Magmatic character and geotectonic setting of some tertiary-quaternary Italian volcanic rocks: Orogenic,anorogenic and «Transitional» association — A review

Discrimination functions based on major element distribution (Pearce, 1976) can be used to define the different basalt types of the Tyrrhenian and Perityrrhenian areas in an attempt to clarify their geodynamic significance.The future Tyrrhenian and Perityrrhenian areas have been affected since Oligocene by either compressional (subduction related) or transitional processes which produced well-defined orogenic and anorogenic magmas. A local development of «transitional» magma types, characteristic of «anomalous» volcanic arcs, also occurred with geochemical features that are intermediate between within-plate and orogenic magmas.The eruption of orogenic rock suites (calcalkaline, shoshonitic and leucite-bearing rocks) took place along the Apennine border on the east and southeast of the Tyrrhenian basin from Upper Miocene to Quaternary (Aeolian and neighbouring seamounts; Campania; Latium; Capraia Island). Absence of spatial zonation and interlayering of products with a various potassic character are the peculiar features of these rocks that appear to be originated from a heterogeneous and variously metasomatized mantle source by the influx of fluids (H₂O andLile enrichment) from the subduction zone affecting the Apennine-Maghrebides collisional front during Tertiary times.In the central Tyrrhenian area oceanic tholeiitic magmatism and creation of a new oceanic crust occurred from Upper Miocene. This activity was probably accomplished by Lower Pliocene when a within-plate volcanism produced the seamounts of the Batial Plain (Magnaghi, Vavilov, base of the Marsili Smts.).Etna and Ustica volcanisms occurring along the Perityrrhenian border on the south and west the Aeolian volcanism respectively, show geochemical characteristics that are transitional between anorogenic and orogenic magmas which could indicate some influence of fluids subduction-related to their mantle sources.The complex magmatic situation of the Tyrrhenian and Perityrrhenian areas may be caused by magma-producing events either from unmodified (anorogenic) or variously modified mantle sources (transitional to orogenic) depending on their proximity to and influenced by the Cainozoic subduction zone which developed along the Apennines-Maghrebides collisional front.     

Distribution of Early Tertiary volcanic rocks in south Sumatra and west Java

Abstract   The evolution of volcanism in Sumatra and Java during Tertiary and Quaternary time can be divided into three phases: (i) lava flows of the Early Tertiary event (43–33 Ma) consisting of island arc tholeiites; followed by (ii) eruption of tholeiitic pillow basalt at the beginning of the Late Tertiary (11 Ma); and succeeded by (iii) medium-K calc-alkaline magmatism in the Pliocene and Quaternary. The present available field data on the occurrence of Paleogene volcanic rocks and subsurface data in south Sumatra and northern west Java indicate a much larger area of distribution of the volcanic rocks than previously recognized. Because the eastward continuation of the northern west Java volcanic rocks had not been found, early investigators were inclined to assume that they continued to south Kalimantan. In contrast, the early Tertiary volcanic rocks that occupy the south coast of Java can be traced further east as far as Flores. The occurrence of Paleogene volcanics in south Sumatra and northern west Java can be interpreted as a Paleogene volcanic arc that was presumably related to the late Cretaceous–Paleogene trench parallel to Sumatra and west Java due to subduction of the Indian Plate toward the northeast (Meratus trend).     

Geochemical variation with time in the Cenezoic volcanic rocks of southwest Hokkaido, Japan

Abundances of major and trace elements were determined for the Tertiary volcanic rocks from SW Hokkaido. The Late Miocene to Pliocene volcanic rocks of this region show geochemical features similar to those of the Quaternary rocks, that is, K/Si, Th/Si and LREE/HREE ratios increasing across the arc, east to west, from the Pacific to the Japan Sea side. In contrast, the Early Miocene volcanic rocks, which are geographically restricted to the Japan Sea coast, are distinct from all later volcanics and show “within-plate” characteristics — in particular, high concentrations of HFS elements. The Quaternary basalts have low Hf/Yb ratios and Hf contents, whereas the Early Miocene basalts are high in Hf/Yb and Hf, similar to Hawaiian alkali basalts. The compositional variation with time may result from the progressive depletion of incompatible HFS elements in the mantle source. Th/Yb ratios increase from Early Miocene to Quaternary, possibly reflecting increase in the LIL element contribution to the mantle source during that time.     

petrological and geochemical characteristics of quarternary volcanic rocks in haixing area,eastern north china

