Geochemistry and petrogenesis of the kilimanjaro volcanic rocks of the Amboseli area,Kenya

The paper summarizes the geochemical and petrogenetic aspects of an investigation of late Tertiary to Recent volcanic rocks in the Amboseli area of southern Kenya. A study of chemical variations in the Amboseli and Kilimanjaro lavas distinguishes a mildly alkaline series (alkali olivine basalts, trachybasalts/trachyandesites, trachytes, rhomb porphyries and phonolites) from a strongly alkaline series embracing subordinate nephelinitic, phonolitic and tephritic lavas. The two series probably evolved independently from a source in the mantle. A comparison of Kilimanjaro with other East African volcanoes shows that the focus of strongly alkaline volcanicity moved from eastern Uganda and western Kenya to northern Tanzania at the end of Miocene times. The Pliocene to Recent centres near the Kenya-Tanzania border show evidence of decreasing alkalinity from a western zone of nephelinite-phonolite volcanoes to an eastern region in which central volcanoes are characterized by the association of strongly and mildly alkaline suites.     

Calc-alkaline volcanic rocks from NW Sardinia: Evaluation of a fractional crystallization model

The volcanic centre of Monte Seda Oro, N. W. Sardinia, representative of a Cenozoic calc-alkaline andesitic suite of rocks is composed of a variety of rocks ranging from high alumina basalts to dacites. The minerals of basaltic, andesitic and dacitic rocks show only limited variation in chemical composition. The geochemical data suggest that the various rock-types are related by a crystal-liquid fractionation. Least-squate numerical calculations, using major element data, support the derivation of andesites with SiO₃ content ranging from 53.8 to 59.0% from basalts having about 48.7% of SiO₂ by low pressure crystal fractionation of the phenocryst phases present in these rocks. However, the origin of dacites cannot be readily explained by this mechanism.     

A statistical model for vesuvius and its volcanological implications

The last 300 years of Vesuvius history are reconstructed as a chronological succession of 4 phenomenological states: i) repose, ii) persistent activity, iii) intermediate eruption and iv) final eruption. It turns out that the times of permanence in each state are distributed according to the same exponential law. Vesuvius activity is then described by a Markov chain of these 4 states, with transition probabilities determined from the previous phenomenological analysis. The model reproduces the Vesuvius activity between 1694 and 1872 and possibly also in the 1872–1944 period. It turns out that, at least between 1694 and 1872, the volcano was behaving like a quasistationary system with 4 equilibrium states, perturbed by a stochastic noise responsible for occasional transitions from an equilibrium state to another. Major physical or structural changes of the volcanic system around 1872 and possibly in the whole subsequent period, are clearly shown by the statistical analysis.     

Major-element petrochemistry of some extrusive rocks from the volcanically active Mariana Islands

Volcanic rocks from six of the currently or recently active volcances of the Mariana Island are show little variation in major element abundances. SiO₂ content averages 51.5 wt.%. The flows are high in Al₂O (mean 17.7 wt.%) and Fe oxides (mean 10.1 wt.% calculated as FeO only), and moderate in MgO content (mean 4.7 wt.%), Na₂O (mean 2.7 wt.%), and K₂O (mean 0.7 wt.%). Only the rocks from Farallon de Pajaros, the northernmost of the Mariana Islands, deviate slightly from the average of the analyses. Three analyses from this island are slightly higher in SiO₂ (about 54 wt.%) and Al₂O₃, and are lower in total Fe oxides and MgO. According to preferred classification, the lavas of the Mariana Islands can be termed mela-andesites, high-alumina basalts, or calc-alkaline (orogenic) basalts. The K₂O values (mean 0.7 wt.%) obtained from lavas of the Mariana Islands are significantly higher than the K₂O values (about 0.33 wt.%) from volcanics of the Izu chain to the north. Inasmuch as the substantial scatter in location of earthquake foci beneath both arcs prevents accurate delineation of the upper boundary of the Benioff zone, it presently cannot be determined whether this discrepancy in K₂O values reflects a difference in depth from the volcanic are to the dipping seismic zone or relates to other phenomena. The older volcanic islands within the Mariana-Bonin island chain apparently defined an island arc system during Eocene to Miocene time. This indicates that the present plane of convergence between the Pacific plate and the Philippine Sea plate has defined the convergence between these plates since Eocene time.     

