东太平洋粘土沉积物的增白实验研究和结构分析

为了有效开发利用深海粘土，必须针对东太平洋粘土的特点提高其自度和活性。对东太平洋中国大洋调查区粘土沉积物进行湿法提纯后，采用酸溶氢气法以锌做还原剂对其进行了增白处理，并在不同温度下焙烧；分析了酸的类型、浓度、还原剂用量、反直时间及焙烧温度等对粘土增自效果的影响，得出了最佳工艺条件；测定增白前后粘土的物理化学性能和粘土矿物的结构，发现增自的同时还可以提高粘土的比表面积和其在有机溶剂中的分散性；增白后粘土矿物总体上保持了层状结构，但局部结构有一定的破坏，因而提高了粘土矿物的结构活性。     

Immersed tunnel foundation on marine clay improved by sand compaction piles

The sand compaction pile (SCP) method can be applied to soft marine clay ground that is a reinforcement of composite ground consisting of compacted sand piles and surrounding clay. The application of SCP method in the immersed tunnel of Hong Kong–Zhuhai–Macao Bridge verify SCP method is a robust solution to limit the total settlement and differential longitudinal settlement and to promote smooth transition from immersed tunnel to artificial island. The SCP method has significant settlement reduction effect on marine clay. The SCPs can also function as a drainage path to accelerate the consolidation process in marine clay. It is also found that the consolidation rate of SCP-improved ground is delayed compared with that predicted program which is most probably because of the soil disturbance effect during the installation of SCPs.     

Enhancing the mechanical properties of marine clay using cement solidification

Abstract

The use of soft clay and dredged marine clays as the construction material is challenging. This is because the high water content, high compressibility and low permeability of the clay causing the instability of ground and structure. This detrimental effect of soft clay can be improved by the cement solidification process, which is relatively cheap and efficient. This paper mainly focuses on the study of improvement on the mechanical behavior of cement mixed marine clay. The soil is reconstituted by using ordinary Portland cement of 5%, 10%, 15% and 20% by its mass. The study reveals that cementation of clay significantly improves the peak and residual strength of soil. Similarly, the primary yield stress of the soil is also improved from 16 to 275?kPa as cement content increases from 5% to 20%, respectively. By using statistical tools, the relationships between various parameters are established, which are very important to define the mechanical behavior of the clay. This study reveals that the yield surface of the solidified marine clay is not a smooth elliptical surface. Rather it is composed of two linear surfaces followed by a log-linear surface which can be modeled by using simple parameters obtained from triaxial tests.     

黏性土淹没射流破土实验研究

海底水力喷射开沟技术在海底管道、光缆埋设等工程中得到广泛应用,然而黏土尤其是硬质黏性土中的水力开沟施工较为困难,为阐明其中的破土机制,开展了二维垂向淹没射流开沟物理模拟实验。通过观察射流破土的过程,发现:软黏土与硬质黏性土中冲坑发展的特点有所不同,破土机制也存在差异。射流对硬质黏性土的破坏中,压力导致的剪切破坏起到很大作用,在土力学原理上近似于地基土整体剪切破坏,据此建立了硬质黏性土射流破土模型,同时提出冲坑颈口直径在硬质黏性土冲坑形态中的重要性,并以此取代原有的冲坑直径作为一个预测指标。     

Study on the Adsorption of Metal Ions by Immobilized Marine Algae with the Existence of Clay

The process of adsorption of metal ions by immobilized marine algae with the existence of clay was investigated. It can be noted from the results that, after mixing with clay, the adsorption rate increases rapidly with the increasing amount of the marine algae. When pH=5, the best ratio between the clay and the marine algae is 1：4 for Pb^2＋. The result of in situ handling of the waste water containing heavy metals shows that the average adsorption rates of heavy metal irons Cu^2＋, Cd^2＋, Pb^2＋ and Ni^2＋ are all over 70 %.     

