Dating Holocene lavas on Stromboli,Italy using cosmogenic He

In-situ cosmogenic ³He exposure ages of pyroxene phenocrysts from basalts from the Upper Neostromboli formation in southwest Stromboli date its eruption at 7.0 ± 0.3 ka (1σ, n = 3, Ginostra site) and 6.8 ± 0.2 ka (1σ, n = 10, Timpone del Fuoco site) respectively. Correlation of our new data to previous K/Ar and palaeomagnetic ages from the northwestern Neostromboli phase suggests that it erupted within a confined period between roughly 6 and 14 ka. The low uncertainty on the ³He_cos ages as well as on individual exposure ages (4.4–8.7%) demonstrates that ³He_cos exposure dating is a viable tool for dating Holocene basalt lavas. The ages compare favourably to uncertainties obtained for radiocarbon dating of similar rocks.     

Procida volcanic history: new insights into the evolution of the Phlegraean Volcanic District (Campania region,Italy)

New stratigraphic, major- and trace-element, and Sr-, Nd- and Pb- isotopic data on volcanic deposits older than 14 ka from the island of Procida, Italy, are presented and compared with published analyses from the rest of the Phlegraean Volcanic District (PVD). Procida rocks range in composition from basalt to shoshonite and trachyte and show ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ²⁰⁶Pb/²⁰⁴Pb, ²⁰⁷Pb/²⁰⁴Pb and ²⁰⁸Pb/²⁰⁴Pb ratios varying within the ranges 0.70523–0.70678, 0.512539–0.512630, 18.99–19.29, 15.67–15.69 and 39.10–39.39, respectively. The presence of a compositional gap in the range SiO₂=54–59 wt % is evidence of magma bimodality, and suggests that the feeding magmatic system was formed by at least two different reservoirs located at different depths. Geochemical and isotopic variations with increasing differentiation can be explained by fractional crystallization mechanisms, that in some cases were associated with crustal contamination that occurred in both deeper and shallower reservoirs; the most evolved magmas formed in the shallower one. Mixing/mingling processes also occurred. The variation of isotopic composition through time observed both for Procida and for Campi Flegrei and Ischia rocks is evidence of strong affinity between magmas that erupted on the entire PVD until about 40 ka. This indicates that they share a common origin and a common plumbing system. Most of the PVD eruptive centers active until about 40 ka lie within a NE-SW-oriented volcano-tectonic belt extending from the southeastern part of Ischia, through Procida and Torregaveta volcano to the northeastern sector of the present Campi Flegrei caldera. This not only indicates the existence of a link between regional structures and volcanism in the area, but also suggests that PVD magma genesis and evolution were strongly regulated by extensional tectonics. In the last 40 ka the mafic rocks erupted along this extensional structure – from Torregaveta and the islands of Ischia and Procida – indicate that it still represents an important crustal discontinuity that focuses mantle-derived magmas. Procida trachybasalts are enriched in large ion lithophile elements (LILE) and light and middle rare earth elements (LREE and MREE), and show slight negative anomalies in the high field strength elements (HFSE) relative to average MORB. A slight depletion in HREE is present. Trace element and isotope systematics can be referred to a lithospheric mantle source. The lithospheric mantle source carries intra-plate and slab-derived components, the latter probably inherited from a previous subduction event.     

Crustal structure, evolution, and volcanic unrest of the Alban Hills, Central Italy

 The Alban Hills, a Quaternary volcanic center lying west of the central Apennines, 15–25 km southeast of Rome, last erupted 19 ka and has produced approximately 290 km³ of eruptive deposits since the inception of volcanism at 580 ka. Earthquakes of moderate intensity have been generated there at least since the Roman age. Modern observations show that intermittent periods of swarm activity originate primarily beneath the youngest features, the phreatomagmatic craters on the west side of the volcano. Results from seismic tomography allow identification of a low-velocity region, perhaps still hot or partially molten, more than 6 km beneath the youngest craters and a high-velocity region, probably a solidified magma body, beneath the older central volcanic construct. Thirty centimeters of uplift measured by releveling supports the contention that high levels of seismicity during the 1980s and 1990s resulted from accumulation of magma beneath these craters. The volume of magma accumulation and the amount of maximum uplift was probably at least 40×10⁶ m³ and 40 cm, respectively. Comparison of newer levelings with those completed in 1891 and 1927 suggests earlier episodes of uplift. The magma chamber beneath the western Alban Hills is probably responsible for much of the past 200 ka of eruptive activity, is still receiving intermittent batches of magma, and is, therefore, continuing to generate modest levels of volcanic unrest. Bending of overburden is the most likely cause of the persistent earthquakes, which generally have hypocenters above the 6-km-deep top of the magma reservoir. In this view, the most recent uplift and seismicity are probably characteristic and not precursors of more intense activity. Received: 15 April 1997 / Accepted: 9 August 1997     

