北秦岭松树沟榴辉岩的确定及其地质意义

松树沟石榴石角闪岩(榴闪岩)呈透镜状产于松树沟超镁铁岩旁侧的斜长角闪岩中,一直以来被认为是形成于接触交代变质或麻粒岩相变质过程。详细岩相学及矿物元素分析,在榴闪岩的基质矿物、石榴石幔部及锆石包体中发现残留的绿辉石,而且石榴石也保存了明显的进变质主、微量元素成分环带,表明松树沟榴闪岩为榴辉岩退变质的产物,至少经历了从角闪岩相到榴辉岩相再到角闪岩相的三阶段顺时针PT演化过程。锆石定年结果得到榴辉岩的变质年龄为500±8Ma,原岩结晶时代为796±16Ma,与秦岭岩群北侧官坡超高压榴辉岩的变质年龄和原岩年龄完全一致,也与北秦岭区域高压-超高压变质时代和原岩的结晶时代一致。表明松树沟榴辉岩与北秦岭造山带已发现的高压-超高压变质岩石一起都应是古生代大陆深俯冲作用的结果,而松树沟超镁铁岩可能是俯冲的大陆板片在折返过程中携带的俯冲隧道中的交代地幔岩。     

金红石中锆含量温度计及其微量元素地球化学特征

Zack et al.(2004a)、Watson et al.(2006)以及Tomkins et al.(2007)(在2GPa条件下)的金红石中锆含量温度计计算结果显示,徐淮地区中生代侵入杂岩所含榴辉岩类包体所经历的榴辉岩相变质的温度范围分别为776～1099℃(平均898℃)、663～923℃(平均750℃)和714～981℃(平均804℃),这些温度结果可能并非榴辉岩相峰期变质温度;其角闪岩相退变质作用过程中保存的温度范围分别为555～777℃(平均697℃)、541～663℃(平均6170C)和588～714℃(平均667℃),这些结果不能代表角闪岩相退变质再平衡后的温度,而只能代表角闪岩相退变质作用过程中某-阶段的温度.微量元素地球化学特征研究表明,榴辉岩类包体所含金红石中的某些微量元素(如Nb、Ta、Cr、Fe、V等)含量与其原岩有继承和对应关系,其原岩主要为镁铁质岩石;榴辉岩类包体与其寄主岩石中部分高价态/高场强元素(HFSE)呈相互消长的关系.榴辉岩的形成与扬子地块和华北地块之间的俯冲,碰撞作用有关.     

鲁山太华群麻粒岩相岩石形成的地球化学限制

鲁山太华群麻粒岩相岩石形成的地球化学限制徐启东，高山，刘庆生（中国地质大学，武汉４３００７４）主题词麻粒岩相岩石，ＬＩＬ元素亏损，下地壳太华群提要河南鲁山太古宙高级区表壳岩中的麻粒岩相岩石及相关的角闪岩相岩石与世界其它地区麻粒岩相岩石相比并没有明显的...     

徐淮地区中生代侵入杂岩中角闪岩和片麻岩类捕虏体的岩石学和地球化学:对深部地壳物质组成的制约

徐淮地区中生代侵入杂岩中角闪岩和片麻岩类捕虏体的主要元素、微量元素地球化学特征及其岩相学的研究表明,它们经历了两期变质作用的改造,即早期的榴辉岩相变质和晚期的角闪岩相退化变质。其原岩为拉斑玄武质岩石,在其形成过程中有较强的陆壳物质混染;部分捕虏体可能代表了本区深部地壳的物质组成,且具有华北地块基底的性质。中生代早期该区上地幔是多种岩石构成的构造混杂岩带,深部地壳主要由片麻岩类、角闪岩类和少量石榴辉石岩类组成。早白垩世时期深部地壳主要由一套快速折返至下地壳的榴辉岩相变质岩石所构成,它们普遍发生了角闪岩相退化变质,并与原下部地壳的深变质岩(片麻岩和角闪岩)混杂在一起,构成了一个构造混杂体。     

The Defluidization of the Rocks and Genesis of Gold Deposits During Deformation and Metamorphism: an Example From the Jinping Mountain

THE DEFLUIDIZATION OF THE ROCKS AND GENESIS OF GOLD DEPOSITS DURING DEFORMATION AND METAMORPHISM: AN EXAMPLE FROM THE JINPING MOUNTAIN     

The chemistry of gabbro/amphibolite transitions in South Norway

Sixteen gabbro (hyperite)/amphibolite pairs were collected from geological situations where it seems clear that the amphibolite formed from material similar in composition to that of the adjacent hyperite.Major element analyses show that the hyperite to amphibolite transition was not an isochemical one. K₂O, H₂O, P₂O₅ and Fe₂O₃ were increased strongly. CaO and FeO were diminished; SiO₂ may have been also. TiO₂, total iron, MgO, MnO and Na₂O were static; so probably was Al₁O₃.     

