P–T–t evolution of garnet amphibolites in the Wutai–Hengshan area,North China Craton: insights from phase equilibria and geochronology

Garnet amphibolites can provide valuable insights into geological processes of orogenic belts, but their metamorphic evolution is still poorly constrained. Garnet amphibolites from the Wutai–Hengshan area of the North China Craton mainly consist of garnet, hornblende, plagioclase, quartz, rutile and ilmenite, with or without titanite and epidote. Four samples selected in a south–north profile were studied by the pseudosection approach in order to elucidate the characteristics of their metamorphic evolution, and to better reveal the northwards prograde change in P–T conditions as established previously. For the sample from the lower Wutai Subgroup, garnet exhibits obvious two‐substage growth zoning characteristic of pyrope (X_py) increasing but grossular (X_gr) decreasing outwards in the core, and both X_py and X_gr increasing outwards in the rim. Phase modelling using thermocalc suggests that the garnet cores were formed by chlorite breakdown over 7–9 kbar at 530–600 °C, and rims grew from hornblende and epidote breakdown over 9.5–11.5 kbar at 600–670 °C. The isopleths of the minimum An in plagioclase and maximum X_py in garnet were used to constrain the peak P–T conditions of ~11.5 kbar/670 °C. The modelled peak assemblage garnet + hornblende + epidote+ plagioclase + rutile + quartz matches well the observed one. Plagioclase–hornblende coronae around garnet indicate post‐peak decompression and fluid ingress. For the samples from the south Hengshan Complex, the garnet zoning weaken gradually, reflecting modifications during decompression of the rocks. Using the same approach, the rocks are inferred to have suprasolidus peak conditions, increasing northwards from 11.5 kbar/745 °C, 12.5 kbar/780 °C to 13 kbar/800 °C. Their modelled peak assemblages involve diopside, garnet, hornblende, plagioclase, rutile and quartz, yet diopside is not observed petrographically. The post‐peak decompression is characterized by diopside + garnet + quartz + melt = hornblende + plagioclase, causing the diopside consumption and garnet compositions to be largely modified. Thus, the pesudosection approach is expected to provide better pressure results than conventional thermobarometry, because the later approach cannot be applied with confidence to rocks with multi‐generation assemblages. U–Pb dating of zircon in the Wutai sample records a protolith age of c. 2.50 Ga, and a metamorphic age of c. 1.95 Ga, while zircon in the Hengshan samples records metamorphic ages of c. 1.92 Ga. The c. 1.95 Ga is interpreted to represent the pre‐peak or peak metamorphic stages, and the ages of c. 1.92 Ga are assigned to represent the cooling stages. All rocks in the Wutai–Hengshan area share similar clockwise P–T morphologies. They may represent metamorphic products at different crustal depths in one orogenic event, which included a main thickening stage at c. 1.95 Ga followed by a prolonged uplift and cooling after 1.92 Ga.     

青海卡巴纽尔多地区中-晚三叠世火山岩地球化学特征及构造环境

青海卡巴纽尔多地区位于华南板块可可西里-松潘甘孜残留洋。该区发育有中-晚三叠世火山岩,呈夹层状产于中三叠统甘德组及上三叠统清水河组。甘德组火山岩为晶屑凝灰岩,其SiO2=46.78%~47.05%,总碱含量ALK为2.38%~2.94%,铝饱和指数A/NK为2.81,山德指数A/CNK=0.66~0.79,里特曼指数σ=1.4~2.3,为亚碱性岩石,属拉斑玄武系列;稀土总量REE在102.84×10-6~179.06×10-6,LREE/HREE比值为4.44~7.07,δEu=0.65~1.01,稀土配分曲线呈向右陡倾型。清水河组火山岩为流纹岩,SiO2含量为74.04%,总碱含量Alk为7.43%,A/NK为1.47,A/CNK=1.31,σ=1.78,为亚碱性岩石,属钙碱性系列;稀土总量REE为26.18×10-6,LREE/HREE比值为5.4,δEu=0.28,具明显铕负异常,稀土配分曲线呈海鸥型。区内火山岩均富集大离子亲石元素,亏损高场强元素,为典型的岛弧火山岩特征。利用里特曼-戈蒂里图解、Ti-Zr图解等判别图解,并结合甘德组与清水河组均为巴颜喀拉边缘前陆盆地的沉积背景,认为该区中-晚三叠世火山岩形成于岛弧环境。     

Late Pliocene–recent tectonic setting for the Tianchi volcanic zone, Changbai Mountains, northeast China

Mafic volcanic rocks have erupted in the Tianchi volcanic zone, Changbai Mountains, northeast China, since late Pliocene time. The zone formed in an extensional environment during early-middle Cenozoic time, and in a compressional environment during late Cenozoic. Crustal thickness (about 40 km) in the Changbai Mountains is larger than the regional average of 34–36 km to the northwest and southeast. The conduit for magma upwelling was not coincident with the NE-striking regional faults, but seem to be confined to a deep-seated NW–WNW-striking fault zone. Since the late Pliocene, the Tianchi volcanic zone was subjected to crustal uplift within an intracontinental, weakly compressional environment (with minor WNW–ESE shearing) related to the westward subduction of the West Pacific plate. The nature of this volcanism is not typical of active, subduction-related continental margin volcanism. The magmatic evolutionary process evolved from trachybasalt through basaltic trachyandesite, trachyte, and pantellerite.     