Melting of Mg2GeO4 under pressure

Melting point of germanate forsterite, Mg₂GeO₄, was raised by compression at the rate of 30°C/GPa. The triple point, at which three phases of olivine- and spinel-type solids and liquid coexisted, was fixed at 1950°C and 3.5GPa. Wen these results are combined with the thermodynamical data of forsterite, Mg₂SiO₄, it is estimated that the triple point of forsterite lies in a region ranging from 2700° to 3000°C in temperature and from 20 to 30GPa in pressure.     

Boninite as a possible calc-alkalic primary magma

Boninite is an unusual, plagioclase-free magnesian andesite, occurring as vesicular pillow lavas and hyaloclastites, accompanied by andesites and dacites in Chichi-jima, Bonin Islands. The Bonin Islands belong to the Izu-Mariana arc and consist of dominant volcanic rocks and subordinate sedimentary rocks of late Oligocene-early Miocene age. The chemistry of boninite is characterized by high contents of MgO. Cr and Ni similar to primitive basalts, but apparently in ill accord with its relatively high SiO₂ content of ? 55%. The relation of SiO₂ to total FeO/MgO ratio indicates that boninite belongs to the cale-alkalic rock suite. The mineralogy of boninite consists of olivine (Fo87-90), orthopyroxene (En87-90), clinopyroxene (Wo38-35En37-44Fs25-21), hydrous glass and Cr-spinel, Experimental studies show that the magma of boninite composition could be in equilibrium with upper mantle peridotite at pressures less than 17 kb and temperatures of 1200–1050°C under high P_H2_O. It is suggested that boninite is a sea-floor quenched product (900°C) of a direct partial melt of the upper mantle. Related andesites and dacites are considered to be probably fractional crystallization products from the same magma.     

Petrology of filicudi,aeolian archipelago

Volcanic rocks on the island of Filicudi are typical of the cale-alkaline association of the Aeolian archipelago, and range in composition from basalt to high-K andesite. All specimens contain abundant phenocrystic plagioclase (cores of An_82–97, rims becoming progressively more sodic with increasing Differentiation Index), clinopyroxene, and magnetite; the most basic samples contain olivine, which is replaced by orthopyroxene at around D.I.=44. SiO₂ generally increases with time, and this in conjunction with the continuity in mineralogy suggests that the lavas are the differentiation products of a single batch of magma. Least-squares mixing calculations are consistent with a shallow fractional model, as is the variation in trace element abundances.     

The figure of the earth — Changes in concepts

The search for the Figure of the Earth is rooted in the age-old wonder about the world we live in. The ancient mythical notions have developed, under the tutelage of Greek systematic thought, into specific questions of the shape and size of the Earth. The history of these questions, now spanning more than two millenia, shows a continuous refinement in formulation, as each bona fide answer prompted refined measurements which, in turn, started a new round of problems. The change in concept of what one was looking for was, and still is, closely connected with the technical capability and its potential for further development. This change in concept is traced here from ancient times to the present throungh some of its milestones: Anaximander's partly invisible celestial sphere and Pythagoras' spherical Earth; Eratosthenes' exemplary combination of astronomy and land surveying for the dual purpose of determining the size of the spherical Earth and making a map of the habitable world; the identical dual purpose followed by the Académie Royale des Sciences in the 17th century, but on a more sophisticated technical level; the challenge to the spherical concept by Newton's gravitational theory and the absorption of that theory into a wider concept of the Figure of the Earth; the acknowledgment of the irregular geoid by Gauss, Bessel, and Helmert, and the changed significance of the ellipsoid; Heiskanen's and Vening Meinesz' ‘Basic Hypothesis of Geodesy’ concerning the hydrostatic equilibrium of the Earth, and O'Keefe's contradiction on the basis of satelite data; the dream of global surveys come true through satellite geodesy and the accompanying inclusion of the outer gravity field of the Earth into the concept of its Figure; and lastly, the present and projected capability of high precision measurement and the widening of the concept of the Figure of the Earth from 3-dimensional rigidity to 4-dimensional time-dependence.     