Modelling of surface ground deformations in the Phlegraean Fields volcanic area,Italy

A preliminary finite elements model of the ground deformations observed at Phlegraean Fields is proposed. The model assumes an oblate-spheroid magma chamber at the depth of 5.4 km with major semiaxis of 1.5 km and minor semiaxis of 0.75 km. The dimensions of the magma chamber have been evaluated by using a thermal model based on the assumptions that a progressively cooling huge magmatic body is responsible for the volcanic activity at Phlegraean Fields in the last 35,000 years. Surface deformations caused by an over-pressure of 30 MPa in the magma chamber have been calculated. Constant, and temperature-dependent elastic parameters of the surrounding medium have been considered. Vertical displacements of the order of those presently observed at Phlegraean Fields can be obtained only with temperature-dependent elastic properties of the medium.     

Pure forsterite in Nyiragongo lavas: evidence for subsolidus oxidation of volcanic rocks

Some volcanic rocks from Nyiragongo volcano in the Democratic Republic of Congo contain highly oxidized olivine crystals.These olivines crystals are made of two phases,dark olivine on backscattered electron images of pure forsterite composition and grey Mg-poor areas made of olivine and iron-rich oxides.Calculation of the initial composition confirms that they are primary olivine with late separation of two different olivine compositions.Pure forsterite is enriched in SiO₂ but contain...     

Late Quaternary deformation history of the volcanic edifice of Panarea,Aeolian Arc,Italy

A series of raised palaeoshorelines is documented along the emergent coastal slopes of Panarea and surrounding islets at elevations of 115 (palaeoshoreline Ia) and 100 m a.s.l. (Ib), 62.5 m (II), 35 m (III), 12 m (IV), 10–12 (Va) and 5 m (Vb). According to stratigraphic constraints and cross-cutting relationships, these palaeoshorelines are correlated with discrete high sea-level stillstands during marine oxygen-isotope stages (MIS) 5e, 5c, 5a and 3. Coastal elevation changes suggest the occurrence of a long-term, sustained uplift trend of the volcanic edifice since the last interglacial (last 124 ka). The uplift rates are not constant but display a progressive deceleration from maximum values of 1.5–1.58 m/ka, in the period between 124 and 100 ka, down to the lowest values of 0.66–0.69 m/ka, which tend to be constant starting from 81 ka BP. The long-term deformation pattern of Panarea suggests that a transitory, volcano-related component of uplift interplayed with the regional tectonic component affecting the sub-volcanic basement, which has undergone a persistent and widespread uplift since the mid-Pleistocene. The volcano-related component of uplift, prevailing between 124 and 100–81 ka, is interpreted as the result of visco-elastic deformation mechanisms which characterize the progressive re-equilibration of the shallow magmatic system following the incoming quiescence of the volcanic edifice. The long-term uplift values at Panarea are higher than in the main portion of the western-central Aeolian Arc, where a mean uplift rate of 0.34 m/ka was estimated since the last interglacial (last 124 ka). Such a pattern of deformation on a regional scale may be a response to active deformation processes connected with the southeastward rollback of the subducting Ionian slab which is still active only in correspondence with the eastern sector of the Aeolian Arc (including Panarea). In the short-term, a localized submergence trend has been documented at the nearby islet of Basiluzzo for the last 2,000 years, likely connected to neo-tectonic movements along main NE–SW trending faults.     

