The history and impact of air pollution at Čertovo Lake,southwestern Czech Republic

This multi-disciplinary investigation documents the longterm effects of atmospheric pollution of metals and acids on a geologically sensitive catchment in the umava Mountains, southwestern Czech Republic, a region with a long history of human disturbance. A 30 cm long sediment core (I) from ertovo Lake was analyzed for natural and artifical radionuclides, metals, diatoms, chrysophytes, and pollen in sediments accumulated during the last 200 years. A second core (II), extending to 95 cm, included sediment judged to be free of atmospheric deposition of pollutants associated with the Industrial Revolution. Chronostratigraphic markers include several changes in the pollen assemblages corresponding to well-documented changes in land-use, and distinct distributions of ¹³⁷Cs, ¹³⁴Cs and ²⁴¹Am from weapons testing and the 1986 nuclear accident at Chernobyl, Russia. These markers corroborate the ²¹⁰Pb dating and, together, produce a reliable chronology extending back nearly to 1800 A.D.Stratigraphic profiles of Cu, Pb, and Zn in Core I are unlike any previously reported in the literature. Concentrations of Cu, Pb, and Zn remain generally above 100, 400, and 200 g g^-1, respectively, for the 200 years represented by Core I. These values are unusually high for sediments from a watershed with no known heavy-metal ore bodies. Accumulation rates for Cu, Pb, and Zn, which include both atmospheric and watershed contributions, are also high (ca 1, > 1 and > 1 g cm^-2 yr^-1, respectively) for the same period, although the anthropogenic contribution of Zn rose from nearly zero at 1800 A.D. The Cu and Pb accumulation rates rose dramatically about 1640 A.D.Accumulation rates of anthropogenically-derived Be, a relatively abundant element in the soft coals of the region, are also elevated by about 0.01 g cm^-2 yr^-1 in sediments of this period. Vanadium accumulation rates increased only since 1980 A.D., presumably along with increased consumption of oil.Diatom assemblages illustrate that the lake was acidic (pH between 4.5 and 5) through at least the past 200 years. The pH declined significantly (from ca 5 to 4) between 1960 and 1985 with a slight increase to 4.5 in the last few years. Recent diatom and chrysophyte assemblages suggest high trace metal concentrations, consistent with the present lake-water chemistry.     

The sedimentary record of environmental lead contamination at St. Louis,Missouri (USA) area smelters

Southeastern Missouri has been a major Pb mining region since 1720 AD. Missouri mines produce a Pb ore that has a distinctive elevated ²⁰⁶Pb/²⁰⁷Pb isotopic ratio (>1.30) that is easily recognized in Pb-contaminated sediments. Five ²¹⁰Pb dated sediment cores from Horseshoe Lake, Madison County, Illinois were examined to reconstruct Pb-contamination of the site from southeastern Missouri mines and from a local Pb smelter located adjacent to the lake. Pb concentrations increased in the cores from 5 ppm in the early 1800s to approximately 350 ppm in the late 1940s and 1950s. Pb concentrations in recently deposited sediment range from 100 to 300 ppm depending on the location within the lake. Throughout the 1800s and early 1900s the ²⁰⁶Pb/²⁰⁷Pb ratios in the sediment cores increased indicating contamination from southeastern Missouri (mean = 1.243). After the local smelter began recycling lead-acid storage batteries in the 1950s, the ²⁰⁶Pb/²⁰⁷Pb ratio declined (mean = 1.224) suggesting contamination of Horseshoe Lake with Pb from sources elsewhere around the world. The results of this study demonstrate how isotopic ratios of Pb can be used to reconstruct historical anthropogenic contamination.     

The Suitability of a South Pennine (UK) Reservoir as an Archive of Recent Environmental Change

The suitability of a south Pennine reservoir as an archive of recent industrial pollution (Pb deposition) and vegetation change was assessed by comparing the sediment record of Pb and pollen with a local blanket peat profile, and the modelled regional SO₂ deposition since 1840. The pollen-based record of vegetation change from the reservoir sediments was obscured by high inputs of eroded peat from the surrounding catchment. Total fluxes of Pb from the catchment into the reservoir varied between 0.05 and 2.67 kg km⁻² year⁻¹ during a 7 year period of increased peat erosion (1976–1984). The presence of concentration peaks in the Pb profile of the blanket peat may have been caused by changes in sulphide or redox chemistry within the peat profile. Large variations in influxes of Pb to the reservoir occurred during periods of increased peat erosion, suggesting the record of aerial pollution deposition has been obscured by terrestrial inputs. Extensive areas of blanket peat in the south Pennines have been subject to denudation, suggesting reservoirs in the region and other areas of high erosion and sediment flux are unsuitable for producing accurate records of the aerial deposition of pollen rain and Pb pollution. The ecological implications of highly variable fluxes of heavy metal contaminants from extensively eroded blanket bogs to ecosystems downstream are poorly understood.     

