论玻片反射器的反射旋转

By introducing the calculation formula of reflected rotation angle, Rγβ, for linear polarized light in dielectric and absorption medium, it is confirmed that the amplitude of the reflected light shift nearly always towards the normal of incidence plane. The following conclusions may be drawn after the calculations of reflected rotation angles with respect to a variety of glass reflectors: (1) Glass reflectors coated by films of high refractive index are preferable because they havethe minimum reflected rotation. (2) When quantitative measurement of optical constants of opaque minerals is to be made, the polarizer of the ore microscope should be strictly oriented in E--W direction and special precautions are required in order to aviod any shifting from this position.     

CO_2 Density-Raman Shift Relation Derived from Synthetic Inclusions in Fused Silica Capillaries and Its Application

Abstract: The densities of CO2 inclusions in minerals are commonly used to determine the crystallizing conditions of the host minerals. However, conventional microthermometry is difficult to apply for inclusions of small size (< 5–10 μm) or low density. Raman analysis is an alternative method for determining CO2 density, provided that the CO2 density–Raman shift relation is known. This study aims to establish this CO2 density–Raman shift relation by using CO2 inclusions synthesized in fused silica capillaries. By using this newly-developed synthetic technique, we formed pure CO2 inclusions, and their densities were determined by microthermometry. The Raman analysis showed that the relation between CO2 density (D in g/cm3) and the separations (Δ in cm?1) between the two main bands (i.e. Fermi diad bands) in CO2 Raman spectra can be represented by a cubic equation: D (g/cm3)=0.74203(?0.019Δ3+5.90332Δ2?610.79472Δ+21050.30165)?3.54278 (r2=0.99920). Our calculated D value for a given Δ is between those obtained from two previously-reported equations, which were derived from different experimental methods. An example was given in this study to demonstrate that the densities of natural CO2 inclusions that could not be derived from microthermometry could be determined by using our method.     

A Comparative Study of Numercial Solution of PDE inGeosciences

A number of phenomena and processes in geosciences can be summarized by second order partial differential equations. The major numerical methods for their solution include the classical finite difference method and the finite element method newly developed in the last two or three decades. Since 1977 the author has proved that for the Laplace and Poisson equations, these two methods are identical and are different only in the process of formulation. For transient problems, such as heat conduction in the earth and the groundwater and oil-gas unsteady flow in porous media, there are some differences in resulting linear algebraic euqations. In general, two methods give similar results, but when the time step is decreased to some extent, the resulting algebraic equation will be consistent with the anti-heat conduction equation rather than the original heat conduction equation. This is the reason why unrealistic potentials are produced by the finite element method. Such a problem can be overcome by using the     

Study of the Stacking Sequences of an Irregular Mixed-Layer Illite/Smectite (I/S) Clay Mineral—with a Discussion on the Existence of Minerals with Two-Dimentional Lattice and One-Dimentional Quasi-Lattice

There are two aspects in the study of irregular mixed-layer clay minerals: one is the kinds and ratios of their basic structural unit layers and the other is the junction probabilities of the unit layers. Irregular mixed-layer illite/smectite clay minerals (I/S) are widespread in nature. While studying the clay minerals from the Permian-Triassic (P/T) boundary bed, the authors found that I/S clay minerals are developed in all P/T boundary clay layers in areas from the northwest to southeast of China. Systematic mineralogical studies of the I/S clay minerals from Hunan, Hubei, Sichuan and Zhejiang were made by means of X-ray, infrared spectroscopic, electron microscopic and chemical analyses and a deepened study of the stacking sequences of their structural unit layers was conducted by the MacEwan one—dimentional direct Fourier transform. It was found that the stacking of the illite and smectite crystal layers along the c axis can be derived from Fibonacci sequences. Hence, the authors propose that such I/S clay minerals are possessed of two—dimentional crystal lattice and one—dimentional quasicrystal lattice.     

Prediction of Overpressure Contributed Mainly by Structural Compression Using Impedance Inversion in Kuqa Depression, Tarim Basin

The origin and distribution of formation overpressure have effect not only on hydrocarbon migration and accumulation, but also on technique of drilling well. The study and prediction of overpressure are very important in basin analysis. At present, overpressure is mostly predicted by stack velocity.The process in calculating inter-velocity from stack velocity is very complex and inevitably leads to errors. Especially, this method is not available in the case that structural compression contribution to overpressure occurred. This paper introduces a new method, impedance inversion, to predict overpressure,and the principle is discussed. This method is used to predict the overpressure in Kuqa depression, Tarim basin and as a result, the absolute errors are less than 0.1, and relative errors are less than 5％ for predicted fluid pressure coefficients to the drill stem test (DST) measurements. It suggests that this method can be widely used to predict overpressure in foreland basins.     

