Effects of Groundwater Development on Uranium: Central Valley,California, USA

Uranium (U) concentrations in groundwater in several parts of the eastern San Joaquin Valley, California, have exceeded federal and state drinking water standards during the last 20 years. The San Joaquin Valley is located within the Central Valley of California and is one of the most productive agricultural areas in the world. Increased irrigation and pumping associated with agricultural and urban development during the last 100 years have changed the chemistry and magnitude of groundwater recharge, and increased the rate of downward groundwater movement. Strong correlations between U and bicarbonate suggest that U is leached from shallow sediments by high bicarbonate water, consistent with findings of previous work in Modesto, California. Summer irrigation of crops in agricultural areas and, to lesser extent, of landscape plants and grasses in urban areas, has increased Pco₂ concentrations in the soil zone and caused higher temperature and salinity of groundwater recharge. Coupled with groundwater pumping, this process, as evidenced by increasing bicarbonate concentrations in groundwater over the last 100 years, has caused shallow, young groundwater with high U concentrations to migrate to deeper parts of the groundwater system that are tapped by public-supply wells. Continued downward migration of U-affected groundwater and expansion of urban centers into agricultural areas will likely be associated with increased U concentrations in public-supply wells. The results from this study illustrate the potential long-term effects of groundwater development and irrigation-supported agriculture on water quality in arid and semiarid regions around the world.     

Describing near surface, transient flow processes in unconfined aquifers below irrigated lands: A deforming finite element model for heterogeneous aquifers

Hydrologic models of irrigated lands generally adopt either a basin-scale or a root-zone perspective. While basin-wide macro-scale models rely on the aggregation of important spatial and temporal data across large areas, micro-scale root-zone models depend on the definition of rigid boundaries around the zone of plant–soil–water interaction. In reality, irrigation management decisions are made on a field by field basis and can interact across field boundaries. This paper first describes a shallow water table model, based on deforming finite element (DFE) framework, to characterize the near-surface field-to-field hydrologic response to various irrigation and drainage management regimes along a gently sloping alluvial fan. The model is then enhanced through changing geometry of a fluctuating water table below a series of irrigated fields. Such an enhancement also offers computational flexibility relative to the saturated–unsaturated models commonly used in micro-scale studies. The model is designed with the alluvial fan aquifers of California’s western San Joaquin Valley as reference systems.     

Sediment storage and transport in Pancho Rico Valley during and after the Pleistocene‐Holocene transition,Coast Ranges of central California (Monterey County)

Factors influencing sediment transport and storage within the 156·6 km² drainage basin of Pancho Rico Creek (PRC), and sediment transport from the PRC drainage basin to its c. 11 000 km² mainstem drainage (Salinas River) are investigated. Numeric age estimates are determined by optically stimulated luminescence (OSL) dating on quartz grains from three sediment samples collected from a ‘quaternary terrace a (Qta)’ PRC terrace/PRC‐tributary fan sequence, which consists dominantly of debris flow deposits overlying fluvial sediments. OSL dating results, morphometric analyses of topography, and field results indicate that the stormy climate of the Pleistocene‐Holocene transition caused intense debris‐flow erosion of PRC‐tributary valleys. However, during that time, the PRC channel was backfilled by Qta sediment, which indicates that there was insufficient discharge in PRC to transport the sediment load produced by tributary‐valley denudation. Locally, Salinas Valley alluvial stratigraphy lacks any record of hillslope erosion occurring during the Pleistocene‐Holocene transition, in that the alluvial fan formed where PRC enters the Salinas Valley lacks lobes correlative to Qta. This indicates that sediment stripped from PRC tributaries was mostly trapped in Pancho Rico Valley despite the relatively moist climate of the Pleistocene‐Holocene transition. Incision into Qta did not occur until PRC enlarged its drainage basin by c. 50% through capture of the upper part of San Lorenzo Creek, which occurred some time after the Pleistocene‐Holocene transition. During the relatively dry Holocene, PRC incision through Qta and into bedrock, as well as delivery of sediment to the San Ardo Fan, were facilitated by the discharge increase associated with stream‐capture. The influence of multiple mechanisms on sediment storage and transport in the Pancho Rico Valley‐Salinas Valley system exemplifies the complexity that (in some instances) must be recognized in order to correctly interpret terrestrial sedimentary sequences in tectonically active areas. Copyright © 2009 John Wiley & Sons, Ltd.     

