Effect of hot desert weathering on the bulk‐rock iron isotope composition of L6 and H5 ordinary chondrites

Abstract– Although iron isotopes are increasingly used for meteorites studies, no attempt has been made to evaluate the effect of terrestrial weathering on this isotopic tracer. We have thus conducted a petrographic, chemical, and iron isotopic study of equilibrated ordinary chondrites (OC) recovered from hot Moroccan and Algerian Saharan deserts environment. As previously noticed, we observe that terrestrial desertic weathering is characterized by the oxidation of Fe‐Ni metal (Fe⁰), sulfide and Fe²⁺ occurring in olivine and pyroxene. It produces Fe‐oxides and oxyhydroxides that partially replace metal, sulfide grains and also fill fractures. The bulk chemical compositions of the ordinary chondrites studied show a strong Sr and Ba enrichment and a S depletion during weathering. Bulk meteoritic iron isotope compositions are well correlated with the degree of weathering and S, Sr, and Ba contents. Most weathered chondrites display the heaviest isotopic composition, by up to 0.1‰, which is of similar magnitude to the isotopic variations resulting from meteorite parent bodies’ formation and evolution. This is probably due to the release of isotopically light Fe²⁺ to waters on the Earth’s surface. Hence, when subtle Fe isotopic effects have to be studied in chondrites, meteorites with weathering grade above W2 should be avoided.     

NanoSIMS studies of Ba isotopic compositions in single presolar silicon carbide grains from AGB stars and supernovae

Abstract— We have studied 74 single presolar silicon carbide grains with sizes between 0.2 and 2.6 μm from the Murchison and Murray meteorites for Ba isotopic compositions using NanoSIMS. We also analyzed 7 SiC particles either consisting of sub‐micron‐size SiC grains or representing a morphologically and isotopically distinct subgroup. Of the 55 (likely) mainstream grains, originating from asymptotic giant branch (AGB) stars, 32 had high enough Ba contents for isotopic analysis. For 26 of them, CsH_x interferences were either negligible or could be corrected with confidence. They exhibit typical s‐process Ba isotopic patterns with slightly higher than solar ¹³⁴Ba/¹³⁶Ba and lower than solar ^135,137,138Ba/¹³⁶Ba ratios. Results are generally well explained in the context of neutron capture nucleosynthesis in low mass (1–3 M_⊙) AGB stars and provide constraints on AGB models, by reducing the needed ¹³C spread from factor of ～20 down to 2. Out of the 19 supernova X grains, three had sufficient concentrations for isotopic analysis. They tend to exhibit higher than solar ¹³⁴Ba/¹³⁶Ba and ¹³⁸Ba/¹³⁶Ba ratios, close to solar ¹³⁷Ba/¹³⁶Ba, and ¹³⁵Ba/¹³⁶Ba lower than solar but higher than in mainstream grains. This signature could indicate a mixture of n‐burst type Ba with either “normal Ba” more s‐process‐rich than solar, or normal Ba plus weak s‐process Ba. In the n‐burst component Cs may have to be separated from Ba at ～10 years after the SN explosion. Depending on predictions for its composition, another possibility is early separation (at ～1 year) coupled with addition of some unfractionated n‐burst matter. Abundances of trace elements (Sr, Zr, Cs, La, and Ce) analyzed along with Ba signify that implantation may have been an important process for their introduction.     

Orbital elements of the mild and strong barium stars formed through a wind accretion scenario

Taking account of the metallicity dependence of the s-process nucleosynthesis in the AGB stars, we adopted the wind accretion model with the condition of total angular momentum conservation and used the Monte-Carlo method to study the variations and the distributions of the orbital elements of the mild and strong Ba stars. The calculated results show that the level of heavy-element overabundance in a Ba star depends on the orbital period. Since there is a strong dependence of s-process yields on the initial stellar metallicity of the AGB star and a strong increase of the s-process yields in AGB stars with decreasing metallicity, the calculated results strongly suggest that the initial metallicity of the Ba star systems is another important parameter for the level of heavy-element overabundance in a Ba star. The strong Ba stars generally have lower metallicities than mild Ba stars. The masses of AGB progenitor and Ba star are other two parameters which also have some impact on the heavy-element overabundance in the Ba star.     