Scaling Properties of Feldspar and Quartz in Micro-images of Ideal Granites

The properties of feldspar and quartze are studied in this article from a fractal point of view using gray-scale micro-images of granite samples collected at the Fangshan (房山) granite body in Hebei (河北) Province, China, which can be regarded as an ideal granite in the sense of Vistelius. We found that there exist power-law relationships between the eigenvalues of the gray-scale matrices and their ranks for the feldspar and quartz. The fractal model used here is a λ-R model similar to the N-λ model proposed by Qiuming Cheng in 2005. Meanwhile, we found that average variances for the gray-scale matrices of feldspar are larger than those of quartz on the same sections, and this may be useful for auto-identification of feldspar and quartz as well as other minerals.     

Multiwave Amplitude Compensation and Its Sensitivity Analysis to AVO Inversion in Viscoelastic Media

We derive formulae of correction for multi-wave geometric spreading and absorption in lay-ered viscoelastic media,this provides the theoretical foundation for true amplitude compensation of field data and for our sensitivity analysis.The imaging matrix at a plane reflector between viscoelastic media can be determined in the frequency domain using linearized reflection coefficients through Born approxi-mation.We quantiqatively analyze the sensitivity by studying eigenvalues and eigenvectors of the imaging matrix.The results show that two linear combinations of petrophysical parameters can be determined from the multi-wave AVO inversion in the case of amplitude compensation.Multi-wave AVO contains the information of attenuation in the media.However,the sensitivity of multi-wave AVO inversion to at-tenuation is small.     

Stratigraphic Division and Correlation of the Nihewan Beds by Multivariate Statistical Analysis

Described in paper is the principle of optimal partitioning method for stratigraphic division and correlation.The Nihewan Beds are taken for example to show how to apply this approach in stratigraphic division and correlation.The semiquantitative spectral analysis data on aggregate trace elements in 324 samples taken from the nine sections in the Nihewan Basin are treated with multivariate statistical method for stratigraphic division and correlation.First ,the data from all the sections are respectively calculated by the optimal partitioning method to establish the stratigraphic boundaries.The optimal partitioning method has proved itself to be applicable to stratigraphic division and correlation. In our practice the Nihewan Beds are divided into five zones (I-V).Zone I includes subzones Ia and Ib,Zones Ia,Ib,II and III are considered to be corresponding to the Pliocene(N2),the early Early Pleistocene,the late Early Pleistocene,and the Middle Pleistocene,respectively .Zones IV and V are probably Late Pleistocene in age.This indicated that sediments deposited con-temporaneous in the sections of the same basin are similar in geochemical characteristics,although dif-ferent in geographical location.However,the sediments also show some variations ,with a transitional relationship from one section to another .For example ,in Zone II,the sediments of the Xiaodukou section show not only the characteristics of the Nangou-Hongya and Hutouliang sections,but also those of the Xiashagou,Shixiaxi,Shixiadong and Wulitai sections.It can be seen from the above that the zones can be characteristically correlated with one another.In addition the feasibility of the optimal partitioning method is also described in the present paper.     

岩浆岩体系氧同位素分馏系数的理论计算

The increment method is applied to calcuation of oxygen isotope fractionation factors for common magmatic rocks by using oxygen isotope indices for known minerals.The results show that there are some differences in the degree of ¹⁸O-enrichment for the different types of magmatic rocks,and their sequence of ¹⁸O-enrichment is reckoned as follows acid rocks > neutral rocks > basic rocks > ultrabasic rocks.Two sets of internally consistent fractionation factors for phenocryst-lava systems at temperacture above 1000K and for rock-water systems in the temperature range of 0 to 1200℃ are acquired, respectively.The theoretical calibrations are consistent with the data from hydrothermal experiments and empirical estimates.The present results can be used to quantitatively determine the history of water-rock exchange and to serve geological thermometry for various magmatic rocks (especially extrusive rocks containing phenocryst).     

REE Tetrad Effects in Rare—metal Granites

Described in this paper are the characteristics of tetrad effects of REE in rare-metal granites.Based on the analytical data and experimental geochemical data available,it is pointed out that the tetrad effects of REE in the granites are produced in the metal-fluid system.Intense fractional crystallization of granitic melt(containing REE accessary minerals)and its interaction with volatile-rich(F,Cl)fluid are the major factors leading to the tetrad effects of REE.From this,this paper presents a composite genetic model for high-degree fractional crystallization-volatile-rich fluid metasomatism of rare-metal granites.With the model,quantitative calculations have been made.Meanwhile,it is pointed out that the tetrad effects of REE can be used as an important indicator to distinguish mineralized granites from barren ones.     

