RETRACTED: A theoretical study of the ligand-exchange reactions of Na+·X complexes (X=O,O2,N2,CO2 and H2O): implications for the upper atmosphere

This article has been retracted at the request of the editor.Reason: The publisher regrets that several errors appeared in this paper and that it therefore has been retracted. A correct version of the complete paper has been published in Volume 64, Issue 7, pages 863–870 of the Journal of Atmospheric and Solar-Terrestrial Physics.     

Seasonal and Long-Term Changes in the Intensity of O2(b1Σ) and OH(X2Π) Airglow in the Mesopause Region

Geomagnetism and Aeronomy - Spectral observations of the mesopause airglow at the Zvenigorod Scientific Station have been used to obtain the midnight emission intensities of molecular oxygen...     

The transformation of γ Fe2O3 to α Fe2O3: thermal activation and the effect of elevated pressure

The transformation of acicular γ Fe₂O₃ particles to α Fe₂O₃ has been monitored using magnetic properties as a proxy for γ Fe₂O₃ concentration during the inversion process. The transformation is thermally activated, the height of the barrier opposing inversion being 3.7 eV at atmospheric pressure and 0.5 eV at a pressure of about 100 MPa. The barrier arises from the combination of a term representing the reduction in lattice energy in an inverted region, and the strain energy associated with the interface between the inverted and non-inverted phases. The sensitivity of the inversion process to pressure can be understood in terms of the dependence of these energy terms, and the energy barrier, on interatomic spacing. Extrapolation of these laboratory data to the conditions of the submarine crust at Site 504B of the Deep Sea Drilling Project is consistent with the inferred magnetic mineralogy of the recovered material.     

Asymmetry of the contours of the Fe X 6374-Å coronal line

The east-west asymmetry has been analyzed using the 1946–2000 corona observation data for the green line at the Kislovodsk station. A positive east-west asymmetry has been revealed throughout the entire observation period except for three years, 1994–1996. Time variations of the east-west asymmetry for certain periods coincide with those for flares. Seasonal variations of the east-west asymmetry revealed earlier by other authors are not confirmed. If seasonal variations of the east-west asymmetry in the corona exist, their amplitudes are smaller than or comparable to the instrumental errors, errors caused by atmospheric variations during the observation period and to differences between the corona-intensity measuring systems used at different observatories.     

Experimental study on N_2O and CH_4 fluxes from the dark coniferous forest zone soil of the Gongga Mountain, China

The increasing concentration of greenhouse gas in the atmosphere and their resultant climatic and environmental changes have been drawing much attention of the governments of various countries in recent years. The sphere of global influence and the comp…     

The role of aerial algae in the formation of the landscape of the Yunnan Stone Forest,Yunnan Province, China

~~The role of aerial algae in the formation of the landscape of the Yunnan Stone Forest,Yunnan Province, China~~     

Extremely strong geomagnetic storm of September 2–3, 1859, according to the archived data of observations at the Russian network

A retrospective analysis of the Russian magnetic observations of the Carrington event that occurred on September 2–3, 1859, has been performed. The conclusion has been made that this event was caused by the series of three recurrent eruptive solar flares during ～40 h. The characteristics of the geomagnetic crochet, related to a considerable flux of the ionizing electromagnetic radiation during this flare, have been studied. The value and direction of a magnetic field disturbance, registered during the maximum of the geomagnetic storm of September 2, unambiguously indicate that all Russian stations were in the auroral oval zone, which was strongly expanded southward from its average position. The disturbance dependence on the station longitude—the absence of magnetometer pinning in Nerchinsk—is interpreted as the possible manifestation of a strong asymmetry in the effective contour of the current system, which was connected to the heliosphere and covered the disturbed magnetosphere and ionosphere during the short period that lasted only 1–3 h.     

Study of the earthquake of the January 23, 1880, in San Cristóbal,Cuba and the Guane fault

All available data on the January 23, 1880, earthquake near San Cristobal, Western Cuba, are compiled and presented here. The earthquake reached a maximum intensity of eight degrees (MSK) and caused three fatalities. It was accompanied by 65 aftershocks and was felt as far away as the Florida Keys. Twentieth century specialists has associated this event, in its day the strongest recorded (Ms = 6.2) in the region, with the Pinar fault. The Pinar fault is well expressed topographically as the boundary between the Guaniguanico Range in the north and an alluvial plain to the south. Most of the major damage caused by the earthquake was located on the alluvial plain, which in consequence has been considered the epicenter area. In the study presented here, the data compiled from the first reports of Father Benito Vines Martorell, S.J., and Pedro Salteraín y Legarra, indicate that the seismic structure was located in the alluvial plain, and that it was the Guane fault, and not the Pinar fault, that was responsible for the earthquake. The Guane fault, found below the alluvial sediments, extends NE-SW for over 110 km. Its eastern extreme, near San José de las Lajas (La Habana), is linked to another active fault which represents a seismoactive knot responsible for the earthquake of March 9, 1995 (I = 5 degrees, MSK). Seismic events of the Western Cuban region are related to the transpressive interaction of the North American and Caribbean Plates, damped by oceanic structures.     

