海洋沉积物甲烷厌氧氧化作用(AOM)及其对无机硫循环的影响

甲烷厌氧氧化作用(AOM)在调控全球甲烷收支平衡以及缓解因甲烷引起的温室效应等方面扮演着十分重要的角色,成为近些年来海洋生物地球化学领域的研究热点之一.一般而言,海洋沉积物孔隙水硫酸盐还原主要是通过2种反应途径来完成,即氧化有机质途径和AOM途径.长期以来,与有机质氧化途径相关的硫酸盐还原作用研究已有充分展示,而由AOM驱动的硫酸盐还原及其对自生硫化铁形成与埋藏的重要贡献却被严重低估.侧重从生物地球化学、同位素地球化学等角度,综述近些年来不同环境条件下海洋沉积物AOM作用发生的地球化学证据和AOM对沉积物孔隙水硫酸盐消耗比例的贡献大小及其调控因素.AOM过程产生的H2S会与沉积物中活性铁结合形成自生铁硫化物.与沉积物浅表层条件相比,AOM过程固定的自生铁硫化物不容易发生再氧化,更利于在沉积物中埋藏保存起来.AOM与海洋沉积物硫酸盐还原作用相偶联,由AOM驱动的硫酸盐还原过程对海底自生铁硫化物形成与埋藏的重要贡献不容忽视.该综述有助加深对海洋沉积物AOM作用的认识及其对硫循环的全面理解.     

华北地台串岭沟组砂脉中自生碳酸盐沉淀和自生黄铁矿——中元古代甲烷厌氧氧化的沉积证据

华北中元古界串岭沟组暗色页岩中普遍发育的砂脉构造被解释为气体逃逸形成的沉积构造。在砂脉和相邻围岩中发现有自生碳酸盐沉淀和自生黄铁矿。自生碳酸盐主要由白云石组成,表现为微晶质条带或隐晶质斑块状胶结物。微晶白云石条带多出现在有机质纹层密集发育的部位,沿微生物膜两侧发育;而隐晶质斑块多以胶结物形式充填粒间孔隙或沿砂脉外缘密集产出。围岩中共生草莓状黄铁矿,砂脉中有具环带黄铁矿。这种特殊的矿物组构以及富有机质沉积和丰富的微生物成因构造(MISS)均表明串岭沟组形成于缺氧环境。层面发育的气泡构造为砂脉的气体逃逸成因提供了支持,而自生碳酸盐和黄铁矿则是沉积浅层硫酸盐-甲烷转换带(SMTZ)甲烷厌氧氧化(AOM)和细菌硫酸盐还原(BSR)的产物;气体源于有机质的厌氧分解和甲烷菌活动。砂脉中发现有疑似微生物化石,围岩含古菌和硫细菌生物标志物,表明有发生AOM和BSR作用的条件。串岭沟组砂脉中识别的自生碳酸盐沉淀及其AOM成因对进一步认识中元古代古海洋与古气候条件具有重要意义。由于海洋的低硫酸盐浓度,SMTZ带很浅,海底沉积层的甲烷仅少量被AOM消耗;而大量甲烷进入大气必然导致中元古代强烈的温室气候效应。     

南海北部琼东南海域HQ-48PC站位地球化学特征及对天然气水合物的指示意义

南海北部陆坡琼东南海域是中国天然气水合物勘探最具潜力的区域之一。对该海域的HQ-48PC站位沉积物样品的顶空气甲烷含量、孔隙水阴、阳离子及微量元素含量等地球化学特征进行综合分析,结果显示:在硫酸盐-甲烷界面(SMI,Sulfate-Methane Interface)(推算深度约为6.05 mbsf)发生了强烈的甲烷厌氧氧化反应(AMO,Anaerobic Meth-ane Oxidation),主要表现为SO24-含量线性降低接近于0、CH4含量发生骤增、有机碳和黄铁矿含量达到最大值及形成一个钡锋等特征。在SMI之上,HCO3-浓度随深度的增加呈明显上升的趋势,Ca2+、Mg2+、Sr2+等离子浓度随深度的增加呈降低的趋势,Mg2+/Ca2+比值随深度的增加呈明显增加的趋势,自生碳酸盐矿物以方解石为主;在SMI之下,HCO3-浓度随深度的增加呈缓慢下降的趋势,Ca2+浓度变化不大,Mg2+、Sr2+浓度和Mg2+/Ca2+比值随深度的增加呈降低的趋势,自生碳酸盐矿物以白云石为主。沉积物孔隙水的PO34-和NH4+含量较高,它们随深度的增加呈明显升高的趋势,且这种变化趋势与SO42-含量的下降趋势大致呈镜像关系。这些地球化学异常特征与国际上已发现有天然气水合物地区的地球化学特征相类似,暗示该采样站位深部沉积物中可能赋存有天然气水合物藏。     