Geochemistry of Permian Mafic Igneous Rocks from the Napo‐Qinzhou Tectonic Belt in Southwest Guangxi,Southwest China: Implications for Arc‐Back Arc Basin Magmatic Evolution

The Napo-Qinzhou Tectonic Belt (NQTB) lies at the junction of the Yangtze, Cathaysia and Indochina (North Vietnam) Blocks, which is composed of five major lithotectonic subunits: the Qinzhou-Fangcheng Suture Zone (QFSZ), the Shiwandashan Basin (SB), the Pingxiang-Nanning Suture Zone (PNSZ), the Damingshan Block (DB) and the Babu-Lingma Suture Zone (BLSZ). On the basis of geochemical compositions, the Permian mafic igneous rocks can be divided into three distinct groups: (1) mafic igneous rocks (Group 1) from the Longjing region in the PNSZ and Hurun region in the BLSZ, which are characterized by intermediate Ti, P and Zr with low Ni and Cr contents; (2) mafic igneous rocks (Group 2) from the Naxiao and Chongzuo region in the DB, characterized by low-intermediate Ti, P and Zr with high Ni and Cr concentrations; and (3) mafic igneous rocks (Group 3) from the Siming region in the Jingxi carbonate platform of the northwestern margin of the NQTB, with intermediate-high Ti, P and Zr and low Ni and Cr contents. The Group 1 rocks yield a weighted mean 206Pb/238U age of 250.5±2.8 Ma and are geochemically similar to basalts occurring in back-arc basin settings. The Group 2 rocks exhibit geochemical features to those basalts in island arcs, whereas the Group 3 rocks show geochemical similarity to that of ocean island basalts. All three groups are characterized by relatively low εNd(t) values (–2.61 to +1.10) and high initial 87Sr/86Sr isotopic ratios (0.705309–0.707434), indicating that they were derived from a subduction-modified lithospheric mantle and experienced assimilation, fractional crystallization, and crustal contamination or mixing during magmatic evolution. Accordingly, we propose the existence of an arc-back arc basin system that developed along the NQTB at the border of SW Guangxi Province (SW China) and northern Vietnam, and it was formed by continued northwestward subduction of the Cathaysian (or Yunkai) Block under the Yangtze Block, and northeastward subduction of the Indochina Block beneath the Yangtze Block during Permian time.     

Carboniferous eclogite and garnet–omphacite granulite from northeastern Hainan Island,South China: Implications for the evolution of the eastern Palaeo‐Tethys

High‐P (HP) eclogite and associated garnet–omphacite granulite have recently been discovered in the Mulantou area, northeastern Hainan Island, South China. These rocks consist mainly of garnet, omphacite, hornblende, quartz and rutile/ilmenite, with or without zoisite and plagioclase. Textural relationships, mineral compositions and thermobarometric calculations demonstrate that the eclogite and garnet–omphacite granulite share the same three‐stage metamorphic evolution, with prograde, peak and retrograde P?T conditions of 620–680°C and 8.7–11.1 kbar, 820–860°C and 17.0–18.2 kbar, and 700–730°C and 7.1–8.5 kbar respectively. Sensitive high‐resolution ion microprobe U–Pb zircon dating, coupled with the identification of mineral inclusions in zircon, reveals the formation of mafic protoliths before 355 Ma, prograde metamorphism at c. 340–330 Ma, peak to retrograde metamorphism at c. 310–300 Ma, and subsequent pegmatite intrusion at 295 Ma. Trace element geochemistry shows that most of the rocks have a MORB affinity, with initial ε_Nd values of +2.4 to +6.7. As with similar transitional eclogite–HP granulite facies rocks in the thickened root in the European Variscan orogen, the occurrence of relatively high P?T metamorphic rocks of oceanic origin in northeastern Hainan Island suggests Carboniferous oceanic subduction leading to collision of the Hainan continental block, or at least part of it, with the South China Block in the eastern Palaeo‐Tethyan tectonic domain.     

