Theoretical and experimental lifetime and oscillator strength determination in singly ionized neodymium (Nd ii)

Radiative lifetime measurements were performed with time-resolved laser-induced fluorescence techniques for 24 levels of Nd  ii in the energy range 20 500–32 500 cm⁻¹. For 17 levels, no previous experimental data exist. These results have allowed the testing of new theoretical calculations with the relativistic Hartree–Fock method taking configuration interactions and core-polarization effects into account, and a satisfying agreement has been found for this complex ion. A new set of calculated oscillator strengths, accurate within a few per cent for the strongest transitions, is presented for 107 lines of astrophysical interest appearing in the wavelength range 358.0–1100.0 nm. These results will be useful to evaluate abundance values of neodymium in chemically peculiar stars in relation with cosmochronology.     

Transition probabilities in singly ionized promethium and the identification of Pm ii lines in Przybylski's star and HR 465★

The first theoretical transition probabilities are obtained for a set of 46 Pm  ii transitions of astrophysical interest. These data fill in a gap in astrophysics and will allow to establish, on a firmer basis, the presence of some lines of this radioactive element in the spectra of chemically peculiar stars and, consequently, a quantitative investigation of the stellar Pm abundance. A search for Pm  ii lines in Przybylski's star (HD 101065) and in HR 465 is reported and discussed, supporting the detection of this ion. A more detailed quantitative analysis is awaiting the availability of dedicated model atmospheres for these stars.     

Measurement of radiative lifetimes and determination of transition probabilities of astrophysical interest in Ho iii

Lifetimes of six levels belonging to the 4f¹⁰6p configuration of Ho  iii have been measured for the first time using the time-resolved laser-induced fluorescence method. They are compared with multiconfigurational pseudo-relativistic Hartree–Fock calculations. A very good agreement is found. Using the experimental lifetimes and theoretical branching fractions, a first set of transition probabilities of astrophysical interest has been obtained for this ion.     

Experimental and theoretical transition probabilities in singly ionized gold

Absolute transition probabilities have been measured for lines originating from the 5d⁹6d and 5d⁹7s electronic configurations in the spectrum of singly ionized gold (Au  ii ). The laser-induced breakdown spectroscopy has been applied to free gold atoms and ions produced by laser ablation. Absolute transition probabilities have been determined using the branching fraction and the Boltzmann plot methods. Theoretical branching fractions as well as radiative lifetime values have also been obtained by a relativistic Hartree–Fock method taking core polarization and configuration interaction effects into account. The new results are compared with previous results when available.     

Experimental and theoretical studies of Dy iii: radiative lifetimes and oscillator strengths of astrophysical interest

The lifetimes of three short-lived levels belonging to the 4f⁹6p configuration and of two long-lived levels of the 4f⁹5d configuration of Dy  iii have been measured for the first time using time-resolved laser-induced fluorescence techniques. They are in good agreement with theoretical values calculated within the framework of a pseudo-relativistic configuration interaction approximation. Using the experimental lifetimes and the theoretical branching fractions, a first set of transition probabilities of astrophysical interest has been obtained for Dy  iii .     

Radiative lifetimes and transition probabilities in Hf I and Hf III

Radiative lifetimes of nine odd levels in Hf III (5d6p z³P_0,1, z¹D₂, z³D_1,2,3, z³F_2,3,4) and of two odd levels in Hf I (5d6s²6p z³D_2,3) have been determined using Time-Resolved Laser-Induced Fluorescence. The investigated levels in Hf I were excited in a single-step process from the ground term (5d²6s² a³F), whereas in Hf III we started from either the ground term 5d² a³F or the low-lying 5d6s a³D term. For all of the investigated levels, the lifetimes have been measured for the first time. A multiconfiguration relativistic Hartree–Fock method, including core-polarization effects, has been used to compute radiative lifetimes of 15 Hf III levels, including those measured in this work. Transition probabilities for 55 transitions in Hf III are also given.     

Radiative decay of the 4d5(6S)5p z5,7Po states in Tc ii: comparison along the homologous and isoelectronic sequences. Application to astrophysics

Using three independent theoretical approaches (CA, HFR + CP, AUTOSTRUCTURE), oscillator strengths have been calculated for a set of Tc  ii transitions of astrophysical interest and the reliability of their absolute scale has been assessed. The examination of the spectra emitted by some Ap stars has allowed the identification of Tc  ii transitions in HD 125248. This Tc  ii detection should however await confirmation from spectral synthesis relying on dedicated model atmospheres. New partition functions are also provided for Tc  i , Tc  ii and Tc  iii for temperatures ranging between 4000 and 13 000 K.