Municipal Wastewater Treatment Using Moringa oleifera Seed and Press Cake Powder: A Comparative Analysis

Moringa oleifera (MO), also known as drumstick tree, has gained worldwide attention among researchers and policy makers, for showing its remarkable potential in environmental management. Recently, MO seed or press cake (a by-product of oil extraction industry) powder has also emerged as an alternative and promising coagulant for environmental remediation. In this view, attempts have been made in this study to evaluate the efficacy of MO seed and press cake powder (MSP & PCP) for the treatment of municipal wastewater. Both MSP and PCP are characterized by using swelling ratio, scanning and transmission electron microscopy analysis. The effect of various operational parameters such as coagulation–flocculation pH (2–10), coagulant dosage (0.1–1 g L⁻¹), and sedimentation time (0–180 min), etc., is investigated to understand the potential of MSP and PCP. At optimized operational conditions, sedimentation kinetics is also performed suggesting that the treatment process is being governed by the second-order kinetic model. The chemical and biological oxygen demand removals at optimized conditions are observed as follows: ≈38 and ≈73% for MSP and ≈47 and ≈85% for PCP. Overall, the results of the present study elucidated that PCP can be employed as a promising alternative of MSP for municipal wastewater with improved treatment efficiencies.     

Electrodialytic Defluoridation of Brackish Water: Effect of Process Parameters and Water Characteristics

The aim of this work is to study the removal of fluoride from brackish polluted water using electrodialysis. The influence of several parameters such as flow rate, initial feed concentration, co‐existing ions, and initial pH on process efficiency were studied. This efficiency is evaluated by the removal rate, demineralization rate, and power consumption. The defluoridation process showed to be independent of pH of feed solution. Although the remained studied parameters plays a significant role on the defluoridation efficiency and mainly on the specific power consumption. The defluoridation of a contaminated real water sample was investigated so as to improve the efficiency of the process. The fluoride concentration could be reduced from 2.9 to 0.4 mg L⁻¹ which was lower than World Health Organization (WHO) standard (1.5 mg L⁻¹). Moreover the concentrations of different species in the obtained treated water are below the amounts recommended by WHO for drinking water.     

Enhancement of Limestone Defluoridation of Water by Acetic and Citric Acids in Fixed Bed Reactor

Limestone defluoridation by fixed bed reactor has been studied with water pre‐acidified with edible organic acids, viz. acetic acid (AA) and citric acid (CA). The study has been carried out by varying acid concentration, contact time (t), number of repeated use of the same limestone bed (n), and chip size of the crushed limestone using fixed fluoride concentration of 10 mg/L in distilled water and groundwater amended to that concentration of fluoride. The presence of both the acids considerably improved the fluoride removal and the removal increased with increase in the acid concentration. Fluoride removal to less than 0.5 and 1.0 mg/L from initial 5 and 10 mg/L, respectively, have been achieved by the method on treatment with single reactor. The mechanism of fluoride removal in the process thought to be the increase in Ca²⁺ activity by dissolution of limestone, which precipitates as CaF₂. XPS analysis reveals that adsorption also contribute to the fluoride removal along with precipitation. The final pH of water remained within acceptable range for drinking water. Initial concentration of fluoride, effects the removal ability of the limestone particles only to some extent. The influence of other anions on fluoride removal process has a little influence which follows the order phosphate > sulfate > bromide > chloride > nitrate.     

Online Preconcentration and Determination of Trace Levels Cadmium in Water Samples Using Flow Injection Systems Coupled with Flame AAS