The discovery of TiO2-Ⅱ,the α-PbO2-structured high-pressure polymorph of rutile,in the Suizhou L6 chondrite

We report the discovery of TiO₂-Ⅱ in the unmelted rock of the shocked Suizhou L6 chondrite.Natural TiO₂-Ⅱ was previously found in ultrahigh-pressure metamorphic and mantle-derived rocks,terrestrial impact structures,and tektite.Our microscopic,Raman spectroscopic,electron microprobe and transmission electron microscopic investigations have revealed:(1) All observed TiO₂-Ⅱ grains are related with ilmenite and pyrophanite;(2) TiO₂-Ⅱ occurs as needle-and ...     

Double-difference Relocation of the Aftershocks of the Tecom��n, Colima, Mexico Earthquake of 22 January 2003

On 22 January 2003, the M _w?=?7.6 Tecomán earthquake struck offshore of the state of Colima, Mexico, near the diffuse triple junction between the Cocos, Rivera, and North American plates. Three-hundred and fifty aftershocks of the Tecomán earthquake with magnitudes between 2.6 and 5.8, each recorded by at least 7 stations, are relocated using the double difference method. Initial locations are determined using P and S readings from the Red Sismológica Telemétrica del Estado de Colima (RESCO) and a 1-D velocity model. Because only eight RESCO stations were operating immediately following the Tecomán earthquake, uncertainties in the initial locations and depths are fairly large, with average uncertainties of 8.0?km in depth and 1.4?km in the north?Csouth and east?Cwest directions. Events occurring between 24 January and 31 January were located using not only RESCO phase readings but also additional P and S readings from 11 temporary stations. Average uncertainties decrease to 0.8?km in depth, 0.3?km in the east?Cwest direction, and 0.7?km in the north?Csouth direction for events occurring while the temporary stations were deployed. While some preliminary studies of the early aftershocks suggested that they were dominated by shallow events above the plate interface, our results place the majority of aftershocks along the plate interface, for a slab dipping between approximately 20° and 30°. This is consistent with the slab positions inferred from geodetic studies. We do see some upper plate aftershocks that may correspond to forearc fault zones, and faults inland in the upper plate, particularly among events occurring more than 3?months after the mainshock.     

Variations of δ~(18)O in precipitation from the Muztagata Glacier, East Pamirs

A primary goal of ice core studies is to reconstruct paleoclimates from information derived from the oxy-gen isotopes records in ice cores. Usually, the δ 18O in precipitation correlates with climatic parameters, such as temperature, precipitation amount, and relative hu-midity of the atmosphere[1-3]. Positive correlations exist between mean annual surface air temperatures and δ 18O in precipitation at mid-high latitudes, namely the “temperature effect”; with higher tem-peratures correspon…     

Origin of the Dashuigou independent tellurium deposit at Qinghai–Xizang Plateau: constraints from the light stable isotopes C,O, and H

By studying the light isotopic compositions of carbon, oxygen, and hydrogen, combined with previous research results on the ore-forming source of the deposit, the authors try to uncover its metallogenic origin. The δ¹⁸O and δ¹³C isotope signatures of dolomite samples vary between 10.2 and 13.0‰, and between-7.2 and-5.2‰, respectively, implying that the carbon derives from the upper mantle. δD and δ¹⁸O of quartz, biotite, and muscovite from different ore veins of ...     

Variation of stress during the rupture process of the 1995 M_L=4.1 Shacheng, Hebei, China, earthquake sequence

Introduction An earthquake could be caused by the failure of focal material or fast slip on the pre-existed faults under the tectonic stress based on the understanding of the occurrence process of earth-quakes in which the stress change could play a key role. Therefore to examine the stress change is beneficial to understanding the physic process actually occurring in the source region deeply. The apparent stress is defined as the product of seismic efficiency and the average stress on the foc…     

Evaluation of models for the origin of Miocene low-δ18O rhyolites of the Yellowstone/Columbia River Large Igneous Province

Two models have been proposed for the origin of the low-δ¹⁸O rhyolites of the Snake River Plain–Yellowstone hotspot trend. The first involves a single multicyclic caldera system, or multiple nested or overlapping systems, in which the early-erupted products become hydrothermally altered and are subsequently melted to form low-δ¹⁸O rhyolites (Bindeman and Valley, 2001; Watts et al., 2011). The second model appeals to a crustal magma source which was hydrothermally altered in a thermal event prior to the onset of Miocene magmatism (Boroughs et al., 2005). We critically evaluate the plausibility of each and provide thermal, temporal, and volume constraints which must be included in any model for the petrogenesis of low-δ¹⁸O rhyolites of the central Snake River Plain. Although the models are not mutually exclusive, we conclude that a component of pre-existing low-δ¹⁸O crust is required in the central Snake River Plain where the greatest volumes of strongly ¹⁸O-depleted rhyolite occur. This component could be provided by meteoric–hydrothermally altered granites of the Idaho batholith, which are cut by the central Snake River Plain.     