Using pore-solid fractal dimension to estimate residual LNAPLs saturation in sandy aquifers: A column experiment

The“tailing”effect caused by residual non-aqueous phase liquids(NAPLs)in porous aquifers is one of the frontiers in pollution hydrogeology research.Based on the current knowledge that the residual NAPLs is mainly controlled by the pore structure of soil,this study established a method for evaluating the residual saturation of NAPLs by investigating the fractal dimension of porous media.In this study,the soil column experiments of residual light NAPLs(LNAPLs)in sandy aquifer with different ratios of sands and soil were carried out,and the correlation between the fractal dimension of the medium,the residual of LNAPLs and the soil structure parameters are statistically analyzed,and its formation mechanism and main control factors are discussed.The results show that:Under our experimental condition:(1)the fractal dimension of the medium has a positive correlation with the residual saturation of NAPLs generally,and the optimal fitting function can be described by a quadratic model:S_R=192.02 D2-890.73 D+1040.8;(2)the dominant formation mechanism is:Smaller pores in the medium is related to larger fractal dimension,which leads to higher residual saturation of NAPLs;stronger heterogeneity of the medium is related to larger fractal dimension,which also leads to higher residual saturation of NAPLs;(3)the micro capillary pores characterized by fine sand are the main controlling factors of the formation mechanism.It is concluded that both the theory and the method of using fractal dimension of the medium to evaluate the residual saturation of NAPLs are feasible.This study provides a new perspective for the research of“tailing”effect of NAPLs in porous media aquifer.     

重砂元素分析与趋势面分析

Summing up the abundant experience obtained by the author through many years of his work in mineral separation, an inversion formula has been proposed for calculating the element content in a sample and thus the proportion of minerals containing those elements in the sample. In terms of this inversion formula, the proportion of associated minerals containing the analyzed elements in the sample can be worked out.Long-term practice has proved that if the elcments analyzed quantitatively excees the defined limits, it will be shown that there exist independent minerals in the analyzed sample, and in the opposite case, it may be indicated that there is no presence of such minerals. The element content mainly depends on the type, proportion and grain-size of host minerals. The approach highly sophisticates the traditional method, by which one can not only know the association relations of minerals, but also get sights into the relative proporthin of associated minerals, thus making a very big step in the study of mineral associations from qualitative to quantitative level.     

我国南海北部湾第三系粘土岩中有机物的赋存状态及其与生油关系的探讨

The chemistry of organo-clay in somc Tertiary clay-stones from the northern part of the South China Sea was studied. The preliminary results are summarized as follows : (1) Three basic types of organic matter are distinguished in the claystones after treated with different chemical agents: spluble, combined and insoluble (kerogen). It is suggested that the distribution of organic matter and its conversion to petroleum are closely related with the composition and structure of expansive clay minerals in the claystones. Therefore, more detailed studies of these expansive clay minerals may provide new indices for oil-generating potentiality. (2) It is considered from the study of the state of existence of organic matter and. of organo-clay complexes in tile clay-stones that the accumulation and preservation of organic substances may substantially take the form of organo-clay complexes in the process of sedimentation and burial and that the organo-clay complexes may make considerable contributions to the formation of petroleum hydrocarbons during diagenesis. Studies in this aspect are of great significance in developing new theories conccrning petroleum generation and in localizing oil-generating occurrences.     

Deep Minerals in Ophiolitic Mantle Peridotites:Discovery and Progress

In the classic theory of plate tectonics, ophiolitic mantle peridotites (i.e., abyssal peridotite) are thought to originate in the shallow mantle beneath ocean spreading centers.Diamonds and other UHP minerals have been found in opholitic mantle peridotites and chromitites along the Neo-Tethyan Yarlung Zangbo suture of southern Tibet, and in a Paleozoic ophiolite in the Polar Urals of Russia,suggesting that UHP minerals may be widespread in ophiolitic peridotites.Diamonds from these different localities all have very similar features in C isotope and mineral inclusions,and are distinct from the other two well known types, i.e. kimberlitic diamonds and UHP metamorphicdiamonds. The occurrence of diamond in ophiolite indicate a completely new environment for diamond formation, which can be regarded as ophiolite-type diamond. These new findings indicate a need to reconsider the nature of the upper mantle and the conditions under which ophiolites form.     