Pesticide residues in ground water of the San Joaquin Valley, California

A regional assessment of non-point-source contamination of pesticide residues in ground water was made of the San Joaquin Valley, an intensively farmed and irrigated structural trough in central California. About 10% of the total pesticide use in the USA is in the San Joaquin Valley. Pesticides detected include atrazine, bromacil, 2.4-DP, diazinon, dibromochloropropane, 1,2-dibromoethane, dicamba, 1,2-dichloropropane, diuron, prometon, prometryn, propazine and simazine. All are soil applied except diazinon.

Pesticide leaching is dependent on use patterns, soil texture, total organic carbon in soil, pesticide half-life and depth to water table. Leaching is enhanced by flood-irrigation methods except where the pesticide is foliar applied such as diazinon. Soils in the western San Joaquin Valley are fine grained and are derived primarily from marine shales of the Coast Ranges. Although shallow ground water is present, the fewest number of pesticides were detected in this region. The fine-grained soil inhibits pesticide leaching because of either low vertical permeability or high surface area; both enhance adsorption on to solid phases. Soils of the valley floor tend to be fine grained and have low vertical permeability. Soils in the eastern part of the valley are coarse grained with low total organic carbon and are derived from Sierra Nevada granites. Most pesticide leaching is in these alluvial soils, particularly in areas where depth to ground water is less than 30m. The areas currently most susceptible to pesticide leaching are eastern Fresno and Tulare Counties.

Tritium in water molecules is an indicator of aquifer recharge with water of recent origin. Pesticide residues transported as dissolved species were not detected in non-tritiated water. Although pesticides were not detected in all samples containing high tritium, these samples are indicative of the presence of recharge water that interacted with agricultural soils.     

Importance of river water recharge to the San Joaquin Valley groundwater system

Groundwater is not a sustainable resource, unless abstraction is balanced by recharge. Identifying the sources of recharge in a groundwater basin is critical for sustainable groundwater management. We studied the importance of river water recharge to groundwater in the south‐eastern San Joaquin Valley (24,000 km², population 4 million). We combined dissolved noble gas concentrations, stable isotopes, tritium, and carbon‐14 analyses to analyse the sources, mechanisms, and timescales of groundwater recharge. Area‐representative groundwater sampling and numerical model input data enabled a stable isotope mass balance and quantitative estimates of river and local recharge. River recharge, identified by a lighter stable isotope signature, represents 47 ± 4% of modern groundwater in the San Joaquin Valley (recharged after 1950) but only 26 ± 4% of premodern groundwater (recharged before 1950). This implies that the importance of river water recharge in the San Joaquin valley has nearly doubled and is likely the result of a 40% increase in total recharge, caused by river water irrigation return flows and increased stream depletion and river recharge due to groundwater pumping. Compared with the large and long‐duration capacity for water storage in the subsurface, storage of water in rivers is limited in time and volume, as evidenced by cold river recharge temperatures resulting from fast infiltration and recharge. Groundwater banking of seasonal surface water flows and expansion of managed aquifer recharge practices therefore appear to be a natural and promising method for increasing the resilience of the San Joaquin Valley water supply system.     