Evaluation of210Pb dating in lake sediments using stable Pb,Ambrosia pollen,and137Cs

We used sediment chronology data from fourteen published studies of lake cores across much of North America and Scandinavia in order to make a large scale comparison of the different dating techniques. The uncertainty of²¹⁰Pb derived dates was determined using common sediment event markers: the stable Pb rise, the¹³⁷Cs rise, and theAmbrosia pollen rise. For all data combined, the 95% confidence intervals for the stable Pb rise and theAmbrosia rise, were approximately 30 years. These 95% confidence intervals are slightly higher than those derived by First-Order Error analysis performed by others on²¹⁰Pb derived dates. When comparing the concordance of two²¹⁰Pb models (CRS and CIC) against markers of known history, we found that the CRS model dates (constant rate of supply) had consistently better agreement than the CIC model dates (constant initial concentration). Major discrepancies between¹³⁷Cs and²¹⁰Pb were common, but were consistently more severe in sediments of soft water lakes pointing to an inability of sediments with low mineral content to immobilize Cs.This is the ninth of a series of papers to be published by this journal following the 20 ^th anniversary of the first application of²¹⁰Pb dating of lake sediments, Dr. P. G. Appleby is guest editing this series.     

Recent Environmental Change and Human Impact on Svalbard: The Lake-Sediment Geochemical Record

As part of a broader investigation into recent environmental change on Svalbard, the inorganic geochemical record of six lake-sediment cores was analysed. The major temporal trends in sediment elemental composition are driven by variations in two contrasting sediment components, both derived from catchment soils: (1) mineral matter, and (2) soil organic matter (SOM), enriched in Fe and Mn oxides and heavy metals. Two environmental impacts are recorded in most or all of the lake sediment sequences. An up-core increase in organic matter can be partly attributed to diagenetic effects, but also requires an enhanced supply of SOM relative to mineral matter. In addition, the central and southern sites all show a ca. 1970 event characterised by an enhanced mineral matter accumulation rate. This requires either an enhanced allochthonous supply or an enhanced mobilisation of littoral sediments. In either case a regional-scale driving force, such as a shift in climate, is required. At five of the lakes the sediment heavy metal concentration profiles can be explained entirely by natural factors. However, at Tenndammen (U), situated close to the Svalbard’s largest settlement at Longyearbyen, possible anthropogenic Pb enrichment is found. Comparison of observed and expected heavy metal profiles (based on Greenland ice-core data) shows that the lakes are generally too insensitive to have recorded a long-transported heavy metal pollution signal.     

Past atmospheric Pb deposition in Lake Qinghai,northeastern Tibetan Plateau

Two short sediment cores were recovered from sub-basins of Lake Qinghai, China and were analyzed for concentrations of Pb and 16 other elements to determine historic, regional atmospheric Pb deposition on the Tibetan Plateau. Core chronologies, dating back to the eighteenth century, were established using activities of ²¹⁰Pb and ¹³⁷Cs. The 17 elements were divided into three principal components. Variations in concentrations of PC1 elements (Al, Cr, Cu, Fe, K, Mn, Ni, and Ti) demonstrate different patterns between the two cores, and are attributed to different sediment sources in the two sub-basins. PC2 elements (Ba, Ca, Na, and Sr) may be associated with the degree of catchment weathering and/or water chemistry. Four elements (Pb, Zn, P, and Co) are related to both PC1 and PC2, and reflect a mixture of natural and anthropogenic sources. The PC3 element is Mg in the north sub-basin, and is perhaps related to aragonite precipitation and/or increased farming. Elevated Pb concentrations in uppermost sediments of both cores signify a recent regional/global increase in anthropogenic Pb release into the environment. After subtracting lithogenic Pb, derived from rock weathering and/or dust and normalized to the background immobile element Ti, results suggest that excess, anthropogenic Pb is transferred to the lake and its sediments predominantly via the atmosphere. This anthropogenic atmospheric Pb is comparable in magnitude and displays similar variation patterns in the two cores, reflecting regional atmospheric deposition and local erosion. The average anthropogenic Pb deposition rate in Lake Qinghai since the 1960s has been ~12.2 ± 3.5 mg/m²/a, comparable with atmospheric Pb fluxes reported for sites elsewhere in the northern hemisphere.     