Mesoproterozoic–Neoproterozoic transition: Geochemistry, provenance and tectonic setting of clastic sedimentary rocks on the SE margin of the Yangtze Block, South China

The SE margin of the Yangtze Block, South China is composed of the Mesoproterozoic Lengjiaxi Group and the Neoproterozoic Banxi Group, with Sinian- and post-Sinian-cover. A geochemical study was undertaken on the Mesoproterozoic–Neoproterozoic clastic sediments in order to delineate the characteristics of the sediment source and to constrain the tectonic development and crustal evolution of South China.Our results show that the Mesoproterozoic clastic sediments have a dominant component derived from a metavolcanic-plutonic terrane, with a large of mafic component. There is a minor contribution of mafic rocks and older upper crustal rocks to the provenance. Strong chemical weathering in the source area occurred before transport and deposition. The provenance for the Neoproterozoic clastic sediments was most likely old upper continental crust composed of tonalite–granodiorite-dominated, tonalite–granodiorite–granite source rocks, which had undergone strong weathering and/or recycling. A minor component of older K-rich granitic plutonic rocks and younger volcanogenic bimodal rocks is also indicated.Based on the regional geology, the geochemical data and the inferred provenance, the Mesoproterozoic Group is interpreted as a successive sedimentary sequence, deposited in an extensional/rifting back-arc basin, adjacent to a >1.80 Ga continental margin arc-terrane. The progressive extension/rifting of the back-arc basin was followed by increasing subsidence and regional uplift during continental marginal arc-continent (the Cathaysian Block) collision at 1.0 Ga caused the deposition of the Neoproterozoic Group into back-arc to retro-arc foreland basin. Therefore, the depositional setting of the Proterozoic clastic sediments and associated volcanic rocks within the back-arc basin reflected basin development from an active continental margin (back-arc basin), with extension or rifting of the back-arc basin, to a passive continental margin.     

A paired metamorphic belt in a subduction‐to‐collision orogen: An example from the South Qilian–North Qaidam orogenic belt,NW China

The early Palaeozoic South Qilian–North Qaidam orogenic belt in northwestern China records a nearly complete history of early‐stage long‐lived oceanic subduction–accretion followed by late‐stage continental collision. Most previous studies have focused on low dT/dP metamorphism (HP–UHP) in this belt whereas the paired high dT/dP belt in the hinterland has received little attention. In this contribution, phase equilibrium modelling is combined with zircon petrochronology to determine the P–T–t evolution of granulites in the North Wulan gneiss complex in the high dT/dP hinterland of the South Qilian–North Qaidam orogen. Granulites record a clockwise P–T path with near‐peak temperatures of ~800–900°C at 5.5–7 kbar. Peak metamorphism was followed by high‐T decompression. Zircon petrochronology reveals protracted zircon growth from c. 474 to 446 Ma during the high‐T portion of the P–T path. High dT/dP metamorphism in the North Wulan gneiss complex was likely the result of heat transfer from the underlying hot asthenosphere and minor coeval magmatism in an arc–back‐arc system during slab retreat and roll‐back of the South Qilian oceanic plate. Broadly contemporaneous but slightly younger HP–UHP metamorphism in the foreland of the South Qilian–North Qaidam orogenic belt indicates that the region records an early Palaeozoic paired metamorphic belt. This early Palaeozoic paired metamorphic belt provides a detailed example of dual thermal regimes in a modern‐style orogenic system that can be applied to understanding the time‐scales and P–T conditions of high dT/dP metamorphism that accompany subduction in Phanerozoic and Precambrian orogenic belts.     

Petrography, geochemistry, and geochronology of granitoid rocks in the Neoproterozoic-Paleozoic Lufilian–Zambezi belt, Zambia: Implications for tectonic setting and regional correlation

There are several pre-orogenic Neoproterozoic granitoid and metavolcanic rocks in the Lufilian–Zambezi belt in Zambia and Zimbabwe that are interpreted to have been emplaced in a continental-rift setting that is linked to the break-up of the Rodinia supercontinent. However, no geochemical data were previously available for these rocks in the Zambian part of the belt to support this model. We conducted petrographic and whole-rock chemical analyses of the Neoproterozoic Nchanga Granite, Lusaka Granite, Ngoma Gneiss and felsic metavolcanic rocks from the Lufilian–Zambezi belt in Zambian, in order to evaluate their chemical characteristics and tectonic settings. Other magmatic rocks of importance for understanding the evolution of the belt in Zambia, included in this study, are the Mesoproterozoic Munali Hills Granite and associated amphibolites and the Mpande Gneiss. The Neoproterozoic rocks have monzogranitic compositions, aluminum-saturation indices (ASI) < 1.1, and high contents of high field strength elements (HFSE) and rare earth elements (REE). The chondrite-normalised spider diagrams are similar to those of A-type granites from the Lachlan fold belt and show negative Sr, P, and Ti anomalies. On various tectonic discrimination diagrams the Neoproterozoic rocks plot mainly in A-type granite fields. These petrographic and trace element compositions indicate that these rocks are A-type felsic rocks, but they do not have features of granites and rhyolites emplaced in true continental-rift settings, as previously suggested. On the basis of the A-type features and independent regional geological and geochronological data, we suggest that the Neoproterozoic granitoid and felsic metavolcanic rocks were emplaced during the earliest extensional stages of continental rifting in the Lufilian–Zambezi belt. The apparent continental-arc like chemistry of the granitoid and felsic metavolcanic rocks is thus inferred to be inherited from calcalkaline sources. The Mesoproterozoic Munali Hills Granite and Mpande Gneiss have trace element features e.g., Nb–Ta depletions, which indicate that that these gneisses were emplaced in a convergent-margin setting. The MORB-normalised spider diagram of co-magmatic amphibolites exhibit a fractionated LILE/HFSE pattern recognized in subduction zones. This inference is consistent with remnants of ocean crust, juvenile Island arcs and ophiolites elsewhere in the Mesoproterozoic Irumide belt in Zambia and Zimbabwe. In addition, we report the first U–Pb zircon age of 1090.1 ± 1.3 Ma for the Munali Hills Granite. The age for the Munali Hills Granite provides new constraints on correlation and tectono-thermal activity in the Lufilian–Zambezi belt. The age of the Munali Hills Granite indicates that some supracrustal rocks in the Zambezi belt of Zambia, which were previously thought to be Neoproterozoic and correlated with the Katanga Supergroup in the Lufilian belt, are Mesoproterozoic or older. Consequently, previous regional lithostratigraphic correlations in the Lufilian–Zambezi belt would require revision.     