In-ground environmental radioactivity monitoring in the Culpeper Basin,Virginia, using LiF thermoluminescence dosimeters

A new environmental in-ground radioactivity monitoring technique using LiF thermoluminescence dosimeters was tested in the Culpeper Basin, Northern Virginia. The dosimeters were buried at a depth of 0.45 m (∼ 18 in.) for approximately four months. There was a significant positive correlation (at the 99.9% confidence level) between the total accumulated radioactivity signal from the dosimeters and the on-site 100 second gamma-ray spectrometer measurements. The minimum-maximum dose rate from the buried thermoluminescence dosimeter measurements was 0.06 to 1.08 mR per day (or 2.5 to 44.5μR per hour). There are two factors which permit better background levels of radioactivity to be established by thermoluminescence dosimeters compared with other methods for environmental monitoring programs. First is the great sensitivity of thermoluminescence dosimeters in terms of minimum dose rate that can be registered (mR per month orμR per hour). Second is the fact that accumulation of radioactivity signal over a long period of time tends to eliminate short-term environmental changes that affect measurements with gamma-ray spectrometers and scintillation counters.     

Characterizing Fracture Spatial Patterns by Using Semivariograms

Semivariogram is applied to fracture data obtained from detailed scanline surveys of nine field sites in western New York, USA in order to investigate the spatial patterns of natural fractures. The length of the scanline is up to 36 m. How both fracture spacing and fracture length vary with distance is determined through semivariogram calculations. In this study, the authors developed a FORTRAN program to resample the fracture data from the scanline survey. By calculating experimental semivariogram, the authors found five different types of spatial patterns that can be described by linear, spherical, reversed spherical, polynomial I (for a<0) and polynomial II (for a>0) models, of which the last three are newly proposed in this study. The well-structured semivariograms of fracture spacing and length indicate that both the location of the fractures and the length distribution within their structure domains are not random. The results of this study also suggest that semivariograms can provide useful infor     

Error Propagation in Geochemical Calculations of Groundwater-Mineral Interactions: A Case Study from the Pingdingshan Coalfield, Henan

The WATEQ4F-based "multiple step method", or the method of running WATEQ4F repeatedly, was used to evaluate the error propagation in computations of water-mineral interactions under the circumstances of constant and varied temperatures due to the uncertainties of input variables. The results show the following: the errors of water chemistry analysis can strongly affect the modelling results of water-mineral reactions; different input variables (errors) have different effects on the saturation indices (S.I.) of different minerals; in many cases, the S.I. errors of minerals change with temperatures.     

Discovering Crustal Deformation Bands by Processing Regional Gravity Field

Objectives: This article presents a new computational procedure to discover scratches buried in the earth's crust. We also validate this new interdisciplinary analysis method with regional gravity data located in a well-known Dabie orogenic zone for test. Methods: Based on the scratch analysis method evolved with mathematical morphology of surfaces, we present a procedure that extracts information of the crustal scratches from regional gravity data. Because the crustal scratches are positively and highly correlated to crustal deformation bands, it can be used for delineation of the crustal deformation belts. The scratches can be quantitatively characterized by calculation of the ridge coefficient function, whose high value traces delineate the deformation bands hidden in the regional gravity field. In addition, because the degree of crustal deformation is an important indicator of tectonic unit divisions, so the crust can be further divided according to the degree of crustal deformation into some tectonic units by using the ridge coefficient data, providing an objective base map for earth scientists to build tectonic models with quantitative evidence. Results: After the ridge coefficients are calculated, we can further enhance the boundary of high ridge-coefficient blocks, resulting in the so-called ridge-edge coefficient function. The high-value ridge-edge coefficients are well correlated with the edge faults of tectonic units underlay, providing accurate positioning of the base map for compilation of regional tectonic maps. In order to validate this new interdisciplinary analysis method, we select the Dabie orogenic zone as a pilot area for test, where rock outcrops are well exposed on the surface and detailed geological and geophysical surveys have been carried out. Tests show that the deformation bands and the tectonic units, which are conformed by tectonic scientists based on surface observations, are clearly displayed on the ridge and ridge-edge coefficient images obtained in this article. Moreover, these computer-generated images provide more accurate locations and geometric details. Conclusions: This work demonstrates that application of modern mathematical tools can promote the quantitative degree in research of modern geosciences, helping to open a door to develop a new branch of mathematical tectonics.     

Applications of Error Propagation Analyses to Geochemical Calculation

Two examples are given for comparing applications and limitations of four methods which can be used to deal with error propagation in geochemical calculations.The examples indicate that the Monte Carlo method can also be employed to evaluate the effect of covariance.A special function of the method for covariance matrix shown here can reveal the correlations of middle variables relative to the independent primary variables.     

The Study of Deep Mineral Association in Chromitites of the Hegenshan Ophiolite, Inner Mongolia, China

<正>Previously reported in the Mesozonic Tibet and the early Paleozoic Polar Ural,Russia,diamond and other deep minerals are found in ophiolite mantle peridotite chromite that need to be reconsidered ophiolite and chromite traditional understanding of the causes of shallow.The ophiolitic chromitite can be divided two classes,the high-Cr chromitite and high-Al chromitite.