Seismicity of Vesuvius on its present state of activity

Reference is hereby made to the characteristics of seismic recordings of volcanic origin as obtained at the Vesuvian Observatory up to date. The new seismic equipment recently put into operation and consisting of four three-component seismographs set up on the slopes of the Vesuvius Great Cone is also described. The characteristics of the records obtained by the above said equipment are hereby explained and related to the activity of the volcano.     

Devonian tioga tuff in Northeastern United States

The Tioga Bentonite ranges from a coarse crystal tuff to a tuffaceous shale enclosed in marine strata. It originally was deposited over the entire northeastern United States during the Middle Devonian. Trends in grain size, thickness, and numbers of preserved ash layers indicate a source volcano in west-central or central Virginia.     

Neutron activation analysis of the 1965 taal volcanic ash

Neutron activation analysis of the Taal volcanic ash revealed the presence of unusual amount of scandium in the volcanic ash as compared to the standard basalt BCR-1. The BCR-1 value for Fe/Sc is 2760 while that of Taal ash is about 2649. It is suggested that the eruption was probably characterized by the ejection of scandium-rich materials. Scandium may be used as supplementary evidence in evaluating an impending future Taal volcanic activity.     

Petrology of tholeiitic lavas from Tanna Island (New Hebrides): Importance of cumulative processes in Island arc magmatism

Tanna, one of the southernmost islands of the New Hebrides volcanic arc, is made of Late Pliocene to Recent island arc tholeiitic basalts and andesites, with SiO₂ contents ranging from 45 to 57%. These lavas are highly porphyritic (30–50% in volume): phenocrysts of plagioclase are the most abundant, together with olivine and clinopyroxene. The groundmass contain plagioclase, augite, olivine, magnetite and glass; pigeonite, tridymite, sanidine and, rarely, biotite may also occur. The olivines and clinopyroxenes show an iron enrichment from the cores of phenocrysts to their rims and the groundmass crystals, but their compositional variations are not correlated with the Mg/Fe ratio of bulk host rocks, the most Fe-rich compositions being found in Mg-rich lavas. Plagioclase compositions range from An₉₅ to An₆₀ in the basalts and An₆₀ to An₅₀ in the andesites, but, within each group, they are not correlated with SiO₂ or Na₂O contents of host lavas. Consequently, the bulk major element compositions of Tanna volcanic rocks cannot be considered as primarily controlled by crystal separation from successive liquids. The oxyde-SiO₂ variations diagrams, and the modal compositions and mineral chemistry show that crystal accumulation is the predominant mechanism accounting for bulk rock compositions. However, this does not exclude fractional crystallization: the variation of the calculated groundmass mineralogy strongly suggest the occurrence of crystal removal mainly clinopyroxene and magnetite.     

Fractional Tajimi–Kanai model for simulating earthquake ground motion

The ground acceleration is usually modeled as a filtered Gaussian process. The most common model is a Tajimi–Kanai (TK) filter that is a viscoelastic Kelvin–Voigt unit (a spring in parallel with a dashpot) carrying a mass excited by a white noise (acceleration at the bedrock). Based upon the observation that every real material exhibits a power law trend in the creep test, in this paper it is proposed the substitution of the purely viscous element in the Kelvin Voigt element with the so called springpot that is an element having an intermediate behavior between purely elastic (spring) and purely viscous (dashpot) behavior ruled by fractional operator. With this choice two main goals are reached: (i) The viscoelastic behavior of the ground may be simply characterized by performing the creep (or the relaxation) test on a specimen of the ground at the given site; (ii) The number of zero crossing of the absolute acceleration at the free field that for the classical TK model is \(\infty \) for a true white noise acceleration, remains finite for the proposed model.     

Geochronology and magmatic character of the pliocene-pleistocene volcanism in Sardinia (Italy)

The Pliocene-Pleistocene subaerial volcanic activity of the island of Sardinia developed from about five million years ago to the Pleistocene. Volcanism was mainly fissural, related to rifting of the Sardinian crustal block and connected to intraplate tensional tectonics involving at the same time the area of the Tyrrhenian Sea. Areally the most abundant rocks are basic, ranging in serial character from alkaline to subalkaline types. In some areas intermediate and salic lavas also occur; trachytic and phonolitic rocks are mainly associated with basalts of alkaline affinity, whereas rhyolites and dacites are mainly related to subalkalic basalts. K/Ar data show that lavas of different serial character (from alkalic to subalkalic) are produced on the island within the same time range, from about four to two million years; it is to be noted, however, that the early products (about 5 million years) are mildly alkalic in character whereas most of the youngest products (0.6–0.14 million years) are strongly alkalic.     