Genesis of the Weiquan Ag–Polymetallic Deposit in East Tianshan, China: Evidence from Zircon U–Pb Geochronology and C–H–O–S–Pb Isotope Systematics

The Weiquan Ag-polymetallic deposit is located on the southern margin of the Central Asian Orogenic Belt and in the western segment of the Aqishan-Yamansu arc belt in East Tianshan,northwestern China. Its orebodies, controlled by faults, occur in the lower Carboniferous volcanosedimentary rocks of the Yamansu Formation as irregular veins and lenses. Four stages of mineralization have been recognized on the basis of mineral assemblages, ore fabrics, and crosscutting relationships among the ore veins. Stage I is the skarn stage(garnet + pyroxene), Stage Ⅱ is the retrograde alteration stage(epidote + chlorite + magnetite ± hematite 士 actinolite ± quartz),Stage Ⅲ is the sulfide stage(Ag and Bi minerals + pyrite + chalcopyrite + galena + sphalerite + quartz ± calcite ± tetrahedrite),and Stage IV is the carbonate stage(quartz + calcite ± pyrite). Skarnization,silicification, carbonatization,epidotization,chloritization, sericitization, and actinolitization are the principal types of hydrothermal alteration. LAICP-MS U-Pb dating yielded ages of 326.5±4.5 and 298.5±1.5 Ma for zircons from the tuff and diorite porphyry, respectively. Given that the tuff is wall rock and that the orebodies are cut by a late diorite porphyry dike, the ages of the tuff and the diorite porphyry provide lower and upper time limits on the age of ore formation. The δ~(13)C values of the calcite samples range from-2.5‰ to 2.3‰, the δ~(18)O_(H2 O) and δD_(VSMOW) values of the sulfide stage(Stage Ⅲ) vary from 1.1‰ to 5.2‰ and-111.7‰ to-66.1‰, respectively,and the δ~(13)C, δ~(18)O_(H2 O) and δD_(V-SMOW) values of calcite in one Stage IV sample are 1.5‰,-0.3‰, and-115.6‰, respectively. Carbon, hydrogen, and oxygen isotopic compositions indicate that the ore-forming fluids evolved gradually from magmatic to meteoric sources. The δ~(34)S_(V-CDT) values of the sulfides have a large range from-6.9‰ to 1.4‰, with an average of-2.2‰, indicating a magmatic source, possibly with sedimentary contributions. The ~(206)Pb/~(204)Pb, ~(207)Pb/~(204)Pb, and ~(208)Pb/~(204)Pb ratios of the sulfides are 17.9848-18.2785,15.5188-15.6536, and 37.8125-38.4650, respectively, and one whole-rock sample at Weiquan yields~(206)Pb/~(204)Pb,~(207)Pb/~(204)Pb, and ~(208)Pb/~(204)Pb ratios of 18.2060, 15.5674, and 38.0511,respectively. Lead isotopic systems suggest that the ore-forming materials of the Weiquan deposit were derived from a mixed source involving mantle and crustal components. Based on geological features, zircon U-Pb dating, and C-H-OS-Pb isotopic data, it can be concluded that the Weiquan polymetallic deposit is a skarn type that formed in a tectonic setting spanning a period from subduction to post-collision. The ore materials were sourced from magmatic ore-forming fluids that mixed with components derived from host rocks during their ascent, and a gradual mixing with meteoric water took place in the later stages.     

