The transformation of γ Fe2O3 to α Fe2O3: thermal activation and the effect of elevated pressure

The transformation of acicular γ Fe₂O₃ particles to α Fe₂O₃ has been monitored using magnetic properties as a proxy for γ Fe₂O₃ concentration during the inversion process. The transformation is thermally activated, the height of the barrier opposing inversion being 3.7 eV at atmospheric pressure and 0.5 eV at a pressure of about 100 MPa. The barrier arises from the combination of a term representing the reduction in lattice energy in an inverted region, and the strain energy associated with the interface between the inverted and non-inverted phases. The sensitivity of the inversion process to pressure can be understood in terms of the dependence of these energy terms, and the energy barrier, on interatomic spacing. Extrapolation of these laboratory data to the conditions of the submarine crust at Site 504B of the Deep Sea Drilling Project is consistent with the inferred magnetic mineralogy of the recovered material.     

Seasonal and Long-Term Changes in the Intensity of O2(b1Σ) and OH(X2Π) Airglow in the Mesopause Region

Geomagnetism and Aeronomy - Spectral observations of the mesopause airglow at the Zvenigorod Scientific Station have been used to obtain the midnight emission intensities of molecular oxygen...     

Asymmetry of the contours of the Fe X 6374-Å coronal line

The east-west asymmetry has been analyzed using the 1946–2000 corona observation data for the green line at the Kislovodsk station. A positive east-west asymmetry has been revealed throughout the entire observation period except for three years, 1994–1996. Time variations of the east-west asymmetry for certain periods coincide with those for flares. Seasonal variations of the east-west asymmetry revealed earlier by other authors are not confirmed. If seasonal variations of the east-west asymmetry in the corona exist, their amplitudes are smaller than or comparable to the instrumental errors, errors caused by atmospheric variations during the observation period and to differences between the corona-intensity measuring systems used at different observatories.     

Origin of the Dashuigou independent tellurium deposit at Qinghai–Xizang Plateau: constraints from the light stable isotopes C,O, and H

By studying the light isotopic compositions of carbon, oxygen, and hydrogen, combined with previous research results on the ore-forming source of the deposit, the authors try to uncover its metallogenic origin. The δ¹⁸O and δ¹³C isotope signatures of dolomite samples vary between 10.2 and 13.0‰, and between-7.2 and-5.2‰, respectively, implying that the carbon derives from the upper mantle. δD and δ¹⁸O of quartz, biotite, and muscovite from different ore veins of ...     

Experimental study on N_2O and CH_4 fluxes from the dark coniferous forest zone soil of the Gongga Mountain, China

The increasing concentration of greenhouse gas in the atmosphere and their resultant climatic and environmental changes have been drawing much attention of the governments of various countries in recent years. The sphere of global influence and the comp…     

Applications of interannual-resolution stable isotope records of speleothem: Climatic changes in Beijing and Tianjin, China during the past 500 years—the δ 18O record

δ¹⁸O of a stalagmite collected from Shihua Cave, 50 km southwest of Beijing is analyzed. The uppermost 2 cm was sampled at about 3-year intervals by a computer-controlled microsampling device. A total of 133 samples were analyzed, covering the last 480 years. A comparison of the δ¹⁸O record with the instrumentally recorded precipitation in Beijing and Tianjin back to 1840 AD shows that high precipitation correlates with negative δ¹⁸O peaks. The long-term δ¹⁸O trend records temperature changes. Between 1620 and 1900 AD, the temperature was cooler than the average value for the 480-year record, corresponding to the Little Ice Age. Temperatures warmer than the average prevailed during 1520–1620 and 1900—present. Superimposed on the long-term trend are about 14 δ¹⁸O cycles of 30–40-year periodicity, with wet periods centered around 1985, 1955, 1910, 1880, 1840, 1800, 1760, 1730, 1690, 1660, 1630, 1600, 1560 and 1530 AD. Project supported by the National Natural Science Foundation of China (Grant No. 9615875).     

The role of aerial algae in the formation of the landscape of the Yunnan Stone Forest,Yunnan Province, China

~~The role of aerial algae in the formation of the landscape of the Yunnan Stone Forest,Yunnan Province, China~~     

Extremely strong geomagnetic storm of September 2–3, 1859, according to the archived data of observations at the Russian network

A retrospective analysis of the Russian magnetic observations of the Carrington event that occurred on September 2–3, 1859, has been performed. The conclusion has been made that this event was caused by the series of three recurrent eruptive solar flares during ～40 h. The characteristics of the geomagnetic crochet, related to a considerable flux of the ionizing electromagnetic radiation during this flare, have been studied. The value and direction of a magnetic field disturbance, registered during the maximum of the geomagnetic storm of September 2, unambiguously indicate that all Russian stations were in the auroral oval zone, which was strongly expanded southward from its average position. The disturbance dependence on the station longitude—the absence of magnetometer pinning in Nerchinsk—is interpreted as the possible manifestation of a strong asymmetry in the effective contour of the current system, which was connected to the heliosphere and covered the disturbed magnetosphere and ionosphere during the short period that lasted only 1–3 h.     