A rapid and sensitive method for the determination of trace levels cadmium in water samples by flame atomic absorption spectrometry was developed. It is based on the online sorption of Cd(II) ions on a microcolumn packed with HCl treated bamboo charcoal. In a pH range of 5.0–7.5, Cd(II) ions were effectively retained on the microcolumn, which exhibited fast kinetics, permitting the use of high sample flow rates up to at least 12.8 mL/min without the loss of retention efficiency. The retained Cd(II) ions were quantitatively eluted with HCl (2.0 mol/L) for an online determination. With a preconcentration time of 80 s at a sample loading flow rate of 8.6 mL/min, a sensitivity enhancement factor of 63 was obtained compared with the slope of the linear portion of the calibration curves before and after preconcentration. The calibration graph using the preconcentration system for cadmium was linear with a correlation coefficient of 0.9997, at levels from 1–40 ng/mL. The precision (RSD) for 11 replicate measurements were 3.2% for the determination of 5 ng/mL Cd(II) and 1.8% for 20 ng/mL Cd(II), respectively, and the detection limit (3s) was 0.36 ng/mL. The accuracy was assessed through the determination of a certified reference material, and also through recovery experiments.     

MODFLOW‐Based Coupled Surface Water Routing and Groundwater‐Flow Simulation

In this paper, we present a flexible approach for simulating one‐ and two‐dimensional routing of surface water using a numerical surface water routing (SWR) code implicitly coupled to the groundwater‐flow process in MODFLOW. Surface water routing in SWR can be simulated using a diffusive‐wave approximation of the Saint‐Venant equations and/or a simplified level‐pool approach. SWR can account for surface water flow controlled by backwater conditions caused by small water‐surface gradients or surface water control structures. A number of typical surface water control structures, such as culverts, weirs, and gates, can be represented, and it is possible to implement operational rules to manage surface water stages and streamflow. The nonlinear system of surface water flow equations formulated in SWR is solved by using Newton methods and direct or iterative solvers. SWR was tested by simulating the (1) Lal axisymmetric overland flow, (2) V‐catchment, and (3) modified Pinder‐Sauer problems. Simulated results for these problems compare well with other published results and indicate that SWR provides accurate results for surface water‐only and coupled surface water/groundwater problems. Results for an application of SWR and MODFLOW to the Snapper Creek area of Miami‐Dade County, Florida, USA are also presented and demonstrate the value of coupled surface water and groundwater simulation in managed, low‐relief coastal settings.     

Analyzing Effects of Shrub Canopy on Throughfall and Phreatic Water Using Water Isotopes,Western China

Alpine shrub Quercus aquifolioides was selected to study the effects of shrub canopy on throughfall and phreatic water by analyzing the isotopic time series of precipitation, canopy throughfall and phreatic water and examining correlations among these series in Wolong Nature Reserve, Western China. Based on analysis of precipitation data in 2003, the local meteoric water line during the rainy season was δD = 8.28 × δ¹⁸O + 8.93, and the primary precipitation moisture in this region originated from the Pacific Ocean in the summer. Stable isotope analysis showed that the main supply of throughfall and phreatic water was from precipitation, and the shrub canopy has an important effect on the processes of rainwater transmuted into throughfall and phreatic water. Moreover, the differences of δD and δ¹⁸O values between rainwater and throughfall were relevant to rainfall. Due to interception of the shrub canopy, there had a response hysteresis of phreatic water to the various rainfall events, which was mostly 2 days, except that this hysteresis was ≤1 day when rainfall was >15 mm/day.     

Using Sealed Wells to Measure Water Levels Beneath Streams and Floodplains

The design of wells beneath streams and floodplains has often employed with tall standpipes to prevent incursion of surface water into the well during flood events. Here, an approach has been presented to minimise the infrastructure demands in these environments by sealing the well top (e.g., prevent water entering the well) and monitor the total pressure in the water column using an absolute (non‐vented) pressure transducer. The sealed well design was tested using a laboratory experiment where the total pressure responses were monitored in both an unsealed and sealed well, while the water level was varied. It is observed that, whether the well is sealed or not, the total pressure at a given depth in the aquifer will be equal to that within the well. This indicates that the sealed well design is a viable alternative to tall standpipes and also facilitates installation of wells beneath streams and floodplains.     