Geochemistry,zircon U–Pb and molybdenite Re–Os dating of the Taolaituo porphyry Mo deposit in the Central Great Hinggan Range: implications for the geodynamic evolution of northeastern China

The Taolaituo porphyry‐type molybdenum deposit is located in the eastern Inner Mongolia Autonomous Region in China. The mineralization occurs mainly as veins, lenses and layers within the host porphyry. To better understand the link between the mineralization and the host igneous rocks, we studied samples from the underground workings and report new SHRIMP II zircon U–Pb and Re–Os molybdenite ages, and geochemical data from both the molybdenites and the porphyry granites. Five molybdenite samples yield a Re–Os isochron weighted mean age of 133.0 ± 0.82 Ma, whereas the porphyry granitoids samples yield crystallization ages of 133 ± 1 Ma and 130.4 ± 1.3 Ma. The U–Pb and Re–Os ages are similar, suggesting that the mineralization is genetically related to the Early Cretaceous porphyry emplacement. Re contents of the molybdenites range from 21.74 to 42.45 ppm, with an average of 32.69 ppm, whereas δ³⁴S values vary between 3.7‰ and 4.2‰, which is typical of mantle sulphur. The ²⁰⁶Pb/²⁰⁴Pb, ²⁰⁷Pb/ ²⁰⁴Pb and ²⁰⁸Pb/²⁰⁴Pb vary in the ranges of 18.276–18.385, 15.566–15.580 and 38.321–38.382, respectively. The Taolaituo Early Cretaceous granitoids are A‐type granites. These observations indicate that the molybdenites and the porphyry granites were derived from a mixed source involving young accretionary materials and enriched subcontinental lithospheric mantle. A synthesis of geochronological and geological data reveals that porphyry emplacement and Mo mineralization in the Taolaituo deposit occurred contemporaneously with the Early Cretaceous tectonothermal events associated with lithospheric thinning, which was caused by delamination and subsequent upwelling of the asthenosphere associated with intra‐continental extension in northeast China. Copyright © 2015 John Wiley & Sons, Ltd.     

Age and provenance of the Ergunahe Group and the Wubinaobao Formation,northeastern Inner Mongolia,NE China: implications for tectonic setting of the Erguna Massif

Here, we present the results of U–Pb dating of detrital zircons from the Ergunahe Group and the Wubinaobao Formation, within northeastern Inner Mongolia, NE China, with the aim of constraining the tectonic setting of the Erguna Massif. The majority of detrital zircons from five samples collected from the Ergunahe Group and the Wubinaobao Formation are magmatic, although some zircons have metamorphic growth rims. Zircons in two mica schists and in feldspar–quartz sandstone from the Ergunahe Group yield age populations that cluster around 738, 760, 792, 837, 890, 964, and 1050 Ma, whereas zircons from two quartz sandstones within the Wubinaobao Formation yield age populations that cluster at 466, 484, 515, 738, 795, 837, and 894 Ma. These data, combined with detrital zircon age populations (ca. 712 Ma) from the adjacent Xinghuadukou Group, and the fact that the Ergunahe Group intruded by Caledonian gabbros is overlain by upper Silurian units, indicate that the Ergunahe Group formed at 738–712 Ma (i.e. during the Neoproterozoic). In addition, the Wubinaobao Formation is subdivided into two units: a calcareous siltstone unit within the western part of the study area and a quartz sandstone within the eastern part. The calcareous siltstone formed at 712–795 Ma, similar to the Ergunahe Group, whereas the quartz sandstone formed between the 466 Ma and late Silurian. The age spectra of detrital zircons from the Ergunahe Group and the Wubinaobao Formation indicate that sediment in both of these units was derived from terranes that outcrop around the basin. The widespread occurrence of Neoproterozoic detrital zircons within both the Ergunahe Group and the Wubinaobao Formation suggests that Precambrian terranes are present within the Erguna Massif and that the massif has an affinity to the Siberian Craton.     

Genesis of Pb–Zn Mineralization Beneath the Xiangshan Uranium Orefield,South China: Constraints from H–O–S–Pb Isotopes and Rb–Sr Dating

The volcanic‐hosted Xiangshan uranium orefield is the largest uranium deposit in South China. Recent exploration has discovered extensive Pb–Zn mineralization beneath the uranium orebodies. Detailed geological investigation reveals that the major metallic minerals include pyrite, sphalerite, galena, and chalcopyrite, whilst the major non‐metallic minerals include quartz, sericite, and calcite. New δ¹⁸O_fluid and δD_fluid data indicate that the ore‐forming fluids were mainly derived from magmatic, and the sulfide δ³⁴S values (2.2–6.9‰) suggest a dominantly magmatic sulfur source. The Pb isotope compositions are homogeneous (²⁰⁶Pb/²⁰⁴Pb = 18.120–18.233, ²⁰⁷Pb/²⁰⁴Pb = 15.575–15.698, and ²⁰⁸Pb/²⁰⁴Pb = 37.047–38.446). The ⁸⁷Sr/⁸⁶Sr ratios of sulfide minerals range from 0.7197 to 0.7204, which is much higher than volcanic rocks and fall into the range of metamorphic basement. Lead and strontium isotopic compositions indicate that the metallogenic materials probably were derived from metamorphic basement. Pyrite Rb–Sr dating of the ores yielded 131.3 ± 4.0 Ma, indicating that the Pb–Zn mineralization occurred in the Early Cretaceous.     