Taxonomic revision of Cylindroporella ? lusitanica Ramalho, 1970: In search for the origins of the Family Dasycladaceae

A study of new material of Cylindroporella ? lusitanica Ramalho, 1970, from the Upper Jurassic (Oxfordian) strata of Portugal identified features not observed previously. This includes the pattern of its laterals, including the gametophores. The algal body plan is unique and justifies the taxonomic reassessment of this species and the introduction of Barattoloporellopsis n. gen. Furthermore this species is most likely a primitive Dasycladaceae, a “missing link” between the modern ones (starting from the Cretaceous times) and their Jurassic ancestors.     

2D site response analysis of a cultural heritage: the case study of the site of Santa Maria di Collemaggio Basilica (L’Aquila,Italy)

The Santa Maria di Collemaggio Basilica is an important cultural heritage site and exemplifies Romanesque-Gothic art in the Abruzzo region (central Italy). Erected in the second half of the XII century, the Basilica was severely damaged during the April 6, 2009 L’Aquila earthquake (M_W 6.1). In particular, the area of the transept collapsed causing the dome to fall. A refined two-dimensional (2D) geotechnical model was built representing a section that includes the Basilica, in order to better understand the soil response of the Basilica site. The subsoil model was constrained using the geophysical and geotechnical data collected from the seismic microzonation studies, the reconstruction of private damaged buildings and other technical and scientific studies realized in the L’Aquila basin and in the area of the Basilica before and after L’Aquila earthquake. 2D site response analyses were performed to verify the presence of local site effects by comparing simulated versus experimental transfer functions. Moreover, a frequency–wavenumber (f–k) analysis was executed with the aim of evaluating the occurrence of surface waves generated within the basin. 2D seismic effects involve significant amplification in the period range of engineering interest, therein providing an appropriate elastic response spectrum for the restoration of the Basilica.     

Study of the earthquake of the January 23, 1880, in San Cristóbal,Cuba and the Guane fault

All available data on the January 23, 1880, earthquake near San Cristobal, Western Cuba, are compiled and presented here. The earthquake reached a maximum intensity of eight degrees (MSK) and caused three fatalities. It was accompanied by 65 aftershocks and was felt as far away as the Florida Keys. Twentieth century specialists has associated this event, in its day the strongest recorded (Ms = 6.2) in the region, with the Pinar fault. The Pinar fault is well expressed topographically as the boundary between the Guaniguanico Range in the north and an alluvial plain to the south. Most of the major damage caused by the earthquake was located on the alluvial plain, which in consequence has been considered the epicenter area. In the study presented here, the data compiled from the first reports of Father Benito Vines Martorell, S.J., and Pedro Salteraín y Legarra, indicate that the seismic structure was located in the alluvial plain, and that it was the Guane fault, and not the Pinar fault, that was responsible for the earthquake. The Guane fault, found below the alluvial sediments, extends NE-SW for over 110 km. Its eastern extreme, near San José de las Lajas (La Habana), is linked to another active fault which represents a seismoactive knot responsible for the earthquake of March 9, 1995 (I = 5 degrees, MSK). Seismic events of the Western Cuban region are related to the transpressive interaction of the North American and Caribbean Plates, damped by oceanic structures.     

The discovery of TiO2-Ⅱ,the α-PbO2-structured high-pressure polymorph of rutile,in the Suizhou L6 chondrite

We report the discovery of TiO₂-Ⅱ in the unmelted rock of the shocked Suizhou L6 chondrite.Natural TiO₂-Ⅱ was previously found in ultrahigh-pressure metamorphic and mantle-derived rocks,terrestrial impact structures,and tektite.Our microscopic,Raman spectroscopic,electron microprobe and transmission electron microscopic investigations have revealed:(1) All observed TiO₂-Ⅱ grains are related with ilmenite and pyrophanite;(2) TiO₂-Ⅱ occurs as needle-and ...     

Double-difference Relocation of the Aftershocks of the Tecom��n, Colima, Mexico Earthquake of 22 January 2003

On 22 January 2003, the M _w?=?7.6 Tecomán earthquake struck offshore of the state of Colima, Mexico, near the diffuse triple junction between the Cocos, Rivera, and North American plates. Three-hundred and fifty aftershocks of the Tecomán earthquake with magnitudes between 2.6 and 5.8, each recorded by at least 7 stations, are relocated using the double difference method. Initial locations are determined using P and S readings from the Red Sismológica Telemétrica del Estado de Colima (RESCO) and a 1-D velocity model. Because only eight RESCO stations were operating immediately following the Tecomán earthquake, uncertainties in the initial locations and depths are fairly large, with average uncertainties of 8.0?km in depth and 1.4?km in the north?Csouth and east?Cwest directions. Events occurring between 24 January and 31 January were located using not only RESCO phase readings but also additional P and S readings from 11 temporary stations. Average uncertainties decrease to 0.8?km in depth, 0.3?km in the east?Cwest direction, and 0.7?km in the north?Csouth direction for events occurring while the temporary stations were deployed. While some preliminary studies of the early aftershocks suggested that they were dominated by shallow events above the plate interface, our results place the majority of aftershocks along the plate interface, for a slab dipping between approximately 20° and 30°. This is consistent with the slab positions inferred from geodetic studies. We do see some upper plate aftershocks that may correspond to forearc fault zones, and faults inland in the upper plate, particularly among events occurring more than 3?months after the mainshock.     