Lead analysis of sediment cores from seven Connecticut lakes

Lead analyses were performed on sediment cores from seven Connecticut lakes by dilute acid leaching. The absolute concentrations of lead varied from core to core, but the lead profiles were similar in all of the cores, and each depicted a point where the concentration of lead sharply increased above background levels. The background lead concentrations observed in the bottom portions of the cores ranged from 12-54 g Pb/g sediment with a mean of 30 g Pb/g, and increased to a mean maximum of 310 g Pb/g. In six of the lakes significant increases above background levels were not noted until between 1924 and 1952, suggesting that, at least for Connecticut lakes, the point in a lake sediment core where the concentration of lead began to increase was after ca. 1924, and on average about 1930. Lead concentrations declined in the surface sediments of only three of the lakes, mostly since the 1980's, and presumably in response to the phasing out of leaded gasoline. However, significant declines in lead concentrations were not observed in the remaining cores, possibly due to increased motor vehicle use within the airshed of the lakes and/or changes in the export of lead to the lakes from their watersheds.     

Stratigraphy of total metals in PIRLA sediment cores

Sediment cores from 30 low-alkalinity lakes in northern New England (NE), New York (NY), the northern Great Lakes States (NGLS) of Minnesota, Michigan, and Wisconsin, and Florida (FL) have been dated by ²¹⁰Pb and analyzed for water and organic content, eight major elements (Al, Ti, Fe, Mn, Ca, Mg, Na, K) plus four trace metals (Pb, Zn, Cu, and V). Variations in the percentages of major elements through time are dominated by long-term independent variations in the abundance of SiO₂, FeO, and to a lesser extent Ca and Al. Additional variations are caused by varying proportions of inorganic matter. Major variations in chemistry are generally unrelated to documented distrubances in the watersheds; most disturbances are minor fires or selective logging.Accelerated accumulation of Pb from atmospheric sources into sediment first occurs in sediment dated between 1800 and 1850 in NY and NE, slightly later in the NGLS region, and about 1900 in FL. Modern accumulation rates in all areas are comparable (ca. 1 to 4 g cm^–2 yr^–1). Accumulation rates of Pb in some lakes have declined significantly from 1975 to 1985. Atmospheric deposition of anthropogenic Zn and Cu is also indicated by generally increasing accumulation rates in sediment cores, but the record is not as clear nor are chemical profiles in all lakes parallel to the trends in atmospheric emissions inferred on the basis of fossil fuel consumption, smelting, and other industrial activities. Inter-lake variations in profiles of Cu and Zn are large. Vanadium accumulation rates increase by the 1940s in NY and NE, but not until the 1950s in the NGLS region. This timing correlates with regional trends in the combustion of fuel oil, a major source of atmospheric V.Acidification of some of the lakes is suggested by decreases in the concentration and accumulation rates of Mn, Ca, and Zn in recent sediment, relative to other elements of catchment origin. The decreases generally occur slightly before the onset of acidification as indicated by diatoms. Increased sediment accumulation rates for Fe may indicate the acidification of watershed soils. The use of the accumulation rate of TiO₂ as an indicator of rates of erosion and for normalization of trace metal accumulation rates is in question for lakes where the flux of TiO₂ from the atmosphere varies and is a significant fraction of the total flux of TiO₂ to the sediment.This is the thirteenth of a series of papers to be published by this journal which is a contribution of the Paleoecological Investigation of Recent Lake Acidification (PIRLA) project. Drs. D. F. Charles and D. R. Whitehead are guest editors for this series.     