Anaerobic oxidation of methane in coastal sediment from Guishan Island (Pearl River Estuary), South China Sea

The concentrations of CH₄, SO₄²⁻, σCO₂ and the carbon isotope compositions of ΣCO₂ and CH₄ in the pore-water of the GS sedimentary core collected from Guishan Island (Pearl River Estuary), South China Sea, were determined. The methane concentration in the pore-water shows dramatic changes and sulfate concentration gradients are linear at the base of the sulfate reduction zone for the station. The carbon isotope of methane becomes heavier at the sulfate-methane transition (SMT) likely because of the Raleigh distillation effect; ¹²CH₄ was oxidized faster than ¹³CH₄, and this caused the enrichment of residual methane δ ¹³C and δ ¹³C-ΣCO₂ minimum. The geochemical profiles of the pore-water support the existence of anaerobic oxidation of methane (AOM), which is mainly controlled by the quality and quantity of the sedimentary organic matter. As inferred from the index of δ ¹³C-TOC value and TOC/TN ratio, the organic matter is a mix of mainly refractory terrestrial component plus some labile alga marine-derived in the study area. A large amount of labile organic matter (mainly labile alga marine-derived) is consumed via the process of sedimentary organic matter diagenesis, and this reduces the amount of labile organic matter incorporated into the base of the sulfate reduction zone. Due to the scarcity of labile organic matter, the sulfate will in turn be consumed by its reaction with methane and therefore AOM takes place. Based on a diffussion model, the portion of pore-water sulfate reduction via AOM is 58.6%, and the percentage of ΣCO₂ in the pore-water derived from AOM is 41.4%. Thus, AOM plays an important role in the carbon and sulfur cycling in the marine sediments of Pearl River Estuary.     

东海陆缘(闽北段)晚第四纪沉积的硅藻学研究

对东海陆缘 (闽北段 )晚第四纪沉积 4口钻井岩心进行系统的硅藻分析研究,获得丰富的硅藻化石,共发现硅藻 117种和变种,分属于 33个属。根据剖面硅藻组合特征变化,结合最优分割法和对应序分法的计算机运算结果,可以详细划分为 12个硅藻带,自下而上为 :1.Cascinodiscusargus-Cos.wittiomus-Cyclotellastriata硅藻带,2.Cos.blandus-Cyclotellastriata硅藻带,3.Cos.excentricus-Trbliepteychuscocconiformis硅藻带,4.Gomphonema-Cos.blandus-Actnolychusralfsii硅藻带,5.Cos.-Cyclotellastriata-Actinocyclusralfsii硅藻带,6.Cos.-Actinolychusralfsii硅藻带,7.贫乏硅藻带,8.Cos.lineatus-Cos.rothii-Actinolyclusralfsii硅藻带,9.Gomphonema-Cyclotellastriata-Cocconeisplacentulavareuglypta硅藻带,10.Cos.rothii-Cyclotellastriata-Actinolychusralfsi,11.Cymbel laaffinis-Cyclotellastriata-Gomphonema硅藻带,12.Coscinodiscuswittinus-Cyclotellastriata-Epithemiahynd manii硅藻带,建立了该区晚第四纪硅藻组合序列,并探讨其相应的古环境演变。     

Accretionary nature of the crust of Central and East Java (Indonesia) revealed by local earthquake travel-time tomography

Reassessment of travel time data from an exceptionally dense, amphibious, temporary seismic network on- and offshore Central and Eastern Java (MERAMEX) confirms the accretionary nature of the crust in this segment of the Sunda subduction zone (109.5–111.5E). Traveltime data of P- and S-waves of 244 local earthquakes were tomographically inverted, following a staggered inversion approach. The resolution of the inversion was inspected by utilizing synthetic recovery tests and analyzing the model resolution matrix. The resulting images show a highly asymmetrical crustal structure. The images can be interpreted to show a continental fragment of presumably Gondwana origin in the coastal area (east of 110E), which has been accreted to the Sundaland margin. An interlaced anomaly of high seismic velocities indicating mafic material can be interpreted to be the mantle part of the continental fragment, or part of obducted oceanic lithosphere. Lower than average crustal velocities of the Java crust are likely to reflect ophiolitic and metamorphic rocks of a subduction melange.     