The composition and differentiation of the volcanic rocks of Carriacou,grenadines, West Indies

Tertiary volcanic rocks of Carriacou occupy two-thirds of the island. The volcanics include volcaniclastics, lava flows and dome lavas and range in composition from basalts to andesites. Carriacou basalts fall into two petrographic types (a) clinopyroxene-plagioclase-phyric basalts and (b) olivine microphyric basalts; the latter having higher MgO and lower Al₂O₃ than the clinopyroxene basalts. Both types are unusually rich in mafic minerals compared with Lesser Antilles basalts in general, although similar types have been reported from the nearby island of Grenada. The potash to silica ratios are relatively high and confirm the similarity between Carriacou and Grenada basalts and the differences between these basalts and basalts from other islands of the Lesser Antilles. The basaltic andesites and andesites from Carriacou correspond closely in mineralogical and chemical composition with typical andesites found elsewhere in the Lesser Antilles. The geochemistry of the volcanics shows that the olivine microphyric basalts display tholeiitic affinities whereas the clinopyroxeneplagioclase-phyric basalt, basaltic andesites and andesites are calcalkaline. The compositional gradation in both the geochemistry and mineralogy of these volcanics suggests that fractional crystallization played an important role in the derivation of the various magma.     

Pumice eruptions of the lesser Antilles

Stratigraphic studies on the active and potentially active volcanoes of the Lesser Antilles have revealed two main types of andesitic pyroclastic deposit. One with dense clasts in a poorly vesicular ash represents nuée ardente eruptions of Pelean type and the other group of vesicular pumice and ash represent both Plinian airfall and ash-pumice flow eruptions. The pumiceous deposits can be divided into airfall lapilli, airfall ash, crystal-pumice surge, ashpumice flow and ash hurricane types. No pumice eruptions have been witnessed in the Lesser Antilles during the period of written history although the stratigraphy of archaeological sites shows they occurred in pre-Columbian times. Detailed stratigraphic studies of Mt. Pelée, Martinique, and the Quill, St. Eustatius, show that, throughout their history, pumice eruptions have alternated with nuée ardente eruptions with approximately equal frequency. The widespread occurrence of pumiceous deposits on many of the West Indian volcanoes and the frequent alternations in the stratigraphic sections suggest the high probability that they will be witnessed in the future. On Martinique, some on the late prehistoric pumiceous pyroclastic flow deposits (the ash hurricanes) have been traced 20 km from the central vent to the out-skirts of Fort de France, indicating that they are the major hazard in the Lesser Antilles. Measured stratigraphic sections show that the Pelean type nuée ardente deposits are separated from the pumiceous pyroclastic deposits by others of intermediate vesicularity and appearance. The presence of such deposits of intermediate vesicularity could provide a future warning of impending change in pyroclastic style. As no such deposits formed on Mt. Pelée this century the present «safer» episode of nuée ardente (Pelean type) activity is expected to continue.     

Two types of alkaline rocks-two types of upper mantle

1) Petrochemical studies of volcanic rocks shows that alkaline rocks of continents and oceans are different genetically in spite of their mineralogical and chemical similarity. 2) Oceanic rocks develop according to the following type: tholeiitic basalt — olivine basalt — alkaline rocks. 3) Continental alkaline rocks are derivatives of initially alkaline basalts and are connected by gradual transitions with calc-alkaline rocks of island arcs. 4) The source of all volcanic rocks is the upper mantle. Therefore the existence of two main types of rocks — oceanic and continental — reflects basic heterogeneities in composition and structure of the upper mantle.     