Field investigation and lab analysis on samples were carried out for Quaternary volcanoes, including Xiaoshan volcano, Dashan volcano and Bianzhuang hidden volcano, in Haixing area, east of North China. Results show that Xiaoshan volcano with the eruptive material of volcanic scoria, crystal fragments and volcanic ash is a maar volcano, the eruptive pattern is pheatomagmatic eruption, and the influence scope is near the crater. Dashan volcano exploded in the early stage, and then the magma intruded, forming the volcanic neck. The eruption strength and scale are limited, and the eruptive materials are scoria, volcanic agglomerate and dense lava neck. The volcanic rocks in Bianzhuang are porosity and dense volcanic rocks and volcanic breccia, reflecting the pattern of weak explosive eruption and lava flow, and the K-Ar age dating on volcanic rocks indicates that the eruption happened in early Pleistocene. Xiaoshan volcanic scoria and Bianzhuang hidden volcanic rocks are mainly basaltic, Dashan volcanic rocks with lower SiO₂ content are nephelinite in composition. Their oxide contents have no linear relationship, indicating that there is no magma evolution relationship between these magmas from the three places. Three volcanic rocks all have enrichment of light rare earth. The Bianzhuang volcanic rocks are rich in large ion lithophile elements, and have no high field strength elements Zr and Hf, Ti losses. The volcanic materials from Xiaoshan and Dashan are intensively rich in Th, U, Nb and Ta, and significantly poor in K and Ti. Although the magmas from these three places in Haixing area may all come from asthenosphere, the volcanic materials have different petrological and geochemical features, and relatively independent volcanic structures, therefore, they experienced different magma processes.     

Some aspects of volcanic rocks of the valley of Mexico

Three periods of volcanic activity connected with tectonic events form the geological history of the Valley of Mexico (Mooser 1963, 1969). An igneous rock suite from rhyodacites to andesites (but lacking rhyolites and basalts) can be observed in each period. During the Tertiary epochs — in the Oligo-Miocene and Upper Miocene-Pliocene — we have a more dacitic volcanism, in the Quaternary epoch a more andesitic volcanism. This result was verified by calculating the average of all available and stratigraphically datable chemical analyses byGunn &Mooser (1971) andNegendank (1972). Using the average chemical composition of the Oligo-Miocene, Upper Miocene-Pliocene and Quaternary products the equivalent igneous rocks were computed using theRittmann-norms in theStreckeisen-Q-A-P-F double triangle with the following result (names in parenthesis are those using the classification ofMiddlemost (1973): Quaternary : quartz-latite-andesite (andesite) Upper Miocene-Pliocene : leuco-quartz-latite-andesite (high lime dacite) Oligo-Miocene : leuco-quartz-latite-andesite (high lime dacite) The equal average composition of the two groups of Tertiary volcanic rocks seems to support the theory of a uniform primary andesite magma apart from which of the two possible theories of petrogenesis one favors. The calculated average trace element abundances show high Cr- and Ni-values which suggests that mantle material was involved if we consider the Tertiary products as partial melting products of the lower crust. A more elegant hypothesis seems to be the model ofGunn &Mooser (1971), who consider these volcanic rocks as partial melting products of oceanic tholeiites or their high pressure derivatives in the sense ofRaleigh &Lee (1969).     

Origin of volcanic rocks from Stromboli (Italy)

Quaternary volcanic rocks of Stromboli (Italy) can be divided into older calc-alkaline and younger shoshonitic series. The SiO₂ contents of the rocks range from 50% to 61% but the majority of them are basalts. The rocks show systematic variations in chemical composition which correlate with the volcanic stratigraphy, such that, at a given SiO₂ content, K and other incompatible elements such as REE increase with decreasing age. In addition, the La/Yb ratio increases while the K/Rb, K/Ba, Zr/Ce and Zr/Nb ratios decrease towards the top of the volcanic pile. On the other hand, the abundances of transition elements, V, Co, Sc and Zn, like most major elements are broadly similar in comparable rocks of different ages. It is suggested that the parent magmas were derived by partial melting from upper mantle peridotite enriched in incompatible elements by fluids released from the descending oceanic lithosphere. The temporal chemical variations may probably be related to the lengths of time during which fluids were in contact with the upper mantle source.     