长江三角洲地区第一古土壤层及其古气候记录

长江三角洲陆相硬粘土层含有典型土壤的特征,如粘粒胶膜、土壤新生体、裂隙和孔洞等,应为古土壤层。通过对土壤形成物分析发现,古土壤形成时,长江三角洲地区气候虽较现今寒冷,降雨量也有所减少,类似现今的温带气候,但当时干湿季节（时期）交替明显,地下水位升降频繁,可能是古季风活动的反映。土壤层中成土程度有强弱变化,植物硅酸体指示的气候有冷暖干湿之分,表明沉积和成土作用交替进行,因此成土作用能够改造已形成的土壤发生层,特别是冰期低海面时持续的成土作用进一步改造早期古土壤,致使土壤发生层分异不够明显。     

苏北盐城天然气储层成岩作用研究

盐城凹陷天然气储层为成分成熟度很低的砂砾岩、砾状砂岩、砂岩和少量粉砂岩,砂岩类型主要为长石岩屑砂岩和少量岩屑长石砂岩。成岩矿物主要类型有粘土矿物、石英、钠长石、碳酸盐、硬石膏和石膏等。储层以次生孔隙发育为特点,以粒间孔隙和骨架颗粒溶孔最为发育,溶解作用发育程度与泥质岩在成岩过程中粘土矿物和有机质的演化关系极其密切。盐城天然气进入储层发生在始新世———新近纪,主要成藏期发生在4.5~10Ma。天然气储层成岩演化阶段处于晚成岩A亚期。储层性质明显地受到沉积相和成岩作用的影响。沉积物粒度较粗、厚度较大的河道砂的储集物性明显优于各种粒度较细、厚度较薄的席状砂体。     

Microstructure analysis on the dynamic behavior of marine clay in the South China Sea

Abstract

The aim of this article was to study the dynamic behavior and microstructural variation of undisturbed marine clay from the South China Sea. First, dynamic cyclic triaxial tests were employed to investigate the dynamic stress–strain-pore pressure paths of the undisturbed clay. Then, scanning electron microscopy and mercury intrusion porosimetry were used to measure the variations of the micromorphology and pore size distribution between before and after the dynamic cyclic tests. Through these tests, the dynamic failure process and microstructure variation of the marine clay were quantitatively analyzed. In particular, their relationships are qualitatively established from the macro-micro perspective. Furthermore, by comparing the tests of the remolded clay with those of the undisturbed marine clay, the influence of the microstructure on the dynamic behavior is systematically investigated. The results show that the microstructural variation of the marine clay is caused by the compression deformation of the mesopores among the granular clusters into the small pores between individual particles. The study provides an effective reference for the selection of the microstructural parameters of marine clay.     

Effects of salinity and clay type on oil-mineral aggregation

Effects of salinity and clay type on the aggregation process of crude oil and clay particles (oil-mineral aggregates--OMA) were studied in the laboratory. OMA were generated by shaking various oil/clay mixtures in water at 20 degrees C and at a pre-determined energy level. Shape, median and maximum sizes, size distribution and concentration of oil droplets forming OMA were measured using epi-fluorescence microscopy. Results showed that the median and maximum sizes and the concentration of mineral-stabilized droplets increase rapidly when salinity increases from zero to a critical aggregation salinity in the range of 1.2-3.5 ppt. The magnitude of the increase of droplet size is controlled by clay type, while the increase of droplet concentration is influenced by oil type. Size distributions of oil droplets are self-similar, but their magnitudes depend on salinity and oil type. The effect of salinity on droplet size distribution is strongly influenced by clay type. Empirical relationships are derived to calculate concentration and size distribution of mineral-stabilized droplets.     

南海沉积岩芯中粘土矿物的研究

对南海中部5个沉积岩芯的粘土矿物做了定性分析和半定量估算。提出南海粘土矿物组合特征为陆架浅海型与大洋型间的过渡型,这一特征表明,南海沉积物以多源性为特征。研究指出,南海沉积岩芯中粘土矿物含量高低呈现出周期性的旋回变化,并且有可对比性,控制这种变化的主要因素是沉积过程中古气候冷暖的周期性旋回变化及其所影响的沉积环境的变化。     

Bearing capacity and critical punch-through depth of spudcan on sand overlying clay

Spudcan may experience punch-through failure on strong over weak layered soils, such as sand overlying clay. A large deformation finite element method （LDFE） is used to simulate the penetration process of spudcan into sand overlying clay. The sand is simulated by smoothed hyperbolic Mohr-Coulomb model, and the clay is simulated by a simple elasto-plastic model which obeys Tresca yield criterion. According to the LDFE results of a large amount of cases, the effects of the strength, unit weight and thickness of the top sand layer, as well as the effect of the strength of the underlying clay on the spudcan punch-through behavior, are investigated. The critical depth occurring punch-through and the critical bearing capacity are presented in charts. Fitting equations to calculate the critical punch-through depth and the critical bearing capacity are proposed for the convenience of engineering practice.     