Garibaldi group volcanic rocks of the salal creek area, southwestern British Columbia: Alkaline lavas on the fringe of the predominantly calc-alkaline garibaldi (cascade) volcanic arc

The Salal Creek area, at the north end of the main group of vents for the Quaternary Garibaldi (Cascade) Volcanic Belt, southwestern British Columbia, was the site of several small eruptions of mafic lava during the past 1 Ma. In contrast to the calc-alkaline character of all other parts of the Garibaldi Belt and the geographically nearly coincident Miocene and older Pemberton Volcanic Belt, the Salal Creek area Quaternary lavas are predominantly alkaline basalt and hawaiite with typical alkaline volcanic petrography, chemistry, and fractionation trends. Trace elements Ti-Zr-Y show within-plate character for the suite. As for other Garibaldi Belt volcanic rocks, Rb is low, Rb/Sr very low, and ⁸⁷Sr/⁸⁶Sr ratio is low, averaging 0.7032. The oxygen isotopic composition average, ¹⁸O = 5.9, is normal for mantle-derived volcanic rocks.This distinct change in magma type at the end of a volcanic are may be the consequence of a smaller degree of melting, melting at a slightly greater depth than calc-alkaline magma production, or a descending-plate edge effect.Ponded flows and pillow-palagonite accumulations indicate that several Salal Creek area eruptions occurred in proximity to ice which filled major valleys during pre-Wisconsin glacial periods.     

Petrology,geochemistry and Sr-isotope characteristics of lavas from the area of Commenda (Mts. Vulsini,Italy)

Major, trace element and Sr-isotope compositions are reported for a suite of lavas coming from the area of Commenda in the SE Vulsinian district. The analyzed samples have all low silica contents and variable but generally high CaO, MgO and FeO_t. Based on K₂O% and K₂O/Na₂O ratio, the rocks from Commenda can be classified as belonging to the Potassic Series (KS) and the High-potassium Series (HKS). The HKS rocks appear to have derived by cristal/liquid fractionation from the most mafic types with separation of olivine and clinopyroxene and then of clinopyroxene + leucite. The most primitive HKS rocks have aphyric texture and high Mg-values, Cr and Ni contents which are close or within the range of values of magmas formed by partial melting of periodititic mantle sources. The KS rocks have lower incompatible element contents as the HKS rocks with similar degree of evolution.The variations of Sr-isotopic ratios of the analyzed rocks and of other Vulsinian lavas, indicate that the basic HKS Vulsinian rocks did not interact significantly with the continental crust. Instead, the KS appears to have evolved by combined crystal fractionation and assimilation processes, starting from parental magmas which had⁸⁷Sr/⁸⁶Sr ratio not significantly lower than that found in the less evolved rocks of the suite.The most primitive HKS rocks from Commenda have hygromagmatophile element distribution pattern characterized by high ratio of LILE/HFSE with negative anomalies of Ta and Ti, resembling closely those of other Roman mafic volcanics. The primitive geochemical characteristics of the Commenda rocks exclude that these features are the products of interaction with the crust and provide a further support to the hypothesis of a genesis within a subduction-modified mantle source.     

The composition of basaltic lavas from Bayuda,Sudan and their place in the cainozoic volcanic history of north-east Africa

Six new analyses of young basaltic rocks from the Bayuda field show the predominant rock types to be strongly undersaturated basanites and nepheline trachybasalts. Both types are believed to represent magmas of deep-seated origin. Similar rocks are widely distributed in north-east Africa but mildly alkaline to tholeiitic basalts were erupted along the eastern margin of the continent in early and late Cainozoic times, whereas along the Tripoli-Tibesti zone to the west mildly alkaline basalts were probably confined to the early Tertiary. The Tripoli-Tibesti zone was one of uplift and strongly tensional tectonics in the late Mesozoic and early Cainozoic, and at this time may have been a line of potential lithospheric rifting, but a period of quiescence followed and resurgence of activity in the late Cainozoic produced weaker tensional structures and more strongly alkaline basic magmas. The region between these two main zones of activity was characterized throughout by intermittent alkaline volcanicity and weak tectonism. Neverthless, fracture zones which apparently controlled the volcanicity are beginning to be recognized in this area. It is argued that African volcanic activity is related to linear, rather than circumscribed, areas of mantle activity. Possible connections with epeirogenic movements within the Alpine orogenic belt appear to have been neglected in the debate on the causes of African igneous activity.     

