The effect of Marmara (Izmit) Earthquake on the chemical oceanography of Izmit Bay,Turkey

After the Marmara (Izmit) Earthquake (magnitude 7.4) on 17 August 1999, chemical oceanographical characteristics of Izmit Bay were investigated in order to examine the possible effects of the refinery fire and uncontrolled entrance of domestic wastes to the surface waters. The dissolved oxygen (DO) content of the water column in August 1999 was the lowest value of all the measurement periods. It was found to be lower than the detection limit of the method (0.03 mgl(-1)) in the lower layer of eastern and central basins of the Bay, whereas the dissolved hydrogen sulfide (DHS) values were high, varying between 0.14 and 1.28 mgl(-1). The deficiency of DO and in turn formation of DHS were caused by the spreading petroleum from the refinery fire onto the sea surface and waste loads from the damaged municipal waste effluent system. The increasing organic/inorganic loads into the Bay stimulated the phytoplankton blooms which cause locally saturated DO concentrations in the eastern basin during autumn 1999. DO concentrations increased in lower layer waters during winter, whilst DHS formation disappeared when water originating from the Marmara Sea replenish the water column of Izmit Bay. However, DHS formation established again in August 2000.     

Izmit Bay (Turkey) ecosystem after Marmara earthquake and subsequent refinery fire: the long-term data.

As a part of Marmara Sea, Izmit Bay (Turkey) has been one of the most polluted sites in the region for the last 25 years. On 17 August 1999, a powerful earthquake along the North Anatolian Fault struck the eastern part of the Marmara region including Izmit Bay. The earthquake destroyed many coastal cities. The Bay was also affected by the quake and subsequent fire in the refinery situated on the north-eastern coast of the Bay. Oceanographic characteristics and polycyclic aromatic hydrocarbon (PAH) levels of Izmit Bay (Marmara Sea) have been investigated to find out the degree of contamination. Seawater samples were collected at nine stations of the Bay in April and September 1999 and the results were compared with those obtained in the previous years (1984 and 1994). Monitoring data are presented for plant nutrients (nitrate + nitrate, ortho-phosphate and silicate), dissolved oxygen and chlorophyll a. Surface sediments and mussels, Mytilus galloprovincialis, have been analysed for total PAH (T-PAH) contents in April and September 1999 (before and after the Marmara Earthquake) for the samples collected from eight coastal stations of the Bay. Biomarker (Lysosomal stability and feeding rate) studies at three different sites of the Bay have also been performed to investigate the effect of pollution on mussels. Nitrate + nitrite levels in the upper layer of the eastern part of the Bay increased significantly compared to those measured before the earthquake. Of the samples analysed, the highest o-phosphate concentrations were found in September 1999 in the bottom waters of the Bay. The concentration of chlorophyll a reached its minimum value of the last 15 years. Dissolved oxygen decreased dramatically from 1984 to 1999. Total PAH concentrations measured in April 1999 at both offshore and coastal sites of the Bay were more or less the same (2 micrograms l-1). The subsequent fire after the earthquake caused an increase in the total PAH levels in water column, in sediment and in mussels. Seawater total PAH concentrations ranged between 3.5 and 11 micrograms l-1 at open coast stations and 5-17.5 micrograms l-1 at coastal stations in September 1999. A 2- to 3-fold increase in sediment PAH concentrations (200-5220 mg kg-1 dry weight) was detected after the earthquake. This increase was much more significant in the sediments located around the refinery. More contaminated mussels were detected around the refinery area (110-170 mg kg-1 dry weight). Overall, sediment and mussel PAH concentrations in Izmit Bay are much higher than those found in the other marine systems. In general, the feeding rate and the neutral red retention times of the mussels decreased in some sites of the Bay after the earthquake, but no direct correlation could be detected between the body burden of mussels and biomarkers or between the two biomarker techniques.     

Ecological risk assessment of trace metal accumulation in sediments of Veraval Harbor,Gujarat, Arabian Sea

In this study, different types of indices were used to assess the ecological risk of trace metal contamination in sediments on the basis of sediment quality guidelines at Veraval Fishery Harbor. Sediment samples were collected from three sectors in pre-, post-, and monsoon seasons in 2006. Trace metal concentrations were higher in the inner sector during post-monsoon, and it showed the highest statistical significance (p < 0.01) among the stations. Pollution load index was higher than unity, indicating alternation by effluent discharge from industries. Enrichment factor and geo-accumulation index showed that Cd, Pb, and Zn were enriched in the northern part of the harbor and Pb had accumulated in the harbor sediment. The ecological risk assessment index revealed that Ni, Zn, and Pb were higher than the effect range median values, indicating their potential toxicity to the aquatic environment in the Veraval Harbor. Hence, the harbor is dominated by anthropogenic activities rather than natural process.     