Stochastic modeling of gold mineralization in the Champion lode system of Kolar gold fields (India)

Stochastic modeling of gold mineralization in the Champion lode of Kolar gold fields was carried out using assay data taken from developmental headings. After dividing the lode into 71 horizontal and 18 vertical strata, autoregressive (AR), moving average (MA), and autoregressive and moving average (ARMA) models were developed and applied. The model selection with the acf and pacf for the various strata showed that in most of the cases, ARMA modeling of first-order would forecast gold headings with a reasonable degree of confidence. This was substantiated by comparing the coefficients of variation. From a parsimony point of view, AR (1) model may also be considered valid. The best overall models are: ARMA (1, 1), ; AR (1), , where a_t is N (0, _a ² ), x is in logarithms of in-dwt, and t is in block units of 100 ft. The applications of these models to a specific stratum are given. These models would also be helpful to describe the characteristics of the gold mineralization process of this lode.     

新疆祁漫塔格于沟子铁多金属矿辉钼矿Re-Os年龄及其地质意义

[摘 要]于沟子铁-稀有多金属矿区位于东昆仑祁漫塔格矿集区西段,其中铁铜（钼）多金属矿体主要分布于正长花岗岩与狼牙山组碳酸盐岩的接触带矽卡岩内,属于矽卡岩型铁铜（钼）多金属矿床,而铌（铷）等稀有-稀土矿化带分布于正长花岗岩和二长花岗岩内。通过对于沟子铁铜（钼）多金属矿体内磁铁矿石中的辉钼矿Re-Os定年表明,辉钼矿中含有对Re-Os定年产生较大影响的普通Os,在扣除普通Os后,辉钼矿Re-Os等时线年龄为（210.1±4.8）Ma（n=5,MSWD=0.37）,厘定了其成矿年龄为晚三叠世,是东昆仑祁漫塔格印支期大规模成矿的产物。     

Deep root of a continent-continent collision belt: Evidence from the Chinese Continental Scientific Drilling (CCSD) deep borehole in the Sulu ultrahigh-pressure (HP-UHP) metamorphic terrane, China

The Chinese Continental Scientific Drilling (CCSD) deep borehole, which reached a depth of 5158 m in the Sulu ultrahigh-pressure (UHP) metamorphic terrane, provides a new window into the deep root of a continent-continent collision belt, and the tectonic processes by which supracrustal material is recycled into the mantle by subduction and then uplifted to the surface. Major research themes of the CCSD project were to: (1) determine the three-dimensional composition, structure and geophysical character of the deep root of this orogenic belt; (2) investigate the nature and timing of the UHP metamorphism; (3) investigate the processes of crust-mantle interaction involved in the formation and exhumation of the UHP rocks; (4) study the process of fluid circulation and mineralization during subduction and exhumation; (5) study the rheological properties of the various rocks during subduction and exhumation; (6) develop and refine dynamic models for deep subduction and exhumation of crustal rocks, and (7) establish a long-term, natural laboratory for the study of present-day crustal dynamics (e.g., stress, strain, fluid activity). The CCSD has developed precise oriented profiles of the main borehole in terms of lithology, geochemistry, oxygen isotopes, zircon SHRIMP U-Pb ages, ⁴⁰Ar-³⁹Ar ages, deformation, rheology, mineralization, physical properties of the rocks, petrophysical logs, seismic reflections and underground fluids. The present paper summarizes the integrated research results of this project, especially the new findings concerning the deep root of a continent-continent collision.     

华北地块北缘内蒙古固阳地区早二叠世岩体的侵位深度及其构造意义

运用角闪石一斜长石温度计和角闪石全铝压力计估算的华北地块北缘内蒙古隆起西段固阳地区早二叠世花岗质岩体的结晶温度和侵位深度分别为679.1~728.7℃和15.6~19.8 km,表明白早二叠世以来,固阳地区至少有15.6km的地壳岩石被剥露。这一构造抬升及剥露是造成该区中—新元古代地层不连续分布及古生代—早中生代地层普遍缺失的最主要原因。岩体侵位深度与区域前二叠纪最大沉积地层厚度(13.0 km)对比结果表明,早二叠世之前,华北地块北缘已经发生了明显的褶皱或逆冲构造变形,从而导致了地壳岩石的叠覆与加厚。这一早二叠世之前的构造变形及地壳加厚可能与晚古生代期间古亚洲洋板块向华北地块下俯冲有关。     