Intensity attenuation in the Campania region,Southern Italy

Ground motion prediction equations (GMPE) in terms of macroseismic intensity are a prerequisite for intensity-based shake maps and seismic hazard assessment and have the advantage of direct relation to earthquake damage and good data availability also for historical events. In this study, we derive GMPE for macroseismic intensity for the Campania region in southern Italy. This region is highly exposed to the seismic hazard related to the high seismicity with moderate- to large-magnitude earthquakes in the Appenninic belt. The relations are based on physical considerations and are easy to implement for the user. The uncertainties in earthquake source parameters are accounted for through a Monte Carlo approach and results are compared to those obtained through a standard regression scheme. One relation takes into account the finite dimensions of the fault plane and describes the site intensity as a function of Joyner–Boore distance. Additionally, a relation describing the intensity as a function of epicentral distance is derived for implementation in cases where the dimensions of the fault plane are unknown. The relations are based on an extensive dataset of macroseismic intensities for large earthquakes in the Campania region and are valid in the magnitude range M _w = 6.3–7.0 for shallow crustal earthquakes. Results indicate that the uncertainties in earthquake source parameters are negligible in comparison to the spread in the intensity data. The GMPE provide a good overall fit to historical earthquakes in the region and can provide the intensities for a future earthquake within 1 intensity unit.     

Evolution of sand waves in the Messina Strait, Italy

In the present paper the morphodynamics of sand waves in the Messina Strait, Italy, is analysed by comparing data gathered during two different surveys carried out in 1991 and 2001, respectively. In particular, a morphometric analysis on the most recent data and a qualitative analysis of the differences between bottom bedform patterns, are carried out. At locations characterised by greater depths, only minor changes to the planimetric configuration of the field, i.e. crest orientation (which is seen to be orthogonal to the direction of net gross sand transport) and wave length are observed, while differences in wave length and crest direction are more evident in more shallow areas. On the other hand, wave height has significantly increased in the whole field. A possible explanation of such a change, based on the previsions of a theory which relates sand-wave growth and migration to the main components of the tidal ellipse, is provided.Responsible Editor: Jens Kappenberg     

Geochemical investigations of submarine volcanic exhalations to the east of Panarea, Aeolian Islands, Italy

Results are presented on scubadiving investigations carried out on thermal manifestations in the area of Panarea (Aeolian Islands). The area investigated falls inside a caldera which extends from the main island to the group of islets located to the northeast. The distribution of the gaseous manifestations is regulated by the NE-SW, NW-SE and N-S regional tectonic directrices, through which the more recent basic magma intruded, giving rise to dikes and pillow lavas. f_O2-temperature relation of the gases sampled in the investigated area was calculated to be: logf_O2 = 11−24,593/T which indicates that a buffering mechanism acted on the gases as they cooled down during their ascent. The high ³He/⁴He ratio (6 × 10⁻⁶) and the δ¹³C = −3.2%. (PDB), suggest the presence of a magmatic component in the gas feeding the investigated manifestations. The above relations and the almost constant high He/N₂ ratio suggest that all the fumaroles are fed by the same deep hot fluids. On the basis of both the chemical characters of the fluids and the geothermo-barometric data, a deep geothermal body, having a temperature of about 240°C, is recognized. Two other shallower thermal aquifers, with a temperature of 170–210°C, are identified. A circulation pattern of the geothermal fluids is also proposed. On the basis of calculations regarding the convective energy released by the geothermal system of Panarea, and the magmatic mass responsible for the positive gravimetric anomaly of the area, it was estimated that the last volcanic activity took place less then 10,000 years ago.     

Monitoring volcanic hazard using eddy covariance at Solfatara volcano, Naples, Italy