Apatite fission track thermochronology of the Precambrian Aksu blueschist, NW China: Implications for thermo–tectonic evolution of the north Tarim basement

The Precambrian Aksu blueschist is located in the northwestern margin of the Tarim Block, NW China. In recent decades, many studies were carried out with focus on the metamorphic age. However, a complete understanding of the evolution of the Tarim Block requires the cooling history of the Precambrian metamorphic rocks and the time–temperature paths as determined by low-temperature thermochronometry. Therefore, apatite fission track (AFT) technique was applied on the Precambrian Aksu blueschist to reveal the thermo–tectonic evolution of the north Tarim basement. All of the six blueschist samples analysed in this study yielded AFT ages spanning 107.5–62.5 Ma, much younger than the blueschist facies metamorphic age of Neoproterozoic, and confined track lengths are between 10.46 and 12.12 µm. Based on regional stratigraphic sequences, the AFT thermal history modeling as well as previous chronological results, the thermo–tectonic evolution of the Aksu blueschist can be roughly reconstructed with four stages: (1) the Precambrain Aksu blueschist exhumed to the surface soon after its formation. Erosion during the Early Sinian is indicated by the lack of sedimentation until the Late Sinian; (2) the Late Sinian strata are continuous, while the Middle–Upper Silurian and the Lower–Middle Carboniferous strata are absent. The total thickness of the Late Sinian and Paleozoic strata probably reached 10,000 m and resulted in the total annealing and thermal resetting of AFT ages; (3) the AFT ages in the Cretaceous are related with the widespread uplift in Tian Shan and its adjacent regions that restarted the AFT clock during the Late Mesozoic. These reflect a distant effect of the collision of the Lhasa terrane with Eurasia in the Late Jurassic–Early Cretaceous; and (4) sediments of Cenozoic are documented in the Aksu area. The Aksu blueschist was heated to partial annealing zone with the overlying Cenozoic sediments. During Miocene time, the Aksu blueschist was re-exhumed which was probably a distant response to the ongoing India–Eurasia convergence.     

Geochronology and Sr–Nd–Hf isotopes of the Mesozoic granitoids from the Great Xing'an and Lesser Xing'an ranges: implications for petrogenesis and tectonic evolution in NE China

The Great Xing′an and Lesser Xing′an ranges are characterized by immense volumes of Mesozoic granitoids. In this study, we present major and trace element geochemistry, U–Pb geochronology and systematic Sr–Nd–Hf isotopes for the representative samples, in order to constrain their petrogenesis and the tectonic evolution in NE China. The granitoids generally have high SiO₂ (66.5–78.8 wt.%) and Na₂O + K₂O (7.0–8.9 wt.%) contents and belong to high‐K calc‐alkaline to shoshonitic series. All of them show enrichment in Rb, Th, U, Pb and light rare earth elements (LREE), and depletion in Nb, Ta, P and Ti. Zircon U–Pb dating suggests that there was continuous magmatism in both the Great Xing′an Range and the Lesser Xing′an Range during the Jurassic–Early Cretaceous interval. Seven Jurassic granitoids have (⁸⁷Sr/⁸⁶Sr)_i values of 0.704351 to 0.707374, with ϵ_Nd(t) values of −3.4 to 2.4 and ϵ_Hf(t) values of 0.8 to 11.3, indicating that they originated from mixed sources involving depleted mantle and pre‐existing crustal components. One Early Cretaceous sample yields (⁸⁷Sr/⁸⁶Sr)_i value of 0.706184, ϵ_Nd(t) value of 0.6, and ϵ_Hf(t) values of 7.0 to 8.2, which is in accordance with previous studies and indicates a major juvenile mantle source for the granitoids in this period. In the Jurassic, the magmatism in the Great Xing′an Range was induced by the subduction of the Mongol–Okhotsk Ocean, while the contemporaneous magmatism in the Lesser Xing′an Range was related to the subduction of the Palaeo‐Pacific Ocean. In the Early Cretaceous, extensive magmatism in NE China was probably attributed to large‐scale lithospheric delamination. Copyright © 2014 John Wiley & Sons, Ltd.     