An explanation of the correlations of abundance ratio between neutron-capture elements and iron group elements in Ba stars

The chemical abundances of the Ba stars are excellent information for setting constraints on models of s-processes nucleosynthesis. In this work, we adopt a new analysis approach to determine the relative contributions from individual neutron-capture processes to the elemental abundances of Ba stars. We find that the production of s-process elements should accompany by the production of Cu and Zn, the calculated results on Cu and Zn abundances are in quite good agreement with observed data. The observed [Cu, Zn/Fe]–[s/Fe] correlations of Ba stars can be explained by binary scenario in which Ba stars formed.     

High resolution study of the abundance pattern of the heavy elements in very metal‐poor field stars

The abundances of heavy elements in EMP stars are not well explained by the simple view of an initial basic “rapid” process. In a careful and homogeneous analysis of the “First Stars” sample (eighty per cent of the stars have a metallicity [Fe/H] ≃ –3.1 ± 0.4), it has been shown that at this metallicity [Eu/Ba] is constant, and therefore the europium‐rich stars (generally called “r‐rich”) are also Ba‐rich. The very large variation of [Ba/Fe] (existence of “r‐poor” and “r‐rich” stars) induces that the early matter was not perfectly mixed. On the other hand, the distribution of the values of [Sr/Ba] vs. [Ba/Fe] appears with well defined upper and lower envelopes. No star was found with [Sr/Ba] < –0.5 and the scatter of [Sr/Ba] increases regularly when [Ba/Fe] decreases. To explain this behavior, we suggest that an early “additional” process forming mainly first peak elements would affect the initial composition of the matter. For a same quantity of accreted matter, this additional Sr production would barely affect the r‐rich matter (which already contains an important quantity of Sr) but would change significantly the composition of the r‐poor matter. The abundances found in the CEMP‐r+s stars reflect the transfer of heavy elements from a defunct AGB companion. But the abundances of the heavy elements in CEMP‐no stars present the same characteristics as the the abundances in the EMP stars. Direct stellar ages may be found from radioactive elements, the precision is limited by the precision in the measurements of abundances from faint lines in faint stars, and the uncertainty in the initial abundances of the radioactive elements. (© 2014 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Ba II lines as luminosity indicators: s-Cepheids and non-variable supergiants

Ba II line equivalent widths appear to be well correlated with the absolute magnitudes for yellow supergiants. Two Ba II lines 5853.6 Å and 6141.7 Å were applied for investigation of the possible relation between their equivalent widths and M_v for small-amplitude Cepheids and non-variable supergiants.     

A Statistical Model for Predicting the Average Abundance Patterns of Heavier Elements in Metal-Poor Stars

We have collected nearly all the available observed data of the elements from Ba to Dy in halo and disk stars in the metallicity range -4.0 <[Fe/H]< 0.5. Based on the observed data of Ba and Eu, we evaluated the least-squares regressions of [Ba/Fe] on [Fe/H], and [Eu/H] on [Ba/H]. Assuming that the heavy elements (heavier than Ba) are produced by a combination of the main components of s- and r-processes in metal-poor stars, and choosing Ba and Eu as respective representative elements of the main s- and the main r-processes, a statistical model for predicting the Galactic chemical evolution of the heavy elements is presented. With this model, we calculate the mean abundance trends of the heavy elements La, Ce, Pr, Nd, Sm, and Dy with the metallicity. We compare our results with the observed data at various metallicities, showing that the predicted trends are in good agreement with the observed trends, at least for the metallicity range [Fe/H]> -2.5. Finally, we discuss our results and deduce some importa     

Deficiencies in the classical model of s-process nucleosynthesis

Abstract— The classical model of s-process nucleosynthesis, based on the concept of a steady neutron flux under astrophysical conditions pertaining to the He-burning phase of red giant stars, has successfully described observed isotopic abundances and provided information on the physical conditions of the s-process environment. Because most of the isotopes on the s-process path are stable, their relevant nuclear parameters can be measured in the laboratory so that as more accurate elemental abundance and neutron capture cross-section data have become available, the classical model has been tested under increasingly stringent conditions. Accurate determinations of the neutron capture cross sections at appropriate astrophysical conditions for the Ba isotopes have shown that the abundance of the s-only isotope ¹³⁶Ba is under-produced by ～20% according to the classical model. This paper describes the accurate assessment of the meteoritic abundance of Ba by the stable isotope dilution mass spectrometric technique, based on the Cl carbonaceous chondrites Orgueil and Ivuna. Repeated analyses of these two Cl chondrites give an abundance that is identical to the presently accepted solar system value for Ba within experimental errors, which indicates a deficiency in the classical model. When combined with similar data for the s-only nuclides ¹¹⁶Sn and ¹⁴²Nd, it is apparent that the classical model, having served a valuable function for many years, must be replaced by stellar models that more accurately reflect the dynamic nature of the He-burning phase in red giant stars, in particular, during the thermal pulses of low-mass asymptotic giant branch (AGB) stars.     