Removal of Cadmium from Aqueous Solution Using Castor Seed Hull: A Kinetic and Equilibrium Study

The effects of various parameters such as initial concentration, adsorbent loading, pH, and contact time on kinetics and equilibrium of adsorption of Cd²⁺ metal ion from its aqueous solution by castor seed hull (CSH) and also by activated carbon have been investigated by batch adsorption experiments. The amount of adsorption increases with initial metal ion concentration, contact time, solution pH, and the loading of adsorbent for both the systems. Kinetic experiments indicate that adsorption of cadmium metal ion on both CSH and on activated carbon consists of three steps – a rapid adsorption of cadmium metal ion, a transition phase, and an almost flat plateau region. This has also been confirmed by the intraparticle diffusion model. The lumped kinetic results show that the cadmium adsorption process follows a pseudo‐second order rate law. The kinetic parameters including the rate constant are determined at different initial metal ion concentrations, pH, amount, and type of adsorbent, respectively. The Langmuir and Freundlich adsorption isotherm models are used to describe the experimental data. The Langmuir model yields a better correlation coefficient than the other model. A comparison of the monolayer adsorption capacity (q_m) of CSH, activated carbon, and several other reported adsorbents has been provided. The value of separation factor (R_L) calculated from the Langmuir equation also gives an indication of favorable adsorption of the metal ion. From comparative studies, it has been found that CSH is a potentially attractive adsorbent than commercial activated carbon for cadmium metal ion (Cd²⁺) removal.     

Using Tracers to Quantify Drilling Water Influence and Obtain Representative Groundwater Samples

This paper describes a practical field method of using applied tracers to determine how much purging is required to collect representative groundwater samples after the introduction of drilling water during borehole advancement. In general, the approach involves adding a tracer of known concentration to the drilling water and then measuring the tracer in the purge water until the tracer concentration declines to a defined target level. If necessary, the dilution effects of residual drilling water can be quantified, and the measured contaminant concentration can be corrected based on the measured tracer concentration. A project example is presented to demonstrate that this method is straightforward and reliable and that applied tracers can be used to quantify the influence of residual drilling water on formation water quality while also ensuring that purge times and volumes are not unnecessarily large.     

Using Alternate Pumping and Cooperative Game Theory to Reduce Sea Water Intrusion

In this article, alternate pumping is studied as a means used to reduce the salinity concentration in coastal aquifers, pumped using a system of wells. This approach has been applied to a hypothetical confined coastal aquifer. Flow has been modeled, using SEAWAT. Two strategies are proposed based on cooperative game theory, to promote alternate pumping. In both strategies an external player will compensate the users that will pump during an unpopular pumping period. In the first strategy it is supposed that this external player aims at protecting a critical well, e.g. a municipal well, reducing its maximum salinity concentration by pumping alternately. In the second strategy proposed, the target is to reduce the overall salinity of the water pumped by the wells. In applying the cooperative game theory, the Shapley value is used to distribute the benefits of cooperation between the players (well users), according to their marginal contribution. Overall, well users can reduce sea water intrusion by cooperatively changing their pumping time schedules. The game theoretical model developed is a useful tool to promote cooperation toward this direction. The methods applied in the hypothetical aquifer, can be tested in actual aquifers to reduce sea water intrusion.     

Ground Water Remediation Using an Extraction, Treatment, and Recharge System

Ground water remediation of volatile organic compound (VOC) contamination at a site in Michigan was initiated as a result of a consent agreement between the Michigan Department of Natural Resources (MDNR) and the responsible party. Under the direction of the MDNR, the responsible party conducted a remedial investigation/feasibility study using federal guidelines to define the extent of contamination at the site and to select a response action for site remediation. The selected alternative included a combination of ground water extraction, treatment, and recharge, and soil flushing. The extraction system withdraws ground water from various depths in heavily contaminated areas. The ground water is treated using an air stripper. A spray distribution system spreads effluent from the stripper over a recharge basin constructed over the most contaminated areas. Additional contaminant removal is achieved by volatilization from the spray and percolation through the gravel bed. Recharge water moves downward through the contaminated soils, thus flushing residual soil contaminants. The initial operating data demonstrated that the system can effectively remove trichloroethylene (TCE) from ground water (approximately 95 percent overall removal efficiency). The annualized capital and operation and maintenance (O & M) costs of the remedial action were estimated for several operating periods (15, 20, and 30 years).     