Climate change sensitivity assessment of streamflow and agricultural pollutant transport in California's Central Valley using Latin hypercube sampling

Bracketing the uncertainty of streamflow and agricultural runoff under climate change is critical for proper future water resource management in agricultural watersheds. This study used the Soil and Water Assessment Tool (SWAT) in conjunction with a Latin hypercube climate change sampling algorithm to construct a 95% confidence interval (95CI) around streamflow, sediment load, and nitrate load predictions under changes in climate for the Sacramento and San Joaquin River watersheds in California's Central Valley. The Latin hypercube algorithm sampled 2000 combinations of precipitation and temperature changes based on Intergovernmental Panel on Climate Change projections from multiple General Circulation Models. Average monthly percent changes of the upper and lower 95CI limits compared to the present‐day simulation and a statistic termed the “r‐factor” (average width of the 95CI band divided by the standard deviation of the 95CI bandwidth) were used to assess watershed sensitivities. 95CI results indicate that streamflow and sediment runoff in the Sacramento River watershed are more likely to decrease under climate change compared to present‐day conditions, whereas the increase and decrease for nitrate runoff were found to be equal. For the San Joaquin River watershed, streamflow slightly decreased under climate change, whereas sediment and nitrate runoff increased compared to present‐day climate. Comparisons of watershed sensitivities indicate that the San Joaquin River watershed is more sensitive to climate changes than the Sacramento River watershed, which is largely caused by the high density of agricultural land. Copyright © 2012 John Wiley & Sons, Ltd.     

Depositional process and alluvial fan-drainage basin morphometric relationships near banff,Alberta, Canada

Two distinct types of alluvial fans occur in the Bow River Valley, Alberta, Canada: fluvially dominated and debris flow dominated. Large, gently sloping fans dominated by fluvial processes are associated with large and less rugged drainage basins, and small rugged basins have produced small, steep fans dominated by debris flow processes. Quantitative analysis demonstrates that strong fan-basin morphometric relationships occur despite a short fan history. Statistical analysis of fan area-basin area relationships indicate that debris flow fan areas do not increase in size as quickly as contributing basins. The relationship of fluvial fan area to basin area is not statistically significant. However, this relationship is probably affected by fan erosion. Examination of fan slope to basin ruggedness relationships indicates that fan slope increases more rapidly than basin ruggedness for both fan types. This is likely related to non-linear discharge and sediment size effects on fluvial fans, and reworking of larger fan surfaces by fluvial processes on debris flow fans.     

Depth‐dependent hydraulic conductivity distribution patterns of a streambed

Characterization of streambed hydraulic conductivity from the channel surface to a great depth below the channel surface can provide needed information for the determination of stream‐aquifer hydrologic connectedness, and it is also important to river restoration. However, knowledge on the streambed hydraulic conductivity for sediments 1 m below the channel surface is scarce. This study describes a method that was used to determine the distribution patterns of streambed hydraulic conductivity for sediments from channel surface to a depth of 15 m below. The method includes Geoprobe's direct‐push techniques and Permeameter tests. Direct‐push techniques were used to generate the electrical conductivity (EC) logs and to collect sequences of continuous sediment cores from river channels, as well as from the alluvial aquifer connected to the river. Permeameter tests on these sediment cores give the profiles of vertical hydraulic conductivity (K_v) of the channel sediments and the aquifer materials. This method was applied to produce K_v profiles for a streambed and an alluvial aquifer in the Platte River Valley of Nebraska, USA. Comparison and statistical analysis of the K_v profiles from the river channel and from the proximate alluvial aquifer indicates a special pattern of K_v in the channel sediments. This depth‐dependent pattern of K_v distribution for the channel sediments is considered to be produced by hyporheic processes. This K_v‐distribution pattern implied that the effect of hyporheic processes on streambed hydraulic conductivity can reach the sediments about 9 m below the channel surface. Copyright © 2010 John Wiley & Sons, Ltd.     

Characteristics of chemistry and stable isotopes in groundwater of Chaobai and Yongding River basin,North China Plain