An interdisciplinary study of weathering effects in ordinary chondrites from the Acfer region,Algeria

Abstract— Weathering effects on meteorite finds from the Acfer region were studied by various analytical techniques and in dependence on the depth of sampling. In thin sections of weathered meteorites, weathering effects usually decrease from the outside to the interior of the meteorite. The results of evolved gas analysis indicate that variation in weathering between surface and core is not significant in respect to the formation of Fe-oxyhydroxides. The secondary alteration effects in the noble gases are distributed unevenly throughout the specimens, as seen in the nonsystematic differences observed for the heavy noble gases. Chemical analyses show significant enrichment of Ba and Sr in the outer parts of the weathered samples due to element contamination through aqueous solution. Iron, Ni, and Co are partly flushed from the system as the metal oxidation proceeds. Oxygen isotopes show increases in δ¹⁸O and δ¹⁷O with increasing terrestrial age. For a set of H3 chondrites, the degree of weathering determined from the water content was correlated with terrestrial ages and is discussed with respect to possible weathering mechanisms.     

Nebular complex in the region of Cas OB2 association; ring nebula Sh157

This paper presents the results of monochromatic [Oiii], [Nii], and [Sii] observations of ring nebula Sh157 around the star (WR + B0III) HD 219460 belonging to the Ba 3 cluster. A stratification of radiation typical for photoionization excitation has been revealed. The observations suggest that the Sh157 ring structure may arise as a result of the HD 219460 stellar wind blowing the surroundingHii region, and the bubble age is found to bet(2–5)×10⁵ yr. Three outer envelopes have been distinguished: a weaker extended emission shell apparently blown out by the wind from B-stars of the Ba 3 cluster, and two dust shells which are likely to be associated with NGC 7510 and Cas OB2. The paper is also concerned with the discussion of young star aggregates Ba 3, NGC 7510, Cas OB1, OB2, OB4, OB5, OB7, and Cep OBI and the associatedHii regions, shells and supershells of gas and dust, molecular clouds, and supernova remnants which may be probable members of a single giant stellar complex where the star formation process is in progress.     

Sensitivity of Selected Ba <Emphasis Type="SmallCaps">ii</Emphasis>, Fe <Emphasis Type="SmallCaps">i</Emphasis>, Fe <Emphasis Type="SmallCaps">ii</Emphasis>, and Cr <Emphasis Type="SmallCaps">i</Emphasis> Spectral Lines to Velocity in Quiet Solar Atmosphere

We examine the sensitivity of selected Ba?ii, Fe?i, Fe?ii, and Cr?i spectral lines to changes of the line-of-sight velocity by sharpness of their line profiles and response functions to line-of-sight velocity evaluated by the 1-D model of the quiet solar atmosphere in the LTE approximation. The set of selected lines includes the Ba?ii 4554 Å line, generally considered to be an excellent Doppler mapper. Our findings confirm earlier results showing that the sensitivity increases not only with wavelength, as anticipated from the Doppler relation, but mainly with the sharpness of line profiles given by the ratio of their depths and widths. The line Fe?i 5247 Å is the most sensitive in our set, whereas the Fe?i and Fe?ii infrared lines show very low sensitivity because of their large thermal widths. The line Ba?ii 4554 Å shows only moderate sensitivity due to its large width, given by a broad hyperfine structure and isotopic split. For the first time we identify a very promising and so far unknown Doppler mapper of the solar photosphere and low chromosphere, which is the line Ba?ii 6497 Å. Its sensitivity is comparable with the sensitivity of Fe?i 5247 Å and clearly surpasses the sensitivity of Ba?ii 4554 Å. The line Ba?ii 6497 Å offers many advantages, making it a highly recommendable choice for future studies of line-of-sight velocities in the photosphere and low chromosphere.     