琼北马鞍岭地区第四纪火山活动期次划分

琼北马鞍岭地区第四纪火山活动具有多期性。据火山作用方式、火山形貌及风化程度、火山喷发产物与沉积地层以及火山机构之间的相互叠置关系 ,结合同位素年龄 ,可分为德义岭、道堂、杨花、雷虎岭、昌道和马鞍岭等 6期 ,其中德义岭期为中更新世 ,道堂和杨花期为晚更新世 ,雷虎岭、昌道和马鞍岭期属全新世。不同期次具有不同的火山活动方式、喷发强度及火山结构类型。德义岭期火山活动以溢流为主 ,火山锥为低缓的熔岩穹丘。杨花期为射气岩浆爆发作用形成的低平火山。雷虎岭与马鞍岭期主要形成由碎屑锥和熔岩流组成的夏威夷式火山 ,熔岩流构造类型以结壳熔岩为主     

A middle-late Quaternary age for the adakitic arc volcanics of Hautere (Solander Island), Southern Ocean

Hautere (Solander Island) and five nearby, mainly submerged volcanic centres represent the only known subduction-related volcanism on the Australian–Pacific plate boundary south of New Zealand. Two new Ar–Ar biotite ages from Hautere indicate magmatism they were active between 150 and 400ka (middle to late Quaternary). This contrasts with the previously proposed Pliocene to early Quaternary age range based on less well constrained K–Ar dating. The new radiometric ages are consistent with revised pollen ages. New trace element analyses confirm the subduction-related and adakitic nature of the igneous rocks.     

Sr isotope diversity of hot spring and volcanic lake waters from Zao volcano,Japan

The ratio of ⁸⁷Sr/⁸⁶Sr was measured from different water samples of thermal/mineral (hot spring as well as crater lake) and meteoric origins, in order to specify the location and to verify the detailed model of a volcano-hydrothermal system beneath Zao volcano. The ratio showed a trimodal distribution for the case of thermal/mineral water: 0.7052–0.7053 (Type A, Zao hot spring), 0.7039–0.7043 (Type B, Okama crater lake and Shin-funkiko hot spring), and 0.7070–0.7073 (Type C, Gaga, Aone, and Togatta hot springs), respectively. However, in comparison, the ratio was found to be higher for meteoric waters (0.7077–0.7079). The water from the central volcanic edifice (Type B) was found to be similar to that of nearby volcanic rocks in their Sr isotopic ratio. This indicates that the Sr in water was derived from shallow volcanic rocks. The ⁸⁷Sr/⁸⁶Sr ratio for water from the Zao hot spring (Type A) was intermediate between those of the pre-Tertiary granitic and the Quaternary volcanic rocks, thus suggesting that the water had reacted with both volcanic and granitic rocks. The location of the vapor–liquid separation was determined as the boundary of the pre-Tertiary granitic and the Quaternary volcanic rocks by comparing the results of this strontium isotopic study with those of Kiyosu and Kurahashi [Kiyosu, Y., Kurahashi, M., 1984. Isotopic geochemistry of acid thermal waters and volcanic gases from Zao volcano in Japan. J. Volcanol. Geotherm. Res. 21, 313–331.].     

The catalogue of Quaternary volcanoes of the Greater Caucasus based on geochronological,volcanological and isotope-geochemical data

A catalogue of Quaternary volcanoes of the Greater Caucasus has been compiled based on recent geological, petrological-geochemical and isotope-geochronological data obtained in the last decades. This catalogue provides insight into the evolution of the youngest magmatism in this part of the Alpine-Himalayan fold belt at the modern level of knowledge. The catalogue is given as a set of tabular data on 74 volcanic edifices that have been found and described in literature in varying detail, including their coordinates, absolute height, type of edifice and the predominant type of eruption, age, as well as main petrographic, isotope-geochemical characteristics, and the chemical composition of the products of magmatic activity. For the sake of convenience, the volcanoes of the Kazbek and Elbrus neovolcanic areas representing two main areals of young magmatism at the Greater Caucasus are described separately. In addition, data on the Kazbek area are grouped by traditionally distinguished volcanic centers. Text presents general information on the Quaternary volcanic activity within the Greater Caucasus, its geochronology, spatiotemporal distribution, and petrogenesis of the youngest volcanic rocks.     

Tertiary and quaternary volcanism of the Erzurumkars area (Eastern Turkey): Geochronological data and geodynamic evolution

This paper presents new geochemical and geochronological data on the Neogene and Quaternary volcanic products from the area of Erzurum and Kars (Eastern Turkey).The affinity of most of the volcanic rocks concerned is calc-alkaline, with the exception of minor Quaternary alkaline rocks that outcrop in the Kars sector. Ages range from 8 m.y. to 1.3 m.y.The time-space distribution of the calc-alkaline volcanism in Eastern Turkey - NW Iran is characterized by a sudden northward jump, that occurred around 6 m.y. ago, from the Van-Erzurum Southern Belt to the Kars Northern Belt. Available data indicate that this northward migration of volcanism was due to changes in the subduction geometry of the Arabian plate under Eurasia.     