To identify the groundwater flow system in the North China Plain, the chemical and stable isotopes of the groundwater and surface water were analysed along the Chaobai River and Yongding River basin. According to the field survey, the study area in the North China Plain was classified hydrogeologically into three parts: mountain, piedmont alluvial fan and lowland areas. The change of electrical conductance and pH values coincided with groundwater flow from mountain to lowland areas. The following groundwater types are recognized: Ca? HCO₃ and Ca? Mg? HCO₃ in mountain areas, Ca? Mg? HCO₃ and Na? K? HCO₃ in piedmont alluvial fan areas, and HCO₃? Na in lowland areas. The stable isotope distribution of groundwater in the study area also has a good corresponding relation with other chemical characteristics. Stable isotope signatures reveal a major recharge from precipitation and surface water in the mountain areas. Chemical and stable isotope analysis data suggest that mountain and piedmont alluvial fan areas were the major recharge zones and the lowland areas belong to the main discharge zone. Precipitation and surface water were the major sources for groundwater in the North China Plain. Stable isotopic enrichment of groundwater near the dam area in front of the piedmont alluvial fan areas shows that the dam water infiltrated to the ground after evaporation. As a result, from the stable isotope analysis, isotope value of groundwater tends to deplete from sea level (horizontal ground surface) to both top of the mountain and the bottom of the lowland areas in symmetrically. This suggests that groundwater in the study area is controlled by the altitude effect. Shallow groundwater in the study area belongs to the local flow system and deep groundwater part of the regional flow system. Copyright © 2007 John Wiley & Sons, Ltd.     

Impact of urbanization on the ecology of Mukuvisi River,Harare, Zimbabwe

The main objective in this study was to compare the physico-chemical characteristics and biota of a river (Mukuvisi) passing through an urban area to that of a non-urbanised river (Gwebi). Five sites in the Mukuvisi River and five sites in the Gwebi River were sampled for water physico-chemical parameters (pH, conductivity, DO, BOD, TDS, ammonia, Cl, SO₄²⁻, PO₄²⁻, NO₃³⁻, F⁻, Pb, Cu, Fe, Mn, Zn and Cr) once every month between August, 2012–August, 2013. Cluster analysis based on the physico-chemical parameters grouped the sites into two groups. Mukuvisi River sites formed their own grouping except for one site which was grouped with Gwebi River sites. Principal Component Analysis (PCA) was used to extract the physico-chemical parameters that account for most variations in water quality in the Mukuvisi and Gwebi Rivers. PCA identified sulphate, chloride, fluoride, iron, manganese and zinc as the major factors contributing to the variability of Mukuvisi River water quality. In the Gwebi river, sulphate, nitrate, fluoride and copper accounted for most of the variation in water quality. Canonical Correspondence Analysis (CCA) was used to explore the relationship between physico-chemical parameters and macroinvertebrate communities. CCA plots in both Mukuvisi and Gwebi Rivers showed significant relationships between macroinvertebrate communities and water quality variables. Phosphate, ammonia and nitrates were correlated with Chironomidae and Simulidae. Gwebi River had higher (P < 0.05, ANOVA) macroinvertebrates and fish diversity than Mukuvisi River. Clarias gariepinus from the Mukuvisi River had high liver histological lesions and low AChE activity and this led to lower growth rates in this river.     

Multiple‐indicator study of groundwater flow and chemistry and the impacts of river and paddy water on groundwater in the alluvial fan of the Tedori River,Japan

To investigate the source, flow paths, and chemistry of rich resources of high‐quality, shallow groundwater in the alluvial fan between the Tedori and Sai rivers in central Japan, we analysed stable isotope ratios of H, O, and Sr and concentrations of major dissolved ions and trace elements in groundwater, river water, and paddy water. The ⁸⁷Sr/⁸⁶Sr ratios of the groundwater are related to near‐surface geology: groundwater in sediment from the Tedori River has high ⁸⁷Sr/⁸⁶Sr ratios (>0.711), whereas that from the Sai River in the north of the fan has low ⁸⁷Sr/⁸⁶Sr ratios (<0.711). δ²H and δ¹⁸O values and ⁸⁷Sr/⁸⁶Sr ratios indicate that groundwater in the central and southern fans is recharged by the Tedori River, whereas recharge in the north is from the Sai River. Mg²⁺, Ca²⁺, Sr²⁺, HCO₃^?, and SO₄^2? concentrations and δ²H and δ¹⁸O values in the groundwater are high in the central fan and, except for the northern area, tend to increase with distance from the Tedori River. There are linear relationships between ⁸⁷Sr/⁸⁶Sr ratio and the reciprocal concentrations of Sr²⁺, Mg²⁺, and Ca²⁺. These geochemical characteristics suggest that as groundwater recharged from the Tedori River flows towards the central fan, it mixes with waters derived from precipitation and paddy water that have become enriched in these components during downward infiltration. These results are consistent with our hydrological analysis and numerical simulation of groundwater flow, thus verifying the validity of the model we used in our simulation of groundwater flow. Copyright © 2016 John Wiley & Sons, Ltd.     