A PROCESS OF STELLAR NUCLEOSYNTHESIS WHICH MIMICKS MASS FRACTIONATION IN P-XENON

The combination of the O-shell theory of Heymann and Dziczkaniec and the supernova theory of Woosley and Howard clearly identifies the astrophysical sites for the formation of the anomalous light Xe component in carbonaceous chondrites. These sites are the O- and Ne-shells, and possibly C-shell of a massive star. Most of the ¹²⁴Xe and ¹²⁶Xe are formed in the O-shell during hydrostatic core silicon-burning, when a seed of heavy nuclei is exposed to an effective temperature near T₉ = 2.0. ¹²⁸Xe is formed via ¹²⁸Ba in the O-shell, but the amounts appear too small to satisfy the deduced ¹²⁸Xe/¹²⁴Xe and ¹²⁸Xe/¹²⁶Xe yield ratios from the chondrites. However, substantial amounts of ¹²⁸Xe can be formed in the adjacent Ne- and C-shells during the explosion. The formation of ¹²⁸Ba in the O-shell would increase if the (γ, α) photodisintegration rate in ¹²⁸Ba is actually smaller than calculated by Woosley and Howard. Lewis et al. have proposed that the anomalous light Xe component is mass-fractionated normal Xe. It is in this sense that the process of stellar nucleosynthesis of the present paper mimicks mass-fractionation.     

The photospheric barium spectrum: Solar abundance and collision broadening of Baii lines by hydrogen

A study of the solar Ba ii spectrum leads to a solar abundance of barium of log ba = = 2.11±0.12, on the scale log h = 12. The observed asymmetry of the resonance line 4554 is consistent with an isotopic abundance ratio equal to the terrestrial one. The meteoritic Ba/Si abundance ratio found in carbonaceous chondrites appears to exceed the solar ratio by 0.1 to 0.2 dex (Section 5).The broadening by collisions with hydrogen atoms is determined from the solar spectrum (Section 4). Damping half-widths, h, of the three stronger Ba ii lines turn out to be larger by a factor of about 3.0 than predicted from pure van der Waals interaction of dipoles. Departures from LTE appear to be present in the cores of the resonance lines and of the lines arising from the metastable 5D levels (Section 6). The equivalent widths, however, remain practically unaffected.Equivalent widths of neutral barium lines are predicted and some new identifications of photospheric Ba i lines are suggested (Section 7).     

Periodic variations of the Ba II 4554 Å and Ca II 8542 Å line profiles in coronal holes

The oscillations of the half-width of the Ba II 4554 ? and Ca II 8542 ? spectral lines have been analyzed using observations at the base of solar coronal holes (CHs). The observed variations (~50 m ? for Ca II and ~4 m ? for Ba II) exceed considerably the thermal broadenings of these lines calculated from the measured intensity oscillations, suggesting their nonthermal nature. We point out a number of observational facts that hamper an unambiguous interpretation of the periodic Ba II and Ca II profile variations solely by the manifestation of torsional Alfve´ n waves in the lower solar atmosphere.     

The evolution of barium and europium in local dwarf spheroidal galaxies

By means of a detailed chemical evolution model, we follow the evolution of barium (Ba) and europium (Eu) in four Local Group Dwarf Spheroidal (dSph) galaxies, in order to set constraints on the nucleosynthesis of these elements and on the evolution of this type of galaxies compared with the Milky Way. The model, which is able to reproduce several observed abundance ratios and the present-day total mass and gas mass content of these galaxies, adopts up-to-date nucleosynthesis and takes into account the role played by supernovae (SNe) of different types (II, Ia) allowing us to follow in detail the evolution of several chemical elements (H, D, He, C, N, O, Mg, Si, S, Ca, Fe, Ba and Eu). By assuming that Ba is a neutron-capture element produced in low-mass asymptotic giant branch stars by s-process but also in massive stars (in the mass range 10–30 M_⊙) by r-process, during the explosive event of SNe of Type II, and that Eu is a pure r-process element synthesized in massive stars also in the range of masses 10–30 M_⊙, we are able to reproduce the observed [Ba/Fe] and [Eu/Fe] as functions of [Fe/H] in all four galaxies studied. We confirm also the important role played by the very low star formation (SF) efficiencies (ν= 0.005–0.5 Gyr⁻¹) and by the intense galactic winds (6–13 times the star formation rate) in the evolution of these galaxies. These low SF efficiencies (compared to the one for the Milky Way disc) adopted for the dSph galaxies are the main reason for the differences between the trends of [Ba/Fe] and [Eu/Fe] predicted and observed in these galaxies and in the metal-poor stars of our Galaxy. Finally, we provide predictions for Sagittarius galaxy for which data of only two stars are available.     