榴辉岩退变质过程中的微量元素地球化学行为：对CCSD主孔退变质榴辉岩的研究

对中国大陆科学钻探工程主孔榴辉岩退变质过程中的微量元素地球化学行为进行了研究。对退变质程度连续变化样品的不同部分的对比研究表明，流体作用下的退变质过程中大离子亲石元素（Cs、Rb、Ba、Sr、K、Th、U）和轻稀土元素表现出较大的活动性，重稀土元素和高场强元素变化相对较小。退变质后大离子亲石元素的显著增加和高场强元素、重稀土元素的轻微变化（甚至相对降低），表明与退变质作用有关的流体中的络阴离子含量很少，并不富集高场强元素和重稀土元素。退变质后总体上表现出的Si、大离子亲石元素和轻稀土元素的明显变化，表明外来流体参与了榴辉岩的退变质过程，带入和带出了一些元素。结合榴辉岩中单矿物微量元素组成以及前人对D^Mineral/Fluid的研究成果，对流体-榴辉岩作用形成的退变质分带（富石英条带→角闪岩→退变质榴辉岩→新鲜榴辉岩）的微量元素组成变化进行了详细研究。结果表明在流体作用下的榴辉岩退变质过程中，大离子亲石元素、轻稀土元素和高场强元素含量的变化除了受退变质流体性质的影响外，更大程度上取决于退变质过程中的矿物相（尤其是副矿物）的变化。     

关于大别山榴辉岩相变质作用

大别山产出的榴辉岩相岩石包括石榴橄榄岩、榴辉岩、榴云片岩、榴辉片麻岩、榴玉英岩和榴辉大理岩等不同系列,它们均分布于花岗质片麻岩中。矿物共生序列研究表明,榴辉岩相岩石经历了从绿帘角闪岩相、柯石英榴辉岩相、角闪榴辉岩相、绿帘角闪岩相到绿片岩相的演化过程。花岗质片麻岩及变质火山—沉积岩系并未经历超高压变质作用,但却与榴辉岩相岩石经历了同一期绿帘角闪岩相变质事件,证明二者在地壳范围内发生了构造合并     

吉林夹皮沟地区变质作用与地壳演化

本区经历四期变质作用,太古宙上壳岩系麻粒岩相变质、晚太古宙英云闪长岩高角闪岩相变质、早元古宙紫苏花岗岩类低角闪岩相变质和元古宙绿片岩相变质。麻粒岩相变质期可分三个阶段,早期角闪岩相、峰期麻粒岩相和晚期角闪岩相,其P-T-t轨迹为逆时针,与IBC型轨迹相似。导致麻粒岩相变质作用的热源为英云闪长质岩浆的垫托作用,形成于岛弧或活动大陆边缘。区内广泛发育的钾长花岗岩与晚太古宙高角闪岩相变质作用晚期的深熔作用有关。     

华南加里东期造山型金矿中金的来源—来自浙江诸暨陈蔡杂岩的证据

造山型金矿中金的来源是目前广泛争论的问题,尽管变质成因模式受到了较多的关注,但研究实例还不多。加里东期是华南地区重要的金矿成矿期,浙江诸暨陈蔡杂岩发育了从绿片岩相到角闪岩相的岩石组合,变质时代为加里东期,同时,其变质温度和压力等都已经得到精确厘定,为研究华南加里东期金矿形成与变质作用的关系提供理想的研究剖面对象。通过系统采集陈蔡杂岩岩石样品,在详细的岩相学研究的基础上对其中的黄铁矿中的金及亲硫元素进行了激光剥蚀-电感耦合-等离子体质谱（LA-ICP-MS）原位微区微量元素分析。研究结果表明：陈蔡杂岩角闪岩相岩石岩相学特征中有绿泥石,角闪石退变质为黑云母,反映退变质作用中有变质流体的回流。华南加里东期变质过程中,从绿片岩相到角闪岩相的相变过程中金及其他亲硫元素从主要赋存矿物黄铁矿中释放出来,进入变质流体,为江南造山带造山型金矿提供了金属来源。利用硫化物单矿物进行金的含量原位分析是解决变质过程中金活化迁移的重要手段。并提出华南加里东期变质过程中金的来源模式图。     

In situ SHRIMP U-Pb dating of monazite integrated with petrology and textures: Does bulk composition control whether monazite forms in low-Ca pelitic rocks during amphibolite facies metamorphism?