Biological and Geochemical Record of Anthropogenic Impacts in Recent Sediments from Lake Pupuke, Auckland City, New Zealand

Frozen sediment cores from Lake Pupuke in Auckland City, New Zealand, contain a high resolution decadal to annual scale record of changing lake paleoenvironments and geochemistry that reflects changing landuse and hydrology in the catchment over the past c. 190 years. A reliable chronology is available from AMS ¹⁴C and ²¹⁰Pb dating of the sediments, with the timing of the older part of the record supported by the first appearance of pollen of introduced Pinus and Plantago lanceolata associated with European settlement of Auckland in the early 1840s. Diatom stratigraphy, sediment elemental and carbon isotope geochemistry reflect changes in sediment sources and lake conditions commensurate with European development of the Lake Pupuke catchment, in particular enhanced algal productivity controlled by the influx of nutrients after c. 1920 AD. Attempts to prevent nuisance algal blooms in 1933, 1934 and 1939 using CuSO₄ addition produced Cu spikes in the sediment that allowed confirmation of the accuracy of the ²¹⁰Pb chronology. Hence, the elemental and isotopic composition of the Lake Pupuke sediments reflect the timing of significant anthropogenic activities, rather than climatic variations, that have occurred within the watershed over the past c. 190 years. The comparison of records of land use change in the catchment with the multi-proxy record of changes in the sediments usually allowed unambiguous identification of the signatures of change and their causes.     

Multi-component carbon isotope evidence of early Holocene environmental change and carbon-flow pathways from a hard-water lake in northern Sweden

A 9000-year carbonate-rich sediment sequence from a small hard-water lake in northernmost Sweden was studied by means of multi-component stable carbon isotope analysis. Radiocarbon dating of different sediment fractions provides chronologic control and reveals a rather constant hard-water effect through time, suggesting that the lake has remained hydrologically open throughout the Holocene. Successive depletion of ¹³C in fine-grained calcite and carbonate shells during the early Holocene correlate with a change in catchment vegetation from pioneer herb communities to boreal forest. The vegetational change and associated soil development likely gave rise to an increased supply of ¹³C-depleted carbon dioxide in groundwater recharging the lake. This process is therefore believed to be the main cause of decreasing values of ¹³C in dissolved inorganic carbon of the lake and thereby in limnic carbonates. Strongly ¹³C-depleted sedimentary organic matter may be related to enhanced kinetic fractionation during photosynthetic assimilation by means of proton pumping in Characean algae. This interpretation is supported by a substantial offset between ¹³C of DIC as recorded by mollusc shells and ¹³C of fine-grained calcite.     

Recent heavy metal accumulation in Dongjiu and Xijiu lakes,East China

Taihu Lake has been recognized as a seriously contaminated waterbody with regard to Cd, Cu, Pb and Zn over the last two decades. The input of pollutants has increased due to economic and social development and population increase. Seventy percent of the pollutants in Taihu Lake comes from rivers, with the Yili River being a major source of pollutants. Lakes Xijiu and Dongjiu are connected to the Yili River and Taihu Lake and are sites where material is preferentially deposited because of hydrodynamic conditions. Sediment cores were collected from Xijiu Lake (core XJ-1) and Dongjiu Lake (core DJ-5) to investigate anthropogenic heavy metal contamination. Concentrations of Cu, Pb and Zn gradually increased since the late 1930s, peaked in 1970, and then dropped slightly. A sudden increase in concentrations of Cu, Pb and Zn occurred in 1991 and peaked again in 1996, then dropped markedly. Maximum concentration of Cd in core XJ-1 was 21.2 mg kg⁻¹ and mean concentration was 12.1 mg kg⁻¹. In core DJ-5, the maximum and mean concentrations were 6.9 and 5.4 mg kg⁻¹, respectively. Cr showed a pattern of variation different from the other heavy metals, but its concentration also dropped after peaking in 1996. Enrichment factors and anthropogenic factors revealed that human activities in the catchment played a key role in the heavy metal contamination. Increases in Cd, Cu, Pb and Zn concentration were caused by industrial development, particularly from non-ferrous metal smelting industries. The recent drop in Cd, Cu, Pb and Zn concentrations is attributed to pollution reduction measures instituted by the government. Cr was influenced by both natural and anthropogenic processes.     