Non-LTE sodium abundance in galactic thick- and thin-disk red giants

The non-LTE sodium abundance has been determined from the Na I 6154 and 6161 Å lines for 38 thin-disk stars (15 of them are Ba II stars), 15 thick-disk stars, 13 Hercules-stream stars, and 13 stars that cannot be attributed neither to the thick Galactic disk nor to the thin one. The Na I model atom has been constructed using the most accurate present-day atomic data. For the Na I 6154 and 6161 Å lines, the non-LTEabundance corrections are from ?0.06 to ?0.24 dex, depending on the stellar parameters. No differences in [Na/Fe] abundance between the thick and thin disks have been detected; the derived ratios are close to the solar ones. The existence of a [Na/Fe] overabundance in the Ba II stars has been confirmed. The Hercules-stream stars exhibit nearly solar [Na/Fe] ratios. The results obtained can be used to test the sodium nucleosynthesis models.     

Rare-earth elements in matrix,inclusions, and chondrules of the Allende meteorite

Rare-earth elements in a whole-rock sample and in major components of the Allende meteorite were investigated; for a few samples, abundances of Ba, Sr, Ca, and Al were also determined. Of the materials investigated in the present work, CaAl-rich inclusions G and O seem to be of the greatest significance. In spite of the minor difference in mineralogy between them, the apparent chondrite-normalized RE pattern is much different between these two inclusions. (Yb and Eu in inclusion G appear exceptionally irregular). This observation is inferred to reflect a rather subtle difference in condition of condensation. It is also worthwhile to note that, while two portions (pink and white) of the inclusion G show similar aspects in the abundances of lithophile trace elements investigated, they show a remarkable difference at the same time. The white portion (G_w) of inclusion G can be considered to be a mixture of chondritic material and highly fractionated material like the faintly pink portion (G_p) picked from the same inclusion. This would suggest the possibility that the G_p-like material was produced from chondritic dust.The “matrix” separated from Allende was found to be fractionated with respect to the RE abundances relative to representative chondrite. It has also a very high value for the Ba abundance.     

Diagnostics of the solar atmosphere by the Non-LTE inversion method: Line of Ba II λ 455.403 nm

The inverse problem of nonequilibrium radiative transfer in the Ba II λ 455.403 nm line is solved taking into account the hyperfine structure and isotopic splitting. Diagnostic capabilities of this line for the study of the solar atmosphere are investigated based on the three-dimensional hydrodynamic model. It is shown that the use of inversion methods for the analysis of the observed Ba II λ 455.403 nm line makes it possible to reproduce physical conditions in the layers of the photosphere and the lower chromosphere (0 < h < 600 km) with a correlation coefficient of 0.9.     

Empirical NLTE analyses of solar spectral lines

The center-to-limb behaviour of the Ba ii 4554 resonance line is analyzed together with data from the extreme limb, flash intensities and profiles of other Ba ii lines. An empirical NLTE method is employed in which the observed profiles are compared with synthesized profiles based on a standard one-dimensional model atmosphere, with the line source function, the barium abundance, the collisional damping and the atmospheric turbulence as free parameters.The line profiles from the extreme limb furnish considerable constraints on the formation of Ba ii 4554. Its wings reverse into emission well inside the solar limb, a phenomenon which cannot be explained by any frequency-independent line source function. Accounting for effects of partially coherent scattering in the line source function is a necessary and adequate step to reproduce the observations both over the disk and near the limb. The form of the empirically derived frequency-dependent line source function is discussed.Results are given for various parameters (gf-values, solar barium abundance and isotope ratios, collisional damping, microturbulence and macroturbulence).The 4554 profile of disk center shows a depression in its blue wing resembling asymetries found in various stellar spectral lines.     

Abundance analysis of Barium stars

We obtain the chemical abundances of six barium stars and two CH subgiant stars based on the high signal-to-noise ratio and high resolution Echelle spectra. The neu- tron capture process elements Y, Zr, Ba, La and Eu show obvious overabundances relative to the Sun, for example, their [Ba/Fe] values are from 0.45 to 1.27. Other elements, in- cluding Na, Mg, A1, Si, Ca, Sc, Ti, V, Cr, Mn and Ni, show comparable abundances to the Solar ones, and their [Fe/H] covers a range from -0.40 to 0.21, which means they belong to the Galactic disk. The predictions of the theoretical model of wind accretion for bi- nary systems can explain the observed abundance patterns of the neutron capture process elements in these stars, which means that their overabundant heavy-elements could be caused by accreting the ejecta of AGB stars, the progenitors of present-day white dwarf companions in binary systems.