Bulk composition and specific reaction history among common silicate minerals have been proposed as controls on monazite growth in metapelitic rocks during amphibolite facies metamorphism. It has also been implied that monazite that formed during greenschist facies metamorphism may be preserved unchanged under upper amphibolite facies conditions. If correct, this would make the interpretation of monazite ages in polymetamorphic rocks exceedingly difficult, because isotopic dates could vary significantly in rocks that have experienced identical metamorphic conditions but differ only slightly in whole-rock composition. Low-Ca pelitic schists from the Mount Barren Group in southwestern Australia display a range of whole-rock compositions in AFM space and different peak mineral assemblages resulting from amphibolite facies metamorphism (∼8 kb, 650 °C). In this study, we test whether bulk composition controls the formation of monazite through geochronology and textural evidence linking monazite growth with deformation and peak metamorphism. X-ray element mapping of monazite from the metapelitic rocks reveals concentric zoning in many grains with compositionally distinct cores and rims. In situ SHRIMP U-Pb geochronology of monazite yields two ²⁰⁷Pb/²⁰⁶Pb age populations. The cores, and texturally early monazite, give an age of 1209 ± 10 Ma, interpreted to record prograde metamorphism, whereas the rims and “late” monazite define a single population of 1186 ± 6 Ma, which is considered the likely age of peak thermal metamorphism. The growth of monazite was widespread in low-Ca pelitic schists representing a broad range of compositions in AFM space, indicating that variations in bulk composition in AFM space did not control the formation of monazite during amphibolite facies metamorphism in the Mount Barren Group.     

Deciphering late Devonian–early Carboniferous P–T–t path of mylonitized garnet-mica schists from Prins Karls Forland,Svalbard

Quartz-in-garnet inclusion barometry integrated with trace element thermometry and calculated phase relations is applied to mylonitized schists of the Pinkie unit cropping out on the island of Prins Karls Forland, western part of the Svalbard Archipelago. This approach combines conventional and novel techniques and allows deciphering of the pressure–temperature (P–T) evolution of mylonitic rocks, for which the P–T conditions could not have been easily deciphered using traditional methods. The results obtained suggest that rocks of the Pinkie unit were metamorphosed under amphibolite facies conditions at 8–10 kbar and 560–630°C and mylonitized at ~500 to 550°C and 9–11 kbar. The P–T results are coupled with in-situ Th–U-total Pb monazite dating, which records amphibolite facies metamorphism at c. 359–355 Ma. This is the very first evidence of late Devonian–early Carboniferous metamorphism in Svalbard and it implies that the Ellesmerian Orogeny on Svalbard was associated with metamorphism up to amphibolite facies conditions. Thus, it can be concluded that the Ellesmerian collision between the Franklinian margin of Laurentia and Pearya and Svalbard caused not only commonly accepted brittle deformation and weak greenschist facies metamorphism, but also a burial and deformation of rock complexes at much greater depths at elevated temperatures.     

桐柏秦岭岩群的两类变质作用

本文重点对河南桐柏地区的秦岭岩群进行了观察与研究,根据野外地质、岩相关系及同位素测年资料,提出该区秦岭岩群具有明显不同的两类变质作用,一是较早期的高温麻粒岩相变质作用,以包体或长透镜群、甚至巨型条块状局限于中部郭庄组的花岗质片麻岩之中。根据伟晶岩、片麻岩及麻粒岩锆石年龄的综合限定,该变质作用的时间可能为~498Ma,多数人主张的445~430Ma的麻粒岩相变质年龄实际上是早期锆石被后期岩浆或变质事件引起的同位素体系重启年龄。另一种是相对晚期的角闪岩相变质作用,变质程度以角闪岩相为主,局部达高角闪岩相,没有任何早期高温或高压变质的残留迹象,形成秦岭岩群中主导类型的变质作用。同样,采用伟晶岩及有关片麻岩和麻粒岩中锆石测年限定,角闪岩相变质时间可能为~472Ma。高温麻粒岩的产出具有其特殊机制,大量的花岗质岩浆侵位过程中把地壳深部的高温麻粒岩裹挟上升至浅部层次,随后一起遭受区域上的角闪岩相变质作用。     

Metamorphism of the East Sector of the Southern Qinling Orogenic Belt and Its Geological Significance