郑州邙山黄土碳酸盐和白云石含量记录的80 ka以来季风降水变化及驱动机制

揭示东亚季风气候精细变化过程和区域差异,是第四纪古气候学研究的重要内容。本文以季风影响显著的中原郑州黄土堆积上部31 m为研究对象,基于高密度光释光独立定年和619份样品的碳酸盐、白云石含量、磁化率测试,重建了约80 ka以来东亚季风降水/季风强度变化过程。黄土碳酸盐、白云石含量时间序列显示,末次间冰期末期以来,中原地区发生过数次季风降水增强事件,每次降水增强期持续时间短于岁差、偏心率等轨道周期,表明存在亚轨道时间尺度季风快速变化现象。中原黄土碳酸盐/白云石含量主要受土壤呼吸CO₂的影响,土壤呼吸CO₂含量由季风降水和土壤温度控制,因此,碳酸盐/白云石含量是东亚夏季风强度的良好替代指标。中原地区千年时间尺度的季风湿润和干旱事件与其他地区黄土、石笋记录具有同步性,证实在东亚季风降水核心区、中心区和边缘区千年时间尺度干湿变化的同步性,支持季风环流大空间同步增强的模式。这一季风降水型式与现代观测到的"南涝北旱"的"+-+"三极型季风降水分布不同,可能表明不同时间尺度季风降水型式有明显区别。进一步分析表明,季风降水增强/减少事件存在约22 ka和约1.6 ka的周期,表明低纬太阳辐射、大洋环流和高纬度冷事件对东亚季风的联合驱动作用。

     

The spatial distribution of trace elements in topsoil from the northern slope of Qomolangma (Everest) in China

The environment of Mt. Qomolangma (Everest) area is of great significance to the global environmental background and environmental change research. However, there are few studies on the content and distribution of soil trace elements in the area. About 130 soil samples were collected nearby the Rongbuk valley at the northern slope of the Qomolangma from 4,400 to 6,600 m elevations. Nine soil trace elements, Cr, Zn, Sr, Pb, Ni, Co, Cd, Mn, Cu, were analyzed with ICP-AES (inductively coupled plasma atom emission spectrometry). The results showed that soil trace elements content increased with altitude; the content of the Cd in this area was very high, which was 5.8 times of the average content of Chinese soil. There was a noticeable change point for soil trace elements content at the altitude of 5,800 m, and the content of Cd increased abruptly above 5,800 m. This point was just located at the boundary of two types of rocks. The Late Precambrian-Neoproterozoic granite–gneiss and metacryst migmatized interbedded with marble located below 5,800 m; black-dark slate and marl of Cambrian located above 5,800 m (including 5,800 m), the geochemical characteristic of different rocks was the main factors controlling the soil trace elements content in the northern slope of Qomolangma Mountain.     

Records of climatic changes and volcanic events in an ice core from Central Dronning Maud Land (East Antarctica) during the past century

The depth profiles of electrical conductance, δ¹⁸O,²¹⁰Pb and cosmogenic radio isotopes¹⁰Be and³⁶Cl have been measured in a 30 m ice core from east Antarctica near the Indian station, Dakshin Gangotri. Using²¹⁰Pb and δ¹⁸O, the mean annual accumulation rates have been calculated to be 20 and 21 cm of ice equivalent per year during the past ∼ 150 years. Using these acumulation rates, the volcanic event that occurred in 1815 AD, has been identified based on electrical conductance measurements. Based on δ¹⁸O measurements, the mean annual surface air temperatures (MASAT) data observed during the last 150 years indicates that the beginning of the 19th century was cooler by about 2‡ C than the recent past and the middle of 18th century. The fallout of cosmogenic radio isotope¹⁰Be compares reasonably well with those obtained on other stations (73‡ S to 90‡ S) from Antarctica and higher latitudes beyond 77‡N. The fallout of³⁶Cl calculated based on the present work agrees well with the mean global production rate estimated earlier by Lal and Peters (1967). The bomb pulse of³⁶Cl observed in Greenland is not observed in the present studies – a result which is puzzling and needs to be studied on neighbouring ice cores from the same region.     