Taxonomy and biogenicity of Archaean spheroidal microfossils (ca. 3.0 Ga) from the Mount Goldsworthy–Mount Grant area in the northeastern Pilbara Craton, Western Australia

Microstructures recently reported from an Archaean sedimentary succession (ca. 3.0 Ga) in the Mount Goldsworthy–Mount Grant area in the northeastern Pilbara Craton meet the criteria for compelling evidence of biogenicity [Sugitani, K., Grey, K., Allwood, A., Nagaoka, T., Mimura, K., Minami, M., Marshall, C.P., Van Kranendonk, M.J., Walter, M.R., 2007. Diverse microstructures from Archaean chert from the Mount Goldsworthy–Mount Grant area, Pilbara Craton, Western Australia: microfossils, dubiofossil, or pseudofossils. Precambrian Res. 158, 228–262]. The structures are morphologically diverse. Although they were tentatively classified into five major morphological types (thread-like, film-like, small (<15 μm) and large (>15 μm) spheroidal, and spindle-like), the possible taxonomic significance of these groups was not discussed. Building on our earlier analysis, we focus on the morphology of the larger spheroids, as well as presenting further evidence relating spindles and several bizarre forms, and attempt to group them taxonomically and adduce additional evidence for their biogenicity.Taphonomic features were identified in each of the various morphological groups, but the range of morphological diversity of the spheroids cannot be attributed solely to taphonomic alteration. Four subdivisions of spheroids are proposed: (1) simple single-walled spheroids, (2) thin-walled spheroids having a diffuse envelope, (3) thick-walled spheroids, and (4) spheroids having an extensively folded wall. Simple single-walled spheroids, 15–60 μm in diameter, with various wall textures but commonly lacking envelopes or appendages form the dominant subgroup. Other complex morphologies are present and include aligned or associated bodies of thin-walled spheroids with diffuse envelopes, and spindle-like structures containing inner spheroidal bodies. The degree of morphological complexity and associations between structures suggest the presence of reproductive phases. If correct, this implies that the early Earth (ca. 3.0 Ga) showed a higher level of biodiversity than is currently postulated.     

Geochemistry and Nd–Sr isotopic studies of Late Mesozoic granitoids in the southeastern Hubei Province, Middle–Lower Yangtze River belt, Eastern China: Petrogenesis and tectonic setting

A geochemical and isotopic study was carried out for the Mesozoic Yangxin, Tieshan and Echeng granitoid batholiths in the southeastern Hubei Province, eastern China, in order to constrain their petrogenesis and tectonic setting. These granitoids dominantly consist of quartz diorite, monzonite and granite. They are characterized by SiO₂ and Na₂O compositions of between 54.6 and 76.6 wt.%, and 2.9 to 5.6 wt.%, respectively, enrichment in light rare earth elements (LREE) and large ion lithophile elements (LILE), and relative depletion in Y (concentrations ranging from 5.17 to 29.3 ppm) and Yb (0.34–2.83 ppm), with the majority of the granitoids being geochemically similar to high-SiO₂ adakites (HSA). Their initial Nd (ε_Nd = − 12.5 to − 6.1) and Sr ((⁸⁷Sr/⁸⁶Sr)_i = 0.7054–0.7085) isotopic compositions, however, distinguish them from adakites produced by partial melting of subducted slab and those produced by partial melting of the lower crust of the Yangtze Craton in the Late Mesozoic. The granitoid batholiths in the southeastern Hubei Province exhibit very low MgO ranging from 0.09 to 2.19 wt.% with an average of 0.96 wt.%, and large variations in negative to positive Eu anomalies (Eu/Eu = 0.22–1.4), especially the Tieshan granites and Yangxin granite porphyry (Eu/Eu = 0.22–0.73). Geochemical and Nd–Sr isotopic data demonstrate that these granitoids originated as partial melts of an enriched mantle source that experienced significant contamination of lower crust materials and fractional crystallization during magma ascent. Late Mesozoic granitoids in the southeastern Hubei Province of the Middle–Lower Yangtze River belt were dominantly emplaced in an extensional tectonic regime, in response to basaltic underplating, which was followed by lithospheric thinning during the early Cretaceous.     

广东洽水地区花岗岩体LA-ICP-MS锆石U-Pb年代:对华南内陆~100Ma构造环境的制约

【研究目的】东南沿海地区发育大量~100Ma的岩浆岩,在华南内陆该期岩浆作用虽报道较少但往往与成矿有关。查明该期岩浆作用在华南内陆的分布,将为该区晚燕山期构造背景的研究及相关找矿勘查提供科学依据。【研究方法】基于1︰5万区域地质调查和详细的岩相学研究,对位于华南内陆的郴州—临武断裂附近的洽水地区花岗岩,划分为5个侵入次：（1）粗—中粒斑状含角闪石黑云母二长花岗岩;（2）中—细粒斑状含角闪石黑云母二长花岗岩;（3）中—细粒斑状黑云母二长花岗岩;（4）中—细粒含斑黑云母二长花岗岩;（5）细粒含斑黑云母正长花岗岩。然后系统地对不同侵入次的代表性岩石进行锆石LA-ICP-MS U-Pb定年。【研究结果】获得第一到第五侵入次的年龄为102～97Ma,均属早—晚白垩世之交（~100Ma）侵入岩。【结论】综合分析对比华南内陆及东南沿海地区~100Ma的岩浆事件,认为华南内陆该期岩浆活动的动力学机制是：古太平洋板块俯冲后撤引发的弧后及陆内岩石圈伸展,导致郴州—临武等古深大断裂重新活化拉张,引起软流圈上涌和岩石圈减薄,进而产生较强烈的幔源和壳源岩浆活动。     