The east sector of the southern Qinling belt is, lithologically, composed mainly of metapelites,quartzites, marbles and small amount of metabasites and gneisses, whose protoliths are the Silurian, Devonian andless commonly the Sinian and Upper Palaeozoic. They have been subjected at least to two epochs of metamorphism.The early epoch belongs to progressive metamorphism which is centered on high amphibolite-granulite facies in theFuping area and changed outwards into low amphibolite facies (staurolite-kyanite zone), epidote amphibolite facies(garnet zone) and greenschist facies (chlorite and biotite zones), the metamorphic age of which is about 220-260 Ma.This early-epoch metamorphism belongs to different pressure types: the rocks from greenschist to low amphibolitefacies belong to the typical medium-pressure type which shows geothermal gradients of about 17-20℃/km and wasprobably produced by a crustal thickening process related to continental collision, and the high amphibolite-granulitefacies belongs to the low-pressure type which shows geothermal gradients of about 25-38℃/km and was probablyaffected by some magmatic heats. Based on the basic characteristics of the P-T paths of the different facies calculatedfrom the garnet zonations, it can be deduced that the metamorphism of medium-pressure facies series took place dur-ing an imbricated thickening process, rather than during the uplifting process after thickening. The late-epoch meta-morphism belongs to dynamic metamorphism of greenschist facies which is overprinted on the early-epoch meta-morphic rocks and is Yanshanian or Himalayan in age, probably related to intracontinental orogeny.     

安徽省潜山县韩长冲地区的地质构造特征

韩长冲地区主要由超高压变质岩、碱长花岗片麻岩、二长花岗片麻岩组成。前者包括超高压片麻岩、大理岩、榴辉岩和石英硬玉岩等。其中存在由黑云斜长片麻岩、石英硬玉岩、大理岩及层状榴辉岩组成的超高压变质表壳岩组合。超高压变质岩先后经过柯石英榴辉岩相、石英榴辉岩相、角闪岩相及绿片岩相多阶段的变质作用;经过榴辉岩相、角闪岩相、角闪岩相后及脆性等四期变形。其中角闪岩相变形形成本区的主要构造要素,以发育大量Ａ型褶皱及普遍的糜棱岩化为特征。碱长花岗片麻岩及二长花岗片麻岩只经过角闪岩相及其后的变质和变形作用。超高压变质岩与碱长花岗片麻岩呈侵入接触,可能沿缓倾向ＳＳＥ的韧性剪切带逆掩于二长花岗片麻岩之上。     

The trace element geochemistry of some high-grade Bergen-Jotun kindred gneisses from the Jotun Nappe around Gjendebu, central southern Norway

Abstract The high-grade meta-plutonic rocks of this study lie entirely within the Jotun Nappe of the southern Norwegian Caledonides. They are divisible on the basis of metamorphic grade and petrographic character into three units, the Storadalen Complex (SCX), the Svartdalen Gneiss (SG), and the Mjølkedøla Purple Gabbro (MPG). The SCX is a differentiated series of ultrabasic to intermediate rocks now showing only tectonite fabrics. It has been metamorphosed to spinel-Iherzolite granulite facies grade. The broadly monzonitic SG is weakly tectonized and internally differentiated. Its metamorphic grade does not exceed plagioclase-lherzolite granulite facies grade. The mis-named MPG is also broadly of monzonitic composition but it retains a coarse ophitic texture, and is of amphibolite facies grade. A gradational boundary exists between the MPG and SG, but the contact between these two units and the SCX is the steeply dipping Tyin-Gjende Fault. The three units represent a comagmatic body of mid-Proterozoic age, metamorphosed during a Sveconorwegian event and finally dismembered and upthrust during the Caledonian Orogeny. The new trace element analyses reported here show that the three rock units have remarkably similar trace element abundances and trends. K-Rb covariation shows increasing K/Rb ratios with increasing K. These patterns were produced by magmatic fractionation processes acting at deep crustal levels, possibly in the presence of a non-aqueous fluid phase. With the exception of K and Sr, close similarities exist between the rocks of this study and present-day calc-alkaline basalts and andesites from island arcs. The high K content is regarded as a primary magmatic feature, but the available data are insufficient to indicate its origin. The Sr contents are abnormally high and are ascribed to metasomatism which occurred during either high-grade metamorphism or post-climactic cooling. There are no systematic geochemical variations with metamorphic grade or degree of deformation.     