The shift between worlds of production as an innovative process in the wine industry in Castile and Leon (Spain)

This article draws on the theory of conventions and the concept of worlds of production for an interpretation of the transformations of a regional production system over several decades. Wine production in the Spanish region of Castile and Leon has shifted from a world of local and interpersonal production (prevailing before 1960) to the current preferred orientation towards quality markets, having passed through an intermediate phase (1960-1980) of table and bulk wines industrial production. Recently, indications have appeared of a return to an interpersonal and neo-artisanal production on the part of prestigious winemakers who distribute their wines to selected international clients. This path is the result of a gradual modification of the dominant conventions of the business, which has experienced a spectacular development in Castile and Leon, whose wines are now appreciated in many foreign markets. This evolution of conventions may be interpreted as an innovative process maintained to challenge the trends and demands of the market. But this argument does not explain how conventions change and how these changes spread along the production chain. Therefore, this article discusses the contribution of three factors to this shift across different worlds of wine production: organization of the production chain; regulations regarding the protection of food differentiated according to its geographic origin; and the setting up of a regional innovation system which supports the wine sector.     

汶川地震断裂带科学钻探1号井(WFSD-1)非弹性应变恢复法(ASR法)三维地应力测试与"5.12"汶川地震的形成机制

汶川地震断裂带科学钻探1号井(WFSD-1)的ASR三维地应力测试结果表明,龙门山前陆逆冲带与其下伏的龙门山前陆盆地和上覆的松潘-甘孜地块的构造及地应力状态存在有重大差异。从整体上看,在汶川地震中,龙门山前陆逆冲带表现为在强烈的区域性挤压背景下,深部物质沿壳内拆离层自SW向NE方向的"层状"流动,在地壳上部转化为沿映秀-北川断裂(YBF)的快速垂向挤出,而其西侧的松潘-甘孜地块作自SE往NW方向的重力滑覆,东侧的龙门山前陆盆地则表现为自NE往SW方向的走滑或右行旋转。晚新生代以来,扬子地块相对于青藏高原东缘的龙门山造山带并无明显的或大尺度的陆内俯冲作用发生。龙门山前陆逆冲带深部高温低粘度物质垂直向上的、快速的流动和挤出,直接导致了"5.12"汶川地震的发生,而松潘-甘孜地块E向扩展导致龙门山前陆带的强烈挤压和陆壳增厚及深部应力和地震能量的积聚则是诱导深部位移场发生突变和物质快速垂向挤出的主因,E向扩展是深部地震能量积聚和快速垂向挤出作用的必要条件,而非地震发生的直接原因。ASR地应力测试得出的主压应力方向完全平行于GPS同震速度场的位移方向,似乎表明ASR测试获得的原地应力场或许真实地反映了或最接近于地震过程中的构造应力状态。     

龙门山构造带北段构造变形特征 ——来自汶川科钻四号孔(WFSD-4)的证据

2008年MW7.9汶川地震在青藏高原东缘龙门山构造带内毫无征兆的情况下发生,并沿灌县—安县断裂和映秀—北川断裂分别产生了约80 km和275 km的不同性质的地表破裂带,在世界地震史上实属罕见,表明龙门山构造带在以往经历了极为复杂的构造演化和运动变形。地震后迅速启动的汶川地震断裂带科学钻探项目,为我们认识龙门山构造带以往运动和变形本质提供了全新的素材和视角。本文以位于龙门山构造带北段的汶川地震断裂带科学钻探四号孔(WFSD-4)岩心作为主要研究对象,并结合地表构造变形研究,对WFSD-4的岩心变形特征和龙门山构造带北段的构造变形序列进行了分析与探讨,认为:D1变形期以岩心和地表早期面理S1顺成份层发育为特征,多被同时期长英质脉体填充,显示伸展机制下的韧性变形,推测为轿子顶穹隆构造的形成时期; D2变形期为区域主导性面理S2的形成时期,岩心中劈理面上可见绢云母等矿物,石香肠构造指示NW–SE的韧性挤压变形特征。岩心和地表均可见S2切割早期面理S1,错断早期顺S1贯入的长英质脉体; D3变形期以NW–SE向挤压冲断为主,岩心中面理S2发生褶皱变形,局部生成间隔劈理S3。地表可见区域主导面理S2变形,形成平行褶皱,轴面走向北东,发育同时期的NW向陡倾的活动断裂,部分成为汶川地震的发震断裂,该期对应于龙门山构造带北段的喜山期构造运动,褶皱强化,推覆强烈,也是唐王寨向斜的最终成型时期;岩心和地表均可见面理S2膝折的构造现象,为局部地表抬升过程中的重力成因,构成D4期变形。