Lithogeochemical,Re–Os and U–Pb Geochronological,Hf–Lu and S–Pb Isotope Data of the Ga'erqiong‐Galale Cu–Au Ore‐Concentrated Area: Evidence for the Late Cretaceous Magmatism and Metallogenic Event in the Bangong‐Nujiang Suture Zone,Northwestern Tibet,China

The Ga'erqiong‐Galale skarn–porphyry copper–gold ore‐concentrated area is located in the western part of the Bangong‐Nujiang suture zone north of the Lhasa Terrane. This paper conducted a systematic study on the magmatism and metallogenic effect in the ore‐concentrated area using techniques of isotopic geochronology, isotopic geochemistry and lithogeochemistry. According to the results, the crystallization age of quartz diorite (ore‐forming mother rock) in the Ga'erqiong deposit is 87.1 ± 0.4 Ma, which is later than the age of granodiorite (ore‐forming mother rock) in the Galale deposit (88.1 ± 1.0 Ma). The crystallization age of granite porphyry (GE granite porphyry) in the Ga'erqiong deposit is 83.2 ± 0.7 Ma, which is later than the age of granite porphyry (GL granite porphyry) in the Galale deposit (84.7 ± 0.8 Ma).The quartz diorite, granodiorite, GE granite porphyry and GL granite porphyry both main shows positive ε_Hf(t) values, suggesting that the magmatic source of the main intrusions in the ore‐concentrated area has the characteristics of mantle source region. The Re–Os isochron age of molybdenite in the Ga'erqiong district is 86.9 ± 0.5 Ma, which is later than the mineralization age of the Galale district (88.6 ± 0.6 Ma). The main intrusive rocks in the ore‐concentrated area have similar lithogeochemical characteristics, for they both show the relative enrichment in large‐ion lithophile elements(LILE: Rb, Ba, K, etc.), more mobile highly incompatible lithophile elements(HILE: U, Th) and relatively depleted in high field strength elements (HFSE: Nb, Ta, Zr, Hf, etc.), and show the characteristics of magmatic arc. The studies on the metal sulfides' S and Pb isotopes and Re content of molybdenite indicate that the metallogenic materials of the deposits in the ore‐concentrated area mainly come from the mantle source with minor crustal source contamination. Based on the regional tectonic evolution process, this paper points out that the Ga'erqiong‐Galale copper–gold ore‐concentrated area is the typical product of the Late Cretaceous magmatism and metallogenic event in the collision stage of the Bangong‐Nujiang suture zone.     

The Late Triassic I–Type Granites from the Longmu Co–Shuanghu Suture Zone in the interior of Tibetan Plateau, China: Petrogenesis and Implication for Slab Break–Off

The Jiangaidarina granitic mass(JM) is an important part of the magmatic belt in Longmu CoShuanghu Suture Zone(LSSZ) in the central Tibetan Plateau. An integrated research involving wholerock geochemistry, zircon LA-ICP-MS U-Pb ages and Hf isotopic compositions was carried out to define the timing, genesis and tectonic setting of the JM. Zircon LA-ICP-MS U-Pb ages have been obtained ranging from 210 to 215 Ma, rather than the Early Jurassic as previously thought. Fifteen granite samples contain hornblendes and show a negative correlation between P_2 O_5 and SiO_2, indicating that the JM is an I-type granite. All the granites are enriched in LREE relative to HREE, with negative Eu anomalies(Eu/Eu*=0.56-0.81), and have similar trace elements patterns, with depletion of Ba, Nb, Sr and P. These suggest that the JM was fractionated, and this is also proved by the characteristic of negative correlations between oxide elements(TiO_2, MgO, FeOt, MnO, CaO) and SiO_2. Almost all ε_(Hf)(t) values of the granites are between-10.3 and-5.8, implying that the JM has a crustal source intimately related with the South Qiangtang Block(SQB), except for one(+10.2), showing a minor contribution from mantle source.Moreover, relatively low Na_2 O/K_2 O ratios(0.42-0.93) and high A/CNK values(0.91-1.50) reflect that the JM was predominately derived from the medium-high potassium basaltic crust, interacted with greywacke. Our new geochemical data and geochronological results imply that the Late Triassic magmas were generated in a post-collisional tectonic setting, probably caused by slab break-off of the Longmu Co-Shuanghu Tethyan Ocean(LSTO). This mechanism caused the asthenosphere upwelling, formed extension setting, offered an enormous amount of heat, and provided favorable conditions for emplacement of voluminous felsic magmas. Furthermore, the LSTO could be completely closed during the Middle Triassic, succeed by continental collision and later the slab broke off in the Late Triassic.