The influence of relative sediment supply on riverine habitat heterogeneity

The diversity of aquatic habitats in streams is linked to physical processes that act at various spatial and temporal scales. Two components of many that contribute to creating habitat heterogeneity in streams are the interaction between sediment supply and transport capacity and the presence of local in-stream structures, such as large woody debris and boulders. Data from previously published flume and field studies and a new field study on tributaries to the South Yuba River in Nevada County, California, USA, were used to evaluate the relationship between habitat heterogeneity, local in-stream structural features and relative sediment supply. Habitat heterogeneity was quantified using spatial heterogeneity measures from the field of landscape ecology. Relative sediment supply, as expressed by the sediment supply/transport capacity ratio, which controls channel morphology and substrate textures, two key physical habitat characteristics, was quantified using a dimensionless bedload transport ratio, q. Calculated q values were plotted against an ecologically meaningful heterogeneity index, Shannon's Diversity Index, measured for each study reach, as well as the percent area of in-stream structural elements. The results indicate two potential mechanisms for how relative sediment supply may drive geomorphic diversity in natural river systems at the reach scale. When less mobile structural elements form a small proportion of the reach landscape, the supply/capacity ratio dictates the range of sediment textures and geomorphic features observed within the reach. In these settings, channels with a moderate relative sediment supply exhibit the highest textural and geomorphic diversity. In contrast, when less mobile structural elements are abundant, forced local scour and deposition creates high habitat heterogeneity, even in the presence of high relative sediment supply.     

A sediment budget for a grazed semi-arid catchment in the Burdekin basin, Australia

In catchments adjacent to the Great Barrier Reef World Heritage Area in Queensland, Australia, there is a growing concern that sediments and nutrients being exported from the land are having a detrimental effect on coral reef communities. There is a need to determine the processes and rates of erosion from the major land use types, so that management intervention can be initiated to reduce sediment yields where required. This paper presents a sediment budget for Weany Creek, a 13.5 km² grazed semi-arid sub-catchment of the Burdekin River catchment, Australia. A range of field methods was used to measure erosion from hillslopes, gullies and stream banks, as well as identify the amount of sediment being deposited and remobilised on the bed of gullies and the stream network. The data suggests that at least during drought conditions, the primary erosion source in this catchment is gully erosion. However, the largest source of sediment in the budget is actually associated with the remobilisation of in-channel sediment stores. Overall, the sediment budget is comprised of  81% coarse material and 19% fine sediment and an agreement between the fine sediment yield estimated in the sediment budget and the yield measured at the catchment outlet is within 10%. The total sediment yield estimated for this catchment is  4205 t yr^− 1 and is much lower than expected for a catchment of this size. This may reflect the drought conditions during the measurement period; however, there is also the possibility that the primary erosion sources have been exhausted, and the rates of sediment loss may be much lower now than they may have been in the past. Nonetheless, the results show that stored sediment, which may have been deposited in the channel many decades ago, is an important contributor to end of catchment sediment yields and warrants further investigation.     

A 2500 year sediment record from Fayetteville Green Lake, New York: evidence for anthropogenic impacts and historic isotope shift

A series (N = 12) of short (< 1 m) sediment cores were collected from meromictic Green Lake in Fayetteville, New York to investigate potential anthropogenic impacts on the watershed during historic time and environmental change over the past ~ 2,500 years. Stratigraphic data document an abrupt basinwide change during the early 1800's A.D. from brown laminated sediments to grey varved sediments separated by a transition zone rich in aquatic moss. Deforestation of the region by European settlers during the early 1800's A.D. resulted in a flux of nutrients and increased biological productivity followed by a 7fold increase in sediment accumulation rates. Elemental geochemical data document the anthropogenic loading of lead to the to the lake basin via atmospheric fallout. Stable oxygen isotope (¹⁸O calcite) data also provide evidence for an abrupt shift in the isotopic composition of lake water ~ 150–200 years ago. This isotopic shift could have been a local phenomenon related to an increased supply of summer enriched precipitation following removal of forest vegetation, or it might have reflected broader scale climatic changes. We hypothesize that the ¹⁸O calcite shift was the result of the polar front jet stream migrating from a more southerly prehistoric position to a contracted, northerly configuration ~ 150–200 years ago. Such a shift could have been natural, associated with the end of the Little Ice Age or it may have been anthropogenically forced.     

Long-term rates of sediment accumulation in the Tonle Sap,Cambodia: a threat to ecosystem health?

The Tonle Sap is an invaluable resource for the people of Cambodia, and is a globally significant ecological site. Much of the literature published on the environmental health and management of the lake suggests that its sustainability is threatened by accelerated rates of infilling related to unfettered land-use in the catchment. However, the evidence for supposedly increased sedimentation rates is confused and contradictory, and there have been very few studies that have attempted to actually measure the rate at which sediment is accumulating on the bed of the lake. This research measures long-term sedimentation rates in the Tonle Sap in an attempt to provide an empirically derived baseline against which more recent and allegedly accelerated sedimentation rates can be compared. Radiometric dating techniques (¹⁴C, ²¹⁰Pb, ¹³⁷Cs) reveal that sediment has been accumulating in the lake at an average long-term rate of less than 1 mm per year. There is a clear and consistent decline in the rate of sediment accumulation in the lake basin over time, with the highest rates recorded in the middle to early Holocene epoch. It is recommended that research be directed toward measuring changes in the morphology of the lake margin over time, rather than focus on changes in the bathymetry of the lake basins themselves, which are here shown to be effectively stable in terms of sediment accumulation.     