Geochemistry of metamorphic processes in mafic rocks of the Krasnaya Guba area,Belomorian Mobile Belt

New data are obtained on the major-component and minor- and trace-element composition of metamorphosed gabbronorites and Fe-Ti gabbro in the Krasnaya Guba area, Belomorian Mobile Belt. These two magmatic complexes, which are spatially combined but are of different age and were produced in different geodynamic environments, were simultaneously metamorphosed in the Paleoproterozoic to parameters transitional between the amphibolite and eclogite facies. Eclogite metamorphism was associated with perceivable changes in the concentrations of alkalis and alkali earth elements, and the metamorphic transformation of the plagioclase eclogite (which can be metamorphosed gabbronorite and/or gabbro) into amphibolite and biotite amphibolite was associated with changes in the concentrations of practically all trace elements. This implies that the metamorphic processes were not isochemical and were accompanied by significant removal and introduction of incompatible elements. However, some trace-element ratios (such as Ti/Y, Ti/Zr, Zr/Y, La/Sm, and Nb/Th) remained unmodified in the course of metamorphism and remained the same as in the pristine gabbronorite or gabbro and likely can be employed as indicators of the composition of the probable protolith and the conditions under which it was produced.     

华中榴辉岩带地球化学和年代学研究

根据地质产状，华中高压超高压变质带中的榴辉岩可划分为与超基性岩伴生的P类和与片麻岩、斜长角闪岩等伴生的G类。它们具有不同的地球化学特征，但均为大洋基性火成岩经复杂成分演化作用的产物。全岩-矿物Sm－Nd和颗粒锆石207Pb-206Pb年代学研究表明，超高压变质作用很可能发生在加里东期（480Ma）；而印支期（265Ma）则可能是超高压变质岩的后期高压退变质改造阶段。     

Volcanism on a Proterozoic continental margin in northwestern Queensland

The oldest rocks exposed in northwestern Queensland are metamorphosed calc-alkaline volcanics (Leichhardt Metamorphics), which are intruded by elongate tonalitic to granitic batholiths (Kalkadoon Granite). These rocks are overlain by a less metamorphosed sequence containing basic lavas (Magna Lynn Metabasalt) overlain by extensive ignimbritic rhyolite and dacite (Argylla Formation). Sequences of basalt and psammite overlie the rhyolite unconformably and are overlain in turn unconformably by psammitic, pelitic, carbonate and possibly evaporitic sediments and minor volcanics. Younger granites intrude these rocks.The mineral assemblages of the Leichhardt Metamorphics, Magna Lynn Metabasalt and Argylla Formation indicate greenschist and lower amphibolite facies of metamorphism. The rocks contain no glass and some are obviously recyrstallized; however, phenocrysts, lithic fragments, spherulites, amygdales and flow-top breccias are still recognizable.Sixty-nine of the least deformed volcanic and sub-volcanic rocks were analysed for major elements and up to twenty trace elements. Element dispersion in these analyses indicated that metasomatism was probably of limited extent. The Magna Lynn Metabasalt is similar to low-potassium tholeiite, as it has less than 0.5% potash, high normative hypersthene, some normative quartz and typical Ti/Zr/Y ratios. The acid volcanics have calc-alkaline affinities although andesite is not common and the alumina content is relatively low. They have high K/Na ratios and their trace elements (especially Ba, Sr, Rb, Zr and Ce) are similar to Andean volcanics. The tholeiitic sequences that overlie the calc-alkaline volcanics in northwestern Queensland resemble the basaltic sequences of western U.S.A. that also overlie calc-alkaline volcanics.The predominantly calc-alkaline volcanics of northwestern Queensland are believed to have formed at a continental margin similar to that in the Andean region. The younger tholeiitic lavas and minor continental acid volcanism possibly accompanied crustal tension. Later regional metamorphism and intrusion of large granite batholiths stabilized the region.     

Uranium in metamorphic rocks

The distribution of U has been studied in two metamorphic rock-series with a gradient of regional metamorphism. One series ranges from the lowest greenschist to amphibolite facies and the other one shows increasing metamorphic grade from amphibolite to granulite facies. Several medium and high pressure granulitic inclusions from alkali basalts were also analyzed. The abundances of U in the rocks do not appear to be affected by metamorphism below the granulite facies grade. Granulites are depleted in U in comparison with equivalent rocks of amphibolite facies grade. There are also differences in their U distribution, as the bulk of U in amphibolite facies rocks is located along the fractures and cleavage planes of ferro-magnesian minerals and in U-rich accessories, while in granulites, most of the U resides in accessory minerals. It seems that the depletion of U in granulites is due to a loss of U which is not located in accessory minerals or in the crystal structure of rock-forming minerals and may also be related to a migration of hydrous fluids, perhaps during dehydration.