Assessment of the statistical significance of global changes in the annual river runoff in XXI century due to possible anthropogenic warming of climate

A number of uncertainties of forecasts of changes in the annual runoff depths at global scale, obtained using information on results of integration of 21 IPCC climate models is studied. Following possible errors of these forecasts are calculated: errors of models; differences between main (IPCC) scenarios of emission of greenhouse gases in the atmosphere and resultant changes of global temperatures; mistakes in estimates of average long-term observed values of the runoff depths for the “control” period. Global maps of a “significance index” of forecasted changes in the runoff depths (estimations of changes in the annual runoff depths divided by mean square root values of errors of these estimations) for 2025, 2050, 2075 and 2100 are presented. It is shown that the most significant global changes of the runoff depths (growth in the north of Eastern Siberia, of the Russian Far East, of North America, falling in the “Greater Mediterranean Region”) are predicted for the second quarter of 21st century. Further changes of the runoff amplify only in the Amazon basin (reduction, by 2075). Almost everywhere else (including almost all European territory of Russia, Western Siberia, south of Eastern Siberia and of the Far East) the significance of changes in the runoff depths during 21st century is negligible.     

A comparison of the recent eruptions of Mt. Pelée,Martinique and Soufrière,St. Vincent

The simultaneous eruption of Mt. Pelée, Martinique and Soufrière, St. Vincent are regarded as the first recognized examples of Pelean-type and St. Vincent-type pyroclastic eruptions. Both produced nuées ardentes, the former usually laterally directed because of the presence of a dome and the latter vertically directed from an open crater. Both volcanoes have subsequently erupted for a second time this century. The 1902–05 and 1929–32 eruptions of Mt. Pelée produced andesite lava of almost identical composition and mineralogy. Both contain two generations of plagioclase, orthopyroxene, Fe-Ti oxide, corroded brown amphibole and olivine rimmed by pyroxene. In contrast, the Soufrière material is more basic in composition varying from basaltic andesite to basalt in 1902–03 and basaltic andesite in 1971–72. The Soufrière material contains two generations of plagioclase (with those of 1971–72 having additional zones of labradorite), clinopyroxene, orthopyroxene, olivine and Fe-Ti oxide. The pyroclastic deposits are strikingly different, those from the Pelean-type eruption are termed «block and ash deposits» being characterised by poorly vesicular lava blocks up to 7 m in diameter, while the St. Vincent-type eruption produced «scoria and ash deposits» containing vesicular ropey blocks or bombs no larger than 1 m in diameter. The differences in styles of eruption are attributed to differences in viscosity and mechanism of eruption of the magmas. Stratigraphic studies of Mt. Pelée reveal that the volcano has produced basaltic andesite scoria and ash deposits from St. Vincent-type eruptions. It is concluded that the recent eruptions of Pelée tapped a deep level magma during both eruptions releasing magma of similar composition, while the 1971 Soufrière magma is thought to be a remnant of the 1903 basaltic magma which remained at a high level within the volcano where it underwent enrichment in plagioclase and loss of olivine and oxide.     

Eruption of Piip Crater (Kamchatka)

In autumn of 1966 on the northern slope of Kliuchevskoy volcano a chain of new adventive craters broke out at the height of about 2200 m. Eighty-four hours before the beginning of the eruption a swarm of preliminary volcanic earthquakes had appeared. The number of preliminary shocks was 457 with total energy of 4 × 10¹⁷ erg. With the beginning of the lava flow the earthquakes stopped and a continuous volcanic tremor appeared. The total energy of volcanic tremor amounts to 10¹⁶ erg. During the eruption numerous explosive earthquakes with the energy of 10¹⁵–10¹⁶ erg were recorded and besides the microbarograph of the Volcanostation recorded 393 explosions with an energy more than 10¹³ erg and their total energy was equal to 10¹⁷ erg. All together it has been formed 8 explosive craters and the lowest 9th crater was effusive. The slag cone was formed round this effusive crater, the lava effusion of basaltic-andesite composition (52,5% SiO₂) tooke place from the lava boccas at the cone base and from the crater. The lava flow covered a distance of 10 km along the valley of the Sopochnoy river and descended to a height of about 800 m. The lava flow velocity at the outflow reached 800 m/hr, the lava temperature was 1050°C. The effused lava volume amounts to 0.1 km³. The eruption stopped on December 25–26, 1966.