Is the invasion of the common reed,Phragmites australis,into tidal marshes of the eastern US an ecological disaster?

Studies of effects of the invasive brackish marsh plant Phragmites australis (common reed) on estuarine biota are reviewed. With few exceptions, most field studies indicate that these P. australis-dominated marshes have diverse and abundant benthic biota, and are utilized by nekton, comparable to Spartina alterniflora marshes. However, larval mummichogs, Fundulus heteroclitus, appear to be reduced in P. australis marshes compared with S. alterniflora marshes. Small epifauna living on plant stems also appear to be denser on S. alterniflora than P. australis stems. Other studies indicate that the detritus produced by decaying P. australis litter provides food value comparable to that of S. alterniflora and that its production enters estuarine food webs. Therefore, the general assumption that these marshes are ecologically "useless" is untrue. This information should be considered by marsh managers when making decisions about restoration projects.     

A GIS-based multi-proxy analysis of the evolution of subglacial dynamics of the Quebec–Labrador ice dome,northeastern Quebec,Canada

The glacial records of the inner-core regions of the Laurentide Ice Sheet (LIS) document complex yet coherent patterns reflecting ice-sheet change (e.g. ice-divide migration), providing unique insights into past glacial conditions. This study develops a conceptual model of subglacial dynamics evolution within a major ice-dispersal centre of the LIS in northeastern Quebec, Canada using a GIS-based analysis of the surficial geologic record. Multiple proxies of subglacial conditions (subglacial streamlined landforms, lake density and lake area over thin drift/bedrock) were analysed through grid-overlay techniques and then classified based on different proxy variables ranging from highly mobile warm-based to immobile cold-based conditions. An additional proxy (till blanket) was used to identify areas of thick till deposition, but with few proxies (few lake or landform metrics). Based on local ice-flow reconstructions, the most ‘relict’ glacial terrain zone (GTZ1) has warm-based conditions over 66% of its area and is remarkably well preserved, suggesting laterally extensive warm-based conditions during the oldest identified ice-flow phase. This relict glacial terrain is partially overprinted by two subsequent ice-flow phases in spatially restricted zones in the northeast (73% warm-based), east-central (41% warm-based), and northwest (33% warm-based) of the study area. A zone of more sluggish conditions (only 3% warm-based) was identified in the highlands at the centre of the study area, characterized by thin till cover, few landforms, yet with large patches of relatively abundant small lakes, indicative of areal scouring. No clear evidence of sustained cold-based conditions (i.e. high chemical index of alteration values or high ¹⁰Be abundances) was found in the study area. These results suggest that warm-based conditions (active erosion and/or deposition) were uniformly widespread during the earliest ice-flow phase, later becoming more spatially restricted with broader sluggish ice conditions. These spatially restricted regions of warm-based subglacial regimes were likely controlled by surrounding and down-flow ice streaming. © 2020 The Authors. Earth Surface Processes and Landforms published by John Wiley & Sons Ltd     

The calculation of TV, VT, VV, VV′ - rate coefficients for the collisions of the main atmospheric components

The first-order perturbation approximation is applied to calculate the rate coefficients of vibrational energy transfer in collisions involving vibrationally excited molecules in the absence of non-adiabatic transitions. The factors of molecular attraction, oscillator frequency change, anharmonicity, 3-dimensionality and quasiclassical motion have been taken into account in the approximation. The analytical expressions presented have been normalized on experimental data of VT-relaxation times in N₂ and O₂ to obtain the steric factors and the extent of repulsive exchange potentials in collisions N₂–N₂ and O₂–O₂. The approach was applied to calculate the rate coefficients of vibrational-vibrational energy transfer in the collisions N₂–N₂, O₂–O₂ and N₂–O₂. It is shown that there is good agreement between our calculations and experimental data for all cases of energy transfer considered.     

Flow Characteristics of Large-Scale Liquefaction-Slip of the Loess Strata in Shibei Tableland, Guyuan City, Induced by the 1920 Haiyuan M8 1/2 Earthquake

Based on the dynamic triaxial liquefaction test of the loess samples which are taken from Shibei tableland, Guyuan City, Ningxia, China, the characteristics of dynamic strain, dynamic stress and pore water pressure are studied under cyclic loading. Triaxial shear test is conducted immediately after the sample reaches liquefaction point. During the test, the property of the liquefied soil is analyzed through fluid mechanics method, whereby the fluidity of the liquefied soil is represented by apparent viscosity.The results show that the fluidity of liquefied loess changes from "shear thickening" to "shear thinning" as the shear force continues, and the fluidity of liquefied loess is closely related to its structure. In addition, in the process of forming a new stable state, the apparent viscosity and deviant stress change with axial strain in a similar approach. When the sample reaches its stable state, it meanwhile shows a relatively stable apparent viscosity. According to the fluid mechanics and the law of conservation of energy, the slip distance of the liquefied soil is estimated, and the results are in good agreement with the field investigation results.