Organochlorine residue and toxic metal (Pb, Cd and Cr) levels in the surface sediments of the Marmara Sea and the coast of Istanbul, Turkey

In this study, organochlorine and toxic metal (Pb, Cd and Cr) analyses have been done in the surface sediments. Sediment samples have been collected from 7 parts of the Marmara Sea and the coast of Istanbul during 2009. Total Pb, Cd and Cr contents vary between 32 μg g(-1) and 122 μg g(-1); 0.19 μg g(-1) and 1.16 μg g(-1); 62 μg g(-1) and 372 μg g(-1), respectively. EF values of Pb and Cr are higher than 1.5 in all the stations. EF value of Cd is considerably high at Station MY1 (Tuzla Port). Total organochlorine residue contents range between 4.33 ng g(-1) and 22.2 ng g(-1) in the surface sediments.     

The distribution and sources of heavy metals in Izmit Bay surface sediments affected by a polluted stream

Dil Deresi stream is a highly contaminated stream passing through the most heavily industrialized area of Izmit Bay. In this research, surface sediments in the <63-microm fraction collected from 34 sites at western part of Izmit Bay, Northeastern Marmara Sea, Turkey were analyzed by ICP-AES for Al, As, Cd, Co, Cr, Cu, Fe, Mg, Mn, Ni, Pb, Sn and Zn. Metal concentrations were compared with the marine sediment quality standards (SQS) and literature data to assess the pollution status of the sediments. Enrichment factors (EFs) were calculated to assess whether the concentrations observed represent background or contaminated levels. The analysis revealed three groups of elements: (1) Sn is the most enriched element; (2) As, Cd, Pb and Zn are minor enriched elements; and (3) Co, Cr, Cu, Fe, Mg, Mn and Ni are at background concentrations. The distribution maps of the concentrations and enrichment factors for all heavy metals were also produced as a contour plot based on Geographic Information System (GIS) technology.     

Metal (Al, Fe, Mn and Cu) distributions and origins of polycyclic aromatic hydrocarbons (PAHs) in the surface sediments of the Marmara Sea and the coast of Istanbul, Turkey

In this study, total metal (Al, Fe, Mn and Cu) and PAHs analyses have been done in the surface sediments. Sediment samples have been collected from seven parts of the Marmara Sea and the coast of Istanbul during 2009. Total Al, Fe, Mn and Cu contents vary between 1.8% and 5.4%; 1.1% and 2.8%; 122 and 259 μg g⁻¹; 27 and 416 μg g⁻¹, respectively. EF and CF values of Fe and Mn are lower than 1.5 and 1, respectively, in all the stations. Total PAH contents range between 135 and 6009 ng g⁻¹ in the surface sediments. The origin of PAHs has been found pyrolitic according to the Phe/Ant ratio in the all stations. Contrastingly, at K0, MKC and MY1 Stations, PAH origins have been observed petrogenic according to the Flu/Pyr ratio.     

Loss estimation in Istanbul based on deterministic earthquake scenarios of the Marmara Sea region (Turkey)

The rapid urban development in Istanbul has lead to an increase in the exposure levels of the urban vulnerability. Due to the steadily increasing population, with improper land-use planning, inappropriate construction techniques and inadequate infrastructure systems, associated with an existing high hazard level, Istanbul is one of the most risky cities in the Mediterranean region. Estimations of casualties and losses, expected for given earthquake scenarios, are necessary to develop sustainable rehabilitation programs and for improving preparedness. Deterministic hazard scenarios and time-dependent probabilistic hazard assessment were used as input to a GIS-based loss estimation model, to evaluate the earthquake risk for Istanbul.     

Assessment of metal contamination in surface sediments from Zhelin Bay,the South China Sea

Metals and biogenic elements were analyzed from surface sediments collected from Zhelin Bay in the South China Sea in December 2008. The high concentrations of TOC, TN and BSi indicate the high nutrient level and diatom productivity in Zhelin Bay. The concentrations of metals were generally far lower than the effects-range-low (ERL) values that define pollutant levels. Enrichment factors (EF) and geoaccumulation indices (I_geo) suggest there are pollution levels of Cd, Cu and Zn at some stations. As, Cu, and Pb are potentially biotoxic in some stations. Correlation and principal component analyses indicate that most of the metals primarily originate from natural sources, and from maricultural activities as well. Mariculture contributes considerable Cd and Cu contamination. As and Pb comes primarily from combustion of gasoline and diesel fuel by ships.     