Prediction to the Efficiency of Soft Clay Sample Preparation with Vacuum Loading

Vacuum loading has been examined as a way of preparing uniformly consolidated soft claysamples.The facility and loading procedure are described in this paper.An analytical solution to the threedimensional consolidation equation is derived for estimating the degree of consolidation of the soil samplewith vacuum loading.The given example shows that the predicted degree of consolidation of a soft claybulk with vacuum loading is close to that measured in the consolidation process.     

中印度洋海盆富稀土沉积地球化学特征及富集机制研究

本文对中印度洋海盆深海富稀土沉积区两根柱样GC02和GC06开展了沉积物涂片观察,X-射线衍射分析,主量、微量和稀土元素分析,以及单矿物原位微区地球化学分析等,探讨了其地球化学特征、物质来源及稀土元素(REY)的富集机制。结果表明,GC02柱状沉积物类型为钙质黏土和沸石黏土,GC06柱状沉积物类型为钙质黏土、含沸石黏土和沸石黏土。稀土元素主要在含沸石黏土和沸石黏土中富集。北美页岩标准化(NASC)配分模式指示沉积物的REY主要来源于海水,矿物学和地球化学等特征表明该地区沉积物陆源组分可能主要源于澳大利亚的风尘物质。元素相关性和CaO/P₂O₅比值等指示了深海富稀土沉积中REY的主要赋存矿物为生物磷灰石(鱼牙/骨等),其次为铁锰微结核。本文总结和探讨了深海富稀土沉积的形成机制,完善了深海富稀土沉积形成过程的概念模型。     

Numerical analysis of suction embedded plate anchors in structured clay

As offshore energy developments move towards deeper water, moored floating production facilities are increasingly preferred to fixed structures. Anchoring systems are therefore of great interest to engineers working on deep water developments. Suction embedded plate anchors (SEPLAs) are rapidly becoming a popular solution, possessing a more accurate and predictable installation process compared to traditional alternatives. In this paper, finite element analysis has been conducted to evaluate the ultimate pullout capacity of SEPLAs in a range of post-keying configurations. Previous numerical studies of anchor pullout capacity have generally treated the soil as an elastic-perfectly plastic medium. However, the mechanical behaviour of natural clays is affected by inter-particle bonding, or structure, which cannot be accounted for using simple elasto-plastic models. Here, an advanced constitutive model formulated within the kinematic hardening framework is used to accurately predict the degradation of structure as an anchor embedded in a natural soft clay deposit is loaded to its pullout capacity. In comparison with an idealised, non-softening clay, the degradation of clay structure due to plastic strains in the soil mass results in a lower pullout capacity factor, a quantity commonly used in design, and a more complex load–displacement relationship. It can be concluded that clay structure has an important effect on the pullout behaviour of plate anchors.     

长江三角洲第一硬土层中微结核的矿物化学特征及其成因

长江三角洲第一硬土层是古土壤层,是长江河漫滩型沉积物,其形成经历多次沉积和成土过程.硬土层中的铁锰结核以菱铁矿、菱锰矿和褐铁矿为主,通过铁锰元素离子和矿物Eh-pH稳定关系分析,最有利于菱锰矿和菱铁矿结核生成的条件是:Eh＜0且pH＞8.成土期处于末次冰期低海面、气候寒冷干燥期,土壤的化学过程是以氧化作用为主,是褐铁矿等氧化性矿物形成时期;冰后期海相层的沉积覆盖使土壤层进入成岩阶段,土壤层的化学过程以还原作用为主,成岩过程是铁锰碳酸盐结核的主要生成期.     