Alkalibasalts from the Tyrrhenian sea Basin: Magmatic and geodynamic significance

Petrological characteristics of basaltic rocks from the Tyrrhenian deep-sea are discussed and related to the geotectonic situation. For the first time, distinctly alkaline basalts (hawaiites) have been found in the Tyrrhenian deep-sea. These are typical within-plate basalts related to the tensional fracturing of the Tyrrhenian area. A suggested age of 100,000 years is among the youngest indications for the Tyrrhenian Sea volcanism. Since the Miocene, magmatic activity in the inner Tyrrhenian sea basin evolved from ocean-floor basalts to ocean island tholeiites and transitional basalts, with alkaline basalts as the most recent products. Seamounts in the southern part of the Tyrrhenian deep-sea (Palinuro, Marsili) add shoshonitic and calcalkaline lavas (some with high Mgvalue) to the complexity of the Tyrrhenian magmatic evolution.     

Geochemistry of mafic cainozoic volcanic rocks from Sardinia (western mediterranean)

The Cainozoic volcanism of Sardinia (Italy) can be divided into two main cycles with different magmatic and geodynamic significance. The early cycle — Oligo-Miocenic in age (29-13 My ago) — shows the calc-alkaline character typical of converging plate areas. The later activity, ranging from Lower Pliocene (about 5 My ago) to recent Pleistocene, produced mostly basic lavas extruded onto a continental plate («within plate basalts»). It was related to a period of tensional tectonics which had affected the western Mediterranean area prior to, and during, the volcanic activity. Intermediate and acid volcanic products were associated with the mafic rocks of the latest magmatic episodes. The main groups of rocks — the basic ones, already classified from their petrographic features and geological setting — can be characterized very well when a statistical elaboration of their chemical analyses is used. In fact, from chemical data it is possible to distinguish the Oligo-Miocene volcanic products from those of Plio-Pleistocene age. Moreover, within this latter group basanites, alkalic and subalkalic basaltic rocks can clearly be distinguished. Samples that had not clearly been defined on the basis of their petrographic characteristics (anonymous samples) have been attributed to one or the other of the main groups by means of discriminant functions. Chemical variations in the Plio-Pleistocenic rocks are due to fractionation episodes at shallow depths superimposed on primary magmatic variations. A model of partial fusion of the mantle accounts for many but not all the observed original chemical variations. Different physical melting conditions, the effects of minor mineral phases in the mantle and, probably, crustal contamination were also effective in creating the observed chemical variations.     

Acid and basic late neogene volcanism in central aegean sea: Its nature and geotectonic significance

Local eruptions of acid volcanic rocks occurred in the Central Aegean region around the Miocene-Pliocene boundary. Rhyolites outcrop on the Island of Antiparos, located in the central part of the Attic-Cycladic Massif. The age of these volcanic rocks ranges from 4.0 to 5.4 m.y., and chemical and Sr isotopic data suggest they were generated by partial melting of the continental crust. At the same time, along the border of the Attic-Cycladic Massif,i.e. on the island of Patmos and Caloyeri, local eruptions of Naalkaline basalts occurred. The whole of the eruptive activity is interpreted as an expression of the marked tensional tectonic phase which has affected the Central Aegean area since Middle Miocene. The contrasting nature of the erupted volcanic rocks (crustal and sub-crustal) is attributed to the different thermal state of the lithosphere beneath the two areas, as emphasized also by the presence of a wide granitic belt, of mainly Miocene age, which developed in the median sector of the Attic-Cycladic Massif.     

Subduction-related episodes of K-alkaline magmatism (15–0.1 Ma) and geodynamic implications in the north Tyrrhenian — central Italy region: a review

In the north Tyrrhenian region and adjoining shores of Alpine Corsica and central Italy, four magmatic phases (15–14; 8–6; 5–2; and 1.3–0.1 Ma) are present which consist prevailingly of either old acidic and lamproitic rocks or young (1.3–0.1 Ma) basic volcanics with potassic–ultrapotassic affinity (the rocks of the K and HK series of the Roman province, and the kamafugitic rocks). Composition, age and location of the igneous phases reveal a geochemical polarity oriented from west to east. The episodes of magmatic activity reflect the evolution of the geodynamic environment (ensialic plate convergence): backarc stretching and attenuation of an Alpine orogenic wedge were accompanied by the eastward roll-back and progressive steepening of the descending Adria plate. The latter process led to enhanced metasomatic modifications of the mantle wedge composition and to eruption of the large volumes of KS and HKS volcanic rocks in central Italy (0.6–0.1 Ma).     