Design and Optimization of a Ground Water Monitoring System Using GIS and Multicriteria Decision Analysis

A GIS-based methodology has been developed to design a ground water monitoring system and implemented for a selected area in Mae-Klong River Basin, Thailand. A multicriteria decision-making analysis has been performed to optimize the network system based on major criteria which govern the monitoring network design such as minimization of cost of construction, reduction of kriging standard deviations, etc. The methodology developed in this study is a new approach to designing monitoring networks which can be used for any site considering site-specific aspects. It makes it possible to choose the best monitoring network from various alternatives based on the prioritization of decision factors.     

Illuminating Subsurface Microbial Water Quality Patterns Using Adenosine Triphosphate and Dynamic Time Warping Approaches

Aquifer microbial water quality evaluations are often performed by collecting groundwater samples from monitoring wells. While samples collected from continuously pumped sources are seldom disputed as representative of the aquifer, natural biofilm present in the vicinity of well screens may introduce unwanted microbial artefacts in monitoring wells that are only periodically sampled. The need for well water purging to obtain samples void of these artefacts has been widely recognized. However, purging methods are not standardized; many approaches presume that physico-chemical water quality stability achieved through the removal of 3 to 5 well volumes is indicative of the stability of target analytes. Using a data set collected from a shallow unconfined aquifer in Southern Ontario, Canada, the need for using dedicated approaches that account for the time-dependent nature of microbial water quality changes was demonstrated. Specifically, the utility of adenosine triphosphate (ATP) as a rapid, field-ready biochemical indicator of microbial water quality stability was investigated. This work shows that ATP concentrations reflect time-limited (bio)colloid transport processes that are consistent with other microbial water quality parameters monitored, but different from commonly measured physical and chemical water quality indicators of well purging adequacy. ATP concentrations occasionally fluctuated even after 3 or 4 h of purging, indicating that microbial artefacts attributable to biofilms in the vicinity of the well screen can still persist. The recurrence of characteristic ATP patterns in each well was systematically examined through the novel application of dynamic time warping (DTW), a nonparametric time series analysis approach. These patterns are believed to be linked with seasonal hydrogeological conditions, which warrant consideration in the design and interpretation of subsurface microbial water quality investigations.     

An Integrated Ground Water Monitoring Program Using Multilevel Gas-Driven Samplers and Conventional Monitoring Wells

Hydrogeologic and ground water quality data obtained from a gas-driven multilevel sampler system and a polyvinyl chloride (PVC) monitoring well nest with the same aquifer communication intervals are compared. All monitoring points are in close proximity to each other. The study was conducted at an eight-acre uncontrolled hazardous waste site. The site is located in an alluvial valley composed of approximately 40 feet of alluvium overlying shale bedrock. The ground water at the site is contaminated with various organic constituents. A ground water monitoring network consisting of 26 conventional monitoring wells, nine observation well points, and six multilevel gas-driven samplers was established to characterize the hydrogeologic regime and define the vertical and horizontal extent of contamination in the vicinity of the abandoned chemical plant. As part of this study, a multilevel monitoring system was installed adjacent to a well nest. The communication zones of the multilevel samplers were placed at the same elevation as the sand packs of the well nest. The multilevel sampler system and well nest are located in a contaminated area directly downgradient of the site. A comparison of the vertical head distribution and ground water quality was performed between the well nest and the multilevel sampling system. The gas-driven multilevel sampling system consists of three gas-driven samplers that monitor separate intervals in the unconsolidated materials. The well nest, composed of two PVC monitoring wells in separate boreholes, has the same communication interval as the other two gas-driven samplers. Hydraulic head information for each multilevel sampler was obtained using capillary tubing. This was compared with heads obtained from the well nest utilizing an electric water level indicator. Chemical analyses from the PVC and multilevel sampler wells were performed and compared with one another. The analyses included organic acids, base neutrals, pesticides, PCBs, metals, volatile organics, TOX, TOC, CN, pH and specific conductance.