Groundwater quality in the semi‐arid region of the Chahardouly basin,West Iran

Chahardouly basin is located in the western part of Iran and is characterized by semi‐arid climatic conditions and scarcity in water resources. The main aquifer systems are developed within alluvial deposits. The availability of groundwater is rather erratic owing to the occurrence of hard rock formation and a saline zone in some parts of the area. The aquifer systems of the area show signs of depletion, which have taken place in recent years due to a decline in water levels. Groundwater samples collected from shallow and deep wells were analysed to examine the quality characteristics of groundwater. The major ion chemistry of groundwater is dominated by Ca²⁺ and HCO₃^?, while higher values of total dissolved solids (TDS) in groundwater are associated with high concentrations of all major ions. An increase in salinity is recorded in the down‐gradient part of the basin. The occurrence of saline groundwater, as witnessed by the high electrical conductivity (EC), may be attributed to the long residence time of water and the dissolution of minerals, as well as evaporation of rainfall and irrigation return flow. Based on SAR values and sodium content (%Na), salinity appears to be responsible for the poor groundwater quality, rendering most of the samples not suitable for irrigation use. Copyright © 2007 John Wiley & Sons, Ltd.     

Dating alluvial fan surfaces in Owens Valley,California, using weathering fractures in boulders

A wide range of sedimentological and geomorphological field research depends on the availability of accurate and detailed depositional age models. Although exposure dating techniques such as cosmogenic nuclide and luminescence dating are now widely available, they remain expensive and time‐consuming, and this frequently limits the density of age constraints and the resolutions of age models for many study areas. We present a simple and effective, field‐based approach for extending and correlating existing age models to un‐dated surfaces. In Owens Valley, California, we make use of detailed beryllium‐10 (¹⁰Be) chronologies reported for four different alluvial fan systems, to precisely calibrate the rate at which weathering fractures are enlarged in granitic surface boulders. We show that these fractures have widened at a time‐integrated rate of 1.05 ± 0.03 mm ka^?1 for at least 140 ka at this location, and this relationship can be represented by a linear regression that makes them ideal chronometers for surface dating. Our analysis offers a new approach to refining the uncertainties of both surface erosion rate and cosmogenic age estimates at this location. Ultimately, we integrate our observations to devise a robust age calibration for clast fracture widths in Owens Valley, and we demonstrate its application by estimating the ages of 27 additional local fan surfaces. We present an updated and extended stratigraphy for eight Sierra Nevada fan systems in total, with exceptional age control. This novel approach to dating sedimentary surfaces is inexpensive and easily applied in the field, and has the potential to significantly increase the temporal and spatial density of age constraints available for a particular study area. Copyright © 2014 John Wiley & Sons, Ltd.     

Diurnal variability in riverine dissolved organic matter composition determined by in situ optical measurement in the San Joaquin River (California,USA)

Dissolved organic matter (DOM) concentration and composition in riverine and stream systems are known to vary with hydrological and productivity cycles over the annual and interannual time scales. Rivers are commonly perceived as homogeneous with respect to DOM concentration and composition, particularly under steady flow conditions over short time periods. However, few studies have evaluated the impact of short term variability (<1 day) on DOM dynamics. This study examined whether diurnal processes measurably altered DOM concentration and composition in the hypereutrophic San Joaquin River (California) during a relatively quiescent period. We evaluated the efficacy of using optical in situ measurements to reveal changes in DOM which may not be evident from bulk dissolved organic carbon (DOC) measurement alone. The in situ optical measurements described in this study clearly showed for the first time diurnal variations in DOM measurements, which have previously been related to both composition and concentration, even though diurnal changes were not well reflected in bulk DOC concentrations. An apparent asynchronous trend of DOM absorbance and chlorophyll‐a in comparison to chromophoric dissolved organic matter (CDOM) fluorescence and spectral slope S_290–350 suggests that no one specific CDOM spectrophotometric measurement explains absolutely DOM diurnal variation in this system; the measurement of multiple optical parameters is therefore recommended. The observed diurnal changes in DOM composition, measured by in situ optical instrumentation likely reflect both photochemical and biologically‐mediated processes. The results of this study highlight that short‐term variability in DOM composition may complicate trends for studies aiming to distinguish different DOM sources in riverine systems and emphasizes the importance of sampling specific study sites to be compared at the same time of day. The utilization of in situ optical technology allows short‐term variability in DOM dynamics to be monitored and serves to increase our understanding of its processing and fundamental role in the aquatic environment. Copyright © 2007 John Wiley & Sons, Ltd.     

Geochemical evidence of hydrothermal recharge in Lake Baringo,central Kenya Rift Valley

Lake Baringo, a freshwater lake in the central Kenya Rift Valley, is fed by perennial and ephemeral rivers, direct rainfall, and hot springs on Ol Kokwe Island near the centre of the lake. The lake has no surface outlet, but despite high evaporation rates it maintains dilute waters by subsurface seepage through permeable sediments and faulted lavas. New geochemical analyses (major ions, trace elements) of the river, lake, and hot spring waters and the suspended sediments have been made to determine the main controls of lake water quality. The results show that evaporative concentration and the binary mixing between two end members (rivers and thermal waters) can explain the hydrochemistry of the lake waters. Two zones are recognized from water composition. The southern part of the lake near sites of perennial river inflow is weakly influenced by evaporation, has low total dissolved species (TDS), and has a seasonally variable load of mainly detrital suspended sediments. In contrast, waters of the northern part of the lake show evidence for strong evaporation (TDS of up to eight times inflow). Authigenic clay minerals and calcite may be precipitating from those more concentrated fluids. The subaerial hot‐spring waters have a distinctive chemistry and are enriched in some elements that are also present in the lake water. Comparison of the chemical composition of the inflowing surface waters and lake water shows (1) an enrichment of some species (HCO₃^?, Cl, SO₄^2?, F, Na, B, V, Cr, As, Mo, Ba and U) in the lake, (2) a depletion in SiO₂ in the lake, and (3) a possible hydrothermal origin for most F. The rare earth element distribution and the F/Cl and Na/Cl ratios give valuable information on the rate of mixing of the river and hydrothermal fluids in the lake water. Calculations imply that thermal fluids may be seeping upward locally into the lake through grid‐faulted lavas, particularly south of Ol Kokwe Island. Copyright © 2006 John Wiley & Sons, Ltd.     

Assimilation of historical head data to estimate spatial distributions of stream bed and aquifer hydraulic conductivity fields

Management of water resources in alluvial aquifers relies mainly on understanding interactions between hydraulically connected streams and aquifers. Numerical models that simulate this interaction often are used as decision support tools for water resource management. However, the accuracy of numerical predictions relies heavily on unknown system parameters (e.g., streambed conductivity and aquifer hydraulic conductivity), which are spatially heterogeneous and difficult to measure directly. This paper employs an ensemble smoother to invert groundwater level measurements to jointly estimate spatially varying streambed and alluvial aquifer hydraulic conductivity along a 35.6‐km segment of the South Platte River in Northeastern Colorado. The accuracy of the inversion procedure is evaluated using a synthetic experiment and historical groundwater level measurements, with the latter constituting the novelty of this study in the inversion and validation of high‐resolution fields of streambed and aquifer conductivities. Results show that the estimated streambed conductivity field and aquifer conductivity field produce an acceptable agreement between observed and simulated groundwater levels and stream flow rates. The estimated parameter fields are also used to simulate the spatially varying flow exchange between the alluvial aquifer and the stream, which exhibits high spatial variability along the river reach with a maximum average monthly aquifer gain of about 2.3 m³/day and a maximum average monthly aquifer loss of 2.8 m³/day, per unit area of streambed (m²). These results demonstrate that data assimilation inversion provides a reliable and computationally affordable tool to estimate the spatial variability of streambed and aquifer conductivities at high resolution in real‐world systems.     

Ground-water surface-water interactions and long-term change in riverine riparian vegetation in the southwestern United States

Riverine riparian vegetation has changed throughout the southwestern United States, prompting concern about losses of habitat and biodiversity. Woody riparian vegetation grows in a variety of geomorphic settings ranging from bedrock-lined channels to perennial streams crossing deep alluvium and is dependent on interaction between ground-water and surface-water resources. Historically, few reaches in Arizona, southern Utah, or eastern California below 1530 m elevation had closed gallery forests of cottonwood and willow; instead, many alluvial reaches that now support riparian gallery forests once had marshy grasslands and most bedrock canyons were essentially barren. Repeat photography using more than 3000 historical images of rivers indicates that riparian vegetation has increased over much of the region. These increases appear to be related to several factors, notably the reduction in beaver populations by trappers in the 19th century, downcutting of arroyos that drained alluvial aquifers between 1880 and 1910, the frequent recurrence of winter floods during discrete periods of the 20th century, an increased growing season, and stable ground-water levels. Reductions in riparian vegetation result from agricultural clearing, excessive ground-water use, complete flow diversion, and impoundment of reservoirs. Elimination of riparian vegetation occurs either where high ground-water use lowers the water table below the rooting depth of riparian species, where base flow is completely diverted, or both. We illustrate regional changes using case histories of the San Pedro and Santa Cruz Rivers, which are adjacent watersheds in southern Arizona with long histories of water development and different trajectories of change in riparian vegetation.     

Earthquake chemical precursors in groundwater: a review

We review changes in groundwater chemistry as precursory signs for earthquakes. In particular, we discuss pH, total dissolved solids (TDS), electrical conductivity, and dissolved gases in relation to their significance for earthquake prediction or forecasting. These parameters are widely believed to vary in response to seismic and pre-seismic activity. However, the same parameters also vary in response to non-seismic processes. The inability to reliably distinguish between changes caused by seismic or pre-seismic activities from changes caused by non-seismic activities has impeded progress in earthquake science. Short-term earthquake prediction is unlikely to be achieved, however, by pH, TDS, electrical conductivity, and dissolved gas measurements alone. On the other hand, the production of free hydroxyl radicals (?OH), subsequent reactions such as formation of H₂O₂ and oxidation of As(III) to As(V) in groundwater, have distinctive precursory characteristics. This study deviates from the prevailing mechanical mantra. It addresses earthquake-related non-seismic mechanisms, but focused on the stress-induced electrification of rocks, the generation of positive hole charge carriers and their long-distance propagation through the rock column, plus on electrochemical processes at the rock-water interface.     

Sediment contamination in floodplains and alluvial terraces as an historical record of gold exploitation in the Carmo River basin,Southeast Quadrilátero Ferrífero,Minas Gerais,Brazil

This paper describes the geochemistry of sediment samples placed in floodplains and alluvial terraces downstream from gold mines in the Carmo River basin, Quadrilátero Ferrífero, Minas Gerais, Brazil. The geochemistry signature Na₂O, K₂O, SiO₂, CaO, MgO, Al₂O₃, Fe₂O₃, TiO₂, P₂O₅, Mn, As, Cu, Zn, Ba, Ni, Cr, S, Co were analyzed in different facies from stratigraphic profiles. As, Cu, Zn, and Mn anomalies are mainly associated with the clayed facies deposited in floodplains and oxbow lakes, and with coarse‐sediment facies deposited in the channel. The facies were accumulated by the gold exploitation activity in the region. The contamination of As, Cu, and Zn was controlled by minerals such as iron oxides and hydroxides (hematite, magnetite, and mainly goethite), manganese oxides, and sulfide‐rich minerals. The As‐bearing sediments of the region characterize one of the most As contaminated area of Brazil. Their main source is associated with gold exploration in the last three centuries.