海洋井架结构非线性分析

根据海洋钻井井架实际结构特点,建立弹性基础上的三维有限元模型.按9种工况对某井架的有限元模型进行加载,并且在传统线弹性理论基础上加以改进,考虑非线性P-△效应的影响.应用有限元分析软件StruCAD进行分析计算,给出可靠的计算结果;并且系统分析结构的受力特点和影响因素,得出对于井架这类高耸结构应该考虑P-△效应的影响.     

深海能源土含气储层力学特性三轴试验研究

为研究深海能源土在负压开采过程中含气储层的力学特性,基于含气土赋存理论,提出一种能够控制含气量及气泡大小的制样方法,通过GDS标准应力路径三轴试验系统,开展深海能源土含气储层的固结排水试验研究,分析深海能源土在不同黏土含量及不同含气量下的力学响应规律。研究结果表明：围压变化对深海能源土含气储层的抗剪强度峰值大小影响显著,围压越大抗剪强度峰值越高;黏土含量是决定应力应变曲线变化趋势的关键影响因素,黏土含量越高试样抗剪强度越低,试样抵抗应变软化效应的能力越强;含气土比饱和土体承载能力更低,且承载能力随含气量的增大呈衰减趋势;黏土含量和含气量是深海能源土含气储层抗剪强度指标的重要影响因素,黏土含量、含气量越高,土体自身的总抗剪强度值越低。     

Effects of fracture grouting with sodium hydroxide during electro-osmosis on clay

ABSTRACT

Electro-osmosis is a foundation treatment method for clay that is not widely used because of its nonuniform consolidation effect and high cost. To overcome these limitations, this study investigates fracture grouting. To determine the optimal grouting method, anode grouting, polyurethane grouting, and fracture grouting were first compared in one-dimensional electro-osmosis consolidation tests using self-made model boxes under an equal electric potential gradient, and then different solution concentrations were tested. By comparing the current, drainage rate, and coefficient of energy consumption during the electro-osmosis process, as well as moisture content, electrical conductivity, and shear strength after the tests, the moisture and shear strength of clay after electro-osmosis were found to be significantly improved by adding chemical reagents at the fracture. In addition, the optimum concentration of fracture grouting was determined to be 1.5%, and the shear strength after testing of clay that had been treated with sodium hydroxide was found to be higher than that of the control group. However, the effects of fracture grouting in the early stage were clearer than the effects of fracture grouting at later stages.     

Evaluation of the uplift behavior of plate anchor in structured marine clay

The uplift behavior of a plate anchor in a structured clay (soft Ariake clay) is investigated through a series of laboratory tests and method of finite element analysis. The tests are adopted to identify the factors influencing the behavior of the anchor, including the thixotropic nature of Ariake clay, consolidation time, and embedment ratio of the anchor. A finite element method (FEM) is used to analyze and predict the uplift behavior of the anchor plate well in the elastic region and the yield load. The results from both the laboratory tests and the FEM analysis suggest that the embedment ratio for a deep anchor in Ariake clay is close to 4. Further increase in embedment ratio improves the capacity to a lesser extent. FEM overestimates the failure load of the uplift anchor in soft Ariake clay by about 20%. This may be ascribed to the hypothesis in the FEM analysis that there is continuous contact between the clay and the anchor until failure. Vesic’s theory for deep anchors, which may be used to predict the ultimate pullout resistance of the plate anchor in reconstituted Ariake clay, is verified to be applicable. In this paper, the plastic flow zone around the anchor is discussed using FEM which makes the behavior of anchor more understandable during the design stage.     

粘土矿物对尖刺拟菱形藻多列型生长和藻毒素产生的影响

于１９９４年１－７月在加拿大贝德福（Ｂｅｄｆｏｒｄ）海洋研究所进行粘土矿物（ｈａｌｌｏｙｓｉｔｅ）对尖刺拟菱形藻（Ｐｓｕｅｄｏｎｉｔｚｓｃｈｉａｐｕｎｇｅｎｓｆ．ｍｕｌｔｉｓｅｒｉｅｓ）生长和藻毒素软骨藻酸（ＤｏｍｏｉｃＡｃｉｄ,下简称ＤＡ）生成的影响研究,在Ｇｏｍｐｅｒｔｚ菌类生长方程的基础上,建立了尖刺拟菱形藻生长速率模型,得到各实验条件下的藻细胞最大生长速率,结果表明,粘土矿物对藻细胞的“遮