The influence of landsliding on sediment supply and channel change in a steep mountain catchment

Rates of sediment supply by landsliding to an alluvial channel in a small catchment in central Switzerland were estimated over an 11-month study period. Fluvial sediment transport in the channel is independently monitored at the upstream and downstream ends of the study reach, yielding a unique opportunity to quantitatively compare the volume of sediment supplied to the channel with the volume in fluvial transport. Landslide-derived sediment discharge to the channel was greatest during the winter and spring months, while most of the fluvial sediment transport occurred during short, intense summer storms. Approximately 98 m³ of sediment was delivered directly to the study reach by landsliding,  80 m³ was transported into the reach from upstream, and  70 m³ was transported out of the reach. Thus, there was a net accumulation of  100 m³ of sediment during the 11-month study. Decadal-scale channel aggradation was independently assessed by comparing channel longitudinal profiles in 1993 and 2004. During this 11-year period, a total of  1500 m³ of sediment has accumulated in the study reach. Aggradation has occurred largely in two broad zones that correspond with both the locations of major landslide complexes and reaches of high channel slope, indicating that hillslope sediment input left an imprint on the morphology of the channel bed that appears to be stable over at least decadal time scales.     

A mineral magnetic and scaled-chrysophyte paleolimnological study of two northeastern Pennsylvania lakes: records of fly ash deposition, land-use change, and paleorainfall variation

A combined mineral magnetic and scaled chrysophyte study of lake sediments from Lake Lacawac and Lake Giles in northeastern Pennsylvania was conducted to determine the effects of land-use and sediment source changes on the variation of pH, conductivity, and alkalinity inferred from biotic changes. Ten 30–40 cm long gravity cores were collected from Lake Lacawac and three from Lake Giles. Isothermal remanent magnetizations (IRMs) were given to the lake sediments in a 1.3 T magnetic field to measure magnetic mineral concentration variations. IRM acquisition experiments were conducted to identify magnetic mineralogy. The bedrock, soils and a peat bog on the shores of Lake Lacawac were also sampled for magnetic analysis to determine possible lake sediment sources. The top 10 cm of sediment collected from Lakes Lacawac and Giles was two to four times more magnetic than deeper sediment. ²¹⁰Pb dating suggests that this intensity increase commenced circa 1900. SEM images of magnetic extracts from the highly magnetic sediments indicates the presence of magnetic fly ash microspheres from fossil fuel burning electric power generation plants. The similarity in magnetic coercivity in the top 8 cm lake sediments and in the peat bog supports an atmospheric source for some of the magnetic minerals in the youngest lake sediments. The highly magnetic sediments also contain an antiferromagnetic mineral in two cores closest to Lake Lacawacs southeastern shore. This magnetic mineral is only present deep in the soil profile and would suggest erosion and significant land-use changes in the Lacawac watershed as another cause for the high magnetic intensities (concentrations) in the top 10 cm of the lake sediments. The most significant changes in the scaled chrysophyte flora occurred immediately above the 10 cm level and were used to infer a doubling of the specific conductivity between circa 1910 and 1929. These variations also support land-use changes in the Lacawac catchment at this time. A similar shift in the scaled chrysophte flora was not observed in the top of Lake Giles, however, distinct changes were found in the deeper sections of the core coupled with a smaller peak in magnetic concentration. Fourier analysis of the ²¹⁰Pb-dated lake sediment magnetics indicates the presence of a 50 year period, low amplitude variation in the Lake Lacawac, Lake Giles, and Lake Waynewood (Lott et al., 1994) magnetic concentration records. After removal of the land-use/fly ash magnetic concentration peak by Gaussian filtering, the 50 year variation correlates strongly from lake to lake even though the lakes are in different watersheds separated by up to 30 km. When this magnetic variation is compared with Gaussian-filtered rainfall variations observed in New York City and Philadelphia over the past 120–250 years there is a strong correlation suggesting that magnetic concentration variations can record regional rainfall variations with an approximately 50 year period. This result indicates that magnetics could be used to document regional variations in climatic change.     