Distribution and sources of organochlorinated contaminants in sediments from Izmir Bay (Eastern Aegean Sea)

Eighteen surface sediment samples representative of the entire Izmir Bay were analyzed for organochlorine pesticides (OCPs) and polychlorinated biphenyls (PCBs). This was in order to provide extensive information concerning the recent deposition of these compounds in this area, together with levels, distribution, possible sources and potential biological risk. Sites that were contaminated by high concentrations of organochlorine compounds were associated with dense population, such as the harbour and the Gediz River estuary. Relatively higher ΣDDT concentrations and high DDT/DDE + DDD ratios in the Gediz River estuary indicated DDT usage, probably linked to public health emergencies. According to the established guidelines for sediment quality, the risk of adverse biological effects from such levels of OCPs and PCBs as recorded at most of the study sites was insignificant. But the higher concentrations in Inner bay and in the Gediz River estuary could cause biological damage.     

Hydrocarbons in surface sediments from the Sfax coastal zone, (Tunisia) Mediterranean Sea

The Semi-enclosed Mediterranean Sea records various signals of high anthropic pressures from surrounding countries and the industrialized European countries. This is particularly true for oil pollution. Although accounting for 1% of the world's ocean surface, it receives about 25% of the petroleum inputs to the ocean. To achieve a global budget we need to collect information from different parts of the Mediterranean. Particularly, we focus in this paper on the Southern Mediterranean, where data are presently very scarce. In this context, the University of Sfax has undertaken an estimation of hydrocarbon pollution along the coasts of Sfax and Gabès Gulf. Non-aromatic hydrocarbons were analysed in 8 surface sediments by FT/IR and GC/MS. Non-aromatic hydrocarbon concentrations vary in the range 310-1406 microg g(-1) sediments dry weight, which is high, compared to other Mediterranean sites. GC/MS data indicate a large group of unresolved compounds suggesting a petroleum contamination, confirmed by the identification of hopanes with predominant C29 and C30alpha,beta compounds and steranes with predominance of C27 over C28) and C29 compounds.     

Long-term trend analysis using discrete wavelet components of annual precipitations measurements in Marmara region (Turkey)

The purpose of this study is to determine the possible trends in annual total precipitation series by using the non-parametric methods such as the wavelet analysis and Mann-Kendall test. The wavelet trend (W-T) analysis is for the first time presented in this study. Using discrete wavelet components of measurement series, we aimed to find which periodicities are mainly responsible for trend of the measurement series. We found that some periodic events clearly affect the trend of precipitation series. 16-yearly periodic component is the effective component on Bal?kesir annual precipitation data and is responsible for producing a real trend founded on the data. Also, global wavelet spectra and continuous wavelet transform were used for analysis to precipitation time series in order to clarify time-scale characteristics of the measured series. The effects of regional differences on W-T analysis are checked by using records of measurement stations located in different climatic areas. The data set spans from 1929 to 1993 and includes precipitation records from meteorological stations of Turkey. The trend analysis on DW components of the precipitation time series (W-T model) clearly explains the trend structure of data.     

Content and distribution of trace metals in surface sediments from the northern Bering Sea,Chukchi Sea and adjacent Arctic areas

Concentrations of trace metals (Zn, Cr, Cu, V, Cd and Pb), total organic carbon (TOC), black carbon (BC) and their granulometry were examined in 25 surface sediment samples from the northern Bering Sea, Chukchi Sea and adjacent areas. Trace metal concentrations in the sediments varied from 21.06–168.21 mg kg⁻¹ for Zn, 8.91–46.94 mg kg⁻¹ for Cr, 2.69–49.39 mg kg⁻¹ for Cu, 32.46–185.54 mg kg⁻¹ for V, 0.09–0.92 mg kg⁻¹ for Cd, and 0.95–15.25 mg kg⁻¹ for Pb. The geoaccumulation index (I_geo) indicated that trace metal contamination (Zn and Cd) existed in some stations of the study area. The distribution of grain size plays an important role in influencing the distribution of trace metals (Zn, Cr, Cu, V, and Pb) in sediments from the Chukchi Sea and adjacent areas.     