Geochemistry of calc-alkaline volcanic rocks from southeastern Iran (kouh-e-shahsavaran)

The Upper Tertiary to Quaternary volcanic complex of Kouh-e-Shahsavaran in southeastern Iran is composed of calc-alkaline rocks of island are type (high-alumina basalts, basic andesites, andesites and dacites) even though it was emplaced on the continental basement. The volcanic rocks of the complex are genetically related and were probably derived by low-pressure fractional crystallization of high-Al basalts. The anomalously high content of Sr in some rocks probably reflects an accumulation of plagioclase. The trace element data are consistent with the origin of the parental magma by partial melting of an “enriched” upper mantle peridotite.     

大同地区玄武岩的岩石学特征

大同盆地第四纪的火山可以划分为两部分:西北区(通常称大同火山群)和东南区。西北区的火山群属典型的中心式喷发,其玄武熔岩是碱性橄榄玄武岩。东南区的火山岩属裂隙式喷溢,其玄武岩流主要是由橄榄拉斑玄武岩组成。本文概括了这两个地区的玄武岩类在岩石学、地球化学、稀土和微量元素等方面的差别和各自的特点     

Two types of alkaline rocks-two types of upper mantle

1) Petrochemical studies of volcanic rocks shows that alkaline rocks of continents and oceans are different genetically in spite of their mineralogical and chemical similarity. 2) Oceanic rocks develop according to the following type: tholeiitic basalt — olivine basalt — alkaline rocks. 3) Continental alkaline rocks are derivatives of initially alkaline basalts and are connected by gradual transitions with calc-alkaline rocks of island arcs. 4) The source of all volcanic rocks is the upper mantle. Therefore the existence of two main types of rocks — oceanic and continental — reflects basic heterogeneities in composition and structure of the upper mantle.     

Garibaldi group volcanic rocks of the salal creek area, southwestern British Columbia: Alkaline lavas on the fringe of the predominantly calc-alkaline garibaldi (cascade) volcanic arc

The Salal Creek area, at the north end of the main group of vents for the Quaternary Garibaldi (Cascade) Volcanic Belt, southwestern British Columbia, was the site of several small eruptions of mafic lava during the past 1 Ma. In contrast to the calc-alkaline character of all other parts of the Garibaldi Belt and the geographically nearly coincident Miocene and older Pemberton Volcanic Belt, the Salal Creek area Quaternary lavas are predominantly alkaline basalt and hawaiite with typical alkaline volcanic petrography, chemistry, and fractionation trends. Trace elements Ti-Zr-Y show within-plate character for the suite. As for other Garibaldi Belt volcanic rocks, Rb is low, Rb/Sr very low, and ⁸⁷Sr/⁸⁶Sr ratio is low, averaging 0.7032. The oxygen isotopic composition average, ¹⁸O = 5.9, is normal for mantle-derived volcanic rocks.This distinct change in magma type at the end of a volcanic are may be the consequence of a smaller degree of melting, melting at a slightly greater depth than calc-alkaline magma production, or a descending-plate edge effect.Ponded flows and pillow-palagonite accumulations indicate that several Salal Creek area eruptions occurred in proximity to ice which filled major valleys during pre-Wisconsin glacial periods.     

青海省扎日根结扎群火山岩形成时代及构造背景分析

青海扎日根结扎群火山岩中基性岩以贫硅、钾,高钛、钙,中性岩类以低硅、中钾、钛、钙,酸性岩类以高硅、钾,中钛,低钙为特征。根据Fe＊/MgO-TiO2图解上显示出本区火山岩绝大多数火山岩落在岛弧区。微量元素中Th/Nb=0.9〉0.11,Nb/Zr〉0.04显示出其构造背景为陆-陆碰撞形成的岛弧区。扎日根结扎群火山岩时代Rb-Sr同位素等时线给出的年龄为231±28Ma和225±8 Ma,属晚三叠世。另外Sr同位素的初始比值ISr=0.70522±0.00023,小于0.719,表明岩浆（原始）来源于上地幔,并且在上升的过程中受到地壳的混染。