Processes affecting deposition of sediment in a small, morphologically complex lake

Devil Lake is morphologically complex as a result of Pleistocene glacial erosion of the Frontenac Axis of the Canadian Shield. In order to assess the processes causing highly variable sedimentation in the lake, we monitored currents, suspended sediment and temperature in the lake before and during autumn overturn in 2002. Strong summer thermal stratification (stability number to 0.11 s^–1 declining with the approach of overturn) was insufficient to prevent a dynamic response in the hypolimnion to wind forcing. Superimposed on a gradual increase in suspended sediment concentration in the last weeks of stratification from less than 2 g/l to about 30 g/l were shorter-term rises lasting up to several days. Associated with these events was an increase in particle size of the sediment from a mode of 40–50 to 150–200 m ascribed to flocculation from primary particles. These events culminated in rapid (<1 h) clearing of the water associated with strong, sustained winds over the lake, especially from the southwest. After overturn, the events were more frequent, and flocculation was unable to develop as well in the more vigorous circulation. However, currents in the hypolimnion occurred throughout the period before, during and after overturn with speed related to wind speed, but direction largely independent of wind direction. The results represent an approach to understanding the nature of sedimentary processes and thus to strengthening the use of sedimentary records as proxy in environmental and paleoenvironmental assessment.     

Paleoecological investigations of recent lake acidification in northern Florida

Thirty-two northern Florida lakes were analyzed to construct a transfer function relating surface sediment diatom assemblages to lakewater pH (R ² =0.89, s.e.=0.34). A paleoecological analysis of sediment cores from six of these lakes indicated that two have become more acidic in the last 50 years. The diatom inferred (DI) pH of L. Barco has declined between 0.56–0.82 in the 1900's and DI ANC (acid neutralizing capacity) by 28–46 eq l^-1. The DI pH of nearby L. Suggs has declined 0.91 pH units and its DI ANC by 19 eq l^-1. The timing of the inferred acidification is synchronous with known increases in emissions of sulfates and nitrates that are associated with acidic precipitation. Also, the increasing accumulation of substances related to emissions from the burning of fossil fuels (e.g., Pb, PAH) co-occurs with the lowering of DI pH in the sedimentary record. However, other processes may have accounted for or contributed to recent lake acidification. For instance, the drawdown of local water tables by human consumption may decrease the inseepage of ANC to seepage lakes. Such an effect would be synchronous with increasing depositions of sulfate. There is also clear evidence that Florida lakes are naturally acidic. Thus, paleoecological results indicate acidic deposition to be at certain contributor, but not necessarily the sole cause, of the recent further acidification of some naturally acidic Florida lakes.This is the tenth of a series of papers to be published by this journal which is a contribution of the Paleoecological Investigation of Recent Lake Acidification (PIRLA) project. Drs. D. F. Charles and D. R. Whitehead are guest editors for this series.     

A lake sediment record of Pb mining from Ullswater,English Lake District,UK

Lake sediments can be significantly impacted by industrial activities. These impacts vary among sites and include both local point sources and atmospherically-derived pollution. Here we present results of a lake sediment pollution record from Ullswater, UK, where lead mining activities have taken place within the catchment since 1690, although large-scale mining did not begin until 1840. Metal concentration data from 12 cores taken along a lake bed transect illustrate that lead mining at Greenside Mine had a significant impact on the lake sediments. High Pb concentrations were identified throughout Ullswater, and exhibited a spatial gradient from south to north, with concentrations decreasing with greater distance from the main source of input at Glenridding. Furthermore, inter-element correlations exhibit spatial variation that reflects the processes by which they are incorporated into the lake sediment record. Together, these observations illustrate potential shortcomings in palaeoenvironmental reconstructions and pollution studies based on single cores from large and morphologically variable lakes. Sedimentation rates were estimated by matching this pollution record with the historical record of mining activities. Within Ullswater, sedimentation rates from 1840 to the present varied from 0.67 to 2.33 mm year⁻¹ with a mean of 1.4 mm year⁻¹; highest sedimentation rates were observed in the deepest section of the lake and close to the main inputs, and lowest sedimentation rates were observed in the northern part of the lake, furthest from the main input. Despite the considerable changes in mining techniques and production, there is little evidence to suggest significant changes in sedimentation rates over time.