An eddy covariance (EC) station was deployed at Solfatara crater, Italy, June 8–25, 2001 to assess if EC could reliably monitor CO₂ fluxes continuously at this site. Deployment at six different locations within the crater allowed areas of focused gas venting to be variably included in the measured flux. Turbulent (EC) fluxes calculated in 30-min averages varied between 950 and 4460 g CO₂ m⁻² d⁻¹; the highest measurements were made downwind of degassing pools. Comparing turbulent fluxes with chamber measurements of surface fluxes using footprint models in diffuse degassing regions yielded an average difference of 0% (±4%), indicating that EC measurements are representative of surface fluxes at this volcanic site. Similar comparisons made downwind of degassing pools yielded emission rates from 12 to 27 t CO₂ d⁻¹ for these features. Reliable EC measurements (i.e. measurements with sufficient and stationary turbulence) were obtained primarily during daytime hours (08:00 and 20:00 local time) when the wind speed exceeded 2 m s⁻¹. Daily average EC fluxes varied by ±50% and variations were likely correlated to changes in atmospheric pressure. Variations in CO₂ emissions due to volcanic processes at depth would have to be on the same order of magnitude as the measured diurnal variability in order to be useful in predicting volcanic hazard. First-order models of magma emplacement suggest that emissions could exceed this rate for reasonable assumptions of magma movement. EC therefore provides a useful method of monitoring volcanic hazard at Solfatara. Further, EC can monitor significantly larger areas than can be monitored by previous methods.     

Isotope geochemistry and origin of calc-alkaline lavas from a caledonian continental margin volcanic arc

Analyses for major and trace elements, including REE, and Sr, Nd and Pb isotopes are reported from a suite of Siluro-Devonian lavas from Fife, Scotland. The rocks form part of a major calc-alkaline igneous province developed on the Scottish continental margin above a WNW-dipping subduction zone. Within the small area (ca. 15 km²) considered, rock types range from primitive basalts and andesites (high Mg, Ni and Cr) to lavas more typical of modern calc-alkaline suites with less than 30 ppm Ni and Cr. There is a marked silica gap between these rocks (< 62%) and the rare rhyolites (> 74%), yet the latter can be generated by fractional crystallization from the more mafic lavas. In contrast, variation in incompatible element concentrations and ratios in the mafic lavas can not be generated by fractional crystallization processes. Increasing SiO₂ is accompanied by increasing Rb, K, Pb, U and Ba relative to Sr and high field strength elements, increasing LREE enrichment and increasing _Sr calculated at 410 Ma, and by decreasing HREE, Eu/Eu*, Sm/Nd and _Nd (410). _Nd and _Sr are roughly anticorrelated and have more radiogenic compositions than the mantle array, in common with data reported elsewhere from this part of the arc. The correlation extrapolates up to cross the mantle array within the composition field of the contemporary MORB source, and extrapolates down towards the probable compositional range of Lower Palaeozoic greywackes, which may form the uppermost 8 km of the crust, or may be supplied to the source by subduction. One sample, however, lies within the mantle array, and closely resembles lavas from northwestern parts of the arc, where a mantle source with mild time-integrated Rb/Sr and LREE enrichment has been inferred. The lavas have relatively high initial ²⁰⁷Pb/²⁰⁴Pb for their ²⁰⁶Pb/²⁰⁴Pb, a feature which has been interpreted elsewhere as the result of incorporation of a sediment component into arc magmas. The systematic changes with increasing SiO₂ in isotopic and chemical parameters can be explained by mixing of a greywacke-derived component with depleted mantle. The various possible mixing mechanisms are discussed, and it is considered most likely that mixing occurred in the mantle source through greywacke subduction. The bulk of the Rb, K, Ba and Pb in the lavas is probably recycled from the crust, whereas less than some 40% of the Sr and Nd is recycled. The calc-alkaline chemical trends are solely a function of mixing with the sediment component.     

Evolution of abyssal lavas along propagating segments of the Galapagos spreading center

The unusual petrological diversity of abyssal lavas erupted along some segments of the Galapagos spreading center is a direct consequence of the propagation (elongation) of these segments into older oceanic crust. With increasing distance behind propagating rift tips, relatively unfractionated MORB erupted close to the tips are joined first by FeTi basalts (bimodal assemblage) and then by a wide range of basaltic and siliceous lavas. Further behind propagating rift tips, this broad range diminishes again, approaching the narrow compositional range of adjacent normal ridge segments.These compositional variations reflect the evolution of the subaxial magmatic system beneath the newly forming spreading center as it propagates through a pre-existing plate. We envisage this evolution as proceeding from small, isolated, ephemeral magma chambers through increasing numbers of larger, increasingly interconnected chambers to the steady-state buffered system of a normal ridge. Throughout this evolution, magma supply rates gradually increase and cooling rates of crustal magma bodies decrease. High degrees of crystal fractionation are favored only when a delicate balance between cooling rate and resupply rate of primitive magma is achieved.At other propagating and non-propagating ridge-transform intersections the degree to which the balance is achieved and the length of ridge over which it evolves control the distribution of fractionated lavas. These effects may be evaluated provided a number of tectonic variables including transform length, spreading and propagation rates are taken into account.     