Concentration and fractionation of trace metals in surface sediments of intertidal Bohai Bay, China

Surface sediments from intertidal Bohai Bay were sampled for the geochemical and environmental assessment of six trace metals (Cd, Cr, Cu, Ni, Pb and Zn). Results indicate that sediment grain size plays an important role in controlling the distribution and fractionation of them. Metal concentrations in clayey silt sediments are all clearly higher than in sand and silty sand ones. Cd and Pb in clayey silt sediments are more mobile than in sand and silty sand ones. Two sediment quality guidelines and two geochemical normalization methods (index of geoaccumulation and enrichment factor) were used to judge the potential risk and accumulation of metals. According to the mean probable effects level quotient, the combination of studied metals may have a 21% probability of being toxic. The sediments with high fraction of clay and silt have been contaminated by trace metals to various degrees, among which Cr contributes the most to contamination.     

Content and distribution of trace metals in surface sediments from the northern Bering Sea, Chukchi Sea and adjacent Arctic areas

Concentrations of trace metals (Zn, Cr, Cu, V, Cd and Pb), total organic carbon (TOC), black carbon (BC) and their granulometry were examined in 25 surface sediment samples from the northern Bering Sea, Chukchi Sea and adjacent areas. Trace metal concentrations in the sediments varied from 21.06-168.21 mg kg(-1) for Zn, 8.91-46.94 mg kg(-1) for Cr, 2.69-49.39 mg kg(-1) for Cu, 32.46-185.54 mg kg(-1) for V, 0.09-0.92 mg kg(-1) for Cd, and 0.95-15.25 mg kg(-1) for Pb. The geoaccumulation index (Igeo) indicated that trace metal contamination (Zn and Cd) existed in some stations of the study area. The distribution of grain size plays an important role in influencing the distribution of trace metals (Zn, Cr, Cu, V, and Pb) in sediments from the Chukchi Sea and adjacent areas.     

Hydrocarbons in surface sediments from the Changjiang (Yangtze River) Estuary, East China Sea

Sedimentary aliphatic (AH) and polycyclic aromatic hydrocarbons (PAHs) were studied in the Changjiang Estuary and the adjacent East China Sea. Total AH ranged from 2.20 to 11.82 μg g⁻¹ and consisted of n-alkanes and a dominant petroleum-related unresolved complex mixture (UCM). Within the n-alkanes, terrestrial plant wax compounds prevailed at nearly all stations. Of the PAHs, biogenic perylene dominated at stations receiving riverine inputs. Anthropogenic PAHs originating from combustion/pyrolysis processes varied from 17 to 157 ng g⁻¹, while fossil PAH concentrations ranged from 42 to 187 ng g⁻¹. Both biogenic and anthropogenic hydrocarbons are primarily derived from riverine discharges and accumulate at shallow-water stations. Distinct phase associations lead, nevertheless, to different sedimentation patterns. Fossil PAHs are enhanced at offshore stations where they are introduced directly by shipping activities. Biomarker fingerprints ascribe their source to Chinese crude oils. The overall levels of anthropogenic hydrocarbons are low compared to relevant areas worldwide and reveal a low/moderate level of hydrocarbon pollution.     

The Marmara Sea region: Seismic behaviour in time and the likelihood of another large earthquake near Istanbul (Turkey)

The North Anatolian Fault (NAF) extends for about 1500 km from Karliova to the east, to the Egean Sea in the west. The Marmara region, located near the western end of the NAF, is a tectonically active zone characterized by the transition between a strike slip stress regime and an extensional one in the Aegean Sea. Microseismic studies performed around the Marmara Sea in 1995 [Tectonophysics 316, 2000, 1], and just before the 1999 Izmit Earthquake Bull. Seism. Soc. Am. 92, 2002a, 361;J. Seismol. 6, 2002b, 287) permitted the analysis of the evolution of seismicity connected to this destructive earthquake and its sequels. Several observations indicate that the aftershock distribution fits well the EW orientation of the NAF, but the ruptures are not simple and linear as a first glance would suggest. Instead they are segmented in at least five pieces as shown by the slip variation and aftershock clusters, showing complexity at different scales (Bull. Seism. Soc. Am. 92, 2002a, 361). There is still a gap, across the northern border of the Marmara Sea that has not ruptured, and this is the only sector that did not break on the NAF since the 1939 great Erzincan earthquake. Will it rupture as a whole with a large magnitude earthquake, or by segments with smaller magnitude events? The Hurst analysis of the overall behaviour of the seismicity in the Marmara region since historical times shows that if a large earthquake occurs in the near future, it might break the complete gap. The Hurst character of the time variation of seismicity is persistent with H= 0.82. The aftershocks of the 1999 Izmit earthquake can be analyzed by using the Hurst method, showing an exceptionally high persistent memory.