formulated artificially. In the well QHD32-6-3 field, taking well A22 for example and using this method, the production contribution of a single zone was calculated. The result showed that the Nm4 zone is a major "contributor", the proportion of the Nm4 zone is 70%, and that of the Nm1 zone is 30%. The ultraviolet spectrum technique provided a new reservoir geochemical technique of monitoring production contribution, especially for biodegraded heavy oil, but it has some limitation, just depending on the GC fingerprint technique. 相似文献
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砂岩油田开发过程中注采结构优化调整是一项非常复杂的工程,采液速度和采油速度是其中两个重要的指标,依照其变化可以把油田不同开采阶段划分为3种模式:提液稳产模式、稳液降产模式和降液控水模式。注采结构直接关系到油田的开发效果,在油气田不同的开发阶段,注采结构中存在的问题也是不同的。为了达到注采结构优化调整目的,针对沉积微相、沉积构造和剩余油分布进行精细的研究,根据构造特点调整注采结构,根据微构造、沉积微相特征进行注采井网的适应性调整,从而提高注水结构面横纵向调整和注水井整体调整以及油田分区、油井分类及单井结构调整等注采结构优化调整的切实效果。 相似文献
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《China Geology》2020,3(2):197-209
Clayey silt reservoirs bearing natural gas hydrates (NGH) are considered to be the hydrate-bearing reservoirs that boast the highest reserves but tend to be the most difficult to exploit. They are proved to be exploitable by the first NGH production test conducted in the South China Sea in 2017. Based on the understanding of the first production test, the China Geological Survey determined the optimal target NGH reservoirs for production test and conducted a detailed assessment, numerical and experimental simulation, and onshore testing of the reservoirs. After that, it conducted the second offshore NGH production test in 1225 m deep Shenhu Area, South China Sea (also referred to as the second production test) from October 2019 to April 2020. During the second production test, a series of technical challenges of drilling horizontal wells in shallow soft strata in deep sea were met, including wellhead stability, directional drilling of a horizontal well, reservoir stimulation and sand control, and accurate depressurization. As a result, 30 days of continuous gas production was achieved, with a cumulative gas production of 86.14 ×104 m3. Thus, the average daily gas production is 2.87 ×104 m3, which is 5.57 times as much as that obtained in the first production test. Therefore, both the cumulative gas production and the daily gas production were highly improved compared to the first production test. As indicated by the monitoring results of the second production test, there was no anomaly in methane content in the seafloor, seawater, and atmosphere throughout the whole production test. This successful production test further indicates that safe and effective NGH exploitation is feasible in clayey silt NGH reservoirs. The industrialization of hydrates consists of five stages in general, namely theoretical research and simulation experiments, exploratory production test, experimental production test, productive production test, and commercial production. The second production test serves as an important step from the exploratory production test to experimental production test. 相似文献
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塔里木盆地英买力地区原油地球化学特征与族群划分 总被引:1,自引:0,他引:1
塔里木盆地英买力地区油气成因复杂,采用多馏分、多组分化学成分分析及单体烃碳同位素分析途径,对该区海相、陆相油进行精细分析。结果表明,英买力油田主要有两大类油组,分别是南部YM2井区的海相油(I类)和北部YM7井区的陆相油(Ⅱ类),各自具有典型的海相油与陆相油的特征。进一步分析表明,两大油组内部仍有分异。将第二油组进一步分为两亚类,以中、古生界产层为主的正常黑油和重质油为一类(Ⅱa),以古近系为主的凝析油为另一类(Ⅱb)。两亚类原油正构烷烃单体烃同位素稍有差异,芳烃组成与分布具有显著差异。较之于Ⅱa原油,Ⅱb原油富含联苯系列与氧芴系列、不同类型芳烃系列中以低分子量同系物占绝对优势,其正构烷烃单体烃碳同位素更重,与相邻的羊塔克地区原油表现出一定的相似性,表明两者之间有一定的成因联系,前者可能为混源油,由位于库车坳陷中拜城凹陷提供两种陆相烃源岩。英买力地区陆相油并非以往确认的一种成因类型,可能至少由两套性质迥异的中生界烃源岩供烃。英买力地区第一类海相油(I类)尽管生物标志物特征相近,但分析原油的单体烃碳同位素具有显著差异,同样存在油气混源的可能。英买力地区海、陆相原油特征与成因的深入剖析,对于该区精细油源确认、油气成藏机制乃至油气资源评价具有重要意义。 相似文献
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大庆深部致密砂砾岩含气储层产能预测 总被引:4,自引:0,他引:4
气层产能预测是气藏工程研究中用于指导气井以及气田合理生产的重要工作和任务,它在气田整体评价和高效开发进程中具有很强的预见性和主动性。讨论了大庆深部致密砂砾岩含气储层的产能与测井响应之间的关系,探讨了根据测井资料应用人工神经网络技术预测含气储层产能的方法。利用已知气井测试结果和测井资料作为网络的训练样本。根据网络学习训练结果,输入储集层的测井资料等静态参数,可预测该储集层的产能。根据这种关系采用神经网络技术实现了测井对产能的预测评价,从而为大庆深部致密砂砾岩含气储层的开发提供了一定的依据。 相似文献
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油层不同开采时期原油组分变化特征 总被引:1,自引:0,他引:1
运用有机地球化学分离、分析技术对取自塔里木盆地的东河、塔中和轮南油田不同时期开采出的原油样品进行剖析,研究其宏观组成和微观分子在时空上的变化规律。分析结果表明,原油饱 /芳比值随开采时间的推移呈下降的趋势;饱和烃与非烃 +沥青质的含量变化有很好的相关性。随着开采时间的增长,原油中正构烷烃的主峰碳数后移,原油的轻 /重组分比降低。原油碱性氮、有机酸等非烃类化合物随开采时间的推移也呈降低的趋势。这些变化与原油在驱替过程中的自然色层吸附作用机理和原油中各种组分的相互作用关系有关。该项研究对于深入探索驱油机理、预测原油润湿性和提高采收率具有重要的实际意义。 相似文献