Origin of the fumarolic fluids of Vulcano Island,Italy and implications for volcanic surveillance

Variations in D and ¹⁸O values with H₂O contents and outlet temperatures indicate that the fumaroles of La Fossa crater have discharged mixtures of magmatic water and marine hydrothermal water, since 1979. The contribution of meteoric water was low in the period 1979–1982 and very low afterwards. The ¹⁸O values of the marine-hydrothermal component of +5 to +7.2 are due to isotopic exchange with the ¹⁸O-rich silicates of the rocks under high-temperature and low-permeability conditions. The ¹⁸O value of the magmatic end-member is generally +3.5 to +4.3, although values as high as +5.5 to +6.5 were reached in the summer of 1988, when magma degassing appears to have extended into the core of the magma body. The D values of the end-member were close to -20, typical of andesitic waters. Both the isotopic values and chemical data strongly support a dry model, consisting of a central magmatic gas column and a surrounding hydrothermal envelope, in which marine hydrothermal brines move along limited fracture zones to undergo total evaporation on approaching the conduits of magmatic fluids. The vents at the eastern and western boundaries of the fumarolic field are fed by fluids whose pressure is governed by the coexistence of vapor, liquid and halite, giving rise to a high risk of phreato magmatic explosions, should magma penetrate into these wet environments. Most La Fossa eruptions were triggered by an initial hydrothermal blast and continued with a series of phreatomagmatic explosions. The fluids discharged by the Forgia Vecchia fumaroles are mixed with meteoric water, which is largely evaporated, although subordinate loss of condensed steam may be responsible for scrubbing most of the acidic gas species. The temperatures and pressures, and the risk of a sudden pressure increase, are low. A boiling hydrothermal aquifer at 230° C is present underneath the Baia di Levante beach. This area has a minor risk of hydrothermal explosions.     

Cross-correlation analysis of seismic and volcanic data at Mt Etna volcano,Italy

Seismic data from the MVT-SLN sesmic station located 7 km from the summit area of Mt Etna volcano, which has been operating steadily for the last two decades, have been analysed together with the volcanic activity during the same period. Cross-correlation techniques are used to investigate possible relationships between seismic and volcanic data and to evaluate the statistical significance of the results. A number of significant correlations have been identified, showing that there is an evident relation between seismic events and flank eruptions, and a less clear relation with summit activity, which appears more linked to tremor rather than to the low-frequency events. Particularly interesting are the low-frequency events whose rate of occurrence increases, starting from 17 to 108 days, prior to the onset of the flank activity and are candidates for a useful precursor. On the other hand, a tendency towards the increase in both the duration and the occurrence rate of transients in the volcanic tremor was observed before the onset of summit eruptions. As a result of this study different stages in the volcanic activity of Mt Etna, represented by changes in the characteristics of the recorded seismic phenomena, are identified.     

Origin of volcanic rocks from Stromboli (Italy)

Quaternary volcanic rocks of Stromboli (Italy) can be divided into older calc-alkaline and younger shoshonitic series. The SiO₂ contents of the rocks range from 50% to 61% but the majority of them are basalts. The rocks show systematic variations in chemical composition which correlate with the volcanic stratigraphy, such that, at a given SiO₂ content, K and other incompatible elements such as REE increase with decreasing age. In addition, the La/Yb ratio increases while the K/Rb, K/Ba, Zr/Ce and Zr/Nb ratios decrease towards the top of the volcanic pile. On the other hand, the abundances of transition elements, V, Co, Sc and Zn, like most major elements are broadly similar in comparable rocks of different ages. It is suggested that the parent magmas were derived by partial melting from upper mantle peridotite enriched in incompatible elements by fluids released from the descending oceanic lithosphere. The temporal chemical variations may probably be related to the lengths of time during which fluids were in contact with the upper mantle source.