Complex dynamics of small-moderate volcanic events: the example of the 2011 rhyolitic Cordón Caulle eruption,Chile

After decades of repose, Puyehue-Cordón Caulle Volcano (Chile) erupted in June 2011 following a month of continuously increasing seismic activity. The eruption dispersed a large volume of rhyolitic tephra over a wide area and was characterized by complex dynamics. During the initial climactic phase of the eruption (24–30 h on 4–5 June), 11–14-km-high plumes dispersed most of the erupted tephra eastward towards Argentina, reaching as far as the Atlantic Ocean. This first eruptive phase was followed by activity of lower intensity, leading to the development of a complex stratigraphic sequence, mainly due to rapid shifts in wind direction and eruptive style. The resulting tephra deposits consist of 13 main layers grouped into four units. Each layer was characterized based on its dispersal direction, sedimentological features, and on the main characteristics of the juvenile fraction (texture, density, petrography, chemistry). The lowest part of the eruptive sequence (Unit I), corresponding to the tephra emitted between 4 and 5 June, is composed of alternating lapilli layers with a total estimated volume of ca. 0.75 km³; these layers record the highest intensity phase, during which a bent-over plume dispersed tephra towards the southeast-east, with negligible up-wind sedimentation. Products emitted during 5–6 June (Unit II) signaled an abrupt shift in wind direction towards the north, leading to the deposition of a coarse ash deposit in the northern sector (ca. 0.21 km³ in volume), followed by a resumption of easterly directed winds. A third phase (Unit III) began on 7 June and resulted in tephra deposits in the eastern sector and ballistic bombs around the vent area. A final phase (Unit IV) started after 15 June and was characterized by the emission of fine-grained white tephra from ash-charged plumes during low-level activity and the extrusion of a viscous lava flow. Timing and duration of the first eruptive phases were constrained based on comparison of the dispersal of the main tephra layers with satellite images, showing that most of the tephra was emitted during the first 72 h of the event. The analyzed juvenile material tightly clusters within the rhyolitic field, with negligible chemical variations through the eruptive sequence. Textural observations reveal that changes in eruption intensity (and consequently in magma ascent velocity within the conduit) and complex interactions between gas-rich and gas-depleted magma portions during ascent resulted in vesicular clasts with variable degrees of shear localization, and possibly in the large heterogeneity of the juvenile material.     

Channel overflows of the Pōhue Bay flow,Mauna Loa,Hawai'i: examples of the contrast between surface and interior lava

A number of overflows from a large lava channel and tube system on the southwest rift zone of Mauna Loa were studied. Initial overflows were very low viscosity gas-rich phoehoe evidenced by flow-unit aspect ratios and vesicle sizes and contents. Calculated volumetric flow-rates in the channel range between 80 and 890 m³/s, and those of the overflows between 35 and 110 m³/s. After traveling tens to hundreds of meters the tops of these sheet-like overflows were disrupted into a surface composed of clinker and phoehoe fragments. After these 'a' overflows came to rest, lava from the interiors was able to break out on to the surface as phoehoe. The surface structure of a lava flow records the interaction between the differential shear rate (usually correlated with the volumetric flow-rate) and viscosity-induced resistance to flow. However, the interior of a flow, being better insulated, may react differently or record a later set of emplacement conditions. Clefts of toothpaste lava occurring within fields of clinker on proximal-type 'a' flows also record different shear rates during different times of flow emplacement. The interplay between viscosity and shear rate determines the final morphological lava type, and although no specific portion of lava ever makes a transition from 'a' back to phoehoe, parts of a flow can appear to do so.     

Measurement of Martian atmospheric winds by the O2 1.27 μm airglow observations using Doppler Michelson Interferometry: A concept study

Science China Earth Sciences - China’s Mars exploration mission has stimulated tremendous interest in planetary science exploration recently. To propose potential scientific research...     

Field experiment in Soultz-sous-Forêts, 1993: Changes of the pattern of induced seismicity

The data of the known field experiment on water injection in the borehole were analyzed. Parameters of self-similarity of seismicity were estimated in comparison with the changes of water pressure. Changes of seismicity parameters that indicate the redistribution of the failure from lower scales to upper are revealed. The total number of earthquakes per series of the water initiation found to be depended exponentially on the water pressure and seismic activity maximum is delayed gradually relative to beginning of initiation. The growth of induced seismicity zone in time differs from diffusion model for water flow in the porous medium. Analysis carried out from laboratory data indicates that diffusion growth of the failure area may be realized in the dry specimen, without fluid. It could be assumed that both kinetic processes — water and the failure diffusion — can be significant for the